CN103642304A - Insulation printing ink and preparation method thereof - Google Patents
Insulation printing ink and preparation method thereof Download PDFInfo
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- CN103642304A CN103642304A CN201310626427.8A CN201310626427A CN103642304A CN 103642304 A CN103642304 A CN 103642304A CN 201310626427 A CN201310626427 A CN 201310626427A CN 103642304 A CN103642304 A CN 103642304A
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- parts
- ink
- oil
- preparation
- resin
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- 238000009413 insulation Methods 0.000 title claims abstract description 12
- 238000002360 preparation method Methods 0.000 title claims description 10
- 238000007639 printing Methods 0.000 title abstract description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 19
- 239000003921 oil Substances 0.000 claims abstract description 17
- 235000019198 oils Nutrition 0.000 claims abstract description 17
- 238000001035 drying Methods 0.000 claims abstract description 11
- 229920000180 alkyd Polymers 0.000 claims abstract description 8
- 229920005989 resin Polymers 0.000 claims abstract description 8
- 239000011347 resin Substances 0.000 claims abstract description 8
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 7
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims abstract description 7
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims abstract description 7
- OKKRPWIIYQTPQF-UHFFFAOYSA-N Trimethylolpropane trimethacrylate Chemical compound CC(=C)C(=O)OCC(CC)(COC(=O)C(C)=C)COC(=O)C(C)=C OKKRPWIIYQTPQF-UHFFFAOYSA-N 0.000 claims abstract description 7
- 230000003647 oxidation Effects 0.000 claims abstract description 7
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 7
- ZTFZSHLWORMEHO-UHFFFAOYSA-A pentaaluminum;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O.[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O.[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O ZTFZSHLWORMEHO-UHFFFAOYSA-A 0.000 claims abstract description 7
- 229920000728 polyester Polymers 0.000 claims abstract description 7
- 239000002994 raw material Substances 0.000 claims abstract description 7
- 239000003549 soybean oil Substances 0.000 claims abstract description 7
- 235000012424 soybean oil Nutrition 0.000 claims abstract description 7
- PIILXFBHQILWPS-UHFFFAOYSA-N tributyltin Chemical compound CCCC[Sn](CCCC)CCCC PIILXFBHQILWPS-UHFFFAOYSA-N 0.000 claims abstract description 7
- LRXTYHSAJDENHV-UHFFFAOYSA-H zinc phosphate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LRXTYHSAJDENHV-UHFFFAOYSA-H 0.000 claims abstract description 7
- 229910000165 zinc phosphate Inorganic materials 0.000 claims abstract description 7
- 238000003756 stirring Methods 0.000 claims description 15
- JHPBZFOKBAGZBL-UHFFFAOYSA-N (3-hydroxy-2,2,4-trimethylpentyl) 2-methylprop-2-enoate Chemical compound CC(C)C(O)C(C)(C)COC(=O)C(C)=C JHPBZFOKBAGZBL-UHFFFAOYSA-N 0.000 claims description 7
- 239000012752 auxiliary agent Substances 0.000 claims description 7
- 239000000178 monomer Substances 0.000 claims description 7
- XDLMVUHYZWKMMD-UHFFFAOYSA-N 3-trimethoxysilylpropyl 2-methylprop-2-enoate Chemical compound CO[Si](OC)(OC)CCCOC(=O)C(C)=C XDLMVUHYZWKMMD-UHFFFAOYSA-N 0.000 claims description 6
- 229920000742 Cotton Polymers 0.000 claims description 6
- 239000004593 Epoxy Substances 0.000 claims description 6
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 claims description 6
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 6
- 238000006243 chemical reaction Methods 0.000 claims description 6
- 239000003153 chemical reaction reagent Substances 0.000 claims description 6
- 230000008878 coupling Effects 0.000 claims description 6
- 238000010168 coupling process Methods 0.000 claims description 6
- 238000005859 coupling reaction Methods 0.000 claims description 6
- 229960000935 dehydrated alcohol Drugs 0.000 claims description 6
- 150000002148 esters Chemical class 0.000 claims description 6
- 229960004756 ethanol Drugs 0.000 claims description 6
- WBHHMMIMDMUBKC-QJWNTBNXSA-N ricinoleic acid Chemical compound CCCCCC[C@@H](O)C\C=C/CCCCCCCC(O)=O WBHHMMIMDMUBKC-QJWNTBNXSA-N 0.000 claims description 6
- 229960003656 ricinoleic acid Drugs 0.000 claims description 6
- FEUQNCSVHBHROZ-UHFFFAOYSA-N ricinoleic acid Natural products CCCCCCC(O[Si](C)(C)C)CC=CCCCCCCCC(=O)OC FEUQNCSVHBHROZ-UHFFFAOYSA-N 0.000 claims description 6
- 210000000582 semen Anatomy 0.000 claims description 6
- 229910000077 silane Inorganic materials 0.000 claims description 6
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 6
- 229920002554 vinyl polymer Polymers 0.000 claims description 6
- JKNCOURZONDCGV-UHFFFAOYSA-N 2-(dimethylamino)ethyl 2-methylprop-2-enoate Chemical compound CN(C)CCOC(=O)C(C)=C JKNCOURZONDCGV-UHFFFAOYSA-N 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 238000009826 distribution Methods 0.000 claims description 3
- 239000000975 dye Substances 0.000 claims description 3
- 238000000227 grinding Methods 0.000 claims description 3
- 239000003112 inhibitor Substances 0.000 claims description 3
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 claims description 3
- 239000000049 pigment Substances 0.000 claims description 3
- 239000002002 slurry Substances 0.000 claims description 3
- 238000010792 warming Methods 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 3
- 230000001681 protective effect Effects 0.000 abstract description 2
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 abstract 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 abstract 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 abstract 1
- 239000002285 corn oil Substances 0.000 abstract 1
- 235000005687 corn oil Nutrition 0.000 abstract 1
- 239000012948 isocyanate Substances 0.000 abstract 1
- 150000002513 isocyanates Chemical class 0.000 abstract 1
- 229920001220 nitrocellulos Polymers 0.000 abstract 1
- 239000012860 organic pigment Substances 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 239000003981 vehicle Substances 0.000 description 2
- 238000003854 Surface Print Methods 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 235000006708 antioxidants Nutrition 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 210000000988 bone and bone Anatomy 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
Landscapes
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention provides insulation printing ink. The insulation printing ink is prepared from the following raw materials in parts by weight: 4-5 parts of epoxidized soybean oil, 2-3 parts of absolute ethyl alcohol, 2-3 parts of corn oil, 5-6 parts of nitrocotton resin, 20-33 parts of methyl methacrylate, 3-5 parts of ethyl acetate, 3-4 parts of aluminium triphosphate, 1-2 parts of zinc phosphate, 30-34 parts of drying oil alkyd resin, 25-30 parts of polyester acrylate, 20-25 parts of methacrylate, 10-12 parts of trimethylolpropane trimethacrylate, 2-3 parts of acrylic acid, 1-2 parts of tributyl tin trichloride, 4-5 parts of isocyanate, 3-4 parts of organic pigment and 4-5 parts of auxiliary. The ink has the characteristics of insulativity, durability, oil resistance, water resistance, oxidation resistance, higher hardness and good fastness and is suitable for printing surfaces of various circuits and cables. The auxiliary can form a protective film on the surface of ink, is resistant to oxidation, keeps the color bright permanently, improves the smoothness and wear resistance and lengthens the service time.
Description
Technical field
The invention belongs to printing ink paint field, relate in particular to a kind of insulation printing-ink and preparation method thereof.
Background technology
The color of ink (form and aspect), body bone (rheological property such as rare thick, degree of mobilization) and drying property are three most important performances of ink.Their kind is a lot, and physical properties is also different, and what have is very thick, very sticky; And have quite rare.What have makes low-melting ink vehicle with vegetables oil; Somely with resin and solvent or water etc., make low-melting ink vehicle.These are to be all that the type of stock, printing process, printing plate and drying means etc. decide according to the object of printing.
The rate of drying of ink, thixotropy, skeleton property have tremendous influence to production efficiency, quality product, and the composition of ink has impact to human body, how to study as far as possible little to harm, production efficiency is high, environmental friendliness, ink that cost is low have profound significance.
Summary of the invention
The object of the present invention is to provide a kind of insulation printing-ink and preparation method thereof, this ink is heat-resisting, resistance to oxidation.
Technical scheme of the present invention is as follows:
An insulation printing-ink, is characterized in that being made by the raw material of following weight part: epoxy soybean oil 4-5, dehydrated alcohol 2-3, Semen Maydis oil 2-3, nitro-cotton resin 5-6, methyl methacrylate 20-33, vinyl acetic monomer 3-5, aluminium triphosphate 3-4, zinc phosphate 1-2, drying oil alkyd resin 30-34, polyester acrylate 25-30, methacrylic ester 20-25, trimethylolpropane trimethacrylate 10-12, vinylformic acid 2-3, tributyl tin trichloride 1-2, isocyanic ester 4-5, pigment dyestuff 3-4, auxiliary agent 4-5;
Described auxiliary agent is made by the raw material of following weight part: Silane coupling reagent KH-570 2-3, dimethylaminoethyl methacrylate 3-4, morpholine 1-2, neopentyl glycol 3-4, oxidation inhibitor 1035 1-2, ricinolic acid 1-2, linking agent TAC1-2, ethanol 20-24; Preparation method mixes Silane coupling reagent KH-570, ricinolic acid, ethanol, is heated to 60-70 ℃, stirs after 20-30 minute, then adds other remaining component, is warming up to 80-85 ℃, stirs 30-40 minutes, obtains.
The preparation method of described insulation printing-ink, it is characterized in that comprising the following steps: by dehydrated alcohol, nitro-cotton resin, methyl methacrylate, vinyl acetic monomer, aluminium triphosphate, zinc phosphate, drying oil alkyd resin, trimethylolpropane trimethacrylate, vinylformic acid mixes, under 1000-1400 rev/min of stirring, add tributyl tin trichloride, isocyanic ester, speed with 5-8 ℃/minute is heated to 60-90 ℃, add epoxy soybean oil, Semen Maydis oil, polyester acrylate, methacrylic ester, continue stirring reaction 20-30 minute, add other remaining components, continue stirring reaction 1.5-2 hour, grinding distribution becomes the slurry of 20-40 μ m, obtain.
Beneficial effect of the present invention
Ink of the present invention is used the monomer polymerizations such as drying oil alkyd resin, methacrylic ester, and the ink obtaining has insulation, durable, oil resistant, water-fast, resistance to oxidation, hardness is higher, fastness is good feature, is applicable to various circuit, cable surface printing.Auxiliary agent of the present invention can form protective membrane in ink pellet surface, isolated air, and the surface that prevents water and other molecules corrosion ink and spraying object in atmosphere, anti-oxidant, make color bright-coloured lastingly, and improve slickness, wear resistance, extend working time.
Embodiment
An insulation printing-ink, by following weight part (kilogram) raw material make: epoxy soybean oil 4.5, dehydrated alcohol 2.5, Semen Maydis oil 2.5, nitro-cotton resin 5.5, methyl methacrylate 26, vinyl acetic monomer 4, aluminium triphosphate 3.5, zinc phosphate 1.5, drying oil alkyd resin 32, polyester acrylate 27, methacrylic ester 23, trimethylolpropane trimethacrylate 11, vinylformic acid 2.5, tributyl tin trichloride 1.5, isocyanic ester 4.5, pigment dyestuff 3.5, auxiliary agent 4.5;
Described auxiliary agent by following weight part (kilogram) raw material make: Silane coupling reagent KH-570 2.5, dimethylaminoethyl methacrylate 3.5, morpholine 1.5, neopentyl glycol 3.5, oxidation inhibitor 1,035 1.5, ricinolic acid 1.5, linking agent TAC1.5, ethanol 23; Preparation method mixes Silane coupling reagent KH-570, ricinolic acid, ethanol, is heated to 65 ℃, stirs after 25 minutes, then adds other remaining component, is warming up to 83 ℃, stirs 35 minutes, obtains.
The preparation method of described insulation printing-ink, comprise the following steps: by dehydrated alcohol, nitro-cotton resin, methyl methacrylate, vinyl acetic monomer, aluminium triphosphate, zinc phosphate, drying oil alkyd resin, trimethylolpropane trimethacrylate, vinylformic acid mixes, under 1200 revs/min of stirrings, add tributyl tin trichloride, isocyanic ester, with the speed of 6 ℃/minute, be heated to 70 ℃, add epoxy soybean oil, Semen Maydis oil, polyester acrylate, methacrylic ester, continue stirring reaction 25 minutes, add other remaining components, continue stirring reaction 1.7 hours, grinding distribution becomes the slurry of 30 μ m, obtain.
Ink quality homogeneous of the present invention, tinting strength, adhere firmly degree, viscosity, first dryness and other performances have reached the requirement of QB/T2024-94 standard.
Claims (2)
1. an insulation printing-ink, is characterized in that being made by the raw material of following weight part: epoxy soybean oil 4-5, dehydrated alcohol 2-3, Semen Maydis oil 2-3, nitro-cotton resin 5-6, methyl methacrylate 20-33, vinyl acetic monomer 3-5, aluminium triphosphate 3-4, zinc phosphate 1-2, drying oil alkyd resin 30-34, polyester acrylate 25-30, methacrylic ester 20-25, trimethylolpropane trimethacrylate 10-12, vinylformic acid 2-3, tributyl tin trichloride 1-2, isocyanic ester 4-5, pigment dyestuff 3-4, auxiliary agent 4-5;
Described auxiliary agent is made by the raw material of following weight part: Silane coupling reagent KH-570 2-3, dimethylaminoethyl methacrylate 3-4, morpholine 1-2, neopentyl glycol 3-4, oxidation inhibitor 1035 1-2, ricinolic acid 1-2, linking agent TAC1-2, ethanol 20-24; Preparation method mixes Silane coupling reagent KH-570, ricinolic acid, ethanol, is heated to 60-70 ℃, stirs after 20-30 minute, then adds other remaining component, is warming up to 80-85 ℃, stirs 30-40 minutes, obtains.
2. the preparation method of printing-ink according to claim 1 insulate, it is characterized in that comprising the following steps: by dehydrated alcohol, nitro-cotton resin, methyl methacrylate, vinyl acetic monomer, aluminium triphosphate, zinc phosphate, drying oil alkyd resin, trimethylolpropane trimethacrylate, vinylformic acid mixes, under 1000-1400 rev/min of stirring, add tributyl tin trichloride, isocyanic ester, speed with 5-8 ℃/minute is heated to 60-90 ℃, add epoxy soybean oil, Semen Maydis oil, polyester acrylate, methacrylic ester, continue stirring reaction 20-30 minute, add other remaining components, continue stirring reaction 1.5-2 hour, grinding distribution becomes the slurry of 20-40 μ m, obtain.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310626427.8A CN103642304A (en) | 2013-12-02 | 2013-12-02 | Insulation printing ink and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310626427.8A CN103642304A (en) | 2013-12-02 | 2013-12-02 | Insulation printing ink and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103642304A true CN103642304A (en) | 2014-03-19 |
Family
ID=50247597
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310626427.8A Pending CN103642304A (en) | 2013-12-02 | 2013-12-02 | Insulation printing ink and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103642304A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106065226A (en) * | 2016-05-31 | 2016-11-02 | 山东鲁信天印务有限公司 | A kind of novel environment friendly printing-ink and preparation method thereof, application |
| CN106221359A (en) * | 2016-08-17 | 2016-12-14 | 胡庆福 | A kind of photosensitive marking fluid composition and preparation method thereof |
| CN118516010A (en) * | 2024-07-19 | 2024-08-20 | 广州精卓新材料有限公司 | Weather-resistant mirror ink and preparation method thereof |
-
2013
- 2013-12-02 CN CN201310626427.8A patent/CN103642304A/en active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106065226A (en) * | 2016-05-31 | 2016-11-02 | 山东鲁信天印务有限公司 | A kind of novel environment friendly printing-ink and preparation method thereof, application |
| CN106221359A (en) * | 2016-08-17 | 2016-12-14 | 胡庆福 | A kind of photosensitive marking fluid composition and preparation method thereof |
| CN118516010A (en) * | 2024-07-19 | 2024-08-20 | 广州精卓新材料有限公司 | Weather-resistant mirror ink and preparation method thereof |
| CN118516010B (en) * | 2024-07-19 | 2024-09-17 | 广州精卓新材料有限公司 | Weather-resistant mirror ink and preparation method thereof |
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| Date | Code | Title | Description |
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| PB01 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
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| C12 | Rejection of a patent application after its publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20140319 |