CN103666083A - High-printability printing ink and preparation method thereof - Google Patents
High-printability printing ink and preparation method thereof Download PDFInfo
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- CN103666083A CN103666083A CN201310574927.1A CN201310574927A CN103666083A CN 103666083 A CN103666083 A CN 103666083A CN 201310574927 A CN201310574927 A CN 201310574927A CN 103666083 A CN103666083 A CN 103666083A
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- 238000002360 preparation method Methods 0.000 title claims description 10
- 238000007639 printing Methods 0.000 title abstract description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000003822 epoxy resin Substances 0.000 claims abstract description 7
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 7
- KCTAWXVAICEBSD-UHFFFAOYSA-N prop-2-enoyloxy prop-2-eneperoxoate Chemical compound C=CC(=O)OOOC(=O)C=C KCTAWXVAICEBSD-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000002994 raw material Substances 0.000 claims abstract description 7
- 229910000476 molybdenum oxide Inorganic materials 0.000 claims abstract description 4
- 230000003647 oxidation Effects 0.000 claims abstract description 4
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 4
- PQQKPALAQIIWST-UHFFFAOYSA-N oxomolybdenum Chemical compound [Mo]=O PQQKPALAQIIWST-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 4
- 235000012239 silicon dioxide Nutrition 0.000 claims abstract description 4
- 238000003756 stirring Methods 0.000 claims description 15
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 12
- 230000003044 adaptive effect Effects 0.000 claims description 10
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 claims description 9
- 239000012752 auxiliary agent Substances 0.000 claims description 7
- XDLMVUHYZWKMMD-UHFFFAOYSA-N 3-trimethoxysilylpropyl 2-methylprop-2-enoate Chemical compound CO[Si](OC)(OC)CCCOC(=O)C(C)=C XDLMVUHYZWKMMD-UHFFFAOYSA-N 0.000 claims description 6
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 6
- SSOONFBDIYMPEU-UHFFFAOYSA-N [3-hydroxy-2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propyl] prop-2-enoate Chemical compound OCC(CO)(CO)COCC(CO)(CO)COC(=O)C=C SSOONFBDIYMPEU-UHFFFAOYSA-N 0.000 claims description 6
- 238000006243 chemical reaction Methods 0.000 claims description 6
- 239000003153 chemical reaction reagent Substances 0.000 claims description 6
- 230000008878 coupling Effects 0.000 claims description 6
- 238000010168 coupling process Methods 0.000 claims description 6
- 238000005859 coupling reaction Methods 0.000 claims description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 6
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 6
- 238000005502 peroxidation Methods 0.000 claims description 6
- WBHHMMIMDMUBKC-QJWNTBNXSA-N ricinoleic acid Chemical compound CCCCCC[C@@H](O)C\C=C/CCCCCCCC(O)=O WBHHMMIMDMUBKC-QJWNTBNXSA-N 0.000 claims description 6
- 229960003656 ricinoleic acid Drugs 0.000 claims description 6
- FEUQNCSVHBHROZ-UHFFFAOYSA-N ricinoleic acid Natural products CCCCCCC(O[Si](C)(C)C)CC=CCCCCCCCC(=O)OC FEUQNCSVHBHROZ-UHFFFAOYSA-N 0.000 claims description 6
- 229910000077 silane Inorganic materials 0.000 claims description 6
- 229920002050 silicone resin Polymers 0.000 claims description 6
- VXHFNALHLRWIIU-UHFFFAOYSA-N tert-butyl 2,2-dimethylpropanoate Chemical compound CC(C)(C)OC(=O)C(C)(C)C VXHFNALHLRWIIU-UHFFFAOYSA-N 0.000 claims description 6
- DAKWPKUUDNSNPN-UHFFFAOYSA-N Trimethylolpropane triacrylate Chemical compound C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 238000009826 distribution Methods 0.000 claims description 3
- 239000000975 dye Substances 0.000 claims description 3
- 238000000227 grinding Methods 0.000 claims description 3
- 239000003112 inhibitor Substances 0.000 claims description 3
- 239000000049 pigment Substances 0.000 claims description 3
- 239000000244 polyoxyethylene sorbitan monooleate Substances 0.000 claims description 3
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 claims description 3
- 229920000053 polysorbate 80 Polymers 0.000 claims description 3
- 229960001866 silicon dioxide Drugs 0.000 claims description 3
- 239000002002 slurry Substances 0.000 claims description 3
- 238000010792 warming Methods 0.000 claims description 3
- 229910052751 metal Inorganic materials 0.000 abstract description 2
- 239000002184 metal Substances 0.000 abstract description 2
- 239000000123 paper Substances 0.000 abstract description 2
- 239000004033 plastic Substances 0.000 abstract description 2
- 229920003023 plastic Polymers 0.000 abstract description 2
- 230000001681 protective effect Effects 0.000 abstract description 2
- 229920005989 resin Polymers 0.000 abstract description 2
- 239000011347 resin Substances 0.000 abstract description 2
- 239000004753 textile Substances 0.000 abstract description 2
- 230000002349 favourable effect Effects 0.000 abstract 3
- -1 polytetrafluoroethylene Polymers 0.000 abstract 2
- 229920001343 polytetrafluoroethylene Polymers 0.000 abstract 2
- 239000004810 polytetrafluoroethylene Substances 0.000 abstract 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 abstract 1
- MPIAGWXWVAHQBB-UHFFFAOYSA-N [3-prop-2-enoyloxy-2-[[3-prop-2-enoyloxy-2,2-bis(prop-2-enoyloxymethyl)propoxy]methyl]-2-(prop-2-enoyloxymethyl)propyl] prop-2-enoate Chemical compound C=CC(=O)OCC(COC(=O)C=C)(COC(=O)C=C)COCC(COC(=O)C=C)(COC(=O)C=C)COC(=O)C=C MPIAGWXWVAHQBB-UHFFFAOYSA-N 0.000 abstract 1
- KUDUQBURMYMBIJ-UHFFFAOYSA-N ethylene glycol diacrylate Substances C=CC(=O)OCCOC(=O)C=C KUDUQBURMYMBIJ-UHFFFAOYSA-N 0.000 abstract 1
- 235000021388 linseed oil Nutrition 0.000 abstract 1
- 239000000944 linseed oil Substances 0.000 abstract 1
- 230000001050 lubricating effect Effects 0.000 abstract 1
- 150000002739 metals Chemical class 0.000 abstract 1
- 239000012860 organic pigment Substances 0.000 abstract 1
- 230000002035 prolonged effect Effects 0.000 abstract 1
- 229910052710 silicon Inorganic materials 0.000 abstract 1
- 239000010703 silicon Substances 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- 239000002352 surface water Substances 0.000 abstract 1
- ZNVWLZGTXSHPMH-UHFFFAOYSA-N tert-butyl 3-hydroperoxy-2,2-dimethylpropanoate Chemical compound CC(C)(C)OC(=O)C(C)(C)COO ZNVWLZGTXSHPMH-UHFFFAOYSA-N 0.000 abstract 1
- 238000001035 drying Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 206010059866 Drug resistance Diseases 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 235000006708 antioxidants Nutrition 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 210000000988 bone and bone Anatomy 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
Landscapes
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention relates to a high-printability printing ink which is prepared from the following raw materials in parts by weight: 30-34 parts of E-12 epoxy resin, 7-10 parts of 1,6-ethylene glycol diacrylate, 5-8 parts of dipentaerythritol hexaacrylate, 1-2 parts of tert-butyl peroxylpivalate, 3-4 parts of linseed oil, 12-14 parts of organic silicon resin, 2-3 parts of polytetrafluoroethylene, 1-2 parts of molybdenum oxide, 30-35 parts of epoxy acrylate, 3-4 parts of polytetrafluoroethylene, 2-4 parts of silicon dioxide, 3-4 parts of organic pigment and 4-5 parts of assistant. The ink has favorable lubricating property and favorable leveling property, and is easy for application; the ink has the advantages of high surface water resistance, high chemical resistance, high curing speed, high toughness, high wear resistance and excellent durability; and the ink has favorable printability, can be printed on the surfaces of paper, plastics, metals and textiles, and has high fastness. The assistant can form a protective film on the ink surface to resist oxidation, so that the color can be bright permanently; and the smoothness and wear resistance are enhanced, and the service time is prolonged.
Description
Technical field
The invention belongs to printing ink paint field, relate in particular to good printing-ink of a kind of adaptive and preparation method thereof.
Background technology
The color of ink (form and aspect), body bone (rheological property such as rare thick, degree of mobilization) and drying property are three most important performances of ink.Their kind is a lot, and physical properties is also different, and what have is very thick, very sticky; And have quite rare.What have makes low-melting ink vehicle with vegetables oil; Somely with resin and solvent or water etc., make low-melting ink vehicle.These are to be all that the type of stock, printing process, printing plate and drying means etc. decide according to the object of printing.
The rate of drying of ink, thixotropy, skeleton property have tremendous influence to production efficiency, quality product, and the composition of ink has impact to human body, how to study as far as possible little to harm, production efficiency is high, environmental friendliness, ink that cost is low have profound significance.
Summary of the invention
The object of the present invention is to provide good printing-ink of a kind of adaptive and preparation method thereof, this ink adaptive is good, rub resistance.
Technical scheme of the present invention is as follows:
The good printing-ink of adaptive, is characterized in that being made by the raw material of following weight part: E-12 epoxy resin 30-34,1.6 glycol diacrylate 7-10, dipentaerythritol acrylate 5-8, peroxidation trimethylacetic acid tert-butyl ester 1-2, oleum lini 3-4, silicone resin 12-14, tetrafluoroethylene 2-3, molybdenum oxide 1-2, epoxy acrylate 30-35, tetrafluoroethylene 3-4, silicon-dioxide 2-4, pigment dyestuff 3-4, auxiliary agent 4-5;
Described auxiliary agent is made by the raw material of following weight part: Silane coupling reagent KH-570 2-3, Viscoat 295 3-4,2-n-octyl-4-isothiazoline-3-ketone 1-2,2-amino-2-methyl-1-propyl alcohol 1-2, polyoxyethylene sorbitan monooleate 2-3, ricinolic acid 1-2, oxidation inhibitor 1035 1-2, linking agent TAC1-2, ethanol 20-24; Preparation method mixes Silane coupling reagent KH-570, ricinolic acid, ethanol, is heated to 60-70 ℃, stirs after 20-30 minute, then adds other remaining component, is warming up to 80-85 ℃, stirs 30-40 minutes, obtains.
The preparation method of the good printing-ink of described adaptive, it is characterized in that comprising the following steps: E-12 epoxy resin, silicone resin, epoxy acrylate are mixed, under 1000-1400 rev/min of stirring, add the peroxidation trimethylacetic acid tert-butyl ester,, speed with 5-8 ℃/minute is heated to 60-90 ℃, add 1.6 glycol diacrylates, dipentaerythritol acrylate, tetrafluoroethylene, continue stirring reaction 10-20 minute, add other remaining components, continue stirring reaction 2-2.5 hour, grinding distribution becomes the slurry of 20-30 μ m, obtains.
Beneficial effect of the present invention
It is good that ink of the present invention has oilness, good leveling property, easily application; Water-fast, the drug resistance in surface, quick solidifying, good toughness, wear-resisting, have excellent weather resistance; Adaptability is good, at paper, plastics, metal, textile surface, all can print, and fastness is high.Auxiliary agent of the present invention can form protective membrane in ink pellet surface, isolated air, and the surface that prevents water and other molecules corrosion ink and spraying object in atmosphere, anti-oxidant, make color bright-coloured lastingly, and improve slickness, wear resistance, extend working time.
Embodiment
The good printing-ink of adaptive, by following weight part (kilogram) raw material make: E-12 epoxy resin 32,1.6 glycol diacrylates 9, dipentaerythritol acrylate 6, the peroxidation trimethylacetic acid tert-butyl ester 1.5, oleum lini 3.5, silicone resin 13, tetrafluoroethylene 2.5, molybdenum oxide 1.5, epoxy acrylate 33, tetrafluoroethylene 3.5, silicon-dioxide 3, pigment dyestuff 3.5, auxiliary agent 4.5;
Described auxiliary agent by following weight part (kilogram) raw material make: Silane coupling reagent KH-570 2.5, Viscoat 295 3.5,2-n-octyl-4-isothiazoline-3-ketone 1.5,2-amino-2-methyl-1-propyl alcohol 1.5, polyoxyethylene sorbitan monooleate 2.5, ricinolic acid 1.5, oxidation inhibitor 1,035 1.5, linking agent TAC1.5, ethanol 22; Preparation method mixes Silane coupling reagent KH-570, ricinolic acid, ethanol, is heated to 65 ℃, stirs after 26 minutes, then adds other remaining component, is warming up to 83 ℃, stirs 34 minutes, obtains.
The preparation method of the good printing-ink of described adaptive, comprise the following steps: E-12 epoxy resin, silicone resin, epoxy acrylate are mixed, under 1200 revs/min of stirrings, add the peroxidation trimethylacetic acid tert-butyl ester,, with the speed of 6 ℃/minute, be heated to 75 ℃, add 1.6 glycol diacrylates, dipentaerythritol acrylate, tetrafluoroethylene, continue stirring reaction 15 minutes, add other remaining components, continue stirring reaction 2.4 hours, grinding distribution becomes the slurry of 25 μ m, obtains.
Ink quality homogeneous of the present invention, tinting strength, adhere firmly degree, viscosity, first dryness and other performances have reached the requirement of QB/T2024-94 standard.
Claims (2)
1. the good printing-ink of adaptive, is characterized in that being made by the raw material of following weight part: E-12 epoxy resin 30-34,1.6 glycol diacrylate 7-10, dipentaerythritol acrylate 5-8, peroxidation trimethylacetic acid tert-butyl ester 1-2, oleum lini 3-4, silicone resin 12-14, tetrafluoroethylene 2-3, molybdenum oxide 1-2, epoxy acrylate 30-35, tetrafluoroethylene 3-4, silicon-dioxide 2-4, pigment dyestuff 3-4, auxiliary agent 4-5;
Described auxiliary agent is made by the raw material of following weight part: Silane coupling reagent KH-570 2-3, Viscoat 295 3-4,2-n-octyl-4-isothiazoline-3-ketone 1-2,2-amino-2-methyl-1-propyl alcohol 1-2, polyoxyethylene sorbitan monooleate 2-3, ricinolic acid 1-2, oxidation inhibitor 1035 1-2, linking agent TAC1-2, ethanol 20-24; Preparation method mixes Silane coupling reagent KH-570, ricinolic acid, ethanol, is heated to 60-70 ℃, stirs after 20-30 minute, then adds other remaining component, is warming up to 80-85 ℃, stirs 30-40 minutes, obtains.
2. the preparation method of the good printing-ink of adaptive according to claim 1, it is characterized in that comprising the following steps: E-12 epoxy resin, silicone resin, epoxy acrylate are mixed, under 1000-1400 rev/min of stirring, add the peroxidation trimethylacetic acid tert-butyl ester,, speed with 5-8 ℃/minute is heated to 60-90 ℃, add 1.6 glycol diacrylates, dipentaerythritol acrylate, tetrafluoroethylene, continue stirring reaction 10-20 minute, add other remaining components, continue stirring reaction 2-2.5 hour, grinding distribution becomes the slurry of 20-30 μ m, obtains.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310574927.1A CN103666083A (en) | 2013-11-18 | 2013-11-18 | High-printability printing ink and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310574927.1A CN103666083A (en) | 2013-11-18 | 2013-11-18 | High-printability printing ink and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103666083A true CN103666083A (en) | 2014-03-26 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310574927.1A Pending CN103666083A (en) | 2013-11-18 | 2013-11-18 | High-printability printing ink and preparation method thereof |
Country Status (1)
| Country | Link |
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| CN (1) | CN103666083A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104177910A (en) * | 2014-07-28 | 2014-12-03 | 蚌埠德美过滤技术有限公司 | Printing ink with fly-killing and insect-expelling effects |
| CN109517434A (en) * | 2018-11-07 | 2019-03-26 | 温雄权 | A kind of adhesive force and the good ink and preparation method thereof of heat resistance |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1970656A (en) * | 2006-11-23 | 2007-05-30 | 北京印刷学院 | Thermoforming plastic printing ink adopting ultraviolet-infra red drying technology |
-
2013
- 2013-11-18 CN CN201310574927.1A patent/CN103666083A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1970656A (en) * | 2006-11-23 | 2007-05-30 | 北京印刷学院 | Thermoforming plastic printing ink adopting ultraviolet-infra red drying technology |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104177910A (en) * | 2014-07-28 | 2014-12-03 | 蚌埠德美过滤技术有限公司 | Printing ink with fly-killing and insect-expelling effects |
| CN109517434A (en) * | 2018-11-07 | 2019-03-26 | 温雄权 | A kind of adhesive force and the good ink and preparation method thereof of heat resistance |
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| PB01 | Publication | ||
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Application publication date: 20140326 |