CN104629533A - Fine ink with anti-rust effect for water-borne metal printing - Google Patents
Fine ink with anti-rust effect for water-borne metal printing Download PDFInfo
- Publication number
- CN104629533A CN104629533A CN201510032467.9A CN201510032467A CN104629533A CN 104629533 A CN104629533 A CN 104629533A CN 201510032467 A CN201510032467 A CN 201510032467A CN 104629533 A CN104629533 A CN 104629533A
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- CN
- China
- Prior art keywords
- water
- parts
- ink
- printing
- deionized water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
Abstract
The invention relates to the field of printing ink, and particularly relates to fine ink with an anti-rust effect for water-borne metal printing. The ink is prepared from the following raw materials in parts by weight: 0.5-1 part of magnesium picolinate, 3-5 parts of songhua stone powder, 2-3 parts of gamma-ureidopropyltrimethoxysilane, 3-5 parts of fumaric acid, 5-8 parts of water-based polishing oil, 32-40 parts of water-based acrylic resin emulsion with solid content of 45-60 percent, 10-18 parts of pigment, 1-2 parts of sodium laureth sulfate, 15-25 parts of deionized water and 1-2 parts of auxiliary. The printing ink has high drying speed, strong metal adhesion capability, reliable hardness, fine texture, water proofing, oil resistance and certain anti-rust capability; the auxiliary is beneficial to wettability of ink, bubbles of a coating can be prevented; and the ink feels fine, is low in toxicity and environment-friendly, has bright and durable patterns, is convenient to print without screen blockage, can be used for preventing corrosion of the metal surface, and has excellent printing and using performances.
Description
Technical field
The present invention relates to printing-ink field, be specifically related to the water-based metal printing ink that a kind of exquisiteness has antirust effect.
Background technology
Ink is a class coloured material very conventional in daily life, it is by the mode of the printing carrier as word and pattern, it is the gluey fluid of a kind of stickiness, be widely used in the various printings such as books and periodicals, packing and decorating, building decoration, along with social demand increases, ink kind and output is respective extension and growth also, improves the use properties of ink, and the production model reaching efficient energy-saving is the inevitable direction of following ink development all the time.
The factor affecting the use properties of ink is mainly the performance of the moietys such as pigment, low-melting ink vehicle, stopping composition and auxiliary agent, and such as pigment affects weather resistance and the tinting strength of ink; Low-melting ink vehicle directly affects set speed, the rate of drying and printing quality etc. of ink.Therefore, improve the use properties of ink, the performance from improving these compositions is needed to set about, improve the consistency between each raw material simultaneously, reach collaborative effect promoted, thus improve existing ink ubiquitous heap ink, fall the problems such as printing quality such as version, scumming, dirty version, set-off, to enhance productivity, avoid the waste of resource.
Summary of the invention
The object of the invention is to, provide the water-based metal printing ink that a kind of exquisiteness has antirust effect, to achieve these goals, the technical solution used in the present invention is as follows:
A kind of exquisiteness has the water-based metal printing ink of antirust effect, it is characterized in that, this ink is made up of the raw material of following weight part: pyridine carboxylic acid magnesium 0.5-1, preserved egg stone flour 3-5, urea propyl trimethoxy silicane 2-3, fumaric acid 3-5, water-based gloss oil 5-8, solid content are water based acrylic resin emulsion 32-40, the pigment 10-18 of 45-60%, laureth sodium sulfovinate 1-2, deionized water 15-25, auxiliary agent 1-2;
The raw material of following weight part is comprised: polymine 1-2 in described auxiliary agent, Triethylene glycol 0.5-0.8, trimethyl benzyl ammonia chloride 0.1-0.2, silicon sol 5-8, microfine diatomaceous 1-3, deionized water is appropriate, preparation method is: be first dissolved in by polymine in appropriate deionized water, be mixed with the solution of 20-30%, add Triethylene glycol again, trimethyl benzyl ammonia chloride, be stirred to after it dissolves completely and drop into microfine diatomaceous, after ground and mixed 30-40min, gained pulp concentration is dry, the powder obtained mixes with silicon sol again, complete dispersed with stirring evenly after and get final product.
Described a kind of exquisiteness has the water-based metal printing ink of antirust effect, its preparation method is: first by after preserved egg stone flour, pigment and urea propyl trimethoxy silicane mixed grinding 30-50min, drop in deionized water, and add laureth sodium sulfovinate, pyridine carboxylic acid magnesium, fumaric acid, after dispersed with stirring 60-80min, mix with other remaining component and be heated to 50-60 DEG C, leave standstill 20-30min, regulate mixture pH in neutral again, fully grinding in last all inputs sand mill, make the particle diameter of gained slurry be≤20 μm, to obtain final product.
Ink prepared by the present invention is using water based acrylic resin emulsion as low-melting ink vehicle, rate of drying is fast, adhesive ability is strong, hardness is reliable, with the preserved egg stone flour after urea propyl trimethoxy silicane mixed grinding and pigment, quality is fine and smooth, and waterproof oil resistant and antirust ability strengthen, auxiliary agent contributes to the wettability improving ink, prevents coating bubbles.This ink feel is fine and smooth, low toxic and environment-friendly, fast drying, and with metal adhere firmly, pattern light durable, the convenient not network blocking of printing, can also prevent metallic surface corrosion, have good printing and use properties.
Embodiment
Embodiment
Printing-ink prepared by the present embodiment is made up of the raw material of following weight part: pyridine carboxylic acid magnesium 0.5, preserved egg stone flour 5, urea propyl trimethoxy silicane 3, fumaric acid 3, water-based gloss oil 6, solid content are water based acrylic resin emulsion 34, pigment 14, laureth sodium sulfovinate 2, deionized water 25, the auxiliary agent 1 of 60%; Wherein auxiliary agent is made up of the raw material of following weight part: polymine 1, Triethylene glycol 0.5, trimethyl benzyl ammonia chloride 0.1, silicon sol 6, microfine diatomaceous 2, deionized water is appropriate, preparation method is: be first dissolved in by polymine in appropriate deionized water, be mixed with the solution of 30%, add Triethylene glycol, trimethyl benzyl ammonia chloride again, be stirred to after it dissolves completely and drop into microfine diatomaceous, after ground and mixed 40min, gained pulp concentration is dry, the powder obtained mixes with silicon sol again, complete dispersed with stirring evenly after and get final product.
The preparation method of this printing-ink is: first by after preserved egg stone flour, pigment and urea propyl trimethoxy silicane mixed grinding 50min, drop in deionized water, and add laureth sodium sulfovinate, pyridine carboxylic acid magnesium, fumaric acid, after dispersed with stirring 70min, mix with other remaining component and be heated to 50-60 DEG C, leaving standstill 30min, regulate mixture pH in neutral again, fully grinding in last all inputs sand mill, makes the particle diameter of gained slurry be≤20 μm, to obtain final product.
By on the ink printing aluminium sheet obtained by the present embodiment, after its complete drying, the surface property test result of this ink is:
| Test item | Detected result |
| Tinting strength | 100 |
| Viscosity (s/25 DEG C) | 33.4 |
| Sticking power/% | ≥100 |
| First dryness (mm) | 23 |
| Glossiness (60 DEG C, specular gloss instrument) | ＞80 |
| Ethanol-tolerant, soda acid, water tolerance | Nondiscoloration, not come off |
Above-mentioned test is all followed relevant criterion and is carried out.
Claims (2)
1. an exquisiteness has the water-based metal printing ink of antirust effect, it is characterized in that, this printing-ink is made up of the raw material of following weight part: pyridine carboxylic acid magnesium 0.5-1, preserved egg stone flour 3-5, urea propyl trimethoxy silicane 2-3, fumaric acid 3-5, water-based gloss oil 5-8, solid content are water based acrylic resin emulsion 32-40, the pigment 10-18 of 45-60%, laureth sodium sulfovinate 1-2, deionized water 15-25, auxiliary agent 1-2;
Described auxiliary agent is made up of the raw material of following weight part: polymine 1-2, Triethylene glycol 0.5-0.8, trimethyl benzyl ammonia chloride 0.1-0.2, silicon sol 5-8, microfine diatomaceous 1-3, deionized water is appropriate, preparation method is: be first dissolved in by polymine in appropriate deionized water, be mixed with the solution of 20-30%, add Triethylene glycol again, trimethyl benzyl ammonia chloride, be stirred to after it dissolves completely and drop into microfine diatomaceous, after ground and mixed 30-40min, gained pulp concentration is dry, the powder obtained mixes with silicon sol again, complete dispersed with stirring evenly after and get final product.
2. a kind of exquisiteness as claimed in claim 1 has the water-based metal printing ink of antirust effect, its preparation method is: first by after preserved egg stone flour, pigment and urea propyl trimethoxy silicane mixed grinding 30-50min, drop in deionized water, and add laureth sodium sulfovinate, pyridine carboxylic acid magnesium, fumaric acid, after dispersed with stirring 60-80min, mix with other remaining component and be heated to 50-60 DEG C, leave standstill 20-30min, regulate mixture pH in neutral again, fully grinding in last all inputs sand mill, make the particle diameter of gained slurry be≤20 μm, to obtain final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510032467.9A CN104629533A (en) | 2015-01-22 | 2015-01-22 | Fine ink with anti-rust effect for water-borne metal printing |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510032467.9A CN104629533A (en) | 2015-01-22 | 2015-01-22 | Fine ink with anti-rust effect for water-borne metal printing |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104629533A true CN104629533A (en) | 2015-05-20 |
Family
ID=53208794
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510032467.9A Pending CN104629533A (en) | 2015-01-22 | 2015-01-22 | Fine ink with anti-rust effect for water-borne metal printing |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104629533A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109679401A (en) * | 2018-12-19 | 2019-04-26 | 王景泉 | A kind of metal surface LED cured printing ink matrix resin and preparation method thereof |
| CN112143266A (en) * | 2020-10-14 | 2020-12-29 | 吉林省春之元硅藻新材料科技有限公司 | Modified pine pollen environment-friendly coating and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101125977A (en) * | 2006-08-15 | 2008-02-20 | 东莞市英科水墨有限公司 | Water flexible painting plate ink and preparing method thereof |
| CN102911558A (en) * | 2012-11-07 | 2013-02-06 | 四川爱科新材料股份有限公司 | Fluorescent water-based ink and preparation method thereof |
| CN104263071A (en) * | 2014-09-09 | 2015-01-07 | 句容市给力包装制品厂 | Water-based gravure ink and preparation method thereof |
-
2015
- 2015-01-22 CN CN201510032467.9A patent/CN104629533A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101125977A (en) * | 2006-08-15 | 2008-02-20 | 东莞市英科水墨有限公司 | Water flexible painting plate ink and preparing method thereof |
| CN102911558A (en) * | 2012-11-07 | 2013-02-06 | 四川爱科新材料股份有限公司 | Fluorescent water-based ink and preparation method thereof |
| CN104263071A (en) * | 2014-09-09 | 2015-01-07 | 句容市给力包装制品厂 | Water-based gravure ink and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109679401A (en) * | 2018-12-19 | 2019-04-26 | 王景泉 | A kind of metal surface LED cured printing ink matrix resin and preparation method thereof |
| CN112143266A (en) * | 2020-10-14 | 2020-12-29 | 吉林省春之元硅藻新材料科技有限公司 | Modified pine pollen environment-friendly coating and preparation method thereof |
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| Date | Code | Title | Description |
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| C06 | Publication | ||
| PB01 | Publication | ||
| EXSB | Decision made by sipo to initiate substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20150520 |