CN104194484B - A kind of high gloss amino resins printing-ink containing spherical argentum powder - Google Patents
A kind of high gloss amino resins printing-ink containing spherical argentum powder Download PDFInfo
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- CN104194484B CN104194484B CN201410362533.4A CN201410362533A CN104194484B CN 104194484 B CN104194484 B CN 104194484B CN 201410362533 A CN201410362533 A CN 201410362533A CN 104194484 B CN104194484 B CN 104194484B
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- Prior art keywords
- ink
- printing
- amino resins
- argentum powder
- spherical argentum
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- 229920003180 amino resin Polymers 0.000 title claims abstract description 16
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 title claims abstract description 15
- 239000000843 powder Substances 0.000 title claims abstract description 15
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims abstract description 21
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 claims abstract description 18
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 9
- 239000002994 raw material Substances 0.000 claims abstract description 9
- 229910002012 Aerosil® Inorganic materials 0.000 claims abstract description 4
- OIFBSDVPJOWBCH-UHFFFAOYSA-N Diethyl carbonate Chemical compound CCOC(=O)OCC OIFBSDVPJOWBCH-UHFFFAOYSA-N 0.000 claims abstract description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 4
- ZSUAFFUECFTRFC-UHFFFAOYSA-N calcium;dodecanoic acid Chemical compound [Ca].CCCCCCCCCCCC(O)=O ZSUAFFUECFTRFC-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000010627 cedar oil Substances 0.000 claims abstract description 4
- 239000012860 organic pigment Substances 0.000 claims abstract description 4
- 239000000344 soap Substances 0.000 claims abstract description 4
- 239000007787 solid Substances 0.000 claims abstract description 4
- 238000003756 stirring Methods 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 7
- 238000002360 preparation method Methods 0.000 claims description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
- SIOXPEMLGUPBBT-UHFFFAOYSA-N Picolinic acid Natural products OC(=O)C1=CC=CC=N1 SIOXPEMLGUPBBT-UHFFFAOYSA-N 0.000 claims description 6
- 238000000498 ball milling Methods 0.000 claims description 6
- 229960000935 dehydrated alcohol Drugs 0.000 claims description 6
- 239000012467 final product Substances 0.000 claims description 6
- 229910021389 graphene Inorganic materials 0.000 claims description 6
- -1 naphthenic acid rare earth Chemical class 0.000 claims description 6
- 229910052761 rare earth metal Inorganic materials 0.000 claims description 6
- VXKWYPOMXBVZSJ-UHFFFAOYSA-N tetramethyltin Chemical compound C[Sn](C)(C)C VXKWYPOMXBVZSJ-UHFFFAOYSA-N 0.000 claims description 6
- 239000000463 material Substances 0.000 claims description 4
- 150000001875 compounds Chemical class 0.000 claims description 3
- 239000003995 emulsifying agent Substances 0.000 claims description 3
- 239000002245 particle Substances 0.000 claims description 3
- 239000002002 slurry Substances 0.000 claims description 3
- 238000001035 drying Methods 0.000 abstract description 4
- 231100000331 toxic Toxicity 0.000 abstract description 4
- 230000002588 toxic effect Effects 0.000 abstract description 4
- 230000007613 environmental effect Effects 0.000 abstract description 3
- 239000000049 pigment Substances 0.000 abstract description 3
- 239000000945 filler Substances 0.000 abstract description 2
- 238000009991 scouring Methods 0.000 abstract description 2
- 239000002253 acid Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 230000001464 adherent effect Effects 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000000549 coloured material Substances 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000036961 partial effect Effects 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Abstract
The present invention relates to printing-ink field, being specifically related to a kind of high gloss amino resins printing-ink containing spherical argentum powder, this ink is made up of the raw material of following weight portion: the Alumina gel 4-5 of solid content 10-15%, nano tin dioxide 1-2, Cedar oil 3-4, lauric acid calcium soap 1-3, spherical argentum powder 0.1-0.2, aerosil 3-5, ethyl acetate 30-40, organic pigment 12-14, amino resins 32-38, diethyl carbonate 5-8, auxiliary agent 2-4; The printing-ink low toxic and environment-friendly of the present invention, the harm of environment and human body is little, and the raw material such as Alumina gel, nano tin dioxide, spherical argentum powder can promote the hardness after ink setting, improves the dispersibility of pigment and filler, promote transparency and glossiness, the interpolation of auxiliary agent can improve rate of drying and the printing performance of ink, and ink adhesion prepared by the present invention is strong, and mass colour gloss becomes clear, wear-resistant scouring, being prone to printing, environmental resistance degree is high, long service life.
Description
Technical field
The present invention relates to printing-ink field, be specifically related to a kind of high gloss amino resins printing-ink containing spherical argentum powder.
Background technology
Printing-ink is a kind of common printed matter coloured material, is mainly made up of compositions such as pigment, link stuff, inserts, is the pulpous state adherent that a class is coloured, have certain fluidity. want to obtain gratifying printing effect, color to ink in actually used process, printing adaptability, rate of drying has certain requirement, simultaneously also will according to using environment to possess water-fast, fast light, acid and alkali-resistance, the features such as low toxic and environment-friendly, following printing-ink developing direction must be directed towards low toxicity, quick-drying, naturally various and multifunction the direction of color is developed, but the existing inadequate environmental protection of ink ubiquity, viscosity controls inequality, the shortcomings such as and partial properties good ink not good with base material adhesive force holds at high price, therefore, the formula of necessary improvement printing-ink and technique, the transition of quickening industry, to reach the production model of high-efficiency environment friendly.
Summary of the invention
It is an object of the invention to, it is provided that a kind of high gloss amino resins printing-ink containing spherical argentum powder, to obtain good printing effect, to achieve these goals, the technical solution used in the present invention is as follows:
A kind of high gloss amino resins printing-ink containing spherical argentum powder, it is characterized in that, this ink is made up of the raw material of following weight portion: the Alumina gel 4-5 of solid content 10-15%, nano tin dioxide 1-2, Cedar oil 3-4, lauric acid calcium soap 1-3, spherical argentum powder 0.1-0.2, aerosil 3-5, ethyl acetate 30-40, organic pigment 12-14, amino resins 32-38, diethyl carbonate 5-8, auxiliary agent 2-4;
Described auxiliary agent comprises the raw material of following weight portion: emulsifier op-10 2-4,2-pyridine carboxylic acid 0.1-0.2, naphthenic acid rare earth 1-2, dehydrated alcohol 10-15, graphene oxide 5-8, preparation method is: first add in dehydrated alcohol by 2-pyridine carboxylic acid, naphthenic acid rare earth, after dispersed with stirring 20-30min, add graphene oxide, mixed material ball milling 1-2h after stirring, it is subsequently added other residual components, continues stirring 20-30min, to obtain final product.
Described a kind of high gloss amino resins printing-ink containing spherical argentum powder, its preparation method is as follows: be first dissolved in ethyl acetate by amino resins, it is subsequently added Alumina gel, nano tin dioxide, after mix and blend 30-40min, add other residual components, after the rotating speed dispersed with stirring 1-2h of 1200-1500 rev/min, compound is put into ball-milling treatment in ball mill, the particle diameter making gained slurry is 5-20 μm, and regulates viscosity as required, to obtain final product.
Ink advantage prepared by the present invention is in that: first have followed the principle of low toxic and environment-friendly in the preparation of raw material, toxic volatile content of organics is low, the harm of environment and human body is little, the Alumina gel added, nano tin dioxide, spherical argentum powder, the hardness after ink setting can be promoted, improve the dispersibility of pigment and filler, promote transparency and glossiness, the interpolation of auxiliary agent can improve rate of drying and the printing performance of ink, ink adhesion prepared by the present invention is strong, mass colour gloss becomes clear, wear-resistant scouring, it is prone to printing, environmental resistance degree is high, long service life.
Detailed description of the invention
Embodiment
Printing-ink prepared by the present embodiment is made up of the raw material of following weight portion: the Alumina gel 4 of solid content 15%, nano tin dioxide 1, Cedar oil 4, lauric acid calcium soap 2, spherical argentum powder 0.1, aerosil 4, ethyl acetate 35, organic pigment 14, amino resins 38, diethyl carbonate 8, auxiliary agent 4; Wherein auxiliary agent is made up of the raw material of following weight portion: emulsifier op-10 4,2-pyridine carboxylic acid 0.1, naphthenic acid rare earth 2, dehydrated alcohol 15, graphene oxide 8, preparation method is: first add in dehydrated alcohol by 2-pyridine carboxylic acid, naphthenic acid rare earth, after dispersed with stirring 30min, add graphene oxide, mixed material ball milling 1h after stirring, it is subsequently added other residual components, continues stirring 30min, to obtain final product.
The preparation method of this printing-ink is as follows: be first dissolved in ethyl acetate by amino resins, it is subsequently added Alumina gel, nano tin dioxide, after mix and blend 40min, add other residual components, after the rotating speed dispersed with stirring 2h of 1200 revs/min, compound puts into ball-milling treatment in ball mill, and the particle diameter making gained slurry is 5 μm, to obtain final product.
The performance test results of ink of the present invention is:
| Detection project | Testing result |
| Form and aspect | Consistent with standard color card |
| Viscosity (No. 4 cups of coating, s/25 DEG C) | 25 |
| Tinting strength, tinting power (%) | 98.6 |
| First dryness (mm) | 16 |
| Gloss (60 DEG C of specular gloss instrument) | 78.3% |
| Attachment fastness (%) | 98.4 |
| Acid and alkali-resistance, resistance to water | Well |
| Bin stability (5 DEG C-30 DEG C) | Well |
Above-mentioned test is all followed relevant criterion and is carried out.
Claims (2)
1. the high gloss amino resins printing-ink containing spherical argentum powder, it is characterized in that, this printing-ink is made up of the raw material of following weight portion: the Alumina gel 4-5 of solid content 10-15%, nano tin dioxide 1-2, Cedar oil 3-4, lauric acid calcium soap 1-3, spherical argentum powder 0.1-0.2, aerosil 3-5, ethyl acetate 30-40, organic pigment 12-14, amino resins 32-38, diethyl carbonate 5-8, auxiliary agent 2-4;
Described auxiliary agent is made up of the raw material of following weight portion: emulsifier op-10 2-4,2-pyridine carboxylic acid 0.1-0.2, naphthenic acid rare earth 1-2, dehydrated alcohol 10-15, graphene oxide 5-8, preparation method is: first add in dehydrated alcohol by 2-pyridine carboxylic acid, naphthenic acid rare earth, after dispersed with stirring 20-30min, add graphene oxide, mixed material ball milling 1-2h after stirring, it is subsequently added other residual components, continues stirring 20-30min, to obtain final product.
2. a kind of high gloss amino resins printing-ink containing spherical argentum powder as claimed in claim 1, its preparation method is as follows: be first dissolved in ethyl acetate by amino resins, it is subsequently added Alumina gel, nano tin dioxide, after mix and blend 30-40min, add other residual components, after the rotating speed dispersed with stirring 1-2h of 1200-1500 rev/min, compound is put into ball-milling treatment in ball mill, the particle diameter making gained slurry is 5-20 μm, and regulates viscosity as required, to obtain final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410362533.4A CN104194484B (en) | 2014-07-28 | 2014-07-28 | A kind of high gloss amino resins printing-ink containing spherical argentum powder |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410362533.4A CN104194484B (en) | 2014-07-28 | 2014-07-28 | A kind of high gloss amino resins printing-ink containing spherical argentum powder |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104194484A CN104194484A (en) | 2014-12-10 |
| CN104194484B true CN104194484B (en) | 2016-06-15 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410362533.4A Active CN104194484B (en) | 2014-07-28 | 2014-07-28 | A kind of high gloss amino resins printing-ink containing spherical argentum powder |
Country Status (1)
| Country | Link |
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| CN (1) | CN104194484B (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115340785B (en) * | 2021-12-29 | 2023-04-07 | 淄博科睿特新材料科技有限公司 | Stamp-pad ink of ceramic silica gel transfer printing ink |
| CN114907719A (en) * | 2022-06-23 | 2022-08-16 | 武汉信息传播职业技术学院 | Waterborne polyurethane printing ink and printing method thereof |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2366970A (en) * | 1941-10-25 | 1945-01-09 | Fred K H Levey Co Inc | Printing ink containing zein |
| CN101818008A (en) * | 2010-03-19 | 2010-09-01 | 西安理工大学 | Silver paste printing ink for scratch notes and preparation method thereof |
| CN102675968A (en) * | 2012-05-22 | 2012-09-19 | 东莞市英科水墨有限公司 | Water-based soybean oil ink and preparation method thereof |
| GB2492641A (en) * | 2011-06-30 | 2013-01-09 | Silvana Beatriz Palacios-Guberti | Process for inkjet printing of textiles |
| CN103031020A (en) * | 2012-12-31 | 2013-04-10 | 蚌埠富源电子科技有限责任公司 | Glass insulator printing ink |
| CN103666053A (en) * | 2013-11-25 | 2014-03-26 | 铜陵方正塑业科技有限公司 | UV curing transfer printing ink and preparation method thereof |
-
2014
- 2014-07-28 CN CN201410362533.4A patent/CN104194484B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2366970A (en) * | 1941-10-25 | 1945-01-09 | Fred K H Levey Co Inc | Printing ink containing zein |
| CN101818008A (en) * | 2010-03-19 | 2010-09-01 | 西安理工大学 | Silver paste printing ink for scratch notes and preparation method thereof |
| GB2492641A (en) * | 2011-06-30 | 2013-01-09 | Silvana Beatriz Palacios-Guberti | Process for inkjet printing of textiles |
| CN102675968A (en) * | 2012-05-22 | 2012-09-19 | 东莞市英科水墨有限公司 | Water-based soybean oil ink and preparation method thereof |
| CN103031020A (en) * | 2012-12-31 | 2013-04-10 | 蚌埠富源电子科技有限责任公司 | Glass insulator printing ink |
| CN103666053A (en) * | 2013-11-25 | 2014-03-26 | 铜陵方正塑业科技有限公司 | UV curing transfer printing ink and preparation method thereof |
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| Publication number | Publication date |
|---|---|
| CN104194484A (en) | 2014-12-10 |
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| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CB03 | Change of inventor or designer information |
Inventor after: Nie Jin Inventor before: Jin Xin Inventor before: Hu Hui |
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| CB03 | Change of inventor or designer information | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20170601 Address after: 528400, 2, Tsing Hui Road, Sha Man Village, Zhongshan City, Guangdong Province Patentee after: Zhongshan Huaye ink coating Co. Ltd. Address before: 233000 Bengbu high tech Zone, Anhui, No. 1599 Yanshan Road Patentee before: Bengbu Shouchuang Filter Co., Ltd. |
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| TR01 | Transfer of patent right | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: High-glossiness amino resin printing ink containing spherical silver powder Effective date of registration: 20180105 Granted publication date: 20160615 Pledgee: Postal Savings Bank of China Limited by Share Ltd Zhongshan branch Pledgor: Zhongshan Huaye ink coating Co. Ltd. Registration number: 2018440000002 |
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| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20190108 Granted publication date: 20160615 Pledgee: Postal Savings Bank of China Limited by Share Ltd Zhongshan branch Pledgor: Zhongshan Huaye ink coating Co. Ltd. Registration number: 2018440000002 |
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| PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: High-glossiness amino resin printing ink containing spherical silver powder Effective date of registration: 20190410 Granted publication date: 20160615 Pledgee: Postal Savings Bank of China Limited by Share Ltd Zhongshan branch Pledgor: Zhongshan Huaye ink coating Co. Ltd. Registration number: 2019440000145 |
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| PE01 | Entry into force of the registration of the contract for pledge of patent right |