CN104250470A - Antistatic environment-friendly printing ink prepared by reutilizing waste plant oil residue - Google Patents
Antistatic environment-friendly printing ink prepared by reutilizing waste plant oil residue Download PDFInfo
- Publication number
- CN104250470A CN104250470A CN201410445760.3A CN201410445760A CN104250470A CN 104250470 A CN104250470 A CN 104250470A CN 201410445760 A CN201410445760 A CN 201410445760A CN 104250470 A CN104250470 A CN 104250470A
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- parts
- friendly
- printing ink
- environment
- vegetable oil
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 239000002699 waste material Substances 0.000 title claims abstract description 23
- 239000010773 plant oil Substances 0.000 title abstract 4
- 239000000203 mixture Substances 0.000 claims abstract description 17
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 9
- 239000002994 raw material Substances 0.000 claims abstract description 9
- 238000001035 drying Methods 0.000 claims abstract description 8
- 238000000034 method Methods 0.000 claims abstract description 8
- 229920005989 resin Polymers 0.000 claims abstract description 6
- 239000011347 resin Substances 0.000 claims abstract description 6
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000000049 pigment Substances 0.000 claims abstract description 5
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 claims abstract description 4
- GMSCBRSQMRDRCD-UHFFFAOYSA-N dodecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCOC(=O)C(C)=C GMSCBRSQMRDRCD-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 claims abstract description 4
- 235000015112 vegetable and seed oil Nutrition 0.000 claims description 18
- 239000008158 vegetable oil Substances 0.000 claims description 18
- GNTDGMZSJNCJKK-UHFFFAOYSA-N divanadium pentaoxide Chemical compound O=[V](=O)O[V](=O)=O GNTDGMZSJNCJKK-UHFFFAOYSA-N 0.000 claims description 14
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 9
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 9
- 239000000243 solution Substances 0.000 claims description 7
- DBCAQXHNJOFNGC-UHFFFAOYSA-N 4-bromo-1,1,1-trifluorobutane Chemical compound FC(F)(F)CCCBr DBCAQXHNJOFNGC-UHFFFAOYSA-N 0.000 claims description 6
- 239000008367 deionised water Substances 0.000 claims description 6
- 229910021641 deionized water Inorganic materials 0.000 claims description 6
- STVZJERGLQHEKB-UHFFFAOYSA-N ethylene glycol dimethacrylate Substances CC(=C)C(=O)OCCOC(=O)C(C)=C STVZJERGLQHEKB-UHFFFAOYSA-N 0.000 claims description 6
- 238000000227 grinding Methods 0.000 claims description 6
- 238000002360 preparation method Methods 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- 239000000839 emulsion Substances 0.000 claims description 4
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 claims description 3
- FCIZRDXBLQAYLY-UHFFFAOYSA-N C(CCCCCCCCCCC)(=O)OCCOCCOC(CCCCCCCCCCC)=O.C(CCCCCCCCCCCCCCCCC)(=O)O Chemical compound C(CCCCCCCCCCC)(=O)OCCOCCOC(CCCCCCCCCCC)=O.C(CCCCCCCCCCCCCCCCC)(=O)O FCIZRDXBLQAYLY-UHFFFAOYSA-N 0.000 claims description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N EtOH Substances CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 3
- 239000008346 aqueous phase Substances 0.000 claims description 3
- 239000007864 aqueous solution Substances 0.000 claims description 3
- 238000009835 boiling Methods 0.000 claims description 3
- 239000006185 dispersion Substances 0.000 claims description 3
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 claims description 3
- -1 ethanol ester Chemical class 0.000 claims description 3
- 239000012467 final product Substances 0.000 claims description 3
- 238000009775 high-speed stirring Methods 0.000 claims description 3
- 238000007654 immersion Methods 0.000 claims description 3
- 239000002245 particle Substances 0.000 claims description 3
- 239000000843 powder Substances 0.000 claims description 3
- 239000002002 slurry Substances 0.000 claims description 3
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 claims description 3
- 238000003756 stirring Methods 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 5
- 239000002904 solvent Substances 0.000 abstract description 5
- 239000000463 material Substances 0.000 abstract description 4
- 230000000694 effects Effects 0.000 abstract description 3
- 238000005516 engineering process Methods 0.000 abstract description 3
- 239000012535 impurity Substances 0.000 abstract description 3
- 231100000053 low toxicity Toxicity 0.000 abstract description 2
- 238000012545 processing Methods 0.000 abstract description 2
- DLYUQMMRRRQYAE-UHFFFAOYSA-N tetraphosphorus decaoxide Chemical compound O1P(O2)(=O)OP3(=O)OP1(=O)OP2(=O)O3 DLYUQMMRRRQYAE-UHFFFAOYSA-N 0.000 abstract 4
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 abstract 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 abstract 2
- 238000004061 bleaching Methods 0.000 abstract 2
- FPVVYTCTZKCSOJ-UHFFFAOYSA-N Ethylene glycol distearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCOC(=O)CCCCCCCCCCCCCCCCC FPVVYTCTZKCSOJ-UHFFFAOYSA-N 0.000 abstract 1
- 239000011248 coating agent Substances 0.000 abstract 1
- 238000000576 coating method Methods 0.000 abstract 1
- 238000005034 decoration Methods 0.000 abstract 1
- 230000001877 deodorizing effect Effects 0.000 abstract 1
- GPLRAVKSCUXZTP-UHFFFAOYSA-N diglycerol Chemical compound OCC(O)COCC(O)CO GPLRAVKSCUXZTP-UHFFFAOYSA-N 0.000 abstract 1
- 230000005611 electricity Effects 0.000 abstract 1
- 230000003068 static effect Effects 0.000 abstract 1
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 3
- 231100000331 toxic Toxicity 0.000 description 2
- 230000002588 toxic effect Effects 0.000 description 2
- 235000019504 cigarettes Nutrition 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000004332 deodorization Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000012855 volatile organic compound Substances 0.000 description 1
Abstract
The invention relates to the field of environment-friendly printing ink research, and concretely relates to antistatic environment-friendly printing ink prepared by reutilizing waste plant oil residue. The printing ink is prepared from the following raw materials in parts by weight: 1-2 parts of phosphorus pentoxide, 8-11 parts of an environment-friendly pigment, 2-4 parts of ethylene glycol distearate, 4-6 parts of diglycerol, 8-10 parts of dodecyl 2-methylacrylate, 20-26 parts of polyvinyl butyral resin, 1-3 parts of waste plant oil residue, 10-14 parts of n-butanol, 12-18 parts of 2-butoxyethanol, proper amount of bleaching earth, and 1-2 parts of an auxiliary agent. The printing ink does not contain toluene and acetone solvents, and is environment-friendly and low toxicity. By utilizing bleaching earth containing phosphorus pentoxide to perform deodorizing, decoloring, impurity removal and drying processing on waste plant oil residue in the production technology, the purposes of reducing production cost and reutilizing resource are reached, and by combining other compositions, the printing ink possesses excellent printing adaptability, and also is strong in bonding capability with a base material. A coating surface is provided with hidden pearl and is good in decoration effect, static electricity is not easy to generate, the production technology is simple, and the printing process is efficient.
Description
Technical field
The present invention relates to a kind of environment-friendly ink, be specifically related to a kind of anti-electrostatic environment-friendly ink of huge profit waste vegetable oil pin.
Background technology
Ink is widely used in printing industry, it is mainly by resin, pigment, solvent, the compositions such as auxiliary agent are formed, the ink major part that current printing industry uses is solvent type ink, this kind of ink can give out VOCs human body and environment being had to harm, some ink that is direct and human contact may work the mischief to health, some objectionable impurities even can penetrate into food by packaging, in the packing material such as cigarette and medicine, therefore the most important thing that feature of environmental protection ink is Future Development is developed, fundamentally to improve the feature of environmental protection of ink, need to set about from change ink formulations, Novel environment-friendlymaterial material is adopted to replace conventional toxic objectionable constituent, obtain gratifying rate of drying simultaneously, use properties and good printing adaptability.
Summary of the invention
The object of the invention is to, provide a kind of anti-electrostatic environment-friendly ink of huge profit waste vegetable oil pin, to achieve these goals, the technical solution used in the present invention is as follows:
A kind of anti-electrostatic environment-friendly ink of huge profit waste vegetable oil pin, it is characterized in that, this ink is made up of the raw material of following weight part: Vanadium Pentoxide in FLAKES 1-2, environmental-friendly pigment 8-11, stearic acid diethylene glycol dilaurate 2-4, contracting two glycerol 4-6, a lauryl methacrylate(LMA) 8-10, polyvinyl butyral resin 20-26, waste vegetable oil pin 1-3, propyl carbinol 10-14, butyl glycol ether 12-18, Fuller's earth are appropriate, auxiliary agent 1-2;
Described auxiliary agent is made up of the raw material of following weight part: propylene glycol phenylate 4-5, oxidized polyethlene wax 5-8, Ethylene glycol dimethacrylate 2-3, deionized water 15-18, Sodium dodecylbenzene sulfonate 1-3, ethylene glycol monomethyl ether 2-3, preparation method is: first oxidized polyethlene wax is heated to molten state, then dropwise Ethylene glycol dimethacrylate is added, do not stop to stir with the speed of 800-1000 rev/min in dropping process, after dropwising, constant temperature keeps 20-30min for subsequent use, again other remaining component is mixed with deionized water, after each composition dissolves completely, solution is heated to boiling, gained aqueous phase solution makes stable emulsion with oxidized polyethlene wax-dimethacrylate ethanol ester mixture mix and blend again.
The anti-electrostatic environment-friendly ink of described a kind of huge profit waste vegetable oil pin, its preparation process is: first Fuller's earth being dropped into the concentration prepared by Vanadium Pentoxide in FLAKES is disperse completely in the 4-5% aqueous solution, cryodrying after immersion 2-3h, and utilize that the powder of gained decolours to waste vegetable oil pin, drying treatment, waste vegetable oil pin after process mixes with other remaining component, drop into grinding machine for grinding after high-speed stirring dispersion 30-50min, to particle diameter≤10 μm of gained slurry, to obtain final product.
First the advantage of ink of the present invention is its feature of environmental protection, the solvent low toxic and environment-friendly of employing, and not containing benzene, ketones solvent, other raw material is also to human body and environment is nontoxic or the composition of low toxicity, waste vegetable oil pin in raw material is waste common in productive life, in order to avoid the wasting of resources, the present invention utilizes the Fuller's earth containing Vanadium Pentoxide in FLAKES to carry out deodorization to waste vegetable oil pin, decolouring, impurity elimination, drying treatment, thus can be used in combination in resin emulsion, reach the object reducing production cost, be combined with drying aid again, accelerate auxiliary agent and other composition of film forming effect, make ink of the present invention compared with currently available products, not only have excellent printing adaptability, and it is strong with the viscosifying power of base material, coatingsurface implies pearly-lustre, good decorating effect, not easily produce electrostatic, production technique is simple, print processing efficient.
Embodiment
Embodiment
Ink prepared by the present embodiment is made up of the raw material of following weight part: Vanadium Pentoxide in FLAKES 1, environmental-friendly pigment 9, stearic acid diethylene glycol dilaurate 3, contracting two glycerol 5, lauryl methacrylate(LMA) 10, polyvinyl butyral resin 23, waste vegetable oil pin 3, propyl carbinol 12, butyl glycol ether 18, Fuller's earth are appropriate, auxiliary agent 2.
Wherein auxiliary agent is made up of the raw material of following weight part: propylene glycol phenylate 5, oxidized polyethlene wax 8, Ethylene glycol dimethacrylate 3, deionized water 18, Sodium dodecylbenzene sulfonate 1, ethylene glycol monomethyl ether 2, preparation method is: first oxidized polyethlene wax is heated to molten state, then dropwise Ethylene glycol dimethacrylate is added, do not stop to stir with the speed of 1000 revs/min in dropping process, after dropwising, constant temperature keeps 30min for subsequent use, again other remaining component is mixed with deionized water, after each composition dissolves completely, solution is heated to boiling, gained aqueous phase solution makes stable emulsion with oxidized polyethlene wax-dimethacrylate ethanol ester mixture mix and blend again.
The preparation process of this printing-ink is: first Fuller's earth being dropped into the concentration prepared by Vanadium Pentoxide in FLAKES is disperse completely in 5% aqueous solution, cryodrying after immersion 3h, and utilize that the powder of gained decolours to waste vegetable oil pin, drying treatment, waste vegetable oil pin after process mixes with other remaining component, grinding machine for grinding is dropped into after high-speed stirring dispersion 50min, to particle diameter≤10 μm of gained slurry, to obtain final product.
By the ink printing obtained by the present embodiment on PET plate, after its complete drying, according to corresponding national examination criteria, this ink in the performance test results of substrate surface is:
Claims (2)
1. the huge profit anti-electrostatic environment-friendly ink of waste vegetable oil pin, it is characterized in that, this printing-ink is made up of the raw material of following weight part: Vanadium Pentoxide in FLAKES 1-2, environmental-friendly pigment 8-11, stearic acid diethylene glycol dilaurate 2-4, contracting two glycerol 4-6, a lauryl methacrylate(LMA) 8-10, polyvinyl butyral resin 20-26, waste vegetable oil pin 1-3, propyl carbinol 10-14, butyl glycol ether 12-18, Fuller's earth are appropriate, auxiliary agent 1-2;
Described auxiliary agent is made up of the raw material of following weight part: propylene glycol phenylate 4-5, oxidized polyethlene wax 5-8, Ethylene glycol dimethacrylate 2-3, deionized water 15-18, Sodium dodecylbenzene sulfonate 1-3, ethylene glycol monomethyl ether 2-3, preparation method is: first oxidized polyethlene wax is heated to molten state, then dropwise Ethylene glycol dimethacrylate is added, do not stop to stir with the speed of 800-1000 rev/min in dropping process, after dropwising, constant temperature keeps 20-30min for subsequent use, again other remaining component is mixed with deionized water, after each composition dissolves completely, solution is heated to boiling, gained aqueous phase solution makes stable emulsion with oxidized polyethlene wax-dimethacrylate ethanol ester mixture mix and blend again.
2. the anti-electrostatic environment-friendly ink of a kind of huge profit waste vegetable oil pin as claimed in claim 1, its preparation process is: first Fuller's earth being dropped into the concentration prepared by Vanadium Pentoxide in FLAKES is disperse completely in the 4-5% aqueous solution, cryodrying after immersion 2-3h, and utilize that the powder of gained decolours to waste vegetable oil pin, drying treatment, waste vegetable oil pin after process mixes with other remaining component, grinding machine for grinding is dropped into after high-speed stirring dispersion 30-50min, to particle diameter≤10 μm of gained slurry, to obtain final product.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201410445760.3A CN104250470B (en) | 2014-09-03 | 2014-09-03 | The antistatic environment-friendly ink of waste vegetable oil pin for a kind of huge profit |
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CN201410445760.3A CN104250470B (en) | 2014-09-03 | 2014-09-03 | The antistatic environment-friendly ink of waste vegetable oil pin for a kind of huge profit |
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CN104250470A true CN104250470A (en) | 2014-12-31 |
CN104250470B CN104250470B (en) | 2016-05-18 |
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Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1077470A (en) * | 1993-05-20 | 1993-10-20 | 清华大学 | The adhesion promoter that is used for photosensitive solder resist |
JPH08120206A (en) * | 1994-10-21 | 1996-05-14 | Tombow Pencil Co Ltd | Fluorescent ink composition for water-based ballpoint pen |
KR20020058117A (en) * | 2000-12-29 | 2002-07-12 | 민태영 | Near-infrared absorber, method for preparing same and ink including same |
US20050282928A1 (en) * | 2004-06-21 | 2005-12-22 | Tyau-Jeen Lin | Ink jet ink |
CN1810895A (en) * | 2005-09-09 | 2006-08-02 | 诸城市腾霞油墨有限公司 | Environment protection plastic printing ink and its prepn |
CN103725085A (en) * | 2013-12-26 | 2014-04-16 | 中山大学 | Stereoscopic offset printing ink prepared by using waste vegetable oil foots as well as preparation method and application of stereoscopic offset printing ink |
-
2014
- 2014-09-03 CN CN201410445760.3A patent/CN104250470B/en active Active
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1077470A (en) * | 1993-05-20 | 1993-10-20 | 清华大学 | The adhesion promoter that is used for photosensitive solder resist |
JPH08120206A (en) * | 1994-10-21 | 1996-05-14 | Tombow Pencil Co Ltd | Fluorescent ink composition for water-based ballpoint pen |
KR20020058117A (en) * | 2000-12-29 | 2002-07-12 | 민태영 | Near-infrared absorber, method for preparing same and ink including same |
US20050282928A1 (en) * | 2004-06-21 | 2005-12-22 | Tyau-Jeen Lin | Ink jet ink |
CN1810895A (en) * | 2005-09-09 | 2006-08-02 | 诸城市腾霞油墨有限公司 | Environment protection plastic printing ink and its prepn |
CN103725085A (en) * | 2013-12-26 | 2014-04-16 | 中山大学 | Stereoscopic offset printing ink prepared by using waste vegetable oil foots as well as preparation method and application of stereoscopic offset printing ink |
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Publication number | Publication date |
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CN104250470B (en) | 2016-05-18 |
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TR01 | Transfer of patent right |
Effective date of registration: 20240326 Address after: 215000 Xuexing Industrial Concentration Zone, Lianshui Economic Development Zone, Huai'an City, Jiangsu Province Patentee after: Jiangsu Shoufu Ink Co.,Ltd. Country or region after: China Address before: No.10 Xiangrong Road, Chahe Industrial Park, Lai'an County, Chuzhou City, Anhui Province, 239200 Patentee before: ANHUI YAMEI INK CO.,LTD. Country or region before: China |
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TR01 | Transfer of patent right |