CN103666095A - Insulating ink for wire printing and preparation method thereof - Google Patents
Insulating ink for wire printing and preparation method thereof Download PDFInfo
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- CN103666095A CN103666095A CN201310575067.3A CN201310575067A CN103666095A CN 103666095 A CN103666095 A CN 103666095A CN 201310575067 A CN201310575067 A CN 201310575067A CN 103666095 A CN103666095 A CN 103666095A
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- 238000002360 preparation method Methods 0.000 title claims description 10
- 238000007639 printing Methods 0.000 title abstract description 8
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 claims abstract description 21
- QFOHBWFCKVYLES-UHFFFAOYSA-N Butylparaben Chemical compound CCCCOC(=O)C1=CC=C(O)C=C1 QFOHBWFCKVYLES-UHFFFAOYSA-N 0.000 claims abstract description 8
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims abstract description 8
- RUMACXVDVNRZJZ-UHFFFAOYSA-N 2-methylpropyl 2-methylprop-2-enoate Chemical compound CC(C)COC(=O)C(C)=C RUMACXVDVNRZJZ-UHFFFAOYSA-N 0.000 claims abstract description 7
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229920000180 alkyd Polymers 0.000 claims abstract description 7
- 239000002994 raw material Substances 0.000 claims abstract description 7
- 230000003647 oxidation Effects 0.000 claims abstract description 4
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 4
- 238000003756 stirring Methods 0.000 claims description 15
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 12
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 12
- 238000001035 drying Methods 0.000 claims description 9
- 239000012752 auxiliary agent Substances 0.000 claims description 7
- XDLMVUHYZWKMMD-UHFFFAOYSA-N 3-trimethoxysilylpropyl 2-methylprop-2-enoate Chemical compound CO[Si](OC)(OC)CCCOC(=O)C(C)=C XDLMVUHYZWKMMD-UHFFFAOYSA-N 0.000 claims description 6
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 6
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 6
- 150000001412 amines Chemical class 0.000 claims description 6
- 238000006243 chemical reaction Methods 0.000 claims description 6
- 239000003153 chemical reaction reagent Substances 0.000 claims description 6
- 230000008878 coupling Effects 0.000 claims description 6
- 238000010168 coupling process Methods 0.000 claims description 6
- 238000005859 coupling reaction Methods 0.000 claims description 6
- 150000001924 cycloalkanes Chemical class 0.000 claims description 6
- 239000003822 epoxy resin Substances 0.000 claims description 6
- 238000005502 peroxidation Methods 0.000 claims description 6
- 229920000647 polyepoxide Polymers 0.000 claims description 6
- WBHHMMIMDMUBKC-QJWNTBNXSA-N ricinoleic acid Chemical compound CCCCCC[C@@H](O)C\C=C/CCCCCCCC(O)=O WBHHMMIMDMUBKC-QJWNTBNXSA-N 0.000 claims description 6
- 229960003656 ricinoleic acid Drugs 0.000 claims description 6
- FEUQNCSVHBHROZ-UHFFFAOYSA-N ricinoleic acid Natural products CCCCCCC(O[Si](C)(C)C)CC=CCCCCCCCC(=O)OC FEUQNCSVHBHROZ-UHFFFAOYSA-N 0.000 claims description 6
- 229910000077 silane Inorganic materials 0.000 claims description 6
- VXHFNALHLRWIIU-UHFFFAOYSA-N tert-butyl 2,2-dimethylpropanoate Chemical compound CC(C)(C)OC(=O)C(C)(C)C VXHFNALHLRWIIU-UHFFFAOYSA-N 0.000 claims description 6
- DAKWPKUUDNSNPN-UHFFFAOYSA-N Trimethylolpropane triacrylate Chemical compound C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 238000009826 distribution Methods 0.000 claims description 3
- 239000000975 dye Substances 0.000 claims description 3
- 238000000227 grinding Methods 0.000 claims description 3
- 239000003112 inhibitor Substances 0.000 claims description 3
- 239000000049 pigment Substances 0.000 claims description 3
- 239000000244 polyoxyethylene sorbitan monooleate Substances 0.000 claims description 3
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 claims description 3
- 229920000053 polysorbate 80 Polymers 0.000 claims description 3
- 239000002002 slurry Substances 0.000 claims description 3
- 239000004408 titanium dioxide Substances 0.000 claims description 3
- 238000010792 warming Methods 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 5
- 230000001681 protective effect Effects 0.000 abstract description 2
- CBCKQZAAMUWICA-UHFFFAOYSA-N 1,4-phenylenediamine Chemical compound NC1=CC=C(N)C=C1 CBCKQZAAMUWICA-UHFFFAOYSA-N 0.000 abstract 1
- 239000000853 adhesive Substances 0.000 abstract 1
- 230000001070 adhesive effect Effects 0.000 abstract 1
- 239000004841 bisphenol A epoxy resin Substances 0.000 abstract 1
- 229940067596 butylparaben Drugs 0.000 abstract 1
- 239000012860 organic pigment Substances 0.000 abstract 1
- 230000002035 prolonged effect Effects 0.000 abstract 1
- ZNVWLZGTXSHPMH-UHFFFAOYSA-N tert-butyl 3-hydroperoxy-2,2-dimethylpropanoate Chemical compound CC(C)(C)OC(=O)C(C)(C)COO ZNVWLZGTXSHPMH-UHFFFAOYSA-N 0.000 abstract 1
- 235000010215 titanium dioxide Nutrition 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 235000006708 antioxidants Nutrition 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 210000000988 bone and bone Anatomy 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- POCFBDFTJMJWLG-UHFFFAOYSA-N dihydrosinapic acid methyl ester Natural products COC(=O)CCC1=CC(OC)=C(O)C(OC)=C1 POCFBDFTJMJWLG-UHFFFAOYSA-N 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
Landscapes
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention relates to an insulating ink for wire printing, which is prepared from the following raw materials in parts by weight: 30-34 parts of dry oil alkyd resin, 12-14 parts of isobutyl methacrylate, 5-8 parts of titanium white, 3-5 parts of butyl paraben, 3-4 parts of methyl ethyl ketone, 12-14 parts of bisphenol A epoxy resin, 4-5 parts of mononaphthenedicarboxylate, 2-3 parts of styrene, 1-2 parts of p-phenylene diamine, 1-2 parts of tert-butyl peroxylpivalate, 3-4 parts of organic pigment and 4-5 parts of assistant. The ink has the advantages of high curing speed, excellent elasticity, excellent durability, excellent glossiness, excellent adhesive force, excellent hardness, excellent wear resistance, excellent water resistance and excellent insulativity, is suitable for printing wires, cables and other circuit facilities, and can not easily shed or abrade. The assistant can form a protective film on the ink surface to isolate air, prevent water and other molecules in air from corroding the surfaces of the ink and sprayed objects and resist oxidation, so that the color can be bright permanently; and the smoothness and wear resistance are enhanced, and the service time is prolonged.
Description
Technical field
The invention belongs to printing ink paint field, relate in particular to dielectric ink and preparation method thereof for a kind of wire marking.
Background technology
The color of ink (form and aspect), body bone (rheological property such as rare thick, degree of mobilization) and drying property are three most important performances of ink.Their kind is a lot, and physical properties is also different, and what have is very thick, very sticky; And have quite rare.What have makes low-melting ink vehicle with vegetables oil; Somely with resin and solvent or water etc., make low-melting ink vehicle.These are to be all that the type of stock, printing process, printing plate and drying means etc. decide according to the object of printing.
The rate of drying of ink, thixotropy, skeleton property have tremendous influence to production efficiency, quality product, and the composition of ink has impact to human body, how to study as far as possible little to harm, production efficiency is high, environmental friendliness, ink that cost is low have profound significance.
Summary of the invention
The object of the present invention is to provide dielectric ink and preparation method thereof for a kind of wire marking, this ink cohesive force is strong, durable, insulation.
Technical scheme of the present invention is as follows:
A wire marking dielectric ink, is characterized in that being made by the raw material of following weight part: drying oil alkyd resin 30-34, Propenoic acid, 2-methyl, isobutyl ester 12-14, titanium dioxide 5-8, Tegosept B 3-5, methyl ethyl ketone 3-4, bisphenol A epoxide resin 12-14, Cycloalkane dicarboxylic acid monoesters 4-5, vinylbenzene 2-3, P-pHENYLENE dI AMINE 1-2, peroxidation trimethylacetic acid tert-butyl ester 1-2, pigment dyestuff 3-4, auxiliary agent 4-5;
Described auxiliary agent is made by the raw material of following weight part: Silane coupling reagent KH-570 2-3, Viscoat 295 3-4,2-n-octyl-4-isothiazoline-3-ketone 1-2,2-amino-2-methyl-1-propyl alcohol 1-2, polyoxyethylene sorbitan monooleate 2-3, ricinolic acid 1-2, oxidation inhibitor 1035 1-2, linking agent TAC1-2, ethanol 20-24; Preparation method mixes Silane coupling reagent KH-570, ricinolic acid, ethanol, is heated to 60-70 ℃, stirs after 20-30 minute, then adds other remaining component, is warming up to 80-85 ℃, stirs 30-40 minutes, obtains.
The preparation method of dielectric ink for described wire marking, it is characterized in that comprising the following steps: by drying oil alkyd resin, Tegosept B, methyl ethyl ketone, P-pHENYLENE dI AMINE mixes, under 1000-1400 rev/min of stirring, add the peroxidation trimethylacetic acid tert-butyl ester, speed with 5-8 ℃/minute is heated to 60-90 ℃, add Propenoic acid, 2-methyl, isobutyl ester, Cycloalkane dicarboxylic acid monoesters, bisphenol A epoxide resin, vinylbenzene, continue stirring reaction 20-30 minute, add other remaining components, continue stirring reaction 1.5-2 hour, grinding distribution becomes the slurry of 20-40 μ m, obtain.
Beneficial effect of the present invention
Ink solidification of the present invention is fast, and elasticity, weather resistance, glossiness, sticking power, hardness, wear resistance, water tolerance, insulativity excellence, be applicable to the printing of the circuit arrangements such as electric wire, cable, difficult drop-off, wearing and tearing.Auxiliary agent of the present invention can form protective membrane in ink pellet surface, isolated air, and the surface that prevents water and other molecules corrosion ink and spraying object in atmosphere, anti-oxidant, make color bright-coloured lastingly, and improve slickness, wear resistance, extend working time.
Embodiment
A wire marking dielectric ink, by following weight part (kilogram) raw material make: drying oil alkyd resin 32, Propenoic acid, 2-methyl, isobutyl ester 13, titanium dioxide 7, Tegosept B 4, methyl ethyl ketone 3.5, bisphenol A epoxide resin 13, Cycloalkane dicarboxylic acid monoesters 4.5, vinylbenzene 2.5, P-pHENYLENE dI AMINE 1.5, the peroxidation trimethylacetic acid tert-butyl ester 1.5, pigment dyestuff 3.5, auxiliary agent 4.5;
Described auxiliary agent by following weight part (kilogram) raw material make: Silane coupling reagent KH-570 2.5, Viscoat 295 3.5,2-n-octyl-4-isothiazoline-3-ketone 1.5,2-amino-2-methyl-1-propyl alcohol 1.5, polyoxyethylene sorbitan monooleate 2.5, ricinolic acid 1.5, oxidation inhibitor 1,035 1.5, linking agent TAC1.5, ethanol 22; Preparation method mixes Silane coupling reagent KH-570, ricinolic acid, ethanol, is heated to 65 ℃, stirs after 26 minutes, then adds other remaining component, is warming up to 83 ℃, stirs 34 minutes, obtains.
The preparation method of dielectric ink for described wire marking, comprise the following steps: drying oil alkyd resin, Tegosept B, methyl ethyl ketone, P-pHENYLENE dI AMINE are mixed, under 1300 revs/min of stirrings, add the peroxidation trimethylacetic acid tert-butyl ester, with the speed of 6 ℃/minute, be heated to 70 ℃, add Propenoic acid, 2-methyl, isobutyl ester, Cycloalkane dicarboxylic acid monoesters, bisphenol A epoxide resin, vinylbenzene, continue stirring reaction 25 minutes, add other remaining components, continue stirring reaction 1.7 hours, grinding distribution becomes the slurry of 30 μ m, obtains.
Ink quality homogeneous of the present invention, tinting strength, adhere firmly degree, viscosity, first dryness and other performances have reached the requirement of QB/T2024-94 standard.
Claims (2)
1. a wire marking dielectric ink, is characterized in that being made by the raw material of following weight part: drying oil alkyd resin 30-34, Propenoic acid, 2-methyl, isobutyl ester 12-14, titanium dioxide 5-8, Tegosept B 3-5, methyl ethyl ketone 3-4, bisphenol A epoxide resin 12-14, Cycloalkane dicarboxylic acid monoesters 4-5, vinylbenzene 2-3, P-pHENYLENE dI AMINE 1-2, peroxidation trimethylacetic acid tert-butyl ester 1-2, pigment dyestuff 3-4, auxiliary agent 4-5;
Described auxiliary agent is made by the raw material of following weight part: Silane coupling reagent KH-570 2-3, Viscoat 295 3-4,2-n-octyl-4-isothiazoline-3-ketone 1-2,2-amino-2-methyl-1-propyl alcohol 1-2, polyoxyethylene sorbitan monooleate 2-3, ricinolic acid 1-2, oxidation inhibitor 1035 1-2, linking agent TAC1-2, ethanol 20-24; Preparation method mixes Silane coupling reagent KH-570, ricinolic acid, ethanol, is heated to 60-70 ℃, stirs after 20-30 minute, then adds other remaining component, is warming up to 80-85 ℃, stirs 30-40 minutes, obtains.
2. the preparation method of dielectric ink for wire marking according to claim 1, it is characterized in that comprising the following steps: by drying oil alkyd resin, Tegosept B, methyl ethyl ketone, P-pHENYLENE dI AMINE mixes, under 1000-1400 rev/min of stirring, add the peroxidation trimethylacetic acid tert-butyl ester, speed with 5-8 ℃/minute is heated to 60-90 ℃, add Propenoic acid, 2-methyl, isobutyl ester, Cycloalkane dicarboxylic acid monoesters, bisphenol A epoxide resin, vinylbenzene, continue stirring reaction 20-30 minute, add other remaining components, continue stirring reaction 1.5-2 hour, grinding distribution becomes the slurry of 20-40 μ m, obtain.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310575067.3A CN103666095A (en) | 2013-11-18 | 2013-11-18 | Insulating ink for wire printing and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310575067.3A CN103666095A (en) | 2013-11-18 | 2013-11-18 | Insulating ink for wire printing and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103666095A true CN103666095A (en) | 2014-03-26 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310575067.3A Pending CN103666095A (en) | 2013-11-18 | 2013-11-18 | Insulating ink for wire printing and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103666095A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107891676A (en) * | 2017-11-02 | 2018-04-10 | 苏州太平洋印务有限公司 | The typography of edge band |
| CN108841248A (en) * | 2018-05-25 | 2018-11-20 | 安徽猛牛彩印包装有限公司 | A kind of printing ink of wear resistant fluorescent anti-counterfeiting performance |
-
2013
- 2013-11-18 CN CN201310575067.3A patent/CN103666095A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107891676A (en) * | 2017-11-02 | 2018-04-10 | 苏州太平洋印务有限公司 | The typography of edge band |
| CN108841248A (en) * | 2018-05-25 | 2018-11-20 | 安徽猛牛彩印包装有限公司 | A kind of printing ink of wear resistant fluorescent anti-counterfeiting performance |
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| Date | Code | Title | Description |
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| PB01 | Publication | ||
| PB01 | Publication | ||
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| C12 | Rejection of a patent application after its publication | ||
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Application publication date: 20140326 |