CN103865326A - Printing ink for surface of light-resistant metal and preparation method thereof - Google Patents
Printing ink for surface of light-resistant metal and preparation method thereof Download PDFInfo
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- CN103865326A CN103865326A CN201410067512.XA CN201410067512A CN103865326A CN 103865326 A CN103865326 A CN 103865326A CN 201410067512 A CN201410067512 A CN 201410067512A CN 103865326 A CN103865326 A CN 103865326A
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Abstract
The invention discloses a printing ink for the surface of a light-resistant metal. The printing ink is prepared from the following raw materials in parts by weight: 4-5 parts by weight of dioctyl maleate, 3-4 parts by weight of acetic ether, 20-24 parts by weight of E-12 epoxy resin, 12-15 parts by weight of alkoxylated pentaerythritol tetraacrylate, 15-20 parts by weight of butyl acrylate, 14-18 parts by weight of dipentaerythritol hexaacrylate, 2-3 parts by weight of dioctyl phthalate, 2-3 parts by weight of benzotriazole, 20-24 parts by weight of epoxy acrylate, 12-14 parts by weight of trimethylolpropane triacrylate, 1-2 parts by weight of calcium naphthenate, 1-2 parts by weight of tert-butyl peroxypivalate, 3-4 parts by weight of organic pigment and 4-5 parts by weight of auxiliary. The printing ink disclosed by the invention is excellent in agglutinating property to the surface of the metal, and has a protection function of preventing the surface of the metal from being rusted and corroded; and a formed ink coating has the characteristics of heat resistance, oil resistance, water resistance, oxidation resistance, high hardness, good flexibility, and good fastness, is excellent in light resistance performance, durably keeps a bright color, and is suitable for coating the surface of the metal such as a kitchen utensil and household appliance.
Description
Technical field
The invention belongs to printing ink paint field, relate in particular to a kind of fast light metallic surface printing-ink and preparation method thereof.
Background technology
The color (form and aspect) of ink, body bone (rheological property such as rare thick, degree of mobilization) and drying property are three most important performances of ink.Their kind is a lot, and physical properties is also different, and what have is very thick, very sticky; And have quite rare.What have makes low-melting ink vehicle with vegetables oil; Somely make low-melting ink vehicle with resin and solvent or water etc.These are all that the type and the drying means etc. that are stock, printing process, printing plate according to the object of printing decide.
The rate of drying of ink, thixotropy, skeleton property have tremendous influence to production efficiency, quality product, and the composition of ink has impact to human body, how to study as far as possible little to harm, production efficiency is high, environmental friendliness, ink that cost is low have profound significance.
Summary of the invention
The object of the present invention is to provide a kind of fast light metallic surface printing-ink and preparation method thereof, this ink is fast light, corrosion-resistant.
Technical scheme of the present invention is as follows:
A kind of fast light metallic surface printing-ink, is characterized in that being made up of the raw material of following weight part: dioctyl maleate 4-5, vinyl acetic monomer 3-4, E-12 epoxy resin 20-24, alkoxylate tetramethylol methane tetraacrylate 12-15, butyl acrylate 15-20, dipentaerythrityl ether six acrylate 14-18, dioctyl phthalate (DOP) 2-3, benzotriazole 2-3, epoxy acrylate 20-24, Viscoat 295 12-14, calcium naphthenate 1-2, peroxidation trimethylacetic acid tert-butyl ester 1-2, pigment dyestuff 3-4, auxiliary agent 4-5;
Described auxiliary agent is made up of the raw material of following weight part: Silane coupling reagent KH-570 2-3, tri (propylene glycol) diacrylate 2-3, methacrylic acid-2-hydroxy methacrylate 2-3, tea-polyphenol 2-3, glyceryl monostearate 4-5, p-tert-butyl benzoic acid 1-2, oxidation inhibitor 1035 1-2, ricinolic acid 1-2, linking agent TAC1-2, ethanol 20-24; Preparation method mixes Silane coupling reagent KH-570, ricinolic acid, ethanol, is heated to 60-70 ℃, stirs after 20-30 minute, then adds other remaining component, is warming up to 80-85 ℃, stirs 30-40 minutes, to obtain final product.
The preparation method of printing-ink for described fast light metallic surface, it is characterized in that comprising the following steps: by dioctyl maleate, vinyl acetic monomer, E-12 epoxy resin, butyl acrylate, dioctyl phthalate (DOP), epoxy acrylate mixes, under 1100-1400 rev/min of stirring, speed with 5-8 ℃/point is heated to 60-80 ℃, add the peroxidation trimethylacetic acid tert-butyl ester, stirring reaction 15-20 minute, add alkoxylate tetramethylol methane tetraacrylate, dipentaerythrityl ether six acrylate, Viscoat 295, continue stirring reaction 20-30 minute, add other remaining components, continue stirring reaction 1.5-2 hour, grinding distribution becomes the slurry of 20-40 μ m, obtain.
Beneficial effect of the present invention
Ink of the present invention has excellent cohesiveness to metallic surface; and there is to antirust, etch-proof provide protection metallic surface; the ink coating forming has that heat-resisting, oil resistant, water-fast, resistance to oxidation, hardness are high, good toughness, feature that fastness is good; and light fastness excellence; the beautiful color of lasting maintenance, is applicable to the coating metal surfaces such as kitchen utensils, household electrical appliances.Auxiliary agent of the present invention can form protective membrane in ink pellet surface, isolated air, and the surface that prevents water and other molecules corrosion ink and spraying object in atmosphere, anti-oxidant, make color bright-coloured lastingly, and improve slickness, wear resistance, extend working time.
Embodiment
A kind of fast light metallic surface printing-ink, by following weight part (kilogram) raw material make: dioctyl maleate 4.5, vinyl acetic monomer 3.5, E-12 epoxy resin 23, alkoxylate tetramethylol methane tetraacrylate 14, butyl acrylate 17, dipentaerythrityl ether six acrylate 16, dioctyl phthalate (DOP) 2.5, benzotriazole 2.5, epoxy acrylate 22, Viscoat 295 13, calcium naphthenate 1.5, the peroxidation trimethylacetic acid tert-butyl ester 1.5, pigment dyestuff 3.5, auxiliary agent 4.5;
Described auxiliary agent by following weight part (kilogram) raw material make: Silane coupling reagent KH-570 2.5, tri (propylene glycol) diacrylate 2.5, methacrylic acid-2-hydroxy methacrylate 2.5, tea-polyphenol 2.5, glyceryl monostearate 4.6, p-tert-butyl benzoic acid 1.4, oxidation inhibitor 1,035 1.5, ricinolic acid 1.5, linking agent TAC1.4, ethanol 23; Preparation method mixes Silane coupling reagent KH-570, ricinolic acid, ethanol, is heated to 65 ℃, stirs after 26 minutes, then adds other remaining component, is warming up to 84 ℃, stirs 38 minutes, to obtain final product.
The preparation method of printing-ink for described fast light metallic surface, comprise the following steps: by dioctyl maleate, vinyl acetic monomer, E-12 epoxy resin, butyl acrylate, dioctyl phthalate (DOP), epoxy acrylate mixes, under 1300 revs/min of stirrings, be heated to 70 ℃ with the speed of 6 ℃/point, add the peroxidation trimethylacetic acid tert-butyl ester, stirring reaction 18 minutes, add alkoxylate tetramethylol methane tetraacrylate, dipentaerythrityl ether six acrylate, Viscoat 295, continue stirring reaction 25 minutes, add other remaining components, continue stirring reaction 1.7 hours, grinding distribution becomes the slurry of 30 μ m, obtain.
Ink quality homogeneous of the present invention, tinting strength, adhere firmly degree, viscosity, first dryness and other performances have reached the requirement of QB/T2024-94 standard.
Claims (2)
1. a fast light metallic surface printing-ink, is characterized in that being made up of the raw material of following weight part: dioctyl maleate 4-5, vinyl acetic monomer 3-4, E-12 epoxy resin 20-24, alkoxylate tetramethylol methane tetraacrylate 12-15, butyl acrylate 15-20, dipentaerythrityl ether six acrylate 14-18, dioctyl phthalate (DOP) 2-3, benzotriazole 2-3, epoxy acrylate 20-24, Viscoat 295 12-14, calcium naphthenate 1-2, peroxidation trimethylacetic acid tert-butyl ester 1-2, pigment dyestuff 3-4, auxiliary agent 4-5;
Described auxiliary agent is made up of the raw material of following weight part: Silane coupling reagent KH-570 2-3, tri (propylene glycol) diacrylate 2-3, methacrylic acid-2-hydroxy methacrylate 2-3, tea-polyphenol 2-3, glyceryl monostearate 4-5, p-tert-butyl benzoic acid 1-2, oxidation inhibitor 1035 1-2, ricinolic acid 1-2, linking agent TAC1-2, ethanol 20-24; Preparation method mixes Silane coupling reagent KH-570, ricinolic acid, ethanol, is heated to 60-70 ℃, stirs after 20-30 minute, then adds other remaining component, is warming up to 80-85 ℃, stirs 30-40 minutes, to obtain final product.
2. the preparation method of printing-ink for fast light metallic surface according to claim 1, it is characterized in that comprising the following steps: by dioctyl maleate, vinyl acetic monomer, E-12 epoxy resin, butyl acrylate, dioctyl phthalate (DOP), epoxy acrylate mixes, under 1100-1400 rev/min of stirring, speed with 5-8 ℃/point is heated to 60-80 ℃, add the peroxidation trimethylacetic acid tert-butyl ester, stirring reaction 15-20 minute, add alkoxylate tetramethylol methane tetraacrylate, dipentaerythrityl ether six acrylate, Viscoat 295, continue stirring reaction 20-30 minute, add other remaining components, continue stirring reaction 1.5-2 hour, grinding distribution becomes the slurry of 20-40 μ m, obtain.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410067512.XA CN103865326A (en) | 2014-02-27 | 2014-02-27 | Printing ink for surface of light-resistant metal and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410067512.XA CN103865326A (en) | 2014-02-27 | 2014-02-27 | Printing ink for surface of light-resistant metal and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103865326A true CN103865326A (en) | 2014-06-18 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
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| CN201410067512.XA Pending CN103865326A (en) | 2014-02-27 | 2014-02-27 | Printing ink for surface of light-resistant metal and preparation method thereof |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104312276A (en) * | 2014-11-10 | 2015-01-28 | 合肥宏图彩印有限公司 | Antibacterial heat-resistant special ink and preparation method thereof |
| CN106349780A (en) * | 2016-08-30 | 2017-01-25 | 无锡益联机械有限公司 | Rust prevention painting for bead ring and preparing method thereof |
| CN111201253A (en) * | 2017-09-27 | 2020-05-26 | 韩华思路信(株) | Vinyl chloride-based resin composition and method for preparing the same |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103555052A (en) * | 2013-10-30 | 2014-02-05 | 合肥市华美光电科技有限公司 | High-lubricity printing ink and preparation method thereof |
-
2014
- 2014-02-27 CN CN201410067512.XA patent/CN103865326A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103555052A (en) * | 2013-10-30 | 2014-02-05 | 合肥市华美光电科技有限公司 | High-lubricity printing ink and preparation method thereof |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104312276A (en) * | 2014-11-10 | 2015-01-28 | 合肥宏图彩印有限公司 | Antibacterial heat-resistant special ink and preparation method thereof |
| CN106349780A (en) * | 2016-08-30 | 2017-01-25 | 无锡益联机械有限公司 | Rust prevention painting for bead ring and preparing method thereof |
| CN111201253A (en) * | 2017-09-27 | 2020-05-26 | 韩华思路信(株) | Vinyl chloride-based resin composition and method for preparing the same |
| CN111201253B (en) * | 2017-09-27 | 2022-05-24 | 韩华思路信(株) | Vinyl chloride-based resin composition and method for preparing the same |
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Application publication date: 20140618 |
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| RJ01 | Rejection of invention patent application after publication |