CN104761949A - Antioxidation durably-bright environment-friendly water-based ink - Google Patents
Antioxidation durably-bright environment-friendly water-based ink Download PDFInfo
- Publication number
- CN104761949A CN104761949A CN201510137162.4A CN201510137162A CN104761949A CN 104761949 A CN104761949 A CN 104761949A CN 201510137162 A CN201510137162 A CN 201510137162A CN 104761949 A CN104761949 A CN 104761949A
- Authority
- CN
- China
- Prior art keywords
- parts
- ink
- water
- ethylene glycol
- deionized water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
- C09D11/037—Printing inks characterised by features other than the chemical nature of the binder characterised by the pigment
Abstract
The invention relates to the field of environment-friendly ink development, particularly an antioxidation durably-bright environment-friendly water-based ink which is prepared from the following raw materials in parts by weight: 1-3 parts of organobentonite, 0.5-1 part of polypropylene acyl dimethyl taurate, 0.01-0.02 part of epsilon-polylysine, 8-12 parts of environment-friendly pigment, 20-30 parts of deionized water, 3-5 parts of ethyl orthosilicate, 25-30 parts of water-based acrylic resin, 10-15 parts of ethylene glycol, 0.01-0.02 part of ascorbic acid-6-palmitate, 1-2 parts of 2,2,4-trimethyl-1,3-pentadiol monoisobutyrate film forming assistant and 1-2 parts of assistant. The ink is free of benzene and ketone organic solvents, has favorable antimicrobial and anticorrosive properties, and can postpone the oxidative stain. By combing the assistant and other components, compared with the existing products, the ink provided by the invention has the advantages of excellent printing adaptability, bright decoration effect and vivid and durable color, has certain waterproof and heat-resistant effects, and can be used for along time.
Description
Technical field
The present invention relates to a kind of environment-friendly ink, be specifically related to a kind of anti-oxidant lasting vivid type Environmental-protection water-based ink.
Background technology
Ink is widely used in printing industry, it is mainly by resin, pigment, solvent, the compositions such as auxiliary agent are formed, the ink major part that current printing industry uses is solvent type ink, this kind of ink can give out VOCs human body and environment being had to harm, some ink that is direct and human contact may work the mischief to health, some objectionable impurities even can penetrate into food by packaging, in the packing material such as cigarette and medicine, therefore the most important thing that feature of environmental protection ink is Future Development is developed, fundamentally to improve the feature of environmental protection of ink, need to set about from change ink formulations, Novel environment-friendlymaterial material is adopted to replace conventional toxic objectionable constituent, obtain gratifying rate of drying simultaneously, use properties and good printing adaptability.
Summary of the invention
The object of the invention is to, provide a kind of anti-oxidant lasting vivid type Environmental-protection water-based ink, to achieve these goals, the technical solution used in the present invention is as follows:
A kind of anti-oxidant lasting vivid type Environmental-protection water-based ink, it is characterized in that, this ink is made up of the raw material of following weight part: organobentonite 1-3, polypropylene acyl group dimethyltaurine ammonium 0.5-1, epsilon-polylysine 0.01-0.02, environmental-friendly pigment 8-12, deionized water 20-30, tetraethoxy 3-5, water-borne acrylic resin 25-30, ethylene glycol 10-15, xitix-6-palmitate 0.01-0.02, alcohol ester 12 film coalescence aid 1-2, auxiliary agent 1-2;
Described auxiliary agent is made up of the raw material of following weight part: propylene glycol phenylate 4-5, oxidized polyethlene wax 5-8, Ethylene glycol dimethacrylate 2-3, deionized water 15-18, Sodium dodecylbenzene sulfonate 1-3, ethylene glycol monomethyl ether 2-3, preparation method is: first oxidized polyethlene wax is heated to molten state, then dropwise Ethylene glycol dimethacrylate is added, do not stop to stir with the speed of 800-1000 rev/min in dropping process, after dropwising, constant temperature keeps 20-30min for subsequent use, again other remaining component is mixed with deionized water, after each composition dissolves completely, solution is heated to boiling, gained aqueous phase solution makes stable emulsion with oxidized polyethlene wax-dimethacrylate ethanol ester mixture mix and blend again.
The anti-oxidant lasting vivid type Environmental-protection water-based ink of described one; its preparation process is: be first dissolved in deionized water by polypropylene acyl group dimethyltaurine ammonium, epsilon-polylysine, xitix-6-palmitate; add environmental-friendly pigment subsequently; after dispersed with stirring 30-50min; add other remaining component, high-speed stirring dispersion 50-60min, gained mixture drops into grinding machine for grinding; to particle diameter≤10 μm of gained slurry, to obtain final product.
First the advantage of ink of the present invention is its feature of environmental protection, and use deionized water as medium, avoid the use of organic solvent, the raw material chosen also is to human body and environment is nontoxic or the composition of low toxicity; And pigment first processes with the mixed aqueous solution of the materials such as polypropylene acyl group dimethyltaurine ammonium, epsilon-polylysine, xitix-6-palmitate in raw material; improve the dispersiveness of pigment; give the performance of its Antimicrobial preservative; delay oxidation stain; be combined with drying aid, the auxiliary agent accelerating film forming effect and other composition again; make ink of the present invention compared with currently available products; not only have excellent printing adaptability; and it is more vivid brilliant at decorative effect; color is vividly lasting; have certain waterproof heat resistant effect concurrently, can use for a long time.
Embodiment
Embodiment
Ink prepared by the present embodiment is made up of the raw material of following weight part: organobentonite 2, polypropylene acyl group dimethyltaurine ammonium 1, epsilon-polylysine 0.01, environmental-friendly pigment 12, deionized water 30, tetraethoxy 5, water-borne acrylic resin 30, ethylene glycol 15, xitix-6-palmitate 0.01, alcohol ester 12 film coalescence aid 1, auxiliary agent 2.
Wherein auxiliary agent is made up of the raw material of following weight part: propylene glycol phenylate 5, oxidized polyethlene wax 8, Ethylene glycol dimethacrylate 3, deionized water 18, Sodium dodecylbenzene sulfonate 1, ethylene glycol monomethyl ether 2, preparation method is: first oxidized polyethlene wax is heated to molten state, then dropwise Ethylene glycol dimethacrylate is added, do not stop to stir with the speed of 1000 revs/min in dropping process, after dropwising, constant temperature keeps 30min for subsequent use, again other remaining component is mixed with deionized water, after each composition dissolves completely, solution is heated to boiling, gained aqueous phase solution makes stable emulsion with oxidized polyethlene wax-dimethacrylate ethanol ester mixture mix and blend again.
The preparation process of this printing-ink is: be first dissolved in deionized water by polypropylene acyl group dimethyltaurine ammonium, epsilon-polylysine, xitix-6-palmitate; add environmental-friendly pigment subsequently; after dispersed with stirring 30-50min; add other remaining component; high-speed stirring dispersion 50-60min; gained mixture drops into grinding machine for grinding, to particle diameter≤10 μm of gained slurry, to obtain final product.
By the ink printing obtained by the present embodiment on PET plate, after its complete drying, according to corresponding national examination criteria, this ink in the performance test results of substrate surface is:
| Test item | Detected result |
| Tinting strength | 100 |
| Viscosity (s/25 DEG C) | 32 |
| Sticking power/% | ≥98 |
| First dryness (mm) | 37 |
| Glossiness (60 DEG C, specular gloss instrument) | ＞80 |
| Ethanol-tolerant, soda acid, water tolerance | Nondiscoloration, not come off |
| Temperature classification | 4 |
Claims (2)
1. an anti-oxidant lasting vivid type Environmental-protection water-based ink, it is characterized in that, this printing-ink is made up of the raw material of following weight part: organobentonite 1-3,
polypropylene acyl group dimethyltaurine ammonium0.5-1, epsilon-polylysine 0.01-0.02, environmental-friendly pigment 8-12, deionized water 20-30, tetraethoxy 3-5, water-borne acrylic resin 25-30, ethylene glycol 10-15, xitix-6-palmitate 0.01-0.02, alcohol ester 12 film coalescence aid 1-2, auxiliary agent 1-2;
Described auxiliary agent is made up of the raw material of following weight part: propylene glycol phenylate 4-5, oxidized polyethlene wax 5-8, Ethylene glycol dimethacrylate 2-3, deionized water 15-18, Sodium dodecylbenzene sulfonate 1-3, ethylene glycol monomethyl ether 2-3, preparation method is: first oxidized polyethlene wax is heated to molten state, then dropwise Ethylene glycol dimethacrylate is added, do not stop to stir with the speed of 800-1000 rev/min in dropping process, after dropwising, constant temperature keeps 20-30min for subsequent use, again other remaining component is mixed with deionized water, after each composition dissolves completely, solution is heated to boiling, gained aqueous phase solution makes stable emulsion with oxidized polyethlene wax-dimethacrylate ethanol ester mixture mix and blend again.
2. a kind of anti-oxidant lasting vivid type Environmental-protection water-based ink as claimed in claim 1; its preparation process is: be first dissolved in deionized water by polypropylene acyl group dimethyltaurine ammonium, epsilon-polylysine, xitix-6-palmitate; add environmental-friendly pigment subsequently; after dispersed with stirring 30-50min; add other remaining component, high-speed stirring dispersion 50-60min, gained mixture drops into grinding machine for grinding; to particle diameter≤10 μm of gained slurry, to obtain final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510137162.4A CN104761949A (en) | 2015-03-26 | 2015-03-26 | Antioxidation durably-bright environment-friendly water-based ink |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510137162.4A CN104761949A (en) | 2015-03-26 | 2015-03-26 | Antioxidation durably-bright environment-friendly water-based ink |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104761949A true CN104761949A (en) | 2015-07-08 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510137162.4A Pending CN104761949A (en) | 2015-03-26 | 2015-03-26 | Antioxidation durably-bright environment-friendly water-based ink |
Country Status (1)
| Country | Link |
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| CN (1) | CN104761949A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110283494A (en) * | 2019-06-10 | 2019-09-27 | 浙江云岭数码科技有限公司 | A kind of ink and the printing technology using the ink |
| CN111501404A (en) * | 2020-04-28 | 2020-08-07 | 曲靖麒麟福牌印刷有限公司 | High-temperature-resistant antibacterial tipping paper gloss oil and preparation method thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104277579A (en) * | 2014-11-11 | 2015-01-14 | 合肥皖为电气设备工程有限责任公司 | Waterproof low-odor environment-friendly printing ink and preparation method thereof |
-
2015
- 2015-03-26 CN CN201510137162.4A patent/CN104761949A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104277579A (en) * | 2014-11-11 | 2015-01-14 | 合肥皖为电气设备工程有限责任公司 | Waterproof low-odor environment-friendly printing ink and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110283494A (en) * | 2019-06-10 | 2019-09-27 | 浙江云岭数码科技有限公司 | A kind of ink and the printing technology using the ink |
| CN111501404A (en) * | 2020-04-28 | 2020-08-07 | 曲靖麒麟福牌印刷有限公司 | High-temperature-resistant antibacterial tipping paper gloss oil and preparation method thereof |
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| C06 | Publication | ||
| PB01 | Publication | ||
| EXSB | Decision made by sipo to initiate substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20150708 |