CN104194469A - Antibacterial waterproof quick dry type water-based acrylic printing ink - Google Patents
Antibacterial waterproof quick dry type water-based acrylic printing ink Download PDFInfo
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- CN104194469A CN104194469A CN201410362512.2A CN201410362512A CN104194469A CN 104194469 A CN104194469 A CN 104194469A CN 201410362512 A CN201410362512 A CN 201410362512A CN 104194469 A CN104194469 A CN 104194469A
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Abstract
The invention relates to the field of printing inks, and particularly relates to an antibacterial waterproof quick dry type water-based acrylic printing ink. The ink is prepared from the following raw materials in parts by weight: 35-40 parts of water-based acrylic resin emulsion, 0.5-0.8 part of zinc pyrithione, 4-5 parts of bis(dimethylamino) ethylether, 2-5 parts of yellow cinnamon leaf, 1-2 parts of ammonium zirconium carbonate, 4-5 parts of bottom ash, 30-34 parts of deionized water, 10-12 parts of water-based pigment, 3-5 parts of hydroxyethyl cellulose and 2-4 parts of an assistant. The raw materials of the printing ink disclosed by the invention contain yellow cinnamon leaf water decoction, can give unique faint scent to the ink, and also has certain antimicrobial and antiseptic efficacies; after the pigment is mixed with bis(dimethylamino) ethyl ether, ammonium zirconium carbonate and the like, the dispersity can be improved; the stability is improved; the assistant has the efficacies of assisting ink drying and improving the printing property; and the prepared ink is strong in tinting strength, controllable in viscosity, quick to dry, strong in adhesive force, strong in bactericidal ability, safe and non-toxic, is not easily corroded by the external environment, and has an application prospect.
Description
Technical field
The present invention relates to printing-ink field, be specifically related to a kind of antibacterial waterproof quick-dry type water soluble acrylic acid printing-ink.
Background technology
Printing-ink is a kind of common printed matter coloured material, mainly formed by compositions such as pigment, low-melting ink vehicle, stopping composition, and be the pulpous state adherent that a class is coloured, have certain degree of mobilization.Want to obtain gratifying printing effect, color to ink in actual use procedure, printing adaptability, rate of drying has certain requirement, also to possess according to environment for use water-fast simultaneously, fast light, acid and alkali-resistance, the features such as low toxic and environment-friendly, following printing-ink developing direction must be towards low toxicity, quick-drying, the future development of the naturally various and multifunction of color, but the inadequate environmental protection of existing ink ubiquity, viscosity control inequality, the not good and good ink of the partial properties shortcoming such as hold at high price with base material sticking power, therefore, the composition and engineering of necessary improvement printing-ink, the transition of quickening industry, to reach the production model of high-efficiency environment friendly.
Summary of the invention
The object of the invention is to, a kind of antibacterial waterproof quick-dry type water soluble acrylic acid printing-ink is provided, to achieve these goals, the technical solution used in the present invention is as follows:
A kind of antibacterial waterproof quick-dry type water soluble acrylic acid printing-ink, it is characterized in that, this ink is made up of the raw material of following weight part: water-borne acrylic resin emulsion 35-40, Zinc Pyrithione 0.5-0.8, two dimethylaminoethyl ether 4-5, leaf of Yellow cinnamon 2-5, zirconium carbonate ammonium 1-2, the bottom of a pan ash 4-5, deionized water 30-34, water-based paint 10-12, Natvosol 3-5, auxiliary agent 2-4;
In described auxiliary agent, comprise the raw material of following weight part: emulsifier op-10 2-4,2-pyridine carboxylic acid 0.1-0.2, naphthenic acid rare earth 1-2, dehydrated alcohol 10-15, graphene oxide 5-8, preparation method is: first 2-pyridine carboxylic acid, naphthenic acid rare earth are added in dehydrated alcohol, after dispersed with stirring 20-30min, add again graphene oxide, mixture ball milling 1-2h after stirring, add subsequently other remaining component, continue to stir 20-30min, to obtain final product.
The solid content of described water-borne acrylic resin emulsion is 50-60%.
The antibacterial waterproof quick-dry type of described one water soluble acrylic acid printing-ink, its preparation method is as follows:
(1) first leaf of Yellow cinnamon is added in deionized water, after decoction 2-3h, filter, gained filtrate is cooled to after room temperature, drops into two dimethylaminoethyl ether, zirconium carbonate ammonium, the bottom of a pan ash and water-based paint, for subsequent use after mix and blend 1-2h;
(2) step (1) gained material is mixed with other remaining component, drop in homogenizer, after the rotating speed dispersed with stirring 60-80min of 1200-1500 rev/min, again compound is dropped into ball-milling processing in ball mill, the particle diameter that makes gained slurry is 5-20 μ m, and adjusting viscosity as required, to obtain final product.
Ink advantage prepared by the present invention is: the principle of first having followed low toxic and environment-friendly in the preparation of raw material, toxicity volatile organic content is low, harm to environment and human body is little, the decocting liquid of leaf of Yellow cinnamon has light delicate fragrance, also there is certain antibacterial preservative efficacy, after the compositions such as pigment and two dimethylaminoethyl ether, zirconium carbonate ammonium mix, can improve its dispersiveness, improve stability, the auxiliary agent of interpolation has auxiliary inks and is dried, improves the effects such as printing performance; Ink tinting strength prepared by the present invention is strong, and viscosity is controlled, fast dry, and strong adhesion is not subject to external environment corrosion, and sterilizing ability is strong, and safety non-toxic has application prospect.
Embodiment
Embodiment
Printing-ink prepared by the present embodiment is made up of the raw material of following weight part: water-borne acrylic resin emulsion 38, Zinc Pyrithione 0.5, two dimethylaminoethyl ether 4, leaf of Yellow cinnamon 4, zirconium carbonate ammonium 1, the bottom of a pan ash 4 deionized waters 34, water-based paint 12, Natvosol 5, auxiliary agent 4; Wherein auxiliary agent is made up of the raw material of following weight part: emulsifier op-10 4,2-pyridine carboxylic acid 0.1, naphthenic acid rare earth 2, dehydrated alcohol 15, graphene oxide 8, preparation method is: first 2-pyridine carboxylic acid, naphthenic acid rare earth are added in dehydrated alcohol, after dispersed with stirring 30min, add again graphene oxide, mixture ball milling 1h after stirring, add subsequently other remaining component, continue to stir 30min, to obtain final product.
The solid content of the water-borne acrylic resin emulsion adopting is 60%.
The preparation method of this printing-ink is as follows:
(1) first leaf of Yellow cinnamon is added in deionized water, after decoction 2h, filter, gained filtrate is cooled to after room temperature, drops into two dimethylaminoethyl ether, zirconium carbonate ammonium, the bottom of a pan ash and water-based paint, for subsequent use after mix and blend 2h;
(2) step (1) gained material is mixed with other remaining component, drop in homogenizer, after the rotating speed dispersed with stirring 60min of 1200 revs/min, then compound is dropped into ball-milling processing in ball mill, the particle diameter that makes gained slurry is 15 μ m, to obtain final product.
The performance test results of ink of the present invention is:
Test item | Detected result |
Form and aspect | Consistent with standard colour card |
Viscosity (No. 4 cups of coating, s/25 DEG C) | 22 |
Tinting strength (%) | 97.2 |
Just dryness (mm) | 18 |
Gloss (60 DEG C, specular gloss instrument) | 70.8% |
Attachment fastness (%) | 96.3 |
Acid and alkali-resistance, water tolerance | Well |
Package stability (5 DEG C-30 DEG C) | Well |
Above-mentioned test is all followed relevant criterion and is carried out.
Claims (3)
1. an antibacterial waterproof quick-dry type water soluble acrylic acid printing-ink, it is characterized in that, this printing-ink is made up of the raw material of following weight part: water-borne acrylic resin emulsion 35-40, Zinc Pyrithione 0.5-0.8, two dimethylaminoethyl ether 4-5, leaf of Yellow cinnamon 2-5, zirconium carbonate ammonium 1-2, the bottom of a pan ash 4-5, deionized water 30-34, water-based paint 10-12, Natvosol 3-5, auxiliary agent 2-4;
Described auxiliary agent is made up of the raw material of following weight part: emulsifier op-10 2-4,2-pyridine carboxylic acid 0.1-0.2, naphthenic acid rare earth 1-2, dehydrated alcohol 10-15, graphene oxide 5-8, preparation method is: first 2-pyridine carboxylic acid, naphthenic acid rare earth are added in dehydrated alcohol, after dispersed with stirring 20-30min, add again graphene oxide, mixture ball milling 1-2h after stirring, add subsequently other remaining component, continue to stir 20-30min, to obtain final product.
2. the antibacterial waterproof quick-dry type of one as claimed in claim 1 water soluble acrylic acid printing-ink, is characterized in that, the solid content of described water-borne acrylic resin emulsion is 50-60%.
3. the antibacterial waterproof quick-dry type of one as claimed in claim 1 water soluble acrylic acid printing-ink, its preparation method is as follows:
(1) first leaf of Yellow cinnamon is added in deionized water, after decoction 2-3h, filter, gained filtrate is cooled to after room temperature, drops into two dimethylaminoethyl ether, zirconium carbonate ammonium, the bottom of a pan ash and water-based paint, for subsequent use after mix and blend 1-2h;
(2) step (1) gained material is mixed with other remaining component, drop in homogenizer, after the rotating speed dispersed with stirring 60-80min of 1200-1500 rev/min, again compound is dropped into ball-milling processing in ball mill, the particle diameter that makes gained slurry is 5-20 μ m, and adjusting viscosity as required, to obtain final product.
Priority Applications (1)
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CN201410362512.2A CN104194469A (en) | 2014-07-28 | 2014-07-28 | Antibacterial waterproof quick dry type water-based acrylic printing ink |
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CN201410362512.2A CN104194469A (en) | 2014-07-28 | 2014-07-28 | Antibacterial waterproof quick dry type water-based acrylic printing ink |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105860709A (en) * | 2016-05-31 | 2016-08-17 | 无锡伊佩克科技有限公司 | Graphene oxide anti-corrosive paint and preparation method thereof |
US10696471B2 (en) | 2017-10-31 | 2020-06-30 | Medline Industries, Inc. | Enclosure for gloves with antimicrobial ink coating and methods for making the same |
Citations (7)
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CN1958687A (en) * | 2006-11-21 | 2007-05-09 | 祁育新 | Multifunctional prepared Chinese ink |
CN101519557A (en) * | 2009-04-10 | 2009-09-02 | 湖南沧海环保科技发展有限公司 | Method for multifunctional water-based ink |
CN102492332A (en) * | 2011-12-05 | 2012-06-13 | 天津市鸵鸟墨水有限公司 | Novel ink and production method thereof |
CN102925000A (en) * | 2012-11-06 | 2013-02-13 | 霍山县雁江印务有限公司 | High-gloss quick-drying skinning-free ink and preparation method thereof |
CN103275555A (en) * | 2013-05-31 | 2013-09-04 | 苏州凹凸彩印厂 | Quick-drying tin printing ink |
CN103555065A (en) * | 2013-11-18 | 2014-02-05 | 三友(天津)高分子技术有限公司 | Quick-drying type water-based ink-jet ink and preparation method thereof |
CN103555060A (en) * | 2013-10-30 | 2014-02-05 | 合肥市华美光电科技有限公司 | Quick-drying printing ink and preparation method thereof |
-
2014
- 2014-07-28 CN CN201410362512.2A patent/CN104194469A/en active Pending
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1958687A (en) * | 2006-11-21 | 2007-05-09 | 祁育新 | Multifunctional prepared Chinese ink |
CN101519557A (en) * | 2009-04-10 | 2009-09-02 | 湖南沧海环保科技发展有限公司 | Method for multifunctional water-based ink |
CN102492332A (en) * | 2011-12-05 | 2012-06-13 | 天津市鸵鸟墨水有限公司 | Novel ink and production method thereof |
CN102925000A (en) * | 2012-11-06 | 2013-02-13 | 霍山县雁江印务有限公司 | High-gloss quick-drying skinning-free ink and preparation method thereof |
CN103275555A (en) * | 2013-05-31 | 2013-09-04 | 苏州凹凸彩印厂 | Quick-drying tin printing ink |
CN103555060A (en) * | 2013-10-30 | 2014-02-05 | 合肥市华美光电科技有限公司 | Quick-drying printing ink and preparation method thereof |
CN103555065A (en) * | 2013-11-18 | 2014-02-05 | 三友(天津)高分子技术有限公司 | Quick-drying type water-based ink-jet ink and preparation method thereof |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105860709A (en) * | 2016-05-31 | 2016-08-17 | 无锡伊佩克科技有限公司 | Graphene oxide anti-corrosive paint and preparation method thereof |
US10696471B2 (en) | 2017-10-31 | 2020-06-30 | Medline Industries, Inc. | Enclosure for gloves with antimicrobial ink coating and methods for making the same |
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