CN103555188A - UV (ultraviolet) photocuring paint and preparation method thereof - Google Patents
UV (ultraviolet) photocuring paint and preparation method thereof Download PDFInfo
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- CN103555188A CN103555188A CN201310487391.XA CN201310487391A CN103555188A CN 103555188 A CN103555188 A CN 103555188A CN 201310487391 A CN201310487391 A CN 201310487391A CN 103555188 A CN103555188 A CN 103555188A
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Abstract
The invention relates to a UV (ultraviolet) photocuring paint which is prepared from the following raw materials in parts by weight: 45-50 parts of polyurethane acrylate, 3-4 parts of butyl methacrylate, 20-24 parts of hydroxyethyl methacrylate, 4-5 parts of photoinitiator 184, 10-15 parts of trimethylolpropane triacrylate, 20-25 parts of ethyl acetate, 2-3 parts of dimethyl silicon oil, 14-16 parts of 1,6-hexanediol diacrylate, 1-2 parts of polyisobutylene, 1-2 parts of nano aluminum oxide, 2-3 parts of isophorone diisocyanate and 4-5 parts of dispersing aid. The paint provided by the invention can be used for spraying plastic shells of electronic and electric appliance products. The invention provides a UV primer product with higher environmental measurement resistance and higher crosslinking degree, and has the advantages of high adhesive force, acid/alkali resistance, corrosion resistance and electric insulation.
Description
Technical field
The invention belongs to paint field, relate in particular to a kind of UV photo-cured coating and preparation method thereof.
Background technology
Development along with market economy, there is great variety in paint field, wherein UV coating has the advantages such as curing speed is fast, energy-conservation, ambient cure, superior performance, environmental protection, on it, ray velocity is fast, rete luminance brightness is high, and dry rear face is firm heat-resisting, and refractive power is effective, make ground produce strong main body sense, be widely used in the fields such as chemical industry, machinery, electronics light industry, communication.Due to its environment-friendly advantage, UV solidifies and to have obtained the strong support of relevant environment rules and the close attention of industry member, and UV radiation curing material is in market requirement rapid growth, and UV Radiation-curing system is just with multiple technologies combination, to overcome some defect, meet actual application.Now in printing industry; the packing that can make UV obtains some special effects: high glossiness, good ink protection feature, the slipping that can add control and rub resistance, low smell or do not have smell, low extract maybe cannot detect extract, and the provide protection to ink.
Current UV solidify material is various, but still in various degree exist some problems, such as: Organic pollutants, xanthochromia, explosive look, not low temperature resistant, the series of problems such as cost is high, corrosion-resistant, all need to continue improvement for different purposes, reduce production costs, expand purposes.
Summary of the invention
The object of the present invention is to provide a kind of UV photo-cured coating and preparation method thereof, this coating has advantages of that shock strength is high, strong adhesion.
Technical scheme of the present invention is as follows:
A kind of UV photo-cured coating, it is characterized in that being made by the raw material of following weight part: urethane acrylate 45-50, butyl methacrylate 3-4, hydroxyethyl methylacrylate 20-24, light trigger 184 4-5, Viscoat 295 10-15, ethyl acetate 20-25, dimethyl silicone oil 2-3,1,6 hexanediyl ester 14-16, polyisobutene 1-2, nano-aluminium oxide 1-2, isoflurane chalcone diisocyanate 2-3, dispersing auxiliary 4-5; Described dispersing auxiliary is made by the raw material of following weight part: diatomite 5-7, jade 3-4, Radix Angelicae Sinensis oil 1-2, anilinomethyl triethoxysilane 1-2, Sodium Selenite 1-2, pentaerythritol triacrylate 2-3, altax 1-2, N-BUTYL ACETATE 22-24; Preparation method puts into calcining furnace by diatomite, jade, at 560-580 ℃, calcine 3-4 hour, take out, be ground into 50-100 order powder, put into 10-15% hydrochloric acid soln and soak foam 2-3 hour, taking-up is cleaned with clear water, be ground into 200-300 order powder, mix with other remaining component, be heated to 50-55 ℃, grinding distribution 1-2 hour, obtains.
The preparation method of described UV photo-cured coating, it is characterized in that other composition except light trigger 184, isoflurane chalcone diisocyanate to mix, be heated to 50-60 ℃, stir 10-15 minute, add again light trigger 184, isoflurane chalcone diisocyanate, continue to stir 10-15 minute, obtain.
Beneficial effect of the present invention:
Coating of the present invention can be used as the spraying coating of electronics and electric equipment products plastic shell.It provides more resistance to ring to survey and the higher UV priming paint product of degree of crosslinking, strong adhesion, acid and alkali-resistance, corrosion-resistant, insulation.
Embodiment
A kind of UV photo-cured coating, by following weight part (kilogram) raw material make: urethane acrylate 45, butyl methacrylate 4, hydroxyethyl methylacrylate 20, light trigger 184 4, Viscoat 295 15, ethyl acetate 20, dimethyl silicone oil 2,1,6 hexanediyl ester 14, polyisobutene 1, nano-aluminium oxide 2, isoflurane chalcone diisocyanate 2, dispersing auxiliary 5; Described dispersing auxiliary by following weight part (kilogram) raw material make: diatomite 7, jade 3, Radix Angelicae Sinensis oil 1, anilinomethyl triethoxysilane 1, Sodium Selenite 2, pentaerythritol triacrylate 3, altax 2, N-BUTYL ACETATE 22; Preparation method puts into calcining furnace by diatomite, jade, at 560-580 ℃, calcine 3-4 hour, take out, be ground into 50-100 order powder, put into 10-15% hydrochloric acid soln and soak foam 2-3 hour, taking-up is cleaned with clear water, be ground into 200-300 order powder, mix with other remaining component, be heated to 50-55 ℃, grinding distribution 1-2 hour, obtains.
Preparation method mixes other composition except light trigger 184, isoflurane chalcone diisocyanate, is heated to 50-60 ℃, stirs 10-15 minute, then adds light trigger 184, isoflurane chalcone diisocyanate, continues to stir 10-15 minute, obtains.
This UV photo-cured coating can adopt the form of construction work of spraying to construct.The paint spraying making by above scheme sticking power on plank is all better than secondary, resistance to 75% ethanol is more than 24 hours, alkaline-resisting 24 hours above, acidproof more than 48 hours, the cold cycling that tolerates subzero 40 degree and 40 degree does not ftracture for 10 times, resistance to 15% salt solution is more than 60 hours, hardness can regulate between 3H at 2HB, and abrasion resistance index turns above 4000.
Claims (2)
1. a UV photo-cured coating, it is characterized in that being made by the raw material of following weight part: urethane acrylate 45-50, butyl methacrylate 3-4, hydroxyethyl methylacrylate 20-24, light trigger 184 4-5, Viscoat 295 10-15, ethyl acetate 20-25, dimethyl silicone oil 2-3,1,6 hexanediyl ester 14-16, polyisobutene 1-2, nano-aluminium oxide 1-2, isoflurane chalcone diisocyanate 2-3, dispersing auxiliary 4-5; Described dispersing auxiliary is made by the raw material of following weight part: diatomite 5-7, jade 3-4, Radix Angelicae Sinensis oil 1-2, anilinomethyl triethoxysilane 1-2, Sodium Selenite 1-2, pentaerythritol triacrylate 2-3, altax 1-2, N-BUTYL ACETATE 22-24; Preparation method puts into calcining furnace by diatomite, jade, at 560-580 ℃, calcine 3-4 hour, take out, be ground into 50-100 order powder, put into 10-15% hydrochloric acid soln and soak foam 2-3 hour, taking-up is cleaned with clear water, be ground into 200-300 order powder, mix with other remaining component, be heated to 50-55 ℃, grinding distribution 1-2 hour, obtains.
2. the preparation method of UV photo-cured coating according to claim 1, it is characterized in that other composition except light trigger 184, isoflurane chalcone diisocyanate to mix, be heated to 50-60 ℃, stir 10-15 minute, add again light trigger 184, isoflurane chalcone diisocyanate, continue to stir 10-15 minute, obtain.
Priority Applications (1)
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CN201310487391.XA CN103555188A (en) | 2013-10-18 | 2013-10-18 | UV (ultraviolet) photocuring paint and preparation method thereof |
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CN201310487391.XA CN103555188A (en) | 2013-10-18 | 2013-10-18 | UV (ultraviolet) photocuring paint and preparation method thereof |
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CN201310487391.XA Pending CN103555188A (en) | 2013-10-18 | 2013-10-18 | UV (ultraviolet) photocuring paint and preparation method thereof |
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Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103834272A (en) * | 2014-03-04 | 2014-06-04 | 芜湖市艾德森自动化设备有限公司 | Ultraviolet-curable coating material with antibacterial and antioxidant effects and preparation method thereof |
CN104194441A (en) * | 2014-08-28 | 2014-12-10 | 苏州洛特兰新材料科技有限公司 | Acrylate coating for ceramics |
WO2015090150A1 (en) * | 2013-12-18 | 2015-06-25 | 四川优特光电科技有限公司 | Photo-curable insulating varnish, preparation method therefor and application method thereof |
CN108822671A (en) * | 2018-05-02 | 2018-11-16 | 苏州捷德瑞精密机械有限公司 | A kind of high attachment scratch-resistant plastic coating and preparation method thereof |
WO2021210598A1 (en) * | 2020-04-16 | 2021-10-21 | 株式会社スリーボンド | Photocurable composition, sealing material, and cured object |
WO2023002973A1 (en) * | 2021-07-21 | 2023-01-26 | 株式会社スリーボンド | Photocurable composition |
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CN1044666A (en) * | 1989-02-01 | 1990-08-15 | 北京大学 | Photocurable composition and its production and use |
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CN1294163A (en) * | 1999-10-28 | 2001-05-09 | 湖南亚大化工建材有限公司 | Ultraviolet ray solidified anticorrosion decorative paint for metal |
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CN101153101A (en) * | 2006-09-25 | 2008-04-02 | 德古萨有限责任公司 | Radiation-curable formulation which forms flexible coatings with increased corrosion protection on metallic substrates |
CN102199375A (en) * | 2010-03-26 | 2011-09-28 | 东莞市佩琦涂料有限公司 | Ultraviolet (UV) paint solidified by ultraviolet light |
CN102977758A (en) * | 2012-12-24 | 2013-03-20 | 上海应用技术学院 | UV (ultraviolet) photocured water-based fluorine-containing polyurethane latex film and preparation method thereof |
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Patent Citations (8)
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CN1044666A (en) * | 1989-02-01 | 1990-08-15 | 北京大学 | Photocurable composition and its production and use |
CN1176985A (en) * | 1997-09-18 | 1998-03-25 | 庞德春 | Wood pencil special purpose ultra-violet cured color coating and prepn. method therefor |
CN1294163A (en) * | 1999-10-28 | 2001-05-09 | 湖南亚大化工建材有限公司 | Ultraviolet ray solidified anticorrosion decorative paint for metal |
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CN101153101A (en) * | 2006-09-25 | 2008-04-02 | 德古萨有限责任公司 | Radiation-curable formulation which forms flexible coatings with increased corrosion protection on metallic substrates |
CN102199375A (en) * | 2010-03-26 | 2011-09-28 | 东莞市佩琦涂料有限公司 | Ultraviolet (UV) paint solidified by ultraviolet light |
CN102977758A (en) * | 2012-12-24 | 2013-03-20 | 上海应用技术学院 | UV (ultraviolet) photocured water-based fluorine-containing polyurethane latex film and preparation method thereof |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2015090150A1 (en) * | 2013-12-18 | 2015-06-25 | 四川优特光电科技有限公司 | Photo-curable insulating varnish, preparation method therefor and application method thereof |
CN103834272A (en) * | 2014-03-04 | 2014-06-04 | 芜湖市艾德森自动化设备有限公司 | Ultraviolet-curable coating material with antibacterial and antioxidant effects and preparation method thereof |
CN104194441A (en) * | 2014-08-28 | 2014-12-10 | 苏州洛特兰新材料科技有限公司 | Acrylate coating for ceramics |
CN108822671A (en) * | 2018-05-02 | 2018-11-16 | 苏州捷德瑞精密机械有限公司 | A kind of high attachment scratch-resistant plastic coating and preparation method thereof |
WO2021210598A1 (en) * | 2020-04-16 | 2021-10-21 | 株式会社スリーボンド | Photocurable composition, sealing material, and cured object |
WO2023002973A1 (en) * | 2021-07-21 | 2023-01-26 | 株式会社スリーボンド | Photocurable composition |
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