CN107739555A - A kind of water soluble acrylic acid printing-ink with fluorescence falsification preventing effect - Google Patents
A kind of water soluble acrylic acid printing-ink with fluorescence falsification preventing effect Download PDFInfo
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- CN107739555A CN107739555A CN201711188689.5A CN201711188689A CN107739555A CN 107739555 A CN107739555 A CN 107739555A CN 201711188689 A CN201711188689 A CN 201711188689A CN 107739555 A CN107739555 A CN 107739555A
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- water soluble
- soluble acrylic
- ink
- printing
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/50—Sympathetic, colour changing or similar inks
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
- C09D11/033—Printing inks characterised by features other than the chemical nature of the binder characterised by the solvent
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention discloses a kind of water soluble acrylic acid printing-ink with fluorescence falsification preventing effect, it is divided into according to raw material weight component, 0.2 0.6 parts of ferric nitrate, 26 parts of anhydrous sodium sulfate, 37 parts of aluminum oxide, 48 parts of nano-silicon, 26 30 parts of water soluble acrylic resin, 22 26 parts of natural rubber, 18 22 parts of epoxy resin, 8 12 parts of fluorescent material, 0.3 0.7 parts of isooctyl acid bismuth, 32 36 parts of deionized water, 15 parts of auxiliary agent.Using technical solution of the present invention, the principle of low toxic and environment-friendly is have followed in the preparation of raw material first, using water as solvent medium, improves the feature of environmental protection, and using water soluble acrylic resin, natural rubber, epoxy resin, fluorescent material, deionized water as fluorescence resin mixed system material, so that add fluorescent anti-fake mark during production, efficiently quick during printing, printing effect is clearly uniform, bright color is lasting, waterproof and dampproof, easy to clean, the market competitiveness is strong.
Description
Technical field
The present invention relates to printing-ink production technical field, more particularly to it is a kind of with fluorescence falsification preventing effect water-based third
Olefin(e) acid printing-ink.
Background technology
Printing-ink is a kind of common printed matter coloured material, mainly by compositions such as pigment, link stuff, inserts
Form, be a kind of pulpous state adherent that is coloured, having certain fluidity.Want to obtain gratifying printing effect, actually make
There is certain requirement to the color of ink, printing adaptability, rate of drying during, while also to be possessed according to use environment
The features such as water-fast, fast light, acid and alkali-resistance, low toxic and environment-friendly, following printing-ink developing direction must be directed towards low toxicity, quick-drying, color
Naturally various and multifunction direction is developed, but existing ink does not possess anti-fake mark more so that ink application prints
Corresponding false proof protection is not had during brush packaging product.A kind of therefore, it is proposed that aqueous acrylamide with fluorescence falsification preventing effect
Sour printing-ink.
The content of the invention
To solve the defects of prior art, the invention discloses a kind of water soluble acrylic acid with fluorescence falsification preventing effect
Printing-ink.
The invention discloses a kind of water soluble acrylic acid printing-ink with fluorescence falsification preventing effect, according to raw material weight component
It is divided into, ferric nitrate 0.2-0.6 parts, anhydrous sodium sulfate 2-6 parts, aluminum oxide 3-7 parts, nano-silicon 4-8 parts, water soluble acrylic resin
26-30 parts, natural rubber 22-26 parts, epoxy resin 18-22 parts, fluorescent material 8-12 parts, isooctyl acid bismuth 0.3-0.7 parts, deionization
Water 32-36 parts, auxiliary agent 1-5 parts.
Preferably, a kind of water soluble acrylic acid printing-ink with fluorescence falsification preventing effect, is divided into according to raw material weight component,
Ferric nitrate 0.3-0.5 parts, anhydrous sodium sulfate 3-5 parts, aluminum oxide 4-6 parts, nano-silicon 5-7 parts, water soluble acrylic resin 27-29
Part, natural rubber 23-25 parts, epoxy resin 19-21 parts, fluorescent material 9-11 parts, isooctyl acid bismuth 0.4-0.6 parts, deionized water 33-
35 parts, auxiliary agent 2-4 parts.
Preferably, a kind of water soluble acrylic acid printing-ink with fluorescence falsification preventing effect, is divided into according to raw material weight component,
0.4 part of ferric nitrate, 4 parts of anhydrous sodium sulfate, 5 parts of aluminum oxide, 6 parts of nano-silicon, 28 parts of water soluble acrylic resin, natural rubber 24
Part, 20 parts of epoxy resin, 10 parts of fluorescent material, 0.5 part of isooctyl acid bismuth, 34 parts of deionized water, 3 parts of auxiliary agent.
Preferably, one or two kinds of mixed aids of the auxiliary agent sodium alginate and polyether-modified silicon defoaming agent.
A kind of water soluble acrylic acid printing-ink with fluorescence falsification preventing effect, its preparation method are as follows:
1)Water soluble acrylic resin, natural rubber, epoxy resin, fluorescent material, deionized water are put into homogenizer,
Under the rotating speed of 1500-2000 revs/min of rotating speed, stirring is warming up to 60-70 DEG C, is stirred 1-1.5h, obtains fluorescence resin
Main body compound;
2)Step 1)Resulting material mixes with other residual components, puts into homogenizer, with 2500-3000 revs/min
After rotating speed is dispersed with stirring 2-2.5h, then by compound put into ball mill in ball-milling treatment, make gained slurry particle diameter be 10-20 μ
M, and viscosity is adjusted as needed, produce.
Beneficial effect is:The principle of low toxic and environment-friendly is have followed in the preparation of raw material first, using water as solvent medium, is carried
The high feature of environmental protection, and using water soluble acrylic resin, natural rubber, epoxy resin, fluorescent material, deionized water as fluorescence resin
Mixed system material so that fluorescent anti-fake mark is added during production, and its compatibility with resin emulsion can be improved, is improved glimmering
The compatible stability of light powder, strengthen its defensive ability/resistance ability to external environment so that efficiently quick during printing, printing effect is clearly equal
Even, bright color is lasting, waterproof and dampproof, easy to clean, and the market competitiveness is strong.
Embodiment
Embodiment 1
The invention discloses a kind of water soluble acrylic acid printing-ink with fluorescence falsification preventing effect, according to raw material weight component point
Into 0.2 part of ferric nitrate, 2 parts of anhydrous sodium sulfate, 3 parts of aluminum oxide, 4 parts of nano-silicon, 26 parts of water soluble acrylic resin, natural rubber
22 parts of glue, 18 parts of epoxy resin, 8 parts of fluorescent material, 0.3 part of isooctyl acid bismuth, 32 parts of deionized water, 1 part of auxiliary agent.
One or two kinds of mixed aids of the auxiliary agent sodium alginate and polyether-modified silicon defoaming agent.
A kind of water soluble acrylic acid printing-ink with fluorescence falsification preventing effect, its preparation method are as follows:
1)Water soluble acrylic resin, natural rubber, epoxy resin, fluorescent material, deionized water are put into homogenizer,
Under the rotating speed of 1500 revs/min of rotating speed, stirring is warming up to 60 DEG C, is stirred 1h, obtains fluorescence resin main body compound;
2)Step 1)Resulting material mixes with other residual components, puts into homogenizer, is stirred with 2500 revs/min of rotating speed
After mixing scattered 2h, then compound put into ball-milling treatment in ball mill, the particle diameter for making gained slurry is 10 μm, and is adjusted as needed
Viscosity is saved, is produced.
Embodiment 2
The invention discloses a kind of water soluble acrylic acid printing-ink with fluorescence falsification preventing effect, according to raw material weight component point
Into 0.3 part of ferric nitrate, 3 parts of anhydrous sodium sulfate, 4 parts of aluminum oxide, 5 parts of nano-silicon, 27 parts of water soluble acrylic resin, natural rubber
23 parts of glue, 19 parts of epoxy resin, 9 parts of fluorescent material, 0.4 part of isooctyl acid bismuth, 33 parts of deionized water, 2 parts of auxiliary agent.
One or two kinds of mixed aids of the auxiliary agent sodium alginate and polyether-modified silicon defoaming agent.
A kind of water soluble acrylic acid printing-ink with fluorescence falsification preventing effect, its preparation method are as follows:
1)Water soluble acrylic resin, natural rubber, epoxy resin, fluorescent material, deionized water are put into homogenizer,
Under the rotating speed of 1600 revs/min of rotating speed, stirring is warming up to 62 DEG C, is stirred 1.1h, obtains fluorescence resin main body compound;
2)Step 1)Resulting material mixes with other residual components, puts into homogenizer, is stirred with 2600 revs/min of rotating speed
After mixing scattered 2.1h, then compound put into ball-milling treatment in ball mill, the particle diameter for making gained slurry is 12 μm, and as needed
Viscosity is adjusted, is produced.
Embodiment 3
The invention discloses a kind of water soluble acrylic acid printing-ink with fluorescence falsification preventing effect, according to raw material weight component point
Into 0.4 part of ferric nitrate, 4 parts of anhydrous sodium sulfate, 5 parts of aluminum oxide, 6 parts of nano-silicon, 28 parts of water soluble acrylic resin, natural rubber
24 parts of glue, 20 parts of epoxy resin, 10 parts of fluorescent material, 0.5 part of isooctyl acid bismuth, 34 parts of deionized water, 3 parts of auxiliary agent.
One or two kinds of mixed aids of the auxiliary agent sodium alginate and polyether-modified silicon defoaming agent.
A kind of water soluble acrylic acid printing-ink with fluorescence falsification preventing effect, its preparation method are as follows:
1)Water soluble acrylic resin, natural rubber, epoxy resin, fluorescent material, deionized water are put into homogenizer,
Under the rotating speed of 1700 revs/min of rotating speed, stirring is warming up to 65 DEG C, is stirred 1.2h, obtains fluorescence resin main body compound;
2)Step 1)Resulting material mixes with other residual components, puts into homogenizer, is stirred with 2700 revs/min of rotating speed
After mixing scattered 2.2h, then compound put into ball-milling treatment in ball mill, the particle diameter for making gained slurry is 15 μm, and as needed
Viscosity is adjusted, is produced.
Embodiment 4
The invention discloses a kind of water soluble acrylic acid printing-ink with fluorescence falsification preventing effect, according to raw material weight component point
Into 0.5 part of ferric nitrate, 5 parts of anhydrous sodium sulfate, 6 parts of aluminum oxide, 7 parts of nano-silicon, 29 parts of water soluble acrylic resin, natural rubber
25 parts of glue, 21 parts of epoxy resin, 11 parts of fluorescent material, 0.6 part of isooctyl acid bismuth, 35 parts of deionized water, 4 parts of auxiliary agent.
One or two kinds of mixed aids of the auxiliary agent sodium alginate and polyether-modified silicon defoaming agent.
A kind of water soluble acrylic acid printing-ink with fluorescence falsification preventing effect, its preparation method are as follows:
1)Water soluble acrylic resin, natural rubber, epoxy resin, fluorescent material, deionized water are put into homogenizer,
Under the rotating speed of 1800 revs/min of rotating speed, stirring is warming up to 68 DEG C, is stirred 1.3h, obtains fluorescence resin main body compound;
2)Step 1)Resulting material mixes with other residual components, puts into homogenizer, is stirred with 2800 revs/min of rotating speed
After mixing scattered 2.3h, then compound put into ball-milling treatment in ball mill, the particle diameter for making gained slurry is 18 μm, and as needed
Viscosity is adjusted, is produced.
Embodiment 5
The invention discloses a kind of water soluble acrylic acid printing-ink with fluorescence falsification preventing effect, according to raw material weight component point
Into 0.6 part of ferric nitrate, 6 parts of anhydrous sodium sulfate, 7 parts of aluminum oxide, 8 parts of nano-silicon, 30 parts of water soluble acrylic resin, natural rubber
26 parts of glue, 22 parts of epoxy resin, 12 parts of fluorescent material, 0.7 part of isooctyl acid bismuth, 36 parts of deionized water, 5 parts of auxiliary agent.
One or two kinds of mixed aids of the auxiliary agent sodium alginate and polyether-modified silicon defoaming agent.
A kind of water soluble acrylic acid printing-ink with fluorescence falsification preventing effect, its preparation method are as follows:
1)Water soluble acrylic resin, natural rubber, epoxy resin, fluorescent material, deionized water are put into homogenizer,
Under the rotating speed of 2000 revs/min of rotating speed, stirring is warming up to 70 DEG C, is stirred 1.5h, obtains fluorescence resin main body compound;
2)Step 1)Resulting material mixes with other residual components, puts into homogenizer, is stirred with 3000 revs/min of rotating speed
After mixing scattered 2.5h, then compound put into ball-milling treatment in ball mill, the particle diameter for making gained slurry is 20 μm, and as needed
Viscosity is adjusted, is produced.
Finally it should be noted that:Above example only not limits technology described in the invention to illustrate the present invention
Scheme;Therefore, although this specification with reference to above-mentioned each embodiment to present invention has been detailed description, this
Field it is to be appreciated by one skilled in the art that still can be modified to the present invention or equivalent substitution;And all do not depart from this
The technical scheme of the spirit and scope of invention and its improvement, it all should cover in scope of the presently claimed invention.
Claims (5)
- A kind of 1. water soluble acrylic acid printing-ink with fluorescence falsification preventing effect, it is characterised in that:According to raw material weight component point Into ferric nitrate 0.2-0.6 parts, anhydrous sodium sulfate 2-6 parts, aluminum oxide 3-7 parts, nano-silicon 4-8 parts, water soluble acrylic resin 26-30 parts, natural rubber 22-26 parts, epoxy resin 18-22 parts, fluorescent material 8-12 parts, isooctyl acid bismuth 0.3-0.7 parts, deionization Water 32-36 parts, auxiliary agent 1-5 parts.
- A kind of 2. water soluble acrylic acid printing-ink with fluorescence falsification preventing effect according to claim 1, it is characterised in that: Be divided into according to raw material weight component, ferric nitrate 0.3-0.5 parts, anhydrous sodium sulfate 3-5 parts, aluminum oxide 4-6 parts, nano-silicon 5-7 parts, Water soluble acrylic resin 27-29 parts, natural rubber 23-25 parts, epoxy resin 19-21 parts, fluorescent material 9-11 parts, isooctyl acid bismuth 0.4-0.6 parts, deionized water 33-35 parts, auxiliary agent 2-4 parts.
- A kind of 3. water soluble acrylic acid printing-ink with fluorescence falsification preventing effect according to claim 1, it is characterised in that: It is divided into according to raw material weight component, 0.4 part of ferric nitrate, 4 parts of anhydrous sodium sulfate, 5 parts of aluminum oxide, 6 parts of nano-silicon, water soluble propene 28 parts of acid resin, 24 parts of natural rubber, 20 parts of epoxy resin, 10 parts of fluorescent material, 0.5 part of isooctyl acid bismuth, 34 parts of deionized water, help 3 parts of agent.
- A kind of 4. water soluble acrylic acid printing-ink with fluorescence falsification preventing effect according to claim 1, it is characterised in that: One or two kinds of mixed aids of the auxiliary agent sodium alginate and polyether-modified silicon defoaming agent.
- A kind of 5. water soluble acrylic acid printing-ink with fluorescence falsification preventing effect, it is characterised in that:Its preparation method is as follows:1)Water soluble acrylic resin, natural rubber, epoxy resin, fluorescent material, deionized water are put into homogenizer, Under the rotating speed of 1500-2000 revs/min of rotating speed, stirring is warming up to 60-70 DEG C, is stirred 1-1.5h, obtains fluorescence resin Main body compound;2)Step 1)Resulting material mixes with other residual components, puts into homogenizer, with 2500-3000 revs/min After rotating speed is dispersed with stirring 2-2.5h, then by compound put into ball mill in ball-milling treatment, make gained slurry particle diameter be 10-20 μ M, and viscosity is adjusted as needed, produce.
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CN201711188689.5A CN107739555A (en) | 2017-11-24 | 2017-11-24 | A kind of water soluble acrylic acid printing-ink with fluorescence falsification preventing effect |
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CN201711188689.5A CN107739555A (en) | 2017-11-24 | 2017-11-24 | A kind of water soluble acrylic acid printing-ink with fluorescence falsification preventing effect |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108841248A (en) * | 2018-05-25 | 2018-11-20 | 安徽猛牛彩印包装有限公司 | A kind of printing ink of wear resistant fluorescent anti-counterfeiting performance |
CN109021704A (en) * | 2018-05-25 | 2018-12-18 | 安徽猛牛彩印包装有限公司 | A kind of printing ink for the fluorescence falsification preventing performance that adhesive force is strong |
CN116120783A (en) * | 2022-12-21 | 2023-05-16 | 银河包装科技(昆山)有限公司 | Formula and preparation process of UV green environment-friendly anti-counterfeiting ink |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101519557A (en) * | 2009-04-10 | 2009-09-02 | 湖南沧海环保科技发展有限公司 | Method for multifunctional water-based ink |
-
2017
- 2017-11-24 CN CN201711188689.5A patent/CN107739555A/en active Pending
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101519557A (en) * | 2009-04-10 | 2009-09-02 | 湖南沧海环保科技发展有限公司 | Method for multifunctional water-based ink |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108841248A (en) * | 2018-05-25 | 2018-11-20 | 安徽猛牛彩印包装有限公司 | A kind of printing ink of wear resistant fluorescent anti-counterfeiting performance |
CN109021704A (en) * | 2018-05-25 | 2018-12-18 | 安徽猛牛彩印包装有限公司 | A kind of printing ink for the fluorescence falsification preventing performance that adhesive force is strong |
CN116120783A (en) * | 2022-12-21 | 2023-05-16 | 银河包装科技(昆山)有限公司 | Formula and preparation process of UV green environment-friendly anti-counterfeiting ink |
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