CN110511653A - Stone surface inorganic agent and preparation method thereof and method for treatment of surface of stone - Google Patents
Stone surface inorganic agent and preparation method thereof and method for treatment of surface of stone Download PDFInfo
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- CN110511653A CN110511653A CN201910727078.6A CN201910727078A CN110511653A CN 110511653 A CN110511653 A CN 110511653A CN 201910727078 A CN201910727078 A CN 201910727078A CN 110511653 A CN110511653 A CN 110511653A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
- C09D163/10—Epoxy resins modified by unsaturated compounds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/24—Electrically-conducting paints
Abstract
The invention discloses stone surface inorganic agents, be made of two kinds of components: component A and B component form, and the component A and B component respectively include the raw material of following parts by weight: component A: at least can carry out the modification acrylate light-cured resin 5-80 of cationic polymerization containing one kind and can carry out the photo-curing monomer 5-80 of radical photopolymerization；B component: radical initiator and cationic initiator mixture 0.1-20 and diluent 0-20；By smearing the inorganic agent to stone material, original polishing treatment is not used, environmental issue can effectively be avoided, it is not in that stone material processing generates a large amount of dust in polishing operation, and water mill expends a large amount of water again and needs to consume many electricity, the problem of vast resources will be saved removing polishing operation from, and prevent the discharge of waste water and dregs.
Description
Technical field
The invention belongs to stone processing technical field more particularly to stone surface inorganic agent and preparation method thereof, Yi Jishi
The processing method on material surface.
Background technique
Due to the improvement of people's living standards, to the decoration of living environment, also gradually concern is got up, then various buildings
Inner-outer wall, ground and table top have largely used the materials such as granite, marble, artificial stone and polished bricks, microlite.Due to these
There is high photosensitiveness after material processing, so that whole building seems steady, elegant, clean.
Existing method for treatment of surface of stone is typically all to use surface polishing treatment, and environmental issue is increasingly serious now,
Stone material processing generates a large amount of dust in polishing operation, and water mill expends a large amount of water again and needs to consume many electricity, In
Vast resources will be saved by removing polishing operation from, and prevent the discharge of waste water and dregs.
Summary of the invention
The present invention provides stone surface inorganic agent and preparation method thereof, it is intended to solve existing method for treatment of surface of stone one
As be all using surface polishing treatment, environmental issue is increasingly serious now, and stone material processing generates a large amount of dust in polishing operation,
And water mill expends a large amount of water again and needs to consume many electricity, will save vast resources, and Du removing polishing operation from
The problem of discharge of exhausted waste water and dregs.
The present invention relates to stone surface inorganic agents, and be made of two kinds of components: component A and B component form, the component A and B
Component respectively includes the raw material of following parts by weight: component A: the modification acrylate light of cationic polymerization can be at least carried out containing one kind
The solidified resin 5-80 and photo-curing monomer 5-80 that radical photopolymerization can be carried out；B component: radical initiator and cation draw
Send out agent composition 0.1~20 and diluent 0-20.
It preferably, also include parts by weight in component A or B component is 0~10 auxiliary agent.
Preferably, the modification acrylate light-cured resin of cationic polymerization can at least be carried out by modified epoxy tree containing one kind
The one or more of lipid acrylate and modified vinyl ethers methacrylate.
Preferably, light-cured resin in component A further include: modified epoxy class acrylic resin, epoxy organosilicon methyl-prop
The epoxy acrylic that olefin(e) acid ester, propoxylated glycerol triacrylate, the epoxy acrylate of SR306 mixing, SR238 are mixed
Ester, epoxidised soybean oil acrylate, the epoxy acrylate of SR351 mixing, the epoxy acrylate of SR306 mixing, benzene second
One or more of the epoxy acrylate of alkene mixing.
Preferably, modified vinyl ethers acrylate is by hydroxy butyl vinyl ether acrylate and tirethylene glycol diethyl
One or more of alkene ether acrylate composition.
Preferably, photo-curing monomer further includes methyl-propen acid alkyl ester, methyl-acrylic acid alkenyl esters and first in component A
Base-acrylic acid heterocycle base ester one or more of methyl-acrylic acid ester monomer.
Preferably, free radical photo-initiation is selected from benzoin ethyl ether, benzoin isopropyl ether, alkylbenzene ketone, acyl group phosphorus oxygen
This in compound, bis(benzoylphenyl) phosphine oxide, benzophenone and acylphosphanes peroxide is a kind of or its any one
Combination；Cationic photopolymerization initiator is selected from aromatic diazonium salt, aromatic series sulfosalt, aromatic iodonium salts, alkyl sulfide
One of the luxuriant iron of salt, virtue, luxuriant titanium, sulfonyl oxygen ketone and triaryl siloxanes ether or their any combination.
Preferably, diluent is alcohol ethers solvent, in esters solvent, ketones solvent, aromatic solvent, petroleum series solvent
One or more of mixing；The auxiliary agent is one or more of levelling agent, defoaming agent, polymerization inhibitor, antistatic agent.
The invention further relates to a kind of preparation methods of stone surface inorganic agent, include the following steps:
Step 1: light-cured resin and photo polymerization monomer is uniform, form mixture；
Step 2: step is added in radical initiator and cationic initiator mixture, diluent and auxiliary agent
Mixture in one.
Step 3: mixture middling speed is dispersed 2 hours in step 2, and filtering obtains inorganic agent.
The invention further relates to a kind of method for treatment of surface of stone, stone surface inorganic agent are coated on the surface of stone material.
Compared with prior art, the beneficial effects of the present invention are: the present invention provide a kind of stone surface inorganic agent and its
Preparation method does not use original polishing treatment, can effectively avoid environmental issue by smearing the inorganic agent to stone material,
It is not in that stone material processing generates a large amount of dust in polishing operation, and water mill expends a large amount of water again and needs to consume very
It is mostly electric, the problem of vast resources will be saved removing polishing operation from, and prevent the discharge of waste water and dregs；What is made simultaneously is double solid
The inorganic agent for changing the polymerizable components of (free radical-cationic hybrid solidifies) can while keeping UV rapid curing advantage
Overcome because of the insufficient bring defect of quick-setting internal curing, to improve the overall performance of final products.
Specific embodiment
In order to make the objectives, technical solutions, and advantages of the present invention clearer, with reference to embodiments, to the present invention
It is further elaborated.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, it is not used to
Limit the present invention.
Embodiment 1
Stone surface inorganic agent, be made of two kinds of components: component A and B component form, component A and B component respectively include with
The raw material of lower parts by weight: component A: at least containing one kind can carry out cationic polymerization modification acrylate light-cured resin 5-80 and
It can carry out the photo-curing monomer 5-80 of radical photopolymerization；B component: radical initiator and cationic initiator mixture 0.1
~20 and diluent 0-20.
Also include in component A or B component parts by weight be 0~10 auxiliary agent.
At least the modification acrylate light-cured resin of cationic polymerization can be carried out by modified epoxy class third containing one kind
The one or more of olefin(e) acid ester and modified vinyl ethers methacrylate.
Light-cured resin in component A further include: modified epoxy class acrylic resin, epoxy organosilicon methacrylate,
Epoxy acrylate, the epoxidation that propoxylated glycerol triacrylate, the epoxy acrylate of SR306 mixing, SR238 are mixed
Soybean oil acrylate, the epoxy acrylate of SR351 mixing, the epoxy acrylate of SR306 mixing, styrene mix
One or more of epoxy acrylate.
Modified vinyl ethers acrylate is by hydroxy butyl vinyl ether acrylate and tirethylene glycol divinyl ether
One or more of acrylate composition.
Photo-curing monomer further includes methyl-propen acid alkyl ester, methyl-acrylic acid alkenyl esters and methyl-the third in component A
One or more of the methyl-acrylic acid ester monomer of olefin(e) acid heterocycle base ester.
Free radical photo-initiation is selected from benzoin ethyl ether, benzoin isopropyl ether, alkylbenzene ketone, acyl group phosphorous oxides, double
This kind of or its any one combination in benzoylphenyl phosphine oxide, benzophenone and acylphosphanes peroxide；Sun
Ion Photoepolymerizationinitiater initiater is selected from aromatic diazonium salt, aromatic series sulfosalt, aromatic iodonium salts, alkyl sulfosalt, Fang Mao
One of iron, luxuriant titanium, sulfonyl oxygen ketone and triaryl siloxanes ether or their any combination
Diluent be one of alcohol ethers solvent, esters solvent, ketones solvent, aromatic solvent, petroleum series solvent or
Several mixing；The auxiliary agent is one or more of levelling agent, defoaming agent, polymerization inhibitor, antistatic agent；The diluent is
Refractive index is greater than 1.5 high boiling solvent, and still more preferably refractive index is higher than 1.53 high boiling solvent, high refractive index solvent
For the solvent containing benzene ring structure, the high refractive index solvent is the aromatic solvents such as toluene, dimethylbenzene, durene, methyl phenyl ethers anisole,
Diphenyl ether, ethylene glycol phenyl ether, propylene glycol phenylate, diethylene glycol dibenzoate, dipropylene glycol dibenzoate, benzoic acid first
The one or more containing benzene ring structure solvent such as ester, ethyl benzoate, n-butylbenzoate, benzyl acetate.
Optional addition antistatic agent makes it have antistatic effect in polymerisable compound, and then improves operation
Yield；Can be used in antistatic agent of the invention is that the technical staff institute with usual knowledge is ripe in the technical field of the invention
Know, is such as, but not limited to ethyoxyl glycerine fatty acid esters, level Four amine compounds, fatty amines derivative.Epoxy resin
(such as polycyclic oxygen second hydrocarbon), silicon oxygen hydrocarbon or other alcohol derivatives
A kind of preparation method of stone surface inorganic agent, characterized by the following steps:
Step 2: step is added in radical initiator and cationic initiator mixture, diluent and auxiliary agent
Mixture in one.
Step 3: mixture middling speed is dispersed 2 hours in step 2, and filtering obtains inorganic agent.
Stone surface inorganic agent is coated on the surface of stone material by a kind of method for treatment of surface of stone.
Embodiment 2
Stone surface inorganic agent, be made of two kinds of components: component A and B component form, component A and B component respectively include with
The raw material of lower parts by weight: component A: at least containing one kind can carry out cationic polymerization modification acrylate light-cured resin 30 and can
Carry out the photo-curing monomer 35 of radical photopolymerization；B component: radical initiator and cationic initiator mixture 8 and dilution
Agent 6.
Also include in component A or B component parts by weight be 2 auxiliary agents.
At least the modification acrylate light-cured resin of cationic polymerization can be carried out by modified epoxy class third containing one kind
The one or more of olefin(e) acid ester and modified vinyl ethers methacrylate.
Light-cured resin in component A further include: modified epoxy class acrylic resin, epoxy organosilicon methacrylate,
Epoxy acrylate, the epoxidation that propoxylated glycerol triacrylate, the epoxy acrylate of SR306 mixing, SR238 are mixed
Soybean oil acrylate, the epoxy acrylate of SR351 mixing, the epoxy acrylate of SR306 mixing, styrene mix
One or more of epoxy acrylate.
Modified vinyl ethers acrylate is by hydroxy butyl vinyl ether acrylate and tirethylene glycol divinyl ether
One or more of acrylate composition.
Photo-curing monomer further includes methyl-propen acid alkyl ester, methyl-acrylic acid alkenyl esters and methyl-the third in component A
One or more of the methyl-acrylic acid ester monomer of olefin(e) acid heterocycle base ester.
Free radical photo-initiation is selected from benzoin ethyl ether, benzoin isopropyl ether, alkylbenzene ketone, acyl group phosphorous oxides, double
This kind of or its any one combination in benzoylphenyl phosphine oxide, benzophenone and acylphosphanes peroxide；Sun
Ion Photoepolymerizationinitiater initiater is selected from aromatic diazonium salt, aromatic series sulfosalt, aromatic iodonium salts, alkyl sulfosalt, Fang Mao
One of iron, luxuriant titanium, sulfonyl oxygen ketone and triaryl siloxanes ether or their any combination
Diluent is the high boiling solvent that refractive index is greater than 1.5, and still more preferably refractive index is high boiling higher than 1.53
Point solvent, high refractive index solvent are the solvent containing benzene ring structure, and the high refractive index solvent is toluene, dimethylbenzene, durene
Equal aromatic solvents, methyl phenyl ethers anisole, diphenyl ether, ethylene glycol phenyl ether, propylene glycol phenylate, diethylene glycol dibenzoate, dipropylene glycol
Dibenzoate, methyl benzoate, ethyl benzoate, n-butylbenzoate, benzyl acetate etc. containing benzene ring structure solvent one
Kind is several；The auxiliary agent is one or more of levelling agent, defoaming agent, polymerization inhibitor, antistatic agent；
Optional addition antistatic agent makes it have antistatic effect in polymerisable compound, and then improves operation
Yield；Can be used in antistatic agent of the invention is that the technical staff institute with usual knowledge is ripe in the technical field of the invention
Know, is such as, but not limited to ethyoxyl glycerine fatty acid esters, level Four amine compounds, fatty amines derivative.Epoxy resin
(such as polycyclic oxygen second hydrocarbon), silicon oxygen hydrocarbon or other alcohol derivatives
A kind of preparation method of stone surface inorganic agent, characterized by the following steps:
Step 2: step is added in radical initiator and cationic initiator mixture, diluent and auxiliary agent
Mixture in one.
Step 3: mixture middling speed is dispersed 2 hours in step 2, and filtering obtains inorganic agent.
Embodiment 3
Stone surface inorganic agent, be made of two kinds of components: component A and B component form, component A and B component respectively include with
The raw material of lower parts by weight: component A: at least containing one kind can carry out cationic polymerization modification acrylate light-cured resin 30 and can
Carry out the photo-curing monomer 35 of radical photopolymerization；B component: radical initiator and cationic initiator mixture 8 and dilution
Agent 6.
Also include in component A or B component parts by weight be 2 auxiliary agents.
At least the modification acrylate light-cured resin of cationic polymerization can be carried out by modified epoxy class third containing one kind
The one or more of olefin(e) acid ester and modified vinyl ethers methacrylate.
Light-cured resin in component A further include: modified epoxy class acrylic resin, epoxy organosilicon methacrylate,
Epoxy acrylate, the epoxidation that propoxylated glycerol triacrylate, the epoxy acrylate of SR306 mixing, SR238 are mixed
Soybean oil acrylate, the epoxy acrylate of SR351 mixing, the epoxy acrylate of SR306 mixing, styrene mix
One or more of epoxy acrylate.
Modified vinyl ethers acrylate is by hydroxy butyl vinyl ether acrylate and tirethylene glycol divinyl ether
One or more of acrylate composition.
Photo-curing monomer further includes methyl-propen acid alkyl ester, methyl-acrylic acid alkenyl esters and methyl-the third in component A
One or more of the methyl-acrylic acid ester monomer of olefin(e) acid heterocycle base ester.
Free radical photo-initiation is selected from benzoin ethyl ether, benzoin isopropyl ether, alkylbenzene ketone, acyl group phosphorous oxides, double
This kind of or its any one combination in benzoylphenyl phosphine oxide, benzophenone and acylphosphanes peroxide；Sun
Ion Photoepolymerizationinitiater initiater is selected from aromatic diazonium salt, aromatic series sulfosalt, aromatic iodonium salts, alkyl sulfosalt, Fang Mao
One of iron, luxuriant titanium, sulfonyl oxygen ketone and triaryl siloxanes ether or their any combination
Diluent is alcohol ethers solvent (solvent without containing benzene ring structure), esters solvent (without containing the molten of benzene ring structure
Agent), the mixing of one or more of petroleum series solvent；The auxiliary agent is levelling agent, in defoaming agent, polymerization inhibitor, antistatic agent
One or more；
Optional addition antistatic agent makes it have antistatic effect in polymerisable compound, and then improves operation
Yield；Can be used in antistatic agent of the invention is that the technical staff institute with usual knowledge is ripe in the technical field of the invention
Know, is such as, but not limited to ethyoxyl glycerine fatty acid esters, level Four amine compounds, fatty amines derivative.Epoxy resin
(such as polycyclic oxygen second hydrocarbon), silicon oxygen hydrocarbon or other alcohol derivatives
A kind of preparation method of stone surface inorganic agent, characterized by the following steps:
Step 2: step is added in radical initiator and cationic initiator mixture, diluent and auxiliary agent
Mixture in one.
Step 3: mixture middling speed is dispersed 2 hours in step 2, and filtering obtains inorganic agent.
Comparative example 2 is high for studying refractive index in inorganic agent of the invention for being compared with embodiment 3
In 1.5 or more influence of the photo polymerization monomer to composition comprehensive performance.The coating that comparative example 2 provides
Composition, the corresponding raw material components of each composition and parts by weight are as shown in the Examples；By corresponding original
Expect that component is mixed by its parts by weight, middling speed is dispersed 2 hours, is filtered to get corresponding coating composition.
Embodiment 4
Stone surface inorganic agent, be made of two kinds of components: component A and B component form, component A and B component respectively include with
The raw material of lower parts by weight: component A: at least containing one kind can carry out cationic polymerization modification acrylate light-cured resin 5 and can
Carry out the photo-curing monomer 5 of radical photopolymerization；B component: radical initiator and cationic initiator mixture 0.1 and dilution
Agent 0.
Also include in component A or B component parts by weight be 0 auxiliary agent.
At least the modification acrylate light-cured resin of cationic polymerization can be carried out by modified epoxy class third containing one kind
The one or more of olefin(e) acid ester and modified vinyl ethers methacrylate.
Light-cured resin in component A further include: modified epoxy class acrylic resin, epoxy organosilicon methacrylate,
Epoxy acrylate, the epoxidation that propoxylated glycerol triacrylate, the epoxy acrylate of SR306 mixing, SR238 are mixed
Soybean oil acrylate, the epoxy acrylate of SR351 mixing, the epoxy acrylate of SR306 mixing, styrene mix
One or more of epoxy acrylate.
Modified vinyl ethers acrylate is by hydroxy butyl vinyl ether acrylate and tirethylene glycol divinyl ether
One or more of acrylate composition.
Photo-curing monomer further includes methyl-propen acid alkyl ester, methyl-acrylic acid alkenyl esters and methyl-the third in component A
One or more of the methyl-acrylic acid ester monomer of olefin(e) acid heterocycle base ester.
Free radical photo-initiation is selected from benzoin ethyl ether, benzoin isopropyl ether, alkylbenzene ketone, acyl group phosphorous oxides, double
This kind of or its any one combination in benzoylphenyl phosphine oxide, benzophenone and acylphosphanes peroxide；Sun
Ion Photoepolymerizationinitiater initiater is selected from aromatic diazonium salt, aromatic series sulfosalt, aromatic iodonium salts, alkyl sulfosalt, Fang Mao
One of iron, luxuriant titanium, sulfonyl oxygen ketone and triaryl siloxanes ether or their any combination
Diluent be one of alcohol ethers solvent, esters solvent, ketones solvent, aromatic solvent, petroleum series solvent or
Several mixing；The auxiliary agent is one or more of levelling agent, defoaming agent, polymerization inhibitor, antistatic agent；The diluent is
Refractive index is greater than 1.5 high boiling solvent, and still more preferably refractive index is higher than 1.53 high boiling solvent, high refractive index solvent
For the solvent containing benzene ring structure, the high refractive index solvent is the aromatic solvents such as toluene, dimethylbenzene, durene, methyl phenyl ethers anisole,
Diphenyl ether, ethylene glycol phenyl ether, propylene glycol phenylate, diethylene glycol dibenzoate, dipropylene glycol dibenzoate, benzoic acid first
The one or more containing benzene ring structure solvent such as ester, ethyl benzoate, n-butylbenzoate, benzyl acetate.
Optional addition antistatic agent makes it have antistatic effect in polymerisable compound, and then improves operation
Yield；Can be used in antistatic agent of the invention is that the technical staff institute with usual knowledge is ripe in the technical field of the invention
Know, is such as, but not limited to ethyoxyl glycerine fatty acid esters, level Four amine compounds, fatty amines derivative.Epoxy resin
(such as polycyclic oxygen second hydrocarbon), silicon oxygen hydrocarbon or other alcohol derivatives
A kind of preparation method of stone surface inorganic agent, characterized by the following steps:
Step 2: step is added in radical initiator and cationic initiator mixture, diluent and auxiliary agent
Mixture in one.
Step 3: mixture middling speed is dispersed 2 hours in step 2, and filtering obtains inorganic agent.
Embodiment 5
Stone surface inorganic agent, be made of two kinds of components: component A and B component form, component A and B component respectively include with
The raw material of lower parts by weight: component A: at least containing one kind can carry out cationic polymerization modification acrylate light-cured resin 80 and can
Carry out the photo-curing monomer 80 of radical photopolymerization；B component: radical initiator and cationic initiator mixture 20 and dilution
Agent 20.
Also include in component A or B component parts by weight be 10 auxiliary agents.
At least the modification acrylate light-cured resin of cationic polymerization can be carried out by modified epoxy class third containing one kind
The one or more of olefin(e) acid ester and modified vinyl ethers methacrylate.
Light-cured resin in component A further include: modified epoxy class acrylic resin, epoxy organosilicon methacrylate,
Epoxy acrylate, the epoxidation that propoxylated glycerol triacrylate, the epoxy acrylate of SR306 mixing, SR238 are mixed
Soybean oil acrylate, the epoxy acrylate of SR351 mixing, the epoxy acrylate of SR306 mixing, styrene mix
One or more of epoxy acrylate.
Modified vinyl ethers acrylate is by hydroxy butyl vinyl ether acrylate and tirethylene glycol divinyl ether
One or more of acrylate composition.
Photo-curing monomer further includes methyl-propen acid alkyl ester, methyl-acrylic acid alkenyl esters and methyl-the third in component A
One or more of the methyl-acrylic acid ester monomer of olefin(e) acid heterocycle base ester.
Free radical photo-initiation is selected from benzoin ethyl ether, benzoin isopropyl ether, alkylbenzene ketone, acyl group phosphorous oxides, double
This kind of or its any one combination in benzoylphenyl phosphine oxide, benzophenone and acylphosphanes peroxide；Sun
Ion Photoepolymerizationinitiater initiater is selected from aromatic diazonium salt, aromatic series sulfosalt, aromatic iodonium salts, alkyl sulfosalt, Fang Mao
One of iron, luxuriant titanium, sulfonyl oxygen ketone and triaryl siloxanes ether or their any combination
Diluent be one of alcohol ethers solvent, esters solvent, ketones solvent, aromatic solvent, petroleum series solvent or
Several mixing；The auxiliary agent is one or more of levelling agent, defoaming agent, polymerization inhibitor, antistatic agent；The diluent is
Refractive index is greater than 1.5 high boiling solvent, and still more preferably refractive index is higher than 1.53 high boiling solvent, high refractive index solvent
For the solvent containing benzene ring structure, the high refractive index solvent is the aromatic solvents such as toluene, dimethylbenzene, durene, methyl phenyl ethers anisole,
Diphenyl ether, ethylene glycol phenyl ether, propylene glycol phenylate, diethylene glycol dibenzoate, dipropylene glycol dibenzoate, benzoic acid first
The one or more containing benzene ring structure solvent such as ester, ethyl benzoate, n-butylbenzoate, benzyl acetate.
Optional addition antistatic agent makes it have antistatic effect in polymerisable compound, and then improves operation
Yield；Can be used in antistatic agent of the invention is that the technical staff institute with usual knowledge is ripe in the technical field of the invention
Know, is such as, but not limited to ethyoxyl glycerine fatty acid esters, level Four amine compounds, fatty amines derivative.Epoxy resin
(such as polycyclic oxygen second hydrocarbon), silicon oxygen hydrocarbon or other alcohol derivatives
A kind of preparation method of stone surface inorganic agent, characterized by the following steps:
Step 2: step is added in radical initiator and cationic initiator mixture, diluent and auxiliary agent
Mixture in one.
Step 3: mixture middling speed is dispersed 2 hours in step 2, and filtering obtains inorganic agent.
Embodiment 6
Stone surface inorganic agent, be made of two kinds of components: component A and B component form, component A and B component respectively include with
The raw material of lower parts by weight: component A: at least containing one kind can carry out cationic polymerization modification acrylate light-cured resin 10 and can
Carry out the photo-curing monomer 10 of radical photopolymerization；B component: radical initiator and cationic initiator mixture 1 and dilution
Agent 1.
Also include in component A or B component parts by weight be 1 auxiliary agent.
At least the modification acrylate light-cured resin of cationic polymerization can be carried out by modified epoxy class third containing one kind
The one or more of olefin(e) acid ester and modified vinyl ethers methacrylate.
Light-cured resin in component A further include: modified epoxy class acrylic resin, epoxy organosilicon methacrylate,
Epoxy acrylate, the epoxidation that propoxylated glycerol triacrylate, the epoxy acrylate of SR306 mixing, SR238 are mixed
Soybean oil acrylate, the epoxy acrylate of SR351 mixing, the epoxy acrylate of SR306 mixing, styrene mix
One or more of epoxy acrylate.
Modified vinyl ethers acrylate is by hydroxy butyl vinyl ether acrylate and tirethylene glycol divinyl ether
One or more of acrylate composition.
Photo-curing monomer further includes methyl-propen acid alkyl ester, methyl-acrylic acid alkenyl esters and methyl-the third in component A
One or more of the methyl-acrylic acid ester monomer of olefin(e) acid heterocycle base ester.
Free radical photo-initiation is selected from benzoin ethyl ether, benzoin isopropyl ether, alkylbenzene ketone, acyl group phosphorous oxides, double
This kind of or its any one combination in benzoylphenyl phosphine oxide, benzophenone and acylphosphanes peroxide；Sun
Ion Photoepolymerizationinitiater initiater is selected from aromatic diazonium salt, aromatic series sulfosalt, aromatic iodonium salts, alkyl sulfosalt, Fang Mao
One of iron, luxuriant titanium, sulfonyl oxygen ketone and triaryl siloxanes ether or their any combination
Diluent be one of alcohol ethers solvent, esters solvent, ketones solvent, aromatic solvent, petroleum series solvent or
Several mixing；The auxiliary agent is one or more of levelling agent, defoaming agent, polymerization inhibitor, antistatic agent；The diluent is
Refractive index is greater than 1.5 high boiling solvent, and still more preferably refractive index is higher than 1.53 high boiling solvent, high refractive index solvent
For the solvent containing benzene ring structure, the high refractive index solvent is the aromatic solvents such as toluene, dimethylbenzene, durene, methyl phenyl ethers anisole,
Diphenyl ether, ethylene glycol phenyl ether, propylene glycol phenylate, diethylene glycol dibenzoate, dipropylene glycol dibenzoate, benzoic acid first
The one or more containing benzene ring structure solvent such as ester, ethyl benzoate, n-butylbenzoate, benzyl acetate.
Optional addition antistatic agent makes it have antistatic effect in polymerisable compound, and then improves operation
Yield；Can be used in antistatic agent of the invention is that the technical staff institute with usual knowledge is ripe in the technical field of the invention
Know, is such as, but not limited to ethyoxyl glycerine fatty acid esters, level Four amine compounds, fatty amines derivative.Epoxy resin
(such as polycyclic oxygen second hydrocarbon), silicon oxygen hydrocarbon or other alcohol derivatives
A kind of preparation method of stone surface inorganic agent, characterized by the following steps:
Step 2: step is added in radical initiator and cationic initiator mixture, diluent and auxiliary agent
Mixture in one.
Step 3: mixture middling speed is dispersed 2 hours in step 2, and filtering obtains inorganic agent.
Embodiment 6
Stone surface inorganic agent, be made of two kinds of components: component A and B component form, component A and B component respectively include with
The raw material of lower parts by weight: component A: at least containing one kind can carry out cationic polymerization modification acrylate light-cured resin 60 and can
Carry out the photo-curing monomer 60 of radical photopolymerization；B component: radical initiator and cationic initiator mixture 10 and dilution
Agent 10.
Also include in component A or B component parts by weight be 5 auxiliary agents.
At least the modification acrylate light-cured resin of cationic polymerization can be carried out by modified epoxy class third containing one kind
The one or more of olefin(e) acid ester and modified vinyl ethers methacrylate.
Light-cured resin in component A further include: modified epoxy class acrylic resin, epoxy organosilicon methacrylate,
Epoxy acrylate, the epoxidation that propoxylated glycerol triacrylate, the epoxy acrylate of SR306 mixing, SR238 are mixed
Soybean oil acrylate, the epoxy acrylate of SR351 mixing, the epoxy acrylate of SR306 mixing, styrene mix
One or more of epoxy acrylate.
Modified vinyl ethers acrylate is by hydroxy butyl vinyl ether acrylate and tirethylene glycol divinyl ether
One or more of acrylate composition.
Photo-curing monomer further includes methyl-propen acid alkyl ester, methyl-acrylic acid alkenyl esters and methyl-the third in component A
One or more of the methyl-acrylic acid ester monomer of olefin(e) acid heterocycle base ester.
Free radical photo-initiation is selected from benzoin ethyl ether, benzoin isopropyl ether, alkylbenzene ketone, acyl group phosphorous oxides, double
This kind of or its any one combination in benzoylphenyl phosphine oxide, benzophenone and acylphosphanes peroxide；Sun
Ion Photoepolymerizationinitiater initiater is selected from aromatic diazonium salt, aromatic series sulfosalt, aromatic iodonium salts, alkyl sulfosalt, Fang Mao
One of iron, luxuriant titanium, sulfonyl oxygen ketone and triaryl siloxanes ether or their any combination
Diluent be one of alcohol ethers solvent, esters solvent, ketones solvent, aromatic solvent, petroleum series solvent or
Several mixing；The auxiliary agent is one or more of levelling agent, defoaming agent, polymerization inhibitor, antistatic agent；The diluent is
Refractive index is greater than 1.5 high boiling solvent, and still more preferably refractive index is higher than 1.53 high boiling solvent, high refractive index solvent
For the solvent containing benzene ring structure, the high refractive index solvent is the aromatic solvents such as toluene, dimethylbenzene, durene, methyl phenyl ethers anisole,
Diphenyl ether, ethylene glycol phenyl ether, propylene glycol phenylate, diethylene glycol dibenzoate, dipropylene glycol dibenzoate, benzoic acid first
The one or more containing benzene ring structure solvent such as ester, ethyl benzoate, n-butylbenzoate, benzyl acetate.
Optional addition antistatic agent makes it have antistatic effect in polymerisable compound, and then improves operation
Yield；Can be used in antistatic agent of the invention is that the technical staff institute with usual knowledge is ripe in the technical field of the invention
Know, is such as, but not limited to ethyoxyl glycerine fatty acid esters, level Four amine compounds, fatty amines derivative.Epoxy resin
(such as polycyclic oxygen second hydrocarbon), silicon oxygen hydrocarbon or other alcohol derivatives
A kind of preparation method of stone surface inorganic agent, characterized by the following steps:
Step 2: step is added in radical initiator and cationic initiator mixture, diluent and auxiliary agent
Mixture in one.
Step 3: mixture middling speed is dispersed 2 hours in step 2, and filtering obtains inorganic agent.
Performance evaluation: carry out interpretation of result to Examples 1 to 7 respectively: comparative example 2 is used to be compared with embodiment 3, uses
Influence of photo polymerization monomer of the refractive index higher than 1.5 or more to composition comprehensive performance in research inorganic agent of the invention.It is right
The coating composition that ratio 2 provides, the corresponding raw material components of each composition and parts by weight are as shown in the Examples；By corresponding original
Expect that component is mixed by its parts by weight, middling speed is dispersed 2 hours, is filtered to get corresponding coating composition.
Embodiment 4-6, for evaluate and test at least containing one kind can carry out cationic polymerization modification acrylate light-cured resin,
It can carry out photo-curing monomer, radical initiator and the cationic initiator mixture and diluent and auxiliary agent of radical photopolymerization
Influence of the content to inorganic agent, by being tested for the property to product, it is known that 6 result of embodiment is more excellent.
Claims (10)
1. stone surface inorganic agent, be made of two kinds of components: component A and B component form, and the component A and B component respectively include
The raw material of following parts by weight: the modification acrylate light-cured resin 5-80 of cationic polymerization component A: can be at least carried out containing one kind
With the photo-curing monomer 5-80 that can carry out radical photopolymerization；B component: radical initiator and cationic initiator mixture
0.1-20 and diluent 0-20.
2. stone surface inorganic agent according to claim 1 and preparation method thereof, it is characterised in that: the component A or B group
Point in also include parts by weight be 0-10 auxiliary agent.
3. stone surface inorganic agent as claimed in claim 1 or 2, it is characterised in that: described at least can carry out sun containing one kind
The modification acrylate light-cured resin of ionic polymerization is by modified epoxy class acrylate and modified vinyl ethers methyl
The one or more of acrylate.
4. stone surface inorganic agent as claimed in claim 3, it is characterised in that: light-cured resin in the component A further include:
Modified epoxy class acrylic resin, epoxy organosilicon methacrylate, propoxylated glycerol triacrylate, SR306 mixing
Epoxy acrylate, SR238 mixing epoxy acrylate, epoxidised soybean oil acrylate, SR351 mixing epoxy third
One or more of olefin(e) acid ester, the epoxy acrylate of SR306 mixing, epoxy acrylate of styrene mixing.
5. stone surface inorganic agent as claimed in claim 4, it is characterised in that: the modified vinyl ethers acrylate by
One or more of hydroxy butyl vinyl ether acrylate and tirethylene glycol divinyl ether acrylate composition.
6. such as stone surface inorganic agent claimed in claims 1-2, it is characterised in that: photo-curing monomer also wraps in the component A
Include the methyl-acrylic acid ester monomer of methyl-propen acid alkyl ester, methyl-acrylic acid alkenyl esters and methyl-acrylic acid heterocycle base ester
One or more of.
7. stone surface inorganic agent as claimed in claim 2, it is characterised in that: the free radical photo-initiation is selected from styrax
Ether, benzoin isopropyl ether, alkylbenzene ketone, acyl group phosphorous oxides, bis(benzoylphenyl) phosphine oxide, benzophenone and acyl
This kind of or its any one combination in base phosphine peroxide；The cationic photopolymerization initiator is selected from aromatic diazo
Salt, the luxuriant iron of aromatic series sulfosalt, aromatic iodonium salts, alkyl sulfosalt, virtue, luxuriant titanium, sulfonyl oxygen ketone and triaryl silicon oxygen
One of alkane ether or their any combination.
8. stone surface inorganic agent as claimed in claim 7, it is characterised in that: the diluent is alcohol ethers solvent, esters
The mixing of one or more of solvent, ketones solvent, aromatic solvent, petroleum series solvent；The auxiliary agent is levelling agent, defoaming
One or more of agent, polymerization inhibitor, antistatic agent.
9. a kind of preparation method of stone surface inorganic agent, characterized by the following steps:
Step 1: light-cured resin and photo polymerization monomer is uniform, form mixture；
Step 2: radical initiator and cationic initiator mixture, diluent and auxiliary agent are added to the mixing in step 1
In object；
Step 3: mixture middling speed is dispersed 2 hours in step 2, and filtering obtains inorganic agent.
10. a kind of method for treatment of surface of stone, it is characterised in that: be coated in stone surface inorganic agent on the surface of stone material.
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| CN114380622A (en) * | 2020-10-20 | 2022-04-22 | 经济开发区聚盛石材经营部 | Stone surface treating agent |
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