CN103666045A - UV solidified printing ink with small particle size and low adhesive force, and preparation method of UV solidified printing ink - Google Patents
UV solidified printing ink with small particle size and low adhesive force, and preparation method of UV solidified printing ink Download PDFInfo
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- CN103666045A CN103666045A CN201310600487.2A CN201310600487A CN103666045A CN 103666045 A CN103666045 A CN 103666045A CN 201310600487 A CN201310600487 A CN 201310600487A CN 103666045 A CN103666045 A CN 103666045A
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Abstract
The invention discloses UV solidified printing ink with small particle size and low adhesive force. The UV solidified printing ink is characterized by comprising the following raw materials by weight: 1 to 3 parts of an organic pigment, 24 to 26 parts of polyurethane acrylate, 12 to 15 parts of 1,6-hexanediol diacrylate, 2 to 4 parts of nano aluminium sesquioxide, 1 to 2 parts of activated charcoal, 4 to 5 parts of oleinic acid, 10 to 12 parts of tripropylene glycol diacrylate, 1 to 2 parts of phenyl glycidyl ether, 1 to 2 parts of ultraviolet light absorber UV-531, 4 to 7 parts of a photoinitiator 2959, 1 to 2 parts of cobalt naphthenate, 2 to 3 parts of sodium silicate, 2 to 3 parts of orange oil, and 4 to 5 parts of an assistant. The additive improves the toughness of the printing ink, enables the printing ink to be dispersed uniformly, and maintains the stability of the printing ink. The UV solidified printing ink has the advantages that the particle size is small; the viscosity is low; the dampening property is favorable; the adhesive force is large; the purposes of energy saving and environment protection are realized.
Description
Technical field
The present invention relates to a kind of ink and preparation method thereof, particularly UV curing inks of the little strong adhesion of a kind of granularity and preparation method thereof.
Background technology
Ultraviolet light polymerization (UV) ink refers under uviolizing, utilizes the UV-light of different wave length and energy to make ink film forming and dry ink.Utilize different UV spectrum, can produce different-energy, the monomer polymerization in different ink vehicles is become to polymkeric substance, so the look film of UV ink has good machinery and chemical property.The major advantage of UV ink has: (1) is without solvent; (2) rate of drying is fast, and power consumption is few; (3) good luster, bright in luster; (4) water-fast, resistance to solvent, wear resisting property is good.In UV ink, light trigger is a kind of light activated compound that is subject to, and after absorb light is shone, is excited into free radical, and energy is transferred to photosensitivity molecule or photocrosslinking agent, makes UV China ink that photocuring reaction occur.UV China ink has become a kind of more ripe ink technology at present, and its pollutant emission is almost nil.Except not containing solvent, UV China ink is also just like being difficult for scumming, and site is clear, the bright-coloured light of mass colour, the advantage such as chemical resistance is excellent, low-consuming.
Summary of the invention
The object of this invention is to provide UV curing inks of the little strong adhesion of a kind of granularity and preparation method thereof.
In order to realize object of the present invention, the present invention passes through following scheme implementation:
The UV curing inks of the little strong adhesion of a kind of granularity, raw material by following weight part is made: pigment dyestuff 1-3, urethane acrylate 24-26,1,6 hexanediyl ester 12-15, nano-aluminium oxide 2-4, gac 1-2, oleic acid 4-5, tri (propylene glycol) diacrylate 10-12, phenyl glycidyl ether 1-2, ultraviolet absorbent UV-531 1-2, light trigger 2959 4-7, cobalt naphthenate 1-2, water glass 2-3, mandarin oil 2-3, auxiliary agent 4-5;
Described auxiliary agent is prepared from by the raw material of following weight part: nano diatomite powder 0.2-0.3, nano mica powder 0.2-0.3, silane resin acceptor kh-550 2-3, morpholine 1-2, neopentyl glycol 3-4, oxidation inhibitor 1035 1-2, linking agent TAC2-3, tri (propylene glycol) diacrylate 10-12,1-Methoxy-2-propyl acetate 5-10, Tenox PG 2-3, coix seed oil 1-2; Its preparation method is by each mixing of materials, is heated to 60-70 ℃, and stirring reaction 30-40 minute, obtains.
The UV curing inks of the little strong adhesion of granularity of the present invention, by following concrete steps, made: first add pigment dyestuff, urethane acrylate, 1,6 hexanediyl esters, nano-aluminium oxide, gac, oleic acid, tri (propylene glycol) diacrylate, phenyl glycidyl ether, ultraviolet absorbent UV-531 stirring and evenly mixing, be heated to 80-90 ℃, stir 25-35 minute; Then add all the other remaining components except light trigger 2959, stirring reaction 3-5 hour; Finally be cooled to 60-70 ℃, add light trigger 2959, stirring reaction 40-50 minute, cooling after, grind and to obtain 20-40 μ m slurry, obtain.
The invention has the beneficial effects as follows: auxiliary agent of the present invention has improved the toughness of ink, make distributes ink even, and maintained the stability of ink; Ink of the present invention has the advantages such as particle diameter is little, viscosity is low, it is good to soak, strong adhesion, and energy-conserving and environment-protective.
Specific embodiments
Below by specific examples, the present invention is described in detail.
The UV curing inks of the little strong adhesion of a kind of granularity, by following weight part (kilogram) raw material make: pigment dyestuff 1, urethane acrylate 24,1,6 hexanediyl ester 12, nano-aluminium oxide 2, gac 1, oleic acid 4, tri (propylene glycol) diacrylate 10, phenyl glycidyl ether 1, ultraviolet absorbent UV-531 1, light trigger 2,959 4, cobalt naphthenate 1, water glass 2, mandarin oil 2, auxiliary agent 4;
Described auxiliary agent by following weight part (kilogram) raw material be prepared from: nano diatomite powder 0.2 nano mica powder 0.2, silane resin acceptor kh-550 2, morpholine 1, neopentyl glycol 3, oxidation inhibitor 1,035 1, linking agent TAC2, tri (propylene glycol) diacrylate 10,1-Methoxy-2-propyl acetate 5, Tenox PG 2, coix seed oil 1; Its preparation method is by each mixing of materials, is heated to 60-70 ℃, and stirring reaction 30-40 minute, obtains.
The UV curing inks of the little strong adhesion of granularity of the present invention, by following concrete steps, made: first add pigment dyestuff, urethane acrylate, 1,6 hexanediyl esters, nano-aluminium oxide, gac, oleic acid, tri (propylene glycol) diacrylate, phenyl glycidyl ether, ultraviolet absorbent UV-531 stirring and evenly mixing, be heated to 80-90 ℃, stir 25-35 minute; Then add all the other remaining components except light trigger 2959, stirring reaction 3-5 hour; Finally be cooled to 60-70 ℃, add light trigger 2959, stirring reaction 40-50 minute, cooling after, grind and to obtain 20-40 μ m slurry, obtain.
The ink of gained, is used cross-hatching ox-hide tape stripping, draws compartment apart from 1mm, and 100% adheres to; Spirituous cotton balls is soaked in use, and 300 grams of pressure wipings 50 times, are as good as shape; Be soaked in salad oil (normal temperature) 8 hours, be as good as shape; Use is soaked with the cotton balls of salt solution, and 300 grams of pressure wipings 50 times, are as good as shape.
Claims (2)
1. the UV curing inks of the little strong adhesion of granularity, it is characterized in that, raw material by following weight part is made: pigment dyestuff 1-3, urethane acrylate 24-26,1,6 hexanediyl ester 12-15, nano-aluminium oxide 2-4, gac 1-2, oleic acid 4-5, tri (propylene glycol) diacrylate 10-12, phenyl glycidyl ether 1-2, ultraviolet absorbent UV-531 1-2, light trigger 2959 4-7, cobalt naphthenate 1-2, water glass 2-3, mandarin oil 2-3, auxiliary agent 4-5;
Described auxiliary agent is prepared from by the raw material of following weight part: nano diatomite powder 0.2-0.3, nano mica powder 0.2-0.3, silane resin acceptor kh-550 2-3, morpholine 1-2, neopentyl glycol 3-4, oxidation inhibitor 1035 1-2, linking agent TAC2-3, tri (propylene glycol) diacrylate 10-12,1-Methoxy-2-propyl acetate 5-10, Tenox PG 2-3, coix seed oil 1-2; Its preparation method is by each mixing of materials, is heated to 60-70 ℃, and stirring reaction 30-40 minute, obtains.
2. the UV curing inks of the little strong adhesion of granularity according to claim 1, it is characterized in that, by following concrete steps, made: first add pigment dyestuff, urethane acrylate, 1,6 hexanediyl esters, nano-aluminium oxide, gac, oleic acid, tri (propylene glycol) diacrylate, phenyl glycidyl ether, ultraviolet absorbent UV-531 stirring and evenly mixing, be heated to 80-90 ℃, stir 25-35 minute; Then add all the other remaining components except light trigger 2959, stirring reaction 3-5 hour; Finally be cooled to 60-70 ℃, add light trigger 2959, stirring reaction 40-50 minute, cooling after, grind and to obtain 20-40 μ m slurry, obtain.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310600487.2A CN103666045B (en) | 2013-11-25 | 2013-11-25 | UV curing inks of the little strong adhesion of a kind of granularity and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201310600487.2A CN103666045B (en) | 2013-11-25 | 2013-11-25 | UV curing inks of the little strong adhesion of a kind of granularity and preparation method thereof |
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| Publication Number | Publication Date |
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| CN103666045A true CN103666045A (en) | 2014-03-26 |
| CN103666045B CN103666045B (en) | 2016-04-13 |
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| CN201310600487.2A Expired - Fee Related CN103666045B (en) | 2013-11-25 | 2013-11-25 | UV curing inks of the little strong adhesion of a kind of granularity and preparation method thereof |
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Cited By (2)
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| CN104263062A (en) * | 2014-09-03 | 2015-01-07 | 安徽雅美油墨有限公司 | High-adsorption wear-resistant water-based environment-friendly photocuring tin printing ink |
| CN104312265A (en) * | 2014-11-11 | 2015-01-28 | 合肥皖为电气设备工程有限责任公司 | Environmentally friendly alcohol soluble anti-yellowing plastic printing ink and preparation method thereof |
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| CN101560348A (en) * | 2009-05-25 | 2009-10-21 | 王景泉 | Ultraviolet light curing offset printing ink and preparation method thereof |
| CN102558580A (en) * | 2012-01-13 | 2012-07-11 | 中国印刷科学技术研究所 | Dissoluble light-cured resin and dissoluble ultraviolet (UV) printing ink and preparing method thereof |
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| CN103232751A (en) * | 2013-04-25 | 2013-08-07 | 深圳市美丽华油墨涂料有限公司 | UV (ultraviolet) curing ink and application thereof |
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| CN101560348A (en) * | 2009-05-25 | 2009-10-21 | 王景泉 | Ultraviolet light curing offset printing ink and preparation method thereof |
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| CN104263062A (en) * | 2014-09-03 | 2015-01-07 | 安徽雅美油墨有限公司 | High-adsorption wear-resistant water-based environment-friendly photocuring tin printing ink |
| CN104263062B (en) * | 2014-09-03 | 2016-04-27 | 安徽雅美油墨有限公司 | A kind of high absorption abrasion-resistance water environmental protection photocuring tin printing ink |
| CN104312265A (en) * | 2014-11-11 | 2015-01-28 | 合肥皖为电气设备工程有限责任公司 | Environmentally friendly alcohol soluble anti-yellowing plastic printing ink and preparation method thereof |
| CN104312265B (en) * | 2014-11-11 | 2016-04-27 | 合肥皖为电气设备工程有限责任公司 | Molten color inhibition plastic printing ink of a kind of environment-friendly type alcohol and preparation method thereof |
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| CN103666045B (en) | 2016-04-13 |
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Effective date of registration: 20240103 Address after: 516121 Yide Industrial Park, Xiaopeng Gang Village, Longxi Street, Boluo County, Huizhou City, Guangdong Province Patentee after: Huizhou Zhimeide Technology Co.,Ltd. Address before: 244000 No. 3201, Cuihu Fourth Road, Tongling Economic Development Zone, Anhui Province Patentee before: TONGLING FOUNDER PLASTICS TECHNOLOGY Co.,Ltd. |
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