CN103666045B - UV curing inks of the little strong adhesion of a kind of granularity and preparation method thereof - Google Patents
UV curing inks of the little strong adhesion of a kind of granularity and preparation method thereof Download PDFInfo
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- CN103666045B CN103666045B CN201310600487.2A CN201310600487A CN103666045B CN 103666045 B CN103666045 B CN 103666045B CN 201310600487 A CN201310600487 A CN 201310600487A CN 103666045 B CN103666045 B CN 103666045B
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Abstract
The invention discloses the UV curing inks of the little strong adhesion of a kind of granularity, it is characterized in that, be made up of the raw material of following weight part: pigment dyestuff 1-3, urethane acrylate 24-26,1,6 hexanediyl ester 12-15, nano-aluminium oxide 2-4, gac 1-2, oleic acid 4-5, tri (propylene glycol) diacrylate 10-12, phenyl glycidyl ether 1-2, ultraviolet absorbent UV-531? 1-2, light trigger 2959? 4-7, cobalt naphthenate 1-2, water glass 2-3, mandarin oil 2-3, auxiliary agent 4-5; Auxiliary agent of the present invention improves the toughness of ink, makes distributes ink even, and maintains the stability of ink; Ink of the present invention has the advantages such as particle diameter is little, viscosity is low, it is excellent to soak, strong adhesion, and energy-conserving and environment-protective.
Description
Technical field
The present invention relates to a kind of ink and preparation method thereof, particularly the UV curing inks and preparation method thereof of the little strong adhesion of a kind of granularity.
Background technology
Ultraviolet light polymerization (UV) ink refers under uviolizing, utilizes the UV-light of different wave length and energy to make ink film forming and dry ink.Utilize different UV spectrum, can different-energy be produced, the monomer polymerization in different ink vehicle is become polymkeric substance, so the look film of UV ink has good machinery and chemical property.The major advantage of UV ink has: (1) is without solvent; (2) rate of drying is fast, and power consumption is few; (3) good luster, bright in luster; (4) water-fast, solvent resistant, wear resisting property is good.In UV ink, light trigger is that one is subject to light activated compound, after absorb light is shone, be excited into free radical, and energy trasfer, to photosensitivity molecule or photocrosslinking agent, makes UV ink that photocuring reaction occur.Current UV ink has become a kind of more ripe ink technology, and its pollutant emission is almost nil.Except not containing solvent, UV ink also just like not easily scumming, the advantages such as site is clear, the bright-coloured light of mass colour, and chemical resistance is excellent, low-consuming.
Summary of the invention
The object of this invention is to provide UV curing inks of the little strong adhesion of a kind of granularity and preparation method thereof.
In order to realize object of the present invention, the present invention is by following scheme implementation:
The UV curing inks of the little strong adhesion of a kind of granularity, be made up of the raw material of following weight part: pigment dyestuff 1-3, urethane acrylate 24-26,1,6 hexanediyl ester 12-15, nano-aluminium oxide 2-4, gac 1-2, oleic acid 4-5, tri (propylene glycol) diacrylate 10-12, phenyl glycidyl ether 1-2, ultraviolet absorbent UV-531 1-2, light trigger 29594-7, cobalt naphthenate 1-2, water glass 2-3, mandarin oil 2-3, auxiliary agent 4-5;
Described auxiliary agent is prepared from by the raw material of following weight part: nano diatomite powder 0.2-0.3, nano mica powder 0.2-0.3, silane resin acceptor kh-550 2-3, morpholine 1-2, neopentyl glycol 3-4, oxidation inhibitor 10351-2, linking agent TAC2-3, tri (propylene glycol) diacrylate 10-12,1-Methoxy-2-propyl acetate 5-10, Tenox PG 2-3, coix seed oil 1-2; Its preparation method is by each mixing of materials, is heated to 60-70 DEG C, and stirring reaction 30-40 minute, to obtain final product.
The UV curing inks of the little strong adhesion of granularity of the present invention, be made up of following concrete steps: first add pigment dyestuff, urethane acrylate, 1,6 hexanediyl esters, nano-aluminium oxide, gac, oleic acid, tri (propylene glycol) diacrylate, phenyl glycidyl ether, ultraviolet absorbent UV-531 stirring and evenly mixing, be heated to 80-90 DEG C, stir 25-35 minute; Then all the other remaining components except light trigger 2959 are added, stirring reaction 3-5 hour; Finally be cooled to 60-70 DEG C, add light trigger 2959, stirring reaction 40-50 minute, after cooling, grinding obtains 20-40 μm of slurry, to obtain final product.
The invention has the beneficial effects as follows: auxiliary agent of the present invention improves the toughness of ink, make distributes ink even, and maintain the stability of ink; Ink of the present invention has the advantages such as particle diameter is little, viscosity is low, it is excellent to soak, strong adhesion, and energy-conserving and environment-protective.
Specific embodiments
Below by specific examples, the present invention is described in detail.
The UV curing inks of the little strong adhesion of a kind of granularity, be made up of the raw material of following weight part (kilogram): pigment dyestuff 1, urethane acrylate 24,1,6 hexanediyl ester 12, nano-aluminium oxide 2, gac 1, oleic acid 4, tri (propylene glycol) diacrylate 10, phenyl glycidyl ether 1, ultraviolet absorbent UV-531 1, light trigger 29594, cobalt naphthenate 1, water glass 2, mandarin oil 2, auxiliary agent 4;
Described auxiliary agent is prepared from by the raw material of following weight part (kilogram): nano diatomite powder 0.2 nano mica powder 0.2, silane resin acceptor kh-550 2, morpholine 1, neopentyl glycol 3, oxidation inhibitor 10351, linking agent TAC2, tri (propylene glycol) diacrylate 10,1-Methoxy-2-propyl acetate 5, Tenox PG 2, coix seed oil 1; Its preparation method is by each mixing of materials, is heated to 60-70 DEG C, and stirring reaction 30-40 minute, to obtain final product.
The UV curing inks of the little strong adhesion of granularity of the present invention, be made up of following concrete steps: first add pigment dyestuff, urethane acrylate, 1,6 hexanediyl esters, nano-aluminium oxide, gac, oleic acid, tri (propylene glycol) diacrylate, phenyl glycidyl ether, ultraviolet absorbent UV-531 stirring and evenly mixing, be heated to 80-90 DEG C, stir 25-35 minute; Then all the other remaining components except light trigger 2959 are added, stirring reaction 3-5 hour; Finally be cooled to 60-70 DEG C, add light trigger 2959, stirring reaction 40-50 minute, after cooling, grinding obtains 20-40 μm of slurry, to obtain final product.
The ink of gained, uses cross-hatching ox-hide tape stripping, draws compartment apart from 1mm, 100% attachment; Use the spirituous cotton balls of leaching, 300 grams of pressure wipings 50 times, are as good as shape; To be soaked in salad oil (normal temperature) 8 hours, to be as good as shape; Use and be soaked with the cotton balls of salt solution, 300 grams of pressure wipings 50 times, are as good as shape.
Claims (2)
1. the UV curing inks of the little strong adhesion of granularity, it is characterized in that, be prepared from by the raw material of following weight part: pigment dyestuff 1-3, urethane acrylate 24-26,1,6 hexanediol diacrylate 12-15, nano-aluminium oxide 2-4, gac 1-2, oleic acid 4-5, tri (propylene glycol) diacrylate 10-12, phenyl glycidyl ether 1-2, ultraviolet absorbent UV-531 1-2, light trigger 29594-7, cobalt naphthenate 1-2, water glass 2-3, mandarin oil 2-3, auxiliary agent 4-5;
Described auxiliary agent is prepared from by the raw material of following weight part: nano diatomite powder 0.2-0.3, nano mica powder 0.2-0.3, silane resin acceptor kh-550 2-3, morpholine 1-2, neopentyl glycol 3-4, oxidation inhibitor 10351-2, linking agent TAC2-3, tri (propylene glycol) diacrylate 10-12,1-Methoxy-2-propyl acetate 5-10, Tenox PG 2-3, coix seed oil 1-2; Its preparation method is by each mixing of materials, is heated to 60-70 DEG C, and stirring reaction 30-40 minute, to obtain final product.
2. the UV curing inks of the little strong adhesion of granularity according to claim 1, it is characterized in that, be made up of following concrete steps: first add pigment dyestuff, urethane acrylate, 1,6-hexanediyl ester, nano-aluminium oxide, gac, oleic acid, tri (propylene glycol) diacrylate, phenyl glycidyl ether, ultraviolet absorbent UV-531 stirring and evenly mixing, be heated to 80-90 DEG C, stir 25-35 minute; Then all the other remaining components except light trigger 2959 are added, stirring reaction 3-5 hour; Finally be cooled to 60-70 DEG C, add light trigger 2959, stirring reaction 40-50 minute, after cooling, grinding obtains 20-40 μm of slurry, to obtain final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310600487.2A CN103666045B (en) | 2013-11-25 | 2013-11-25 | UV curing inks of the little strong adhesion of a kind of granularity and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201310600487.2A CN103666045B (en) | 2013-11-25 | 2013-11-25 | UV curing inks of the little strong adhesion of a kind of granularity and preparation method thereof |
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| CN103666045A CN103666045A (en) | 2014-03-26 |
| CN103666045B true CN103666045B (en) | 2016-04-13 |
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Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN104263062B (en) * | 2014-09-03 | 2016-04-27 | 安徽雅美油墨有限公司 | A kind of high absorption abrasion-resistance water environmental protection photocuring tin printing ink |
| CN104312265B (en) * | 2014-11-11 | 2016-04-27 | 合肥皖为电气设备工程有限责任公司 | Molten color inhibition plastic printing ink of a kind of environment-friendly type alcohol and preparation method thereof |
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| CN101560348A (en) * | 2009-05-25 | 2009-10-21 | 王景泉 | Ultraviolet light curing offset printing ink and preparation method thereof |
| CN102558580A (en) * | 2012-01-13 | 2012-07-11 | 中国印刷科学技术研究所 | Dissoluble light-cured resin and dissoluble ultraviolet (UV) printing ink and preparing method thereof |
| CN102653650A (en) * | 2012-04-24 | 2012-09-05 | 东莞上海大学纳米技术研究院 | UV-cured white character inkjet and preparation method thereof |
| CN102964916A (en) * | 2012-11-23 | 2013-03-13 | 东莞市佳烨化工科技有限公司 | A kind of UV offset printing iron printing ink and preparation method thereof |
| CN102964915A (en) * | 2012-11-23 | 2013-03-13 | 东莞市佳烨化工科技有限公司 | A kind of UV screen printing plastic ink and preparation method thereof |
| CN102964913A (en) * | 2012-11-23 | 2013-03-13 | 东莞市佳烨化工科技有限公司 | A kind of environmental protection UV screen printing anti-counterfeiting ink and preparation method thereof |
| CN103232751A (en) * | 2013-04-25 | 2013-08-07 | 深圳市美丽华油墨涂料有限公司 | UV (ultraviolet) curing ink and application thereof |
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2013
- 2013-11-25 CN CN201310600487.2A patent/CN103666045B/en active Active
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN101560348A (en) * | 2009-05-25 | 2009-10-21 | 王景泉 | Ultraviolet light curing offset printing ink and preparation method thereof |
| CN102558580A (en) * | 2012-01-13 | 2012-07-11 | 中国印刷科学技术研究所 | Dissoluble light-cured resin and dissoluble ultraviolet (UV) printing ink and preparing method thereof |
| CN102653650A (en) * | 2012-04-24 | 2012-09-05 | 东莞上海大学纳米技术研究院 | UV-cured white character inkjet and preparation method thereof |
| CN102964916A (en) * | 2012-11-23 | 2013-03-13 | 东莞市佳烨化工科技有限公司 | A kind of UV offset printing iron printing ink and preparation method thereof |
| CN102964915A (en) * | 2012-11-23 | 2013-03-13 | 东莞市佳烨化工科技有限公司 | A kind of UV screen printing plastic ink and preparation method thereof |
| CN102964913A (en) * | 2012-11-23 | 2013-03-13 | 东莞市佳烨化工科技有限公司 | A kind of environmental protection UV screen printing anti-counterfeiting ink and preparation method thereof |
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Effective date of registration: 20240103 Address after: 516121 Yide Industrial Park, Xiaopeng Gang Village, Longxi Street, Boluo County, Huizhou City, Guangdong Province Patentee after: Huizhou Zhimeide Technology Co.,Ltd. Address before: 244000 No. 3201, Cuihu Fourth Road, Tongling Economic Development Zone, Anhui Province Patentee before: TONGLING FOUNDER PLASTICS TECHNOLOGY Co.,Ltd. |
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