CN104250469A - Soft highly-bright antiwear environment-friendly aqueous fluorocarbon resin printing ink - Google Patents
Soft highly-bright antiwear environment-friendly aqueous fluorocarbon resin printing ink Download PDFInfo
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- CN104250469A CN104250469A CN201410445392.2A CN201410445392A CN104250469A CN 104250469 A CN104250469 A CN 104250469A CN 201410445392 A CN201410445392 A CN 201410445392A CN 104250469 A CN104250469 A CN 104250469A
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Abstract
The invention relates to the field of research of environment-friendly printing ink, and concretely relates to soft highly-bright antiwear environment-friendly aqueous fluorocarbon resin printing ink. The printing ink is prepared from the following raw materials in parts by weight: 0.1-0.2 part of nanometer silicon boride, 1-2 parts of fine hair powder, 0.1-0.2 part of nanometer aluminium powder, 5-8 parts of methylal, 8-12 parts of environmental-friendly pigment, 15-24 parts of deionized water, 18-25 parts of aqueous fluorocarbon resin emulsion with the solid content of 40-50%, 1-3 parts of fluoro alkyl polyester modified polysiloxane, 3-5 parts of isopropanol, and 1-2 parts of an auxiliary agent. The printing ink is aqueous environment-friendly printing ink. Nanometer silicon boride, the fine hair powder and the nanometer aluminium powder, which are subjected to grinding processing by employing the fluoro alkyl polyester modified polysiloxane, have reduced surface tension and relatively good dispersity and give play to good filling and modification effect, and by combining other compositions, the printing ink possesses excellent printing adaptability, and is resistant to heat and weather, good in low-temperature flexibility,and soft and smooth in handfeel. A dried coating is compact, bright, and resistant to exterior wear, and the construction process is simple and efficient.
Description
Technical field
The present invention relates to a kind of environment-friendly ink, be specifically related to a kind of soft feeling highlighted wearable environment protection water-based fluorocarbon resin ink.
Background technology
Ink is widely used in printing industry, it is mainly by resin, pigment, solvent, the compositions such as auxiliary agent are formed, the ink major part that current printing industry uses is solvent type ink, this kind of ink can give out VOCs human body and environment being had to harm, some ink that is direct and human contact may work the mischief to health, some objectionable impurities even can penetrate into food by packaging, in the packing material such as cigarette and medicine, therefore the most important thing that feature of environmental protection ink is Future Development is developed, fundamentally to improve the feature of environmental protection of ink, need to set about from change ink formulations, Novel environment-friendlymaterial material is adopted to replace conventional toxic objectionable constituent, obtain gratifying rate of drying simultaneously, use properties and good printing adaptability.
Summary of the invention
The object of the invention is to, provide a kind of soft feeling highlighted wearable environment protection water-based fluorocarbon resin ink, to achieve these goals, the technical solution used in the present invention is as follows:
A kind of soft feeling highlighted wearable environment protection water-based fluorocarbon resin ink, it is characterized in that, this ink is made up of the raw material of following weight part: nanometer silicon boride 0.1-0.2, fine hair powder 1-2, nanometer aluminium powder 0.1-0.2, methylal 5-8, environmental-friendly pigment 8-12, deionized water 15-24, solid content are the water-based fluorocarbon resin emulsion 18-25 of 40-50%, fluorine-based alkyl, polyether modified polyorganosiloxane 1-3, Virahol 3-5, auxiliary agent 1-2;
Described auxiliary agent is made up of the raw material of following weight part: propylene glycol phenylate 4-5, oxidized polyethlene wax 5-8, Ethylene glycol dimethacrylate 2-3, deionized water 15-18, Sodium dodecylbenzene sulfonate 1-3, ethylene glycol monomethyl ether 2-3, preparation method is: first oxidized polyethlene wax is heated to molten state, then dropwise Ethylene glycol dimethacrylate is added, do not stop to stir with the speed of 800-1000 rev/min in dropping process, after dropwising, constant temperature keeps 20-30min for subsequent use, again other remaining component is mixed with deionized water, after each composition dissolves completely, solution is heated to boiling, gained aqueous phase solution makes stable emulsion with oxidized polyethlene wax-dimethacrylate ethanol ester mixture mix and blend again.
Described a kind of soft feeling highlighted wearable environment protection water-based fluorocarbon resin ink, its preparation process is: first nanometer silicon boride, fine hair powder, nanometer aluminium powder are mixed with fluorine-based alkyl, polyether modified polyorganosiloxane, dispersion grinding 30-40min, subsequently gained material is mixed with other remaining component, after high-speed stirring dispersion 30-50min, whole input grinding machine for grinding, to particle diameter≤10 μm of gained slurry, to obtain final product.
First the advantage of ink prepared by the present invention is its feature of environmental protection, and use deionized water as medium, avoid the use of organic solvent, the raw material chosen also is to human body and environment is nontoxic or the composition of low toxicity, in addition, nanometer silicon boride after fluorine-based alkyl, polyether modified polyorganosiloxane milled processed, fine hair powder and nanometer aluminium powder, surface tension is reduced, can better disperse in resin emulsion, powder does not come off, fly away, play good filling, modifying function, be combined with drying aid again, accelerate auxiliary agent and other composition of film forming effect, make ink of the present invention compared with currently available products, not only have excellent printing adaptability, and it is heat-resisting weather-proof, low temperature flexibility is good, feel is soft and smooth, compact after coating drying vivid, the wearing and tearing of the resistance to external world, construction process is simply efficient.
Embodiment
Embodiment
Ink prepared by the present embodiment is made up of the raw material of following weight part: nanometer silicon boride 0.1, fine hair powder 1, nanometer aluminium powder 0.1, methylal 8, environmental-friendly pigment 12, deionized water 20, solid content are the water-based fluorocarbon resin emulsion 20 of 50%, fluorine-based alkyl, polyether modified polyorganosiloxane 2, Virahol 5, auxiliary agent 1.5.
Wherein auxiliary agent is made up of the raw material of following weight part: propylene glycol phenylate 5, oxidized polyethlene wax 8, Ethylene glycol dimethacrylate 3, deionized water 18, Sodium dodecylbenzene sulfonate 1, ethylene glycol monomethyl ether 2, preparation method is: first oxidized polyethlene wax is heated to molten state, then dropwise Ethylene glycol dimethacrylate is added, do not stop to stir with the speed of 1000 revs/min in dropping process, after dropwising, constant temperature keeps 30min for subsequent use, again other remaining component is mixed with deionized water, after each composition dissolves completely, solution is heated to boiling, gained aqueous phase solution makes stable emulsion with oxidized polyethlene wax-dimethacrylate ethanol ester mixture mix and blend again.
The preparation process of this printing-ink is: first nanometer silicon boride, fine hair powder, nanometer aluminium powder are mixed with fluorine-based alkyl, polyether modified polyorganosiloxane, dispersion grinding 40min, subsequently gained material is mixed with other remaining component, after high-speed stirring dispersion 50min, whole input grinding machine for grinding, to particle diameter≤10 μm of gained slurry, to obtain final product.
By the ink printing obtained by the present embodiment on PET plate, after its complete drying, according to corresponding national examination criteria, this ink in the performance test results of substrate surface is:
Claims (2)
1. a soft feeling highlighted wearable environment protection water-based fluorocarbon resin ink, it is characterized in that, this printing-ink is made up of the raw material of following weight part: nanometer silicon boride 0.1-0.2, fine hair powder 1-2, nanometer aluminium powder 0.1-0.2, methylal 5-8, environmental-friendly pigment 8-12, deionized water 15-24, solid content are the water-based fluorocarbon resin emulsion 18-25 of 40-50%, fluorine-based alkyl, polyether modified polyorganosiloxane 1-3, Virahol 3-5, auxiliary agent 1-2;
Described auxiliary agent is made up of the raw material of following weight part: propylene glycol phenylate 4-5, oxidized polyethlene wax 5-8, Ethylene glycol dimethacrylate 2-3, deionized water 15-18, Sodium dodecylbenzene sulfonate 1-3, ethylene glycol monomethyl ether 2-3, preparation method is: first oxidized polyethlene wax is heated to molten state, then dropwise Ethylene glycol dimethacrylate is added, do not stop to stir with the speed of 800-1000 rev/min in dropping process, after dropwising, constant temperature keeps 20-30min for subsequent use, again other remaining component is mixed with deionized water, after each composition dissolves completely, solution is heated to boiling, gained aqueous phase solution makes stable emulsion with oxidized polyethlene wax-dimethacrylate ethanol ester mixture mix and blend again.
2. a kind of soft feeling as claimed in claim 1 highlighted wearable environment protection water-based fluorocarbon resin ink, its preparation process is: first nanometer silicon boride, fine hair powder, nanometer aluminium powder are mixed with fluorine-based alkyl, polyether modified polyorganosiloxane, dispersion grinding 30-40min, subsequently gained material is mixed with other remaining component, after high-speed stirring dispersion 30-50min, whole input grinding machine for grinding, to particle diameter≤10 μm of gained slurry, to obtain final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410445392.2A CN104250469A (en) | 2014-09-03 | 2014-09-03 | Soft highly-bright antiwear environment-friendly aqueous fluorocarbon resin printing ink |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410445392.2A CN104250469A (en) | 2014-09-03 | 2014-09-03 | Soft highly-bright antiwear environment-friendly aqueous fluorocarbon resin printing ink |
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| CN104250469A true CN104250469A (en) | 2014-12-31 |
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| CN201410445392.2A Pending CN104250469A (en) | 2014-09-03 | 2014-09-03 | Soft highly-bright antiwear environment-friendly aqueous fluorocarbon resin printing ink |
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Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6429477A (en) * | 1987-07-23 | 1989-01-31 | Shinetsu Chemical Co | Marking ink composition |
| JP2004292707A (en) * | 2003-03-27 | 2004-10-21 | Fuji Photo Film Co Ltd | Ink for inkjet recording and inkjet recording method |
| US20050143490A1 (en) * | 2001-02-21 | 2005-06-30 | Seiko Epson Corporation | Ink composition containing polyether-modified polysiloxane |
| CN101429362A (en) * | 2008-12-09 | 2009-05-13 | 天津环球磁卡股份有限公司 | Watersoluble silk screen printing ink and method of producing the same |
| CN102482521A (en) * | 2009-09-04 | 2012-05-30 | 富士胶片株式会社 | Ink set, recording method, recorded material and printed material |
| CN103045008A (en) * | 2011-10-14 | 2013-04-17 | 富士施乐株式会社 | Image-recording composition, image-recording apparatus, and image-recording method |
| CN103666093A (en) * | 2013-11-18 | 2014-03-26 | 蚌埠市英路光电有限公司 | Fluorocarbon-resin-base printing ink and preparation method thereof |
-
2014
- 2014-09-03 CN CN201410445392.2A patent/CN104250469A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6429477A (en) * | 1987-07-23 | 1989-01-31 | Shinetsu Chemical Co | Marking ink composition |
| US20050143490A1 (en) * | 2001-02-21 | 2005-06-30 | Seiko Epson Corporation | Ink composition containing polyether-modified polysiloxane |
| JP2004292707A (en) * | 2003-03-27 | 2004-10-21 | Fuji Photo Film Co Ltd | Ink for inkjet recording and inkjet recording method |
| CN101429362A (en) * | 2008-12-09 | 2009-05-13 | 天津环球磁卡股份有限公司 | Watersoluble silk screen printing ink and method of producing the same |
| CN102482521A (en) * | 2009-09-04 | 2012-05-30 | 富士胶片株式会社 | Ink set, recording method, recorded material and printed material |
| CN103045008A (en) * | 2011-10-14 | 2013-04-17 | 富士施乐株式会社 | Image-recording composition, image-recording apparatus, and image-recording method |
| CN103666093A (en) * | 2013-11-18 | 2014-03-26 | 蚌埠市英路光电有限公司 | Fluorocarbon-resin-base printing ink and preparation method thereof |
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Application publication date: 20141231 |
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| RJ01 | Rejection of invention patent application after publication |