CN106118841A - A kind of environment-friendly type special mold releasing agent for fair-faced concrete and preparation method thereof - Google Patents
A kind of environment-friendly type special mold releasing agent for fair-faced concrete and preparation method thereof Download PDFInfo
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- CN106118841A CN106118841A CN201610500385.7A CN201610500385A CN106118841A CN 106118841 A CN106118841 A CN 106118841A CN 201610500385 A CN201610500385 A CN 201610500385A CN 106118841 A CN106118841 A CN 106118841A
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-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M173/00—Lubricating compositions containing more than 10% water
- C10M173/02—Lubricating compositions containing more than 10% water not containing mineral or fatty oils
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
- B28B7/00—Moulds; Cores; Mandrels
- B28B7/38—Treating surfaces of moulds, cores, or mandrels to prevent sticking
- B28B7/384—Treating agents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
- B28B7/00—Moulds; Cores; Mandrels
- B28B7/38—Treating surfaces of moulds, cores, or mandrels to prevent sticking
- B28B7/388—Treating surfaces of moulds, cores, or mandrels to prevent sticking with liquid material, e.g. lubricating
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/02—Hydroxy compounds
- C10M2207/021—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/04—Ethers; Acetals; Ortho-esters; Ortho-carbonates
- C10M2207/046—Hydroxy ethers
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/08—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/102—Polyesters
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/104—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2215/042—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2217/04—Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/36—Release agents or mold release agents
Abstract
The invention discloses a kind of environment-friendly type special mold releasing agent for fair-faced concrete, it is made up of the raw material of following weight percent: macromolecule resin 25-45%, coalescents 1-4%, leveling auxiliary agent 15-28%, defoamer 3-5%, activating agent 1-3%, antirust agent 0.5-2%, and surplus is water.The present invention is the water-based emulsion releasing agent of the environment-friendly type being exclusively used in the clear-water concrete component demoulding, biological degradation rate is high, environment-protecting asepsis, use advanced reaction for forming films, stripping result is good, component surface is smooth, without a large amount of pores, releasing agent to punching block non-corroding, scientific formulation, preparation technology is simple, can ensure repeatedly stripping result.
Description
Technical field
The invention belongs to chemical industry formulation products technical field, be specifically related to a kind of for preventing or reduce concrete and template
Environment-friendly type special mold releasing agent for fair-faced concrete that surface is mutually bonded and preparation method thereof.
Background technology
Along with the enhancing of modern society's people's environmental consciousness, the thought recovered one's original simplicity is rooted in the hearts of the people, and clear-water concrete is in state
Interior development is in the extensive application accelerating the projects such as trend, especially housing industrialization, exterior wall cladding and stadiums so that clear
Water coagulation soil skill upgrading lags behind number of applications.Actual in conjunction with domestic architectural engineering, it is desirable to clear-water concrete cement products
Not only speed of application is fast, and whole structure natural beauty also to reduce investment the reduction of erection time.The quality problems of clear-water concrete goods
Increasingly being paid close attention to by people in building field, in order to shorten the engineering production cycle, protection template exempts from corrosion simultaneously, and
And require that the appearance after the demoulding is more smooth, the complete bubble-free in surface, spraying once can ensure repeatedly stripping result,
The parting agent special selecting a kind of environment-friendly type is requisite to the preparation of clear-water concrete.
Summary of the invention
Present invention aim to overcome that the deficiencies in the prior art, develop a kind of formula environmental protection, preparation technology is simple, ensure
Repeatedly a kind of environment-friendly type special mold releasing agent for fair-faced concrete of stripping result.
Present invention also offers the preparation method of above-mentioned environment-friendly type special mold releasing agent for fair-faced concrete.
For achieving the above object, the present invention adopts the following technical scheme that
A kind of environment-friendly type special mold releasing agent for fair-faced concrete, it is made up of the raw material of following weight percent:
Macromolecule resin 25-45%, coalescents 1-4%, leveling auxiliary agent 15-28%, defoamer 3-5%, activating agent 1-3%,
Antirust agent 0.5-2%, surplus is water.
Concrete, described macromolecule resin is the one in alkyd resin, amino resins, epoxy resin and acrylic resin
Or several combinations.
Concrete, described coalescents is ethylenediamine, diethylenetriamine, triethylene tetramine, diethylaminopropylamine and diformazan
The combination of one or more in ethylethanolamine.
Concrete, described leveling auxiliary agent is the one in butanol or ethylene glycol monobutyl ether.
Concrete, described defoamer is in organic silicon defoamer, polysiloxane defoaming agent and acrylic resin defoamer
The combination of one or more.
Concrete, described activating agent is fatty alcohol-polyoxyethylene ether, alkylphenol polyoxyethylene and aliphatic acid polyethenoxy
The combination of one or more in ester.
The preparation method of above-mentioned environment-friendly type special mold releasing agent for fair-faced concrete, it comprises the steps:
1) stir in proportion (general stirring 10-15 minute) by coalescents and water, is sequentially added into defoamer, prevents
Rust agent and activating agent, stir (stirring about 30 minutes), then stands 15-20 minute, obtains mixed solution, standby;
2) macromolecule resin and leveling auxiliary agent are mixed in proportion (general stirring 15-30 minute), joins step
1), in gained mixed solution, stir, to obtain final product.
Above-mentioned releasing agent using method: the present invention is a kind of emulsion type releasing agent, dense to using after dilute 3 ~ 5 times
Degree.
The releasing agent using above-mentioned formula and method preparation to produce is smeared once, can the demoulding is repeatedly repeatedly.Releasing agent formula
In containing antirust agent, in use can protect Shimizu concrete template, improve template service life.The present invention is for being exclusively used in
The water-based emulsion releasing agent of the environment-friendly type of the clear-water concrete component demoulding, biological degradation rate is high, and environment-protecting asepsis uses advanced person's
Reaction for forming films, stripping result is good, component surface is smooth, without a large amount of pores, releasing agent to punching block non-corroding, scientific formulation,
Preparation technology is simple, can ensure repeatedly stripping result.
Releasing agent of the present invention belongs to water soluble organic polymer class releasing agent, its most renewable, degradable, again will not be to ring
Border volatilization harmful substance.First, this type of releasing agent is water-soluble, and its raw material is the macromolecule filming material of environment-friendly type, can reach
Environmental requirement.Being sprayed on clear-water concrete surface of steel plate, can quickly form layer of transparent thin film, secure adhesion is in steel form and mixes
Solidifying soil surface, filming performance is good, nonpoisonous and tasteless pollution-free, easy to use, can spray and can be coated with.Releasing agent of the present invention can be obviously reduced mixed
Absorption affinity between solidifying soil and template, reduces or prevents concrete from adhering with template surface so that it is peeling off smoothly with template so that
Concrete component corner angle are the most lossless and surface color is homogeneous, smooth, it is ensured that the quality of prefabricated components.Releasing agent of the present invention
On the one hand form fluid-tight thin film at concrete surface, prevent moisture from evaporating;On the other hand, at certain permeable formation model on top layer
Enclose interior generation chemical reaction, and form one layer of solid thin film, the pore in blocking concrete, stop Free water mistake in cement
Early evaporate too much, make cement can rely on the abundant aquation of mixing water of self, reach the purpose of autotrophy.It is sprayed on concrete surface
After, may also operate as the effect of concrete oxidant to a certain extent.
Detailed description of the invention
Below in conjunction with embodiment, technical scheme is discussed in detail further, but protection scope of the present invention
It is not limited thereto.
In following embodiment, water-soluble antirust agent (ANTI CORRO HB-200) selected by antirust agent, purchased from Shanghai with firmization
Work company limited;Epoxy resin selects CYD-115 aqueous epoxy resins, pacifies Chemical Co., Ltd. purchased from Guangzhou thousand;Acrylic acid tree
Fat selects water soluble acrylic resin, purchased from Shanghai weathercock chemistry Science and Technology Ltd.;Amino resins selects methyl-etherified amino tree
Fat, purchased from Shanghai weathercock chemistry Science and Technology Ltd.;Alkyd resin selects SC-1 water soluble alkyd resin, elegant purchased from Shandong treasured
Chemical Co., Ltd..
Embodiment 1
The preparation method of a kind of environment-friendly type special mold releasing agent for fair-faced concrete, it comprises the steps:
1) by 2.5g ethylenediamine and 41g water mix and blend 10-15 minute, be sequentially added into 3.5g organic silicon defoamer, 1g antirust agent,
2g fatty alcohol-polyoxyethylene ether, stirs and obtains homogeneous solution in about 30 minutes, then stands 15-20 minute, obtains mixed solution,
Standby;
2) by 23g epoxy resin and 7g amino resins and 20g butanol, stir 15-30 minute mix homogeneously, join step 1) institute
Obtain in mixed solution, stir, to obtain final product.
According to the detection method in JC/T949-2005 " concrete product releasing agent ", to the release agent solution after dilution
Carrying out homogeneity and Construction performance standard detects, result is as follows:
Project | Testing result |
Solid content/% | 38 |
Drying and forming-film time/min | 25-45 |
Stability | After being diluted to concentration, diluent, without laminated segregation, can keep uniform state |
Demolding performace | The energy demoulding more than 12 times smoothly, keep corner angle intact, smooth surface |
Steel had action of rust | Steel mold non-corroding is endangered |
Embodiment 2
The preparation method of a kind of environment-friendly type special mold releasing agent for fair-faced concrete, it comprises the steps:
1) by 4g dimethylethanolamine and 26.5g water mix and blend 8-10 minute, it is sequentially added into 4.0g organic silicon defoamer, 1g prevents
Rust agent, 2.5g polyoxyethylene carboxylate, stir and obtain homogeneous solution in about 30 minutes, then stands 15-20 minute, is mixed
Close solution, standby;
2) 28g alkyd resin, 9g amino resins are mixed homogeneously with the stirring of 25g ethylene glycol monobutyl ether for 20-30 minute, join step
Rapid 1), in gained mixed solution, stir, to obtain final product.
According to the detection method in JC/T949-2005 " concrete product releasing agent ", to the release agent solution after dilution
Carrying out homogeneity and Construction performance standard detects, result is as follows:
Project | Testing result |
Solid content/% | 45 |
Drying and forming-film time/min | 20-35 |
Stability | After being diluted to concentration, diluent, without laminated segregation, can keep uniform state |
Demolding performace | The energy demoulding more than 15 times smoothly, keep corner angle intact, smooth surface |
Steel had action of rust | Steel mold non-corroding is endangered |
Embodiment 3
The preparation method of a kind of environment-friendly type special mold releasing agent for fair-faced concrete, it comprises the steps:
1) by 4.0g ethylenediamine and 20.5g water mix and blend 10-15 minute, be sequentially added into 4g organic silicon defoamer, 1g antirust agent,
2.5g alkylphenol polyoxyethylene, stirs and obtains homogeneous solution in about 30 minutes, then stands 15-20 minute, obtains mixing molten
Liquid, standby;
2) 25g epoxy resin, 15g amino resins are mixed homogeneously with the stirring of 28g butanol for 15-25 minute, join step 1) institute
Obtain in mixed solution, stir, to obtain final product.
According to the detection method in JC/T949-2005 " concrete product releasing agent ", to the release agent solution after dilution
Carrying out homogeneity and Construction performance standard detects, result is as follows:
Project | Testing result |
Solid content/% | 48 |
Drying and forming-film time/min | 25-45 |
Stability | After being diluted to concentration, diluent, without laminated segregation, can keep uniform state |
Demolding performace | The energy demoulding more than 15 times smoothly, keep corner angle intact |
Steel had action of rust | Steel mold non-corroding is endangered |
Embodiment 4
The preparation method of a kind of environment-friendly type special mold releasing agent for fair-faced concrete, it comprises the steps:
1) by 3g diethylaminopropylamine and 32.5g water mix and blend 10-15 minute, it is sequentially added into 4g polysiloxane defoaming agent, 1g
Antirust agent, 2.5g fatty alcohol-polyoxyethylene ether, stir and obtain homogeneous solution in about 30 minutes, then stands 15-20 minute, obtains
Mixed solution, standby;
2) 20g alkyd resin, 15g amino resins are mixed homogeneously with the stirring of 22g butanol for 15-30 minute, join step 1) institute
Obtain in mixed solution, stir, to obtain final product.
According to the detection method in JC/T949-2005 " concrete product releasing agent ", to the release agent solution after dilution
Carrying out homogeneity and Construction performance standard detects, result is as follows:
Project | Testing result |
Solid content/% | 43 |
Drying and forming-film time/min | 20-35 |
Stability | After being diluted to concentration, diluent, without laminated segregation, can keep uniform state |
Demolding performace | The energy demoulding more than 15 times smoothly, keep corner angle intact, smooth surface |
Steel had action of rust | Steel mold non-corroding is endangered |
Embodiment 5
The preparation method of a kind of environment-friendly type special mold releasing agent for fair-faced concrete, it comprises the steps:
1) by 1g diethylenetriamine and 53.5g water mix and blend 10-15 minute, be sequentially added into 3.0g acrylic resin defoamer,
1.5g antirust agent, 1g fatty alcohol-polyoxyethylene ether, stir and obtain homogeneous solution in about 30 minutes, then stands 15-20 minute,
To mixed solution, standby;
2) 25g acrylic resin is mixed homogeneously with the stirring of 15g butanol for 15-30 minute, join step 1) gained mixed solution
In, stir, to obtain final product.
According to the detection method in JC/T949-2005 " concrete product releasing agent ", to the release agent solution after dilution
Carrying out homogeneity and Construction performance standard detects, result is as follows:
Project | Testing result |
Solid content/% | 31 |
Drying and forming-film time/min | 16-30 |
Stability | After being diluted to concentration, diluent, without laminated segregation, can keep uniform state |
Demolding performace | The energy demoulding more than 12 times smoothly, concrete adhesive capacity is not more than 5g/m2 |
Steel had action of rust | Steel mold non-corroding is endangered |
Claims (7)
1. an environment-friendly type special mold releasing agent for fair-faced concrete, it is characterised in that be made up of the raw material of following weight percent:
Macromolecule resin 25-45%, coalescents 1-4%, leveling auxiliary agent 15-28%, defoamer 3-5%, activating agent 1-3%,
Antirust agent 0.5-2%, surplus is water.
Environment-friendly type special mold releasing agent for fair-faced concrete the most according to claim 1, it is characterised in that described macromolecule resin
For the combination of one or more in alkyd resin, amino resins, epoxy resin and acrylic resin.
Environment-friendly type special mold releasing agent for fair-faced concrete the most according to claim 1, it is characterised in that described coalescents is
The combination of one or more in ethylenediamine, diethylenetriamine, triethylene tetramine, diethylaminopropylamine and dimethylethanolamine.
Environment-friendly type special mold releasing agent for fair-faced concrete the most according to claim 1, it is characterised in that described leveling auxiliary agent is
One in butanol or ethylene glycol monobutyl ether.
Environment-friendly type special mold releasing agent for fair-faced concrete the most according to claim 1, it is characterised in that described defoamer is for having
The combination of one or more in machine silicon defoaming agent, polysiloxane defoaming agent and acrylic resin defoamer.
Environment-friendly type special mold releasing agent for fair-faced concrete the most according to claim 1, it is characterised in that described activating agent is fat
The combination of one or more in fat polyoxyethylenated alcohol, alkylphenol polyoxyethylene and polyoxyethylene carboxylate.
7. the preparation method of the arbitrary described environment-friendly type special mold releasing agent for fair-faced concrete of claim 1 to 6, it is characterised in that bag
Include following steps: 1) coalescents is stirred in proportion with water, it is sequentially added into defoamer, antirust agent and activating agent, stirring
Uniformly, then stand 15-20 minute, obtain mixed solution, standby;
2) being mixed in proportion with leveling auxiliary agent by macromolecule resin, join in step 1) gained mixed solution, stirring is all
Even, to obtain final product.
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Cited By (7)
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CN106985264A (en) * | 2017-03-30 | 2017-07-28 | 佛山市蓝海石英石材有限公司 | A kind of quartz aqueous release agent and preparation method thereof |
CN107903750A (en) * | 2017-11-24 | 2018-04-13 | 东莞市明天纳米科技有限公司 | Non-sticky concrete water paint and its preparation method and application |
CN108822945A (en) * | 2018-08-02 | 2018-11-16 | 株洲加美乐素建材有限公司 | A kind of clear-water concrete demoulding paint and preparation method thereof |
CN109207244A (en) * | 2017-06-30 | 2019-01-15 | 北京市建筑工程研究院有限责任公司 | A kind of concrete prefabricated element aqueous release agent |
CN111633787A (en) * | 2020-05-26 | 2020-09-08 | 长江水利委员会长江科学院 | Make smooth concrete external mold device of concrete surface mirror surface |
CN113025173A (en) * | 2019-12-24 | 2021-06-25 | 西北民族大学 | Concrete water-based demoulding protective emulsion and application thereof |
CN115161101A (en) * | 2022-02-22 | 2022-10-11 | 马鞍山中集瑞江润滑油有限公司 | Releasing agent for bright cement products |
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