CN103642312A - Printing ink and preparation method thereof - Google Patents
Printing ink and preparation method thereof Download PDFInfo
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- CN103642312A CN103642312A CN201310626827.9A CN201310626827A CN103642312A CN 103642312 A CN103642312 A CN 103642312A CN 201310626827 A CN201310626827 A CN 201310626827A CN 103642312 A CN103642312 A CN 103642312A
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Abstract
The invention discloses a printing ink prepared from the following raw materials in parts by weight: 2-3 parts of an organic pigment, 4-6 parts of aluminum hydroxide, 20-24 parts of polyacrylate, 4-5 parts of silicon dioxide, 5-8 parts of pentaerythritol, 2-3 parts of poly amine phosphate, 40-45 parts of bisphenol A epoxy acrylate, 10-12 parts of tripropylene glycol diacrylate, 3-4 parts of tetra-(2-hydroxyethyl) adipamide, 2-3 parts of tri-(2-hydroxyethyl) isocyanuratem 4-5 parts of dimethyl sulfoxide, 6-9 parts of pentaerythritol triacrylate, 2-3 parts of tributyl tin trichloride and 4-5 parts of an auxiliary agent. The printing ink disclosed by the invention is high in adhesive force and good in toughness and fastness, is scratch-resistant, wear-resistant, high-temperature-resistant, oil-proof, waterproof and oxidation-resistant, has a good bonding effect on glass, metals, textiles and plastics, and is good in lubricating property and dispersity, suitable for spray coating and roller coating, and high in production efficiency. The auxiliary agent of the printing ink disclosed by the invention can form a protective film on the surface of the ink, so that the ink is oxidation-resistant, the color of the ink is lastingly bright, and the smoothness and wear resistance of the ink are improved.
Description
Technical field
The invention belongs to printing ink paint field, relate in particular to a kind of printing-ink and preparation method thereof.
Background technology
The color of ink (form and aspect), body bone (rheological property such as rare thick, degree of mobilization) and drying property are three most important performances of ink.Their kind is a lot, and physical properties is also different, and what have is very thick, very sticky; And have quite rare.What have makes low-melting ink vehicle with vegetables oil; Somely with resin and solvent or water etc., make low-melting ink vehicle.These are to be all that the type of stock, printing process, printing plate and drying means etc. decide according to the object of printing.
The rate of drying of ink, thixotropy, skeleton property have tremendous influence to production efficiency, quality product, and the composition of ink has impact to human body, how to study as far as possible little to harm, production efficiency is high, environmental friendliness, ink that cost is low have profound significance.
Summary of the invention
The object of the present invention is to provide a kind of printing-ink and preparation method thereof, this ink adaptive is good, wear-resisting.
Technical scheme of the present invention is as follows:
A printing-ink, is characterized in that being made by the raw material of following weight part: pigment dyestuff 2-3, aluminium hydroxide 4-6, polyacrylic ester 20-24, silicon-dioxide 4-5, tetramethylolmethane 5-8, polyphosphoric acid amine 2-3, bisphenol A epoxy acrylate 40-45, tri (propylene glycol) diacrylate 10-12, four (2-hydroxyethyl) adipamide 3-4, three (2-hydroxyethyl) chlorinated isocyanurates 2-3, methyl-sulphoxide 4-5, pentaerythritol triacrylate 6-9, tributyl tin trichloride 2-3, auxiliary agent 4-5;
Described auxiliary agent is made by the raw material of following weight part: Silane coupling reagent KH-570 2-3, tri (propylene glycol) diacrylate 2-3, methacrylic acid-2-hydroxy methacrylate 2-3, tea-polyphenol 2-3, glyceryl monostearate 4-5, p-tert-butyl benzoic acid 1-2, oxidation inhibitor 1035 1-2, ricinolic acid 1-2, linking agent TAC1-2, ethanol 20-24; Preparation method mixes Silane coupling reagent KH-570, ricinolic acid, ethanol, is heated to 60-70 ℃, stirs after 20-30 minute, then adds other remaining component, is warming up to 80-85 ℃, stirs 30-40 minutes, obtains.
The preparation method of described printing-ink, it is characterized in that comprising the following steps: by tetramethylolmethane, polyphosphoric acid amine, bisphenol A epoxy acrylate, four (2-hydroxyethyl) adipamide, methyl-sulphoxide, pentaerythritol triacrylate mixes, under 1000-1400 rev/min of stirring, speed with 5-8 ℃/minute is heated to 60-80 ℃, add tributyl tin trichloride, stirring reaction 10-20 minute, add polyacrylic ester, three (2-hydroxyethyl) chlorinated isocyanurates, tri (propylene glycol) diacrylate, continue stirring reaction 50-70 minute, add other remaining components, continue stirring reaction 1-1.5 hour, grinding distribution becomes the slurry of 20-40 μ m, obtain.
Beneficial effect of the present invention
Ink adhesion of the present invention is high, and scrape resistant, wear-resisting, high temperature resistant, oil resistant, water-fast, resistance to oxidation, good toughness, fastness are good, and glass, metal, textiles, plastics are had to good bond effect; Oilness is good, and good dispersity is applicable to spraying, roller coating, and production efficiency is high.Auxiliary agent of the present invention can form protective membrane in ink pellet surface, isolated air, and the surface that prevents water and other molecules corrosion ink and spraying object in atmosphere, anti-oxidant, make color bright-coloured lastingly, and improve slickness, wear resistance, extend working time.
Embodiment
A printing-ink, by following weight part (kilogram) raw material make: pigment dyestuff 2.5, aluminium hydroxide 5, polyacrylic ester 22, silicon-dioxide 5, tetramethylolmethane 7, polyphosphoric acid amine 3, bisphenol A epoxy acrylate 43, tri (propylene glycol) diacrylate 11, four (2-hydroxyethyl) adipamide 3.5, three (2-hydroxyethyl) chlorinated isocyanurates 2.5, methyl-sulphoxide 5, pentaerythritol triacrylate 8, tributyl tin trichloride 2.5, auxiliary agent 4.5;
Described auxiliary agent by following weight part (kilogram) raw material make: Silane coupling reagent KH-570 2.5, tri (propylene glycol) diacrylate 2.5, methacrylic acid-2-hydroxy methacrylate 2.5, tea-polyphenol 2.5, glyceryl monostearate 4.6, p-tert-butyl benzoic acid 1.4, oxidation inhibitor 1,035 1.5, ricinolic acid 1.5, linking agent TAC1.4, ethanol 23; Preparation method mixes Silane coupling reagent KH-570, ricinolic acid, ethanol, is heated to 65 ℃, stirs after 26 minutes, then adds other remaining component, is warming up to 84 ℃, stirs 38 minutes, obtains.
The preparation method of described printing-ink, comprise the following steps: by tetramethylolmethane, polyphosphoric acid amine, bisphenol A epoxy acrylate, four (2-hydroxyethyl) adipamide, methyl-sulphoxide, pentaerythritol triacrylate mixes, under 1200 revs/min of stirrings, with the speed of 7 ℃/minute, be heated to 70 ℃, add tributyl tin trichloride, stirring reaction 15 minutes, add polyacrylic ester, three (2-hydroxyethyl) chlorinated isocyanurates, tri (propylene glycol) diacrylate, continue stirring reaction 60 minutes, add other remaining components, continue stirring reaction 1.5 hours, grinding distribution becomes the slurry of 30 μ m, obtain.
Ink quality homogeneous of the present invention, tinting strength, adhere firmly degree, viscosity, first dryness and other performances have reached the requirement of QB/T2024-94 standard.
Claims (2)
1. a printing-ink, is characterized in that being made by the raw material of following weight part: pigment dyestuff 2-3, aluminium hydroxide 4-6, polyacrylic ester 20-24, silicon-dioxide 4-5, tetramethylolmethane 5-8, polyphosphoric acid amine 2-3, bisphenol A epoxy acrylate 40-45, tri (propylene glycol) diacrylate 10-12, four (2-hydroxyethyl) adipamide 3-4, three (2-hydroxyethyl) chlorinated isocyanurates 2-3, methyl-sulphoxide 4-5, pentaerythritol triacrylate 6-9, tributyl tin trichloride 2-3, auxiliary agent 4-5;
Described auxiliary agent is made by the raw material of following weight part: Silane coupling reagent KH-570 2-3, tri (propylene glycol) diacrylate 2-3, methacrylic acid-2-hydroxy methacrylate 2-3, tea-polyphenol 2-3, glyceryl monostearate 4-5, p-tert-butyl benzoic acid 1-2, oxidation inhibitor 1035 1-2, ricinolic acid 1-2, linking agent TAC1-2, ethanol 20-24; Preparation method mixes Silane coupling reagent KH-570, ricinolic acid, ethanol, is heated to 60-70 ℃, stirs after 20-30 minute, then adds other remaining component, is warming up to 80-85 ℃, stirs 30-40 minutes, obtains.
2. the preparation method of printing-ink according to claim 1, it is characterized in that comprising the following steps: by tetramethylolmethane, polyphosphoric acid amine, bisphenol A epoxy acrylate, four (2-hydroxyethyl) adipamide, methyl-sulphoxide, pentaerythritol triacrylate mixes, under 1000-1400 rev/min of stirring, speed with 5-8 ℃/minute is heated to 60-80 ℃, add tributyl tin trichloride, stirring reaction 10-20 minute, add polyacrylic ester, three (2-hydroxyethyl) chlorinated isocyanurates, tri (propylene glycol) diacrylate, continue stirring reaction 50-70 minute, add other remaining components, continue stirring reaction 1-1.5 hour, grinding distribution becomes the slurry of 20-40 μ m, obtain.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310626827.9A CN103642312A (en) | 2013-12-02 | 2013-12-02 | Printing ink and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310626827.9A CN103642312A (en) | 2013-12-02 | 2013-12-02 | Printing ink and preparation method thereof |
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| Publication Number | Publication Date |
|---|---|
| CN103642312A true CN103642312A (en) | 2014-03-19 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
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| CN201310626827.9A Pending CN103642312A (en) | 2013-12-02 | 2013-12-02 | Printing ink and preparation method thereof |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103865322A (en) * | 2014-02-27 | 2014-06-18 | 安徽颍美彩印包装有限公司 | Printing ink and preparation method thereof |
| CN104177910A (en) * | 2014-07-28 | 2014-12-03 | 蚌埠德美过滤技术有限公司 | Printing ink with fly-killing and insect-expelling effects |
| CN104559312A (en) * | 2014-12-31 | 2015-04-29 | 丽王化工(南通)有限公司 | High-temperature-resistant fluorescent pigment and preparing method thereof |
-
2013
- 2013-12-02 CN CN201310626827.9A patent/CN103642312A/en active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103865322A (en) * | 2014-02-27 | 2014-06-18 | 安徽颍美彩印包装有限公司 | Printing ink and preparation method thereof |
| CN104177910A (en) * | 2014-07-28 | 2014-12-03 | 蚌埠德美过滤技术有限公司 | Printing ink with fly-killing and insect-expelling effects |
| CN104559312A (en) * | 2014-12-31 | 2015-04-29 | 丽王化工(南通)有限公司 | High-temperature-resistant fluorescent pigment and preparing method thereof |
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Application publication date: 20140319 |