CN104356751A - Nano barium titanate coated alkyd resin type printing ink - Google Patents
Nano barium titanate coated alkyd resin type printing ink Download PDFInfo
- Publication number
- CN104356751A CN104356751A CN201410541210.1A CN201410541210A CN104356751A CN 104356751 A CN104356751 A CN 104356751A CN 201410541210 A CN201410541210 A CN 201410541210A CN 104356751 A CN104356751 A CN 104356751A
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- Prior art keywords
- parts
- printing ink
- nano barium
- barium titanate
- ink
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
- C09D11/104—Polyesters
- C09D11/105—Alkyd resins
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
- C09D11/104—Polyesters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention relates to the field of printing ink, in particular to nano barium titanate coated alkyd resin type printing ink. The printing ink is prepared by raw materials in parts by weight as follows: 2-4 parts of polymethyl methacrylate, 1-3 parts of nano barium titanate, 6-10 parts of PLGA (poly(lactic-co-glycolic acid) copolymer, 1-2 parts of oleic acid, 15-20 parts of proprylene glycol monomethyl ether, 8-24 parts of alkyd resin, 10-12 parts of ethyl acetate, 4-5 parts of absolute ethyl alcohol, 2-5 parts of alumina gel, 10-15 parts of a pigment and 1-2 parts of an assistant. The printing ink takes a mixture of the alkyd resin and the PLGA copolymer as a vehicle, has excellent adhesion and is good in compatibility with all components; nano barium titanate after dispersion treatment by an alumina gel alcoholic solution is uniformly dispersed in a resin solution more easily, so that the hardness and heat resistance of a coating are improved, the wettability of the printing ink can be improved by the assistant, and coating bubbles are avoided and prevented from affecting the decoration effect; and the printing ink has good printability in an actual use process and can be prevented from decoloration and shading for a long time at higher environment temperature.
Description
Technical field
The present invention relates to printing-ink field, be specifically related to a kind of Synolac type ink of clad nano barium titanate.
Background technology
Ink is a class coloured material very conventional in daily life, it is by the mode of the printing carrier as word and pattern, it is the gluey fluid of a kind of stickiness, be widely used in the various printings such as books and periodicals, packing and decorating, building decoration, along with social demand increases, ink kind and output is respective extension and growth also, improves the use properties of ink, and the production model reaching efficient energy-saving is the inevitable direction of following ink development all the time.
The factor affecting the use properties of ink is mainly the performance of the moietys such as pigment, low-melting ink vehicle, stopping composition and auxiliary agent, and such as pigment affects weather resistance and the tinting strength of ink; Low-melting ink vehicle directly affects set speed, the rate of drying and printing quality etc. of ink.Therefore, improve the use properties of ink, the performance from improving these compositions is needed to set about, improve the consistency between each raw material simultaneously, reach collaborative effect promoted, thus improve existing ink ubiquitous heap ink, fall the problems such as printing quality such as version, scumming, dirty version, set-off, to enhance productivity, avoid the waste of resource.
Summary of the invention
The object of the invention is to, provide a kind of Synolac type ink of clad nano barium titanate, to achieve these goals, the technical solution used in the present invention is as follows:
A kind of Synolac type ink of clad nano barium titanate, it is characterized in that, this ink is made up of the raw material of following weight part: polymethylmethacrylate 2-4, nano barium phthalate 1-3, Poly(D,L-lactide-co-glycolide 6-10, zinc oleate 1-2, propylene glycol monomethyl ether 15-20, Synolac 18-24, ethyl acetate 10-12, dehydrated alcohol 4-5, alumina gel agent 2-5, pigment 10-15, auxiliary agent 1-2;
The raw material of following weight part is comprised: trolamine 0.1-0.2, alumina sol 4-6, microfine diatomaceous 1-2, limonene 1-2, dehydrated alcohol 3-5, nano rare earth cerium colloidal sol 0.2-0.4 in described auxiliary agent, preparation method is: first by trolamine, the abundant stirring and dissolving of limonene in dehydrated alcohol, add microfine diatomaceous subsequently, after ground and mixed 30-40min, gained pulp concentration is dry, the powder obtained mixes with alumina sol, nano rare earth cerium colloidal sol again, after complete dispersed with stirring is even.
The Synolac type ink of described a kind of clad nano barium titanate, its preparation method is: be first dispersed in dehydrated alcohol by nano barium phthalate, alumina gel agent, and add pigment, mixed grinding 20-30min, mix with other remaining component subsequently, continue to be stirred to material and dissolve dispersion completely, then dropped in sand mill and fully grind, make the particle diameter of gained slurry be≤20 μm, to obtain final product.
Ink prepared by the present invention is using Synolac, Poly(D,L-lactide-co-glycolide mixing as low-melting ink vehicle, there is excellent cohesive force, good with each component compatibility, have good glossiness and toughness, the nano barium phthalate after alumina gel agent alcoholic solution dispersion treatment, is more easily dispersed in resin solution, thus improve the use properties of ink, the hardness of effective raising coating and resistance toheat, the auxiliary agent of interpolation can improve the wettability of ink, prevents coating bubbles and affects decorative effect; Ink of the present invention in actual use printing adaptability is good, difficult drop-off after ink setting, at higher ambient temperatures still can the dizzy dye of nondiscoloration for a long time.
Embodiment
Embodiment
Printing-ink prepared by the present embodiment is made up of the raw material of following weight part: polymethylmethacrylate 2, nano barium phthalate 2, Poly(D,L-lactide-co-glycolide 8, zinc oleate 1, propylene glycol monomethyl ether 20, Synolac 20, ethyl acetate 10, dehydrated alcohol 5, alumina gel agent 3, pigment 12, auxiliary agent 2; Wherein auxiliary agent is made up of the raw material of following weight part: trolamine 0.1, alumina sol 4, microfine diatomaceous 1, limonene 2, dehydrated alcohol 5, nano rare earth cerium colloidal sol 0.2, preparation method is: first by trolamine, the abundant stirring and dissolving of limonene in dehydrated alcohol, add microfine diatomaceous subsequently, after ground and mixed 30min, gained pulp concentration is dry, the powder obtained mixes with alumina sol, nano rare earth cerium colloidal sol again, after complete dispersed with stirring is even.
The preparation method of this printing-ink is: be first dispersed in dehydrated alcohol by nano barium phthalate, alumina gel agent, and add pigment, mixed grinding 30min, mix with other remaining component subsequently, continue to be stirred to material and dissolve dispersion completely, dropped in sand mill again and fully ground, make the particle diameter of gained slurry be≤20 μm, to obtain final product.
By the ink printing obtained by the present embodiment on PE film, after its complete drying, this ink in the performance test results of substrate surface is:
Above-mentioned test is all followed relevant criterion and is carried out.
Claims (2)
1. the Synolac type ink of a clad nano barium titanate, it is characterized in that, this printing-ink is made up of the raw material of following weight part: polymethylmethacrylate 2-4, nano barium phthalate 1-3, Poly(D,L-lactide-co-glycolide 6-10, zinc oleate 1-2, propylene glycol monomethyl ether 15-20, Synolac 18-24, ethyl acetate 10-12, dehydrated alcohol 4-5, alumina gel agent 2-5, pigment 10-15, auxiliary agent 1-2;
Described auxiliary agent is made up of the raw material of following weight part: trolamine 0.1-0.2, alumina sol 4-6, microfine diatomaceous 1-2, limonene 1-2, dehydrated alcohol 3-5, nano rare earth cerium colloidal sol 0.2-0.4, preparation method is: first by trolamine, the abundant stirring and dissolving of limonene in dehydrated alcohol, add microfine diatomaceous subsequently, after ground and mixed 30-40min, gained pulp concentration is dry, the powder obtained mixes with alumina sol, nano rare earth cerium colloidal sol again, after complete dispersed with stirring is even.
2. the Synolac type ink of a kind of clad nano barium titanate as claimed in claim 1, its preparation method is: be first dispersed in dehydrated alcohol by nano barium phthalate, alumina gel agent, and add pigment, mixed grinding 20-30min, mix with other remaining component subsequently, continue to be stirred to material and dissolve dispersion completely, then dropped in sand mill and fully grind, make the particle diameter of gained slurry be≤20 μm, to obtain final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410541210.1A CN104356751A (en) | 2014-10-14 | 2014-10-14 | Nano barium titanate coated alkyd resin type printing ink |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410541210.1A CN104356751A (en) | 2014-10-14 | 2014-10-14 | Nano barium titanate coated alkyd resin type printing ink |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104356751A true CN104356751A (en) | 2015-02-18 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410541210.1A Pending CN104356751A (en) | 2014-10-14 | 2014-10-14 | Nano barium titanate coated alkyd resin type printing ink |
Country Status (1)
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| CN (1) | CN104356751A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2616151C1 (en) * | 2016-02-18 | 2017-04-12 | Федеральное государственное автономное образовательное учреждение высшего профессионального образования "Санкт-Петербургский национальный исследовательский университет информационных технологий, механики и оптики" (Университет ИТМО) | Method of ink-jet printing with colorless sol-gel ink of iridescent holographic images on holographic paper or micro-embossed surface and printed product with iridescent holographic images |
| CN106565916A (en) * | 2016-10-26 | 2017-04-19 | 章功国 | Polymer cladding dielectric material and preparing method thereof |
| CN108822618A (en) * | 2018-05-25 | 2018-11-16 | 安徽猛牛彩印包装有限公司 | A kind of printing ink improving heat-resistant stability |
| CN108912881A (en) * | 2018-05-17 | 2018-11-30 | 阜南县海源工艺品有限公司 | A kind of bamboo product surface anticorrosion coating |
| CN114015285A (en) * | 2021-12-01 | 2022-02-08 | 慈溪市美臣文具有限公司 | Oil-stain-resistant ink, preparation process thereof and oil-stain-resistant writing pen |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101880485A (en) * | 2010-07-09 | 2010-11-10 | 重庆航利实业有限责任公司 | Rare-earth sol modified composite zinc-aluminum low-temperature sintered coating slurry |
| CN102659152A (en) * | 2012-04-24 | 2012-09-12 | 上海应用技术学院 | Method for preparing nanometer alumina slurry with good water dispersibility |
| CN103992692A (en) * | 2014-06-04 | 2014-08-20 | 苏州宇希新材料科技有限公司 | Scratch-resistant UV-cured light conducting ink |
-
2014
- 2014-10-14 CN CN201410541210.1A patent/CN104356751A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101880485A (en) * | 2010-07-09 | 2010-11-10 | 重庆航利实业有限责任公司 | Rare-earth sol modified composite zinc-aluminum low-temperature sintered coating slurry |
| CN102659152A (en) * | 2012-04-24 | 2012-09-12 | 上海应用技术学院 | Method for preparing nanometer alumina slurry with good water dispersibility |
| CN103992692A (en) * | 2014-06-04 | 2014-08-20 | 苏州宇希新材料科技有限公司 | Scratch-resistant UV-cured light conducting ink |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2616151C1 (en) * | 2016-02-18 | 2017-04-12 | Федеральное государственное автономное образовательное учреждение высшего профессионального образования "Санкт-Петербургский национальный исследовательский университет информационных технологий, механики и оптики" (Университет ИТМО) | Method of ink-jet printing with colorless sol-gel ink of iridescent holographic images on holographic paper or micro-embossed surface and printed product with iridescent holographic images |
| CN106565916A (en) * | 2016-10-26 | 2017-04-19 | 章功国 | Polymer cladding dielectric material and preparing method thereof |
| CN108912881A (en) * | 2018-05-17 | 2018-11-30 | 阜南县海源工艺品有限公司 | A kind of bamboo product surface anticorrosion coating |
| CN108822618A (en) * | 2018-05-25 | 2018-11-16 | 安徽猛牛彩印包装有限公司 | A kind of printing ink improving heat-resistant stability |
| CN114015285A (en) * | 2021-12-01 | 2022-02-08 | 慈溪市美臣文具有限公司 | Oil-stain-resistant ink, preparation process thereof and oil-stain-resistant writing pen |
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Application publication date: 20150218 |
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| RJ01 | Rejection of invention patent application after publication |