CN104263062B - A kind of high absorption abrasion-resistance water environmental protection photocuring tin printing ink - Google Patents
A kind of high absorption abrasion-resistance water environmental protection photocuring tin printing ink Download PDFInfo
- Publication number
- CN104263062B CN104263062B CN201410445768.XA CN201410445768A CN104263062B CN 104263062 B CN104263062 B CN 104263062B CN 201410445768 A CN201410445768 A CN 201410445768A CN 104263062 B CN104263062 B CN 104263062B
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- CN
- China
- Prior art keywords
- ink
- environmental protection
- auxiliary agent
- deionized water
- raw material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 24
- 230000007613 environmental effect Effects 0.000 title claims abstract description 13
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 title claims abstract description 9
- 238000010521 absorption reaction Methods 0.000 title claims abstract description 9
- 238000000016 photochemical curing Methods 0.000 title claims abstract description 9
- 239000000203 mixture Substances 0.000 claims abstract description 17
- 239000008367 deionised water Substances 0.000 claims abstract description 14
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 14
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 11
- 239000002994 raw material Substances 0.000 claims abstract description 11
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000000839 emulsion Substances 0.000 claims abstract description 10
- -1 methyl glucose glucoside Chemical class 0.000 claims abstract description 9
- ITRNXVSDJBHYNJ-UHFFFAOYSA-N tungsten disulfide Chemical compound S=[W]=S ITRNXVSDJBHYNJ-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000007787 solid Substances 0.000 claims abstract description 8
- 229930182478 glucoside Natural products 0.000 claims abstract description 7
- MNCGMVDMOKPCSQ-UHFFFAOYSA-M sodium;2-phenylethenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C=CC1=CC=CC=C1 MNCGMVDMOKPCSQ-UHFFFAOYSA-M 0.000 claims abstract description 7
- 239000000049 pigment Substances 0.000 claims abstract description 5
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims abstract description 4
- VDGJOQCBCPGFFD-UHFFFAOYSA-N oxygen(2-) silicon(4+) titanium(4+) Chemical compound [Si+4].[O-2].[O-2].[Ti+4] VDGJOQCBCPGFFD-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229920002635 polyurethane Polymers 0.000 claims abstract description 4
- 239000004814 polyurethane Substances 0.000 claims abstract description 4
- 239000000725 suspension Substances 0.000 claims abstract description 4
- 239000000463 material Substances 0.000 claims description 11
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 9
- STVZJERGLQHEKB-UHFFFAOYSA-N ethylene glycol dimethacrylate Substances CC(=C)C(=O)OCCOC(=O)C(C)=C STVZJERGLQHEKB-UHFFFAOYSA-N 0.000 claims description 7
- DBCAQXHNJOFNGC-UHFFFAOYSA-N 4-bromo-1,1,1-trifluorobutane Chemical compound FC(F)(F)CCCBr DBCAQXHNJOFNGC-UHFFFAOYSA-N 0.000 claims description 6
- 238000000227 grinding Methods 0.000 claims description 6
- 238000002360 preparation method Methods 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 claims description 3
- 239000008346 aqueous phase Substances 0.000 claims description 3
- 238000009835 boiling Methods 0.000 claims description 3
- 239000006185 dispersion Substances 0.000 claims description 3
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 claims description 3
- 239000012467 final product Substances 0.000 claims description 3
- 238000009775 high-speed stirring Methods 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 3
- 239000002245 particle Substances 0.000 claims description 3
- 239000002002 slurry Substances 0.000 claims description 3
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 claims description 3
- 238000001035 drying Methods 0.000 abstract description 5
- 239000000758 substrate Substances 0.000 abstract description 3
- 239000011248 coating agent Substances 0.000 abstract description 2
- 238000000576 coating method Methods 0.000 abstract description 2
- 238000011161 development Methods 0.000 abstract description 2
- 239000002904 solvent Substances 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 235000019504 cigarettes Nutrition 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 239000012855 volatile organic compound Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/101—Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
Abstract
The present invention relates to environment-friendly ink development field, be specifically related to a kind of high absorption abrasion-resistance water environmental protection photocuring tin printing ink, this ink is made up of the raw material of following weight part: nanometer titanium dioxide silicon suspension 5-8, the Sodium styrene sulfonate 1-2 of tungsten disulfide 0.1-0.2, solid content 30%, methyl glucose glucoside 0.1-0.2, solid content are aqueous polyurethane acrylate emulsion 20-26, light trigger 3-6, deionized water 15-26, ethanol 8-10, environmental-friendly pigment 8-13, the auxiliary agent 1-2 of 40-50%; Ink of the present invention is water color ink, and environmental protection degree is high, and the tungsten disulfide of interpolation has good oilness, the consistency between each raw material can be improved, promote the adsorptivity of ink in metallic substrate surface, then in conjunction with auxiliary agent and other composition, make ink of the present invention compared with currently available products, not only have excellent printing adaptability, ink exquisiteness is stable, and not easily reunite, uniform drying is quick, coating tough and hard wear resistant, prints quickness and high efficiency.
Description
Technical field
The present invention relates to a kind of environment-friendly ink, be specifically related to a kind of high absorption abrasion-resistance water environmental protection photocuring tin printing ink.
Background technology
Ink is widely used in printing industry, it is mainly by resin, pigment, solvent, the compositions such as auxiliary agent are formed, the ink major part that current printing industry uses is solvent type ink, this kind of ink can give out VOCs human body and environment being had to harm, some ink that is direct and human contact may work the mischief to health, some objectionable impurities even can penetrate into food by packaging, in the packing material such as cigarette and medicine, therefore the most important thing that feature of environmental protection ink is Future Development is developed, fundamentally to improve the feature of environmental protection of ink, need to set about from change ink formulations, Novel environment-friendlymaterial material is adopted to replace conventional toxic objectionable constituent, obtain gratifying rate of drying simultaneously, use properties and good printing adaptability.
Summary of the invention
The object of the invention is to, provide a kind of high absorption abrasion-resistance water environmental protection photocuring tin printing ink, to achieve these goals, the technical solution used in the present invention is as follows:
A kind of high absorption abrasion-resistance water environmental protection photocuring tin printing ink, it is characterized in that, this ink is made up of the raw material of following weight part: nanometer titanium dioxide silicon suspension 5-8, the Sodium styrene sulfonate 1-2 of tungsten disulfide 0.1-0.2, solid content 30%, methyl glucose glucoside 0.1-0.2, solid content are aqueous polyurethane acrylate emulsion 20-26, light trigger 3-6, deionized water 15-26, ethanol 8-10, environmental-friendly pigment 8-13, the auxiliary agent 1-2 of 40-50%;
Described auxiliary agent is made up of the raw material of following weight part: propylene glycol phenylate 4-5, oxidized polyethlene wax 5-8, Ethylene glycol dimethacrylate 2-3, deionized water 15-18, Sodium dodecylbenzene sulfonate 1-3, ethylene glycol monomethyl ether 2-3, preparation method is: first oxidized polyethlene wax is heated to molten state, then dropwise Ethylene glycol dimethacrylate is added, do not stop to stir with the speed of 800-1000 rev/min in dropping process, after dropwising, constant temperature keeps 20-30min for subsequent use, again other remaining component is mixed with deionized water, after each composition dissolves completely, solution is heated to boiling, gained aqueous phase solution makes stable emulsion with oxidized polyethlene wax-dimethacrylate ethanol ester mixture mix and blend again.
Described one height absorption abrasion-resistance water environmental protection photocuring tin printing ink, its preparation process is: be first dissolved in by tungsten disulfide in the deionized water of 50-60 DEG C, add Sodium styrene sulfonate, methyl glucose glucoside subsequently, continue to be stirred to after material dissolves completely, add polyurethane-acrylate emulsion, continue dispersed with stirring to material cool to room temperature, the material of gained is mixed with other remaining component, after high-speed stirring dispersion 40-50min, drop into grinding machine for grinding, to particle diameter≤10 μm of gained slurry, to obtain final product.
First the advantage of ink of the present invention is its feature of environmental protection, and use deionized water as medium, avoid the use of organic solvent, the raw material chosen also is to human body and environment is nontoxic or the composition of low toxicity; Tungsten disulfide in raw material has good oilness, the consistency between each raw material can be improved, the adsorptivity of ink in metallic substrate surface can be increased simultaneously, prevent from coming off, be combined with drying aid, the auxiliary agent accelerating film forming effect and other composition again, make ink of the present invention compared with currently available products, not only have excellent printing adaptability, ink exquisiteness is stable, not easily reunite, uniform drying is quick, coating tough and hard wear resistant, prints quickness and high efficiency.
Embodiment
Embodiment
Ink prepared by the present embodiment is made up of the raw material of following weight part: the nanometer titanium dioxide silicon suspension 8 of tungsten disulfide 0.1, solid content 30%, Sodium styrene sulfonate 1, methyl glucose glucoside 0.1, solid content are aqueous polyurethane acrylate emulsion 24, light trigger 4, deionized water 26, ethanol 8, environmental-friendly pigment 12, the auxiliary agent 1 of 50%.
Wherein auxiliary agent is made up of the raw material of following weight part: propylene glycol phenylate 5, oxidized polyethlene wax 8, Ethylene glycol dimethacrylate 3, deionized water 18, Sodium dodecylbenzene sulfonate 1, ethylene glycol monomethyl ether 2, preparation method is: first oxidized polyethlene wax is heated to molten state, then dropwise Ethylene glycol dimethacrylate is added, do not stop to stir with the speed of 1000 revs/min in dropping process, after dropwising, constant temperature keeps 30min for subsequent use, again other remaining component is mixed with deionized water, after each composition dissolves completely, solution is heated to boiling, gained aqueous phase solution makes stable emulsion with oxidized polyethlene wax-dimethacrylate ethanol ester mixture mix and blend again.
The preparation process of this printing-ink is: be first dissolved in by tungsten disulfide in the deionized water of 50-60 DEG C, add Sodium styrene sulfonate, methyl glucose glucoside subsequently, continue to be stirred to after material dissolves completely, add polyurethane-acrylate emulsion, continue dispersed with stirring to material cool to room temperature, the material of gained is mixed with other remaining component, after high-speed stirring dispersion 50min, drop into grinding machine for grinding, to particle diameter≤10 μm of gained slurry, to obtain final product.
By the ink printing obtained by the present embodiment on thin aluminum sheet, after its complete drying, according to corresponding national examination criteria, this ink in the performance test results of substrate surface is:
Claims (2)
1. one kind high absorption abrasion-resistance water environmental protection photocuring tin printing ink, it is characterized in that, this printing-ink is made up of the raw material of following weight part: nanometer titanium dioxide silicon suspension 5-8, the Sodium styrene sulfonate 1-2 of tungsten disulfide 0.1-0.2, solid content 30%, methyl glucose glucoside 0.1-0.2, solid content are aqueous polyurethane acrylate emulsion 20-26, light trigger 3-6, deionized water 15-26, ethanol 8-10, environmental-friendly pigment 8-13, the auxiliary agent 1-2 of 40-50%;
Described auxiliary agent is made up of the raw material of following weight part: propylene glycol phenylate 4-5, oxidized polyethlene wax 5-8, Ethylene glycol dimethacrylate 2-3, deionized water 15-18, Sodium dodecylbenzene sulfonate 1-3, ethylene glycol monomethyl ether 2-3;
The preparation method of described auxiliary agent is: first oxidized polyethlene wax is heated to molten state, then dropwise Ethylene glycol dimethacrylate is added, do not stop to stir with the speed of 800-1000 rev/min in dropping process, after dropwising, constant temperature keeps 20-30min for subsequent use, again other remaining component is mixed with deionized water, after each composition dissolves completely, solution is heated to boiling, and gained aqueous phase solution makes stable emulsion with oxidized polyethlene wax-Ethylene glycol dimethacrylate mixture mix and blend again.
2. a kind of high absorption abrasion-resistance water environmental protection photocuring tin printing ink as claimed in claim 1, its preparation process is: be first dissolved in by tungsten disulfide in the deionized water of 50-60 DEG C, add Sodium styrene sulfonate, methyl glucose glucoside subsequently, continue to be stirred to after material dissolves completely, add polyurethane-acrylate emulsion, continue dispersed with stirring to material cool to room temperature, the material of gained is mixed with other remaining component, after high-speed stirring dispersion 40-50min, drop into grinding machine for grinding, to particle diameter≤10 μm of gained slurry, to obtain final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410445768.XA CN104263062B (en) | 2014-09-03 | 2014-09-03 | A kind of high absorption abrasion-resistance water environmental protection photocuring tin printing ink |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410445768.XA CN104263062B (en) | 2014-09-03 | 2014-09-03 | A kind of high absorption abrasion-resistance water environmental protection photocuring tin printing ink |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104263062A CN104263062A (en) | 2015-01-07 |
| CN104263062B true CN104263062B (en) | 2016-04-27 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410445768.XA Active CN104263062B (en) | 2014-09-03 | 2014-09-03 | A kind of high absorption abrasion-resistance water environmental protection photocuring tin printing ink |
Country Status (1)
| Country | Link |
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| CN (1) | CN104263062B (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106647167A (en) * | 2016-09-30 | 2017-05-10 | 河南工程学院 | Matte photosensitive resin for photocuring quick molding and preparation method thereof |
| CN112759973A (en) * | 2021-02-03 | 2021-05-07 | 浙江大胜达包装股份有限公司 | Environment-friendly wear-resistant water-based ink for printing packaging box and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102367339A (en) * | 2011-07-01 | 2012-03-07 | 深圳市美丽华油墨涂料有限公司 | UV (Ultra Violet) hectograph printing ink used for printing |
| CN102964916A (en) * | 2012-11-23 | 2013-03-13 | 东莞市佳烨化工科技有限公司 | Ultraviolet (UV) offset tin printing ink and method for preparing same |
| CN103666043A (en) * | 2013-11-25 | 2014-03-26 | 铜陵方正塑业科技有限公司 | UV printing ink having quick solidification effect and good adhesive attraction |
| CN103666045A (en) * | 2013-11-25 | 2014-03-26 | 铜陵方正塑业科技有限公司 | UV solidified printing ink with small particle size and low adhesive force, and preparation method of UV solidified printing ink |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2012097191A (en) * | 2010-11-02 | 2012-05-24 | Mimaki Engineering Co Ltd | Aqueous ink |
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2014
- 2014-09-03 CN CN201410445768.XA patent/CN104263062B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102367339A (en) * | 2011-07-01 | 2012-03-07 | 深圳市美丽华油墨涂料有限公司 | UV (Ultra Violet) hectograph printing ink used for printing |
| CN102964916A (en) * | 2012-11-23 | 2013-03-13 | 东莞市佳烨化工科技有限公司 | Ultraviolet (UV) offset tin printing ink and method for preparing same |
| CN103666043A (en) * | 2013-11-25 | 2014-03-26 | 铜陵方正塑业科技有限公司 | UV printing ink having quick solidification effect and good adhesive attraction |
| CN103666045A (en) * | 2013-11-25 | 2014-03-26 | 铜陵方正塑业科技有限公司 | UV solidified printing ink with small particle size and low adhesive force, and preparation method of UV solidified printing ink |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104263062A (en) | 2015-01-07 |
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Effective date of registration: 20240326 Address after: 215000 Xuexing Industrial Concentration Zone, Lianshui Economic Development Zone, Huai'an City, Jiangsu Province Patentee after: Jiangsu Shoufu Ink Co.,Ltd. Country or region after: China Address before: No.10 Xiangrong Road, Chahe Industrial Park, Lai'an County, Chuzhou City, Anhui Province, 239200 Patentee before: ANHUI YAMEI INK CO.,LTD. Country or region before: China |