CN108841248A - A kind of printing ink of wear resistant fluorescent anti-counterfeiting performance - Google Patents

A kind of printing ink of wear resistant fluorescent anti-counterfeiting performance Download PDF

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Publication number
CN108841248A
CN108841248A CN201810513254.1A CN201810513254A CN108841248A CN 108841248 A CN108841248 A CN 108841248A CN 201810513254 A CN201810513254 A CN 201810513254A CN 108841248 A CN108841248 A CN 108841248A
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CN
China
Prior art keywords
parts
powder
printing ink
wear resistant
counterfeiting performance
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810513254.1A
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Chinese (zh)
Inventor
李峰
郑志龙
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ANHUI MENGNIU COLOR PRINTING PACKAGING Co Ltd
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ANHUI MENGNIU COLOR PRINTING PACKAGING Co Ltd
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Priority to CN201810513254.1A priority Critical patent/CN108841248A/en
Publication of CN108841248A publication Critical patent/CN108841248A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/50Sympathetic, colour changing or similar inks
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/03Printing inks characterised by features other than the chemical nature of the binder
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/10Printing inks based on artificial resins
    • C09D11/102Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/10Printing inks based on artificial resins
    • C09D11/102Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
    • C09D11/104Polyesters
    • C09D11/105Alkyd resins

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a kind of printing ink of wear resistant fluorescent anti-counterfeiting performance, it is divided into according to raw material weight component, 37-39 parts of modified alkyd resin, 41-43 parts of epoxy resin, 2-4 parts of fluorescent powder, 1-3 parts of graphite powder, 2-4 parts of diabase flour, 1-3 parts of talcum powder, 2-4 parts of mica powder, 54-56 parts of epoxy propane butyl ether, 45-47 parts of polyglycidyl ether, 3-5 parts of zircon sand, 3-5 parts of plasticizer, 5-7 parts of dispersing agent, 6-8 parts of defoaming agent.Using technical solution of the present invention, using modified alkyd resin, epoxy resin epoxy propane butyl ether, polyglycidyl ether organic solvent in homogenization, and the filling fines such as graphite powder, diabase flour, talcum powder, mica powder, zircon sand is added, the wear-resisting property of printing ink can be improved, furthermore it joined phosphor substance, the printing antiforge function of printing ink may be implemented.

Description

A kind of printing ink of wear resistant fluorescent anti-counterfeiting performance
Technical field
The present invention relates to the technical field of printing ink more particularly to a kind of printing ink of wear resistant fluorescent anti-counterfeiting performance.
Background technique
Printing is to arrive printing ink transfer through processes such as plate-making, Shi Mo, pressurizations the original copys such as text, picture, photo, anti-fake The material surfaces such as paper, textile, plastic products, leather, the technology of batch duplicating original copy content.
Oil plant, that is, ink of printing, is the important materials of printing, expresses the pattern and text printing by printing or air brushing On object.It include main component and auxiliary element in ink, they uniformly mix and form a kind of stickiness glue through repeat-rolling Fluid.It is made of resin, pigment, filler auxiliary agent and organic solvent etc..For books and periodicals including decoration, building decoration and electric wire The various printings such as road plate.As social demand increases, also respective extension and the growth of various ink.
Existing printing ink is not wear-resisting in printing process, wear-resisting property is poor, and does not have fluorescence falsification preventing function, is This, it is proposed that a kind of printing ink of wear resistant fluorescent anti-counterfeiting performance.
Summary of the invention
For the defect for solving prior art, the invention discloses a kind of printing ink of wear resistant fluorescent anti-counterfeiting performance.
The invention discloses a kind of printing ink of wear resistant fluorescent anti-counterfeiting performance, are divided into according to raw material weight component, modified 37-39 parts of alkyd resin, 41-43 parts of epoxy resin, 2-4 parts of fluorescent powder, 1-3 parts of graphite powder, 2-4 parts of diabase flour, talcum powder 1-3 parts, 2-4 parts of mica powder, 54-56 parts of epoxy propane butyl ether, 45-47 parts of polyglycidyl ether, 3-5 parts of zircon sand, plasticising 3-5 parts of agent, 5-7 parts of dispersing agent, 6-8 parts of defoaming agent.
Preferably, a kind of printing ink of wear resistant fluorescent anti-counterfeiting performance, is divided into, acid modified alcoholic tree according to raw material weight component 38 parts of rouge, 42 parts of epoxy resin, 3 parts of fluorescent powder, 2 parts of graphite powder, 3 parts of diabase flour, 2 parts of talcum powder, 3 parts of mica powder, epoxy 55 parts of propane butyl ether, 46 parts of polyglycidyl ether, 4 parts of zircon sand, 4 parts of plasticizer, 6 parts of dispersing agent, 7 parts of defoaming agent.
Preferably, the plasticizer is epoxidized oil, epoxidized fat acid monoester and epoxidation tetrahydrophthalic acid ester One or more mixtures.
Preferably, the dispersing agent is one or two kinds of mixtures of sodium pyrophosphate, calgon.
Preferably, the defoaming agent is dimethicone.
Preferably, a kind of printing ink of wear resistant fluorescent anti-counterfeiting performance, specific preparation method are as follows:
1)Modified alkyd resin, epoxy resin, epoxy propane butyl ether, polyglycidyl ether is weighed to put into homogenizer, Under 2000-3000 revs/min of revolving speed, 1-2h is pre-processed;
2)It weighs graphite powder, diabase flour, talcum powder, mica powder, zircon sand to be mixed evenly, and crosses 800-900 mesh Sieve obtains mixing filling fine powder material;
3)By step 2)The mixing filling fine powder material of middle acquisition is put into 1)In middle homogenizer, and be added fluorescent powder, plasticizer, Dispersing agent, defoaming agent, homogenizer temperature is controlled at 70-80 DEG C, 2000-3000 revs/min of stirring 2-3h of revolving speed, then is cooled to It 25-30 DEG C, stands and places 1-2h;
4)To step 3)For the middle mixed liquor placed that stands through filtering, the partial size of gained slurry is 10-20 μm, and is adjusted as needed Save viscosity.
Beneficial effect is:Had using modified alkyd resin, epoxy resin in epoxy propane butyl ether, polyglycidyl ether Homogenization in solvent, and filling fines, the Ke Yiti such as graphite powder, diabase flour, talcum powder, mica powder, zircon sand is added The wear-resisting property of height printing ink, furthermore joined phosphor substance, the printing antiforge function of printing ink may be implemented.
Specific embodiment
Embodiment 1
The invention discloses a kind of printing ink of wear resistant fluorescent anti-counterfeiting performance, are divided into according to raw material weight component, acid modified alcoholic 37 parts of resin, 41 parts of epoxy resin, 2 parts of fluorescent powder, 1 part of graphite powder, 2 parts of diabase flour, 1 part of talcum powder, 2 parts of mica powder, ring 54 parts of Ethylene Oxide butyl ether, 45 parts of polyglycidyl ether, 3 parts of zircon sand, 3 parts of plasticizer, 5 parts of dispersing agent, 6 parts of defoaming agent.
The plasticizer is that epoxidized oil, epoxidized fat acid monoester and epoxidation tetrahydrophthalic acid ester are a kind of or more Kind mixture.
The dispersing agent is one or two kinds of mixtures of sodium pyrophosphate, calgon.
The defoaming agent is dimethicone.
A kind of printing ink of wear resistant fluorescent anti-counterfeiting performance, specific preparation method are as follows:
1)Modified alkyd resin, epoxy resin, epoxy propane butyl ether, polyglycidyl ether is weighed to put into homogenizer, Under 2000 revs/min of revolving speed, 1h is pre-processed;
2)It weighs graphite powder, diabase flour, talcum powder, mica powder, zircon sand to be mixed evenly, and crosses 800 meshes, obtain Filling fine powder material must be mixed;
3)By step 2)The mixing filling fine powder material of middle acquisition is put into 1)In middle homogenizer, and be added fluorescent powder, plasticizer, Dispersing agent, defoaming agent, homogenizer temperature is controlled at 70 DEG C, 2000 revs/min of stirring 2h of revolving speed, then is cooled to 25 DEG C, is stood Place 1h;
4)To step 3)For the middle mixed liquor placed that stands through filtering, the partial size of gained slurry is 10 μm, and is adjusted as needed Viscosity.
Embodiment 2
The invention discloses a kind of printing ink of wear resistant fluorescent anti-counterfeiting performance, are divided into according to raw material weight component, acid modified alcoholic 38 parts of resin, 42 parts of epoxy resin, 3 parts of fluorescent powder, 2 parts of graphite powder, 3 parts of diabase flour, 2 parts of talcum powder, 3 parts of mica powder, ring 55 parts of Ethylene Oxide butyl ether, 46 parts of polyglycidyl ether, 4 parts of zircon sand, 4 parts of plasticizer, 6 parts of dispersing agent, 7 parts of defoaming agent.
The plasticizer is that epoxidized oil, epoxidized fat acid monoester and epoxidation tetrahydrophthalic acid ester are a kind of or more Kind mixture.
The dispersing agent is one or two kinds of mixtures of sodium pyrophosphate, calgon.
The defoaming agent is dimethicone.
A kind of printing ink of wear resistant fluorescent anti-counterfeiting performance, specific preparation method are as follows:
1)Modified alkyd resin, epoxy resin, epoxy propane butyl ether, polyglycidyl ether is weighed to put into homogenizer, Under 2500 revs/min of revolving speed, 1.5h is pre-processed;
2)It weighs graphite powder, diabase flour, talcum powder, mica powder, zircon sand to be mixed evenly, and crosses 850 meshes, obtain Filling fine powder material must be mixed;
3)By step 2)The mixing filling fine powder material of middle acquisition is put into 1)In middle homogenizer, and be added fluorescent powder, plasticizer, Dispersing agent, defoaming agent, homogenizer temperature is controlled at 75 DEG C, 2500 revs/min of stirring 2.5h of revolving speed, then is cooled to 28 DEG C, quiet Placement location 1.5h;
4)To step 3)For the middle mixed liquor placed that stands through filtering, the partial size of gained slurry is 15 μm, and is adjusted as needed Viscosity.
Embodiment 3
The invention discloses a kind of printing ink of wear resistant fluorescent anti-counterfeiting performance, are divided into according to raw material weight component, acid modified alcoholic 39 parts of resin, 43 parts of epoxy resin, 4 parts of fluorescent powder, 3 parts of graphite powder, 4 parts of diabase flour, 3 parts of talcum powder, 4 parts of mica powder, ring 56 parts of Ethylene Oxide butyl ether, 47 parts of polyglycidyl ether, 5 parts of zircon sand, 5 parts of plasticizer, 7 parts of dispersing agent, 8 parts of defoaming agent.
The plasticizer is that epoxidized oil, epoxidized fat acid monoester and epoxidation tetrahydrophthalic acid ester are a kind of or more Kind mixture.
The dispersing agent is one or two kinds of mixtures of sodium pyrophosphate, calgon.
The defoaming agent is dimethicone.
A kind of printing ink of wear resistant fluorescent anti-counterfeiting performance, specific preparation method are as follows:
1)Modified alkyd resin, epoxy resin, epoxy propane butyl ether, polyglycidyl ether is weighed to put into homogenizer, Under 3000 revs/min of revolving speed, 2h is pre-processed;
2)It weighs graphite powder, diabase flour, talcum powder, mica powder, zircon sand to be mixed evenly, and crosses 900 meshes, obtain Filling fine powder material must be mixed;
3)By step 2)The mixing filling fine powder material of middle acquisition is put into 1)In middle homogenizer, and be added fluorescent powder, plasticizer, Dispersing agent, defoaming agent, homogenizer temperature is controlled at 80 DEG C, 3000 revs/min of stirring 3h of revolving speed, then is cooled to 30 DEG C, is stood Place 2h;
4)To step 3)For the middle mixed liquor placed that stands through filtering, the partial size of gained slurry is 20 μm, and is adjusted as needed Viscosity.
Finally it should be noted that:Above embodiments are only to illustrate the present invention and not limit technology described in the invention Scheme;Therefore, although this specification is referring to above-mentioned each embodiment, the present invention has been described in detail, this Field it is to be appreciated by one skilled in the art that still can modify to the present invention or equivalent replacement;And all do not depart from this The technical solution and its improvement of the spirit and scope of invention, should all cover within the scope of the claims of the present invention.

Claims (6)

1. a kind of printing ink of wear resistant fluorescent anti-counterfeiting performance, it is characterised in that:It is divided into according to raw material weight component, acid modified alcoholic 37-39 parts of resin, 41-43 parts of epoxy resin, 2-4 parts of fluorescent powder, 1-3 parts of graphite powder, 2-4 parts of diabase flour, talcum powder 1-3 Part, 2-4 parts of mica powder, 54-56 parts of epoxy propane butyl ether, 45-47 parts of polyglycidyl ether, 3-5 parts of zircon sand, plasticizer 3- 5 parts, 5-7 parts of dispersing agent, 6-8 parts of defoaming agent.
2. a kind of printing ink of wear resistant fluorescent anti-counterfeiting performance according to claim 1, it is characterised in that:According to raw material weight Amount component is divided into, 38 parts of modified alkyd resin, 42 parts of epoxy resin, 3 parts of fluorescent powder, 2 parts of graphite powder, 3 parts of diabase flour, talcum 2 parts of powder, 3 parts of mica powder, 55 parts of epoxy propane butyl ether, 46 parts of polyglycidyl ether, 4 parts of zircon sand, 4 parts of plasticizer, dispersion 6 parts of agent, 7 parts of defoaming agent.
3. a kind of printing ink of wear resistant fluorescent anti-counterfeiting performance according to claim 1, it is characterised in that:The plasticizer For epoxidized oil, epoxidized fat acid monoester and the one or more mixtures of epoxidation tetrahydrophthalic acid ester.
4. a kind of printing ink of wear resistant fluorescent anti-counterfeiting performance according to claim 1, it is characterised in that:The dispersing agent For sodium pyrophosphate, one or two kinds of mixtures of calgon.
5. a kind of printing ink of wear resistant fluorescent anti-counterfeiting performance according to claim 1, it is characterised in that:The defoaming agent For dimethicone.
6. a kind of printing ink of wear resistant fluorescent anti-counterfeiting performance according to claim 1, it is characterised in that:It is specifically made Preparation Method is as follows:
Modified alkyd resin, epoxy resin, epoxy propane butyl ether, polyglycidyl ether is weighed to put into homogenizer, Under 2000-3000 revs/min of revolving speed, 1-2h is pre-processed;
It weighs graphite powder, diabase flour, talcum powder, mica powder, zircon sand to be mixed evenly, and crosses 800-900 mesh, Obtain mixing filling fine powder material;
By step 2)The mixing filling fine powder material of middle acquisition is put into 1)In middle homogenizer, and fluorescent powder is added, plasticizer, divides Powder, defoaming agent, homogenizer temperature is controlled at 70-80 DEG C, 2000-3000 revs/min of stirring 2-3h of revolving speed, then is cooled to It 25-30 DEG C, stands and places 1-2h;
To step 3)For the middle mixed liquor placed that stands through filtering, the partial size of gained slurry is 10-20 μm, and is adjusted as needed Viscosity.
CN201810513254.1A 2018-05-25 2018-05-25 A kind of printing ink of wear resistant fluorescent anti-counterfeiting performance Pending CN108841248A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113429834A (en) * 2021-07-16 2021-09-24 深圳市裕同包装科技股份有限公司 Preparation formula and drying method of fluorescent printing ink

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CN103666095A (en) * 2013-11-18 2014-03-26 蚌埠市英路光电有限公司 Insulating ink for wire printing and preparation method thereof
KR101425426B1 (en) * 2014-02-14 2014-08-06 주식회사 동양잉크 Offset fluoroscent ink base and the manufacturing method thereof
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CN104194475A (en) * 2014-08-12 2014-12-10 安徽猛牛彩印包装有限公司 Printing ink containing modified seashell mud
JP2016190933A (en) * 2015-03-31 2016-11-10 日本化薬株式会社 Magenta ink for inkjet printing and fiber printing method using the same
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