CN103666084A - Durable printing ink and preparation method thereof - Google Patents
Durable printing ink and preparation method thereof Download PDFInfo
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- CN103666084A CN103666084A CN201310574931.8A CN201310574931A CN103666084A CN 103666084 A CN103666084 A CN 103666084A CN 201310574931 A CN201310574931 A CN 201310574931A CN 103666084 A CN103666084 A CN 103666084A
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Abstract
The invention relates to a durable printing ink which is prepared from the following raw materials in parts by weight: 10-12 parts of amino resin, 8-10 parts of ethanol, 2-5 parts of isophorone, 2-4 parts of DBE (Eibasic Acid Ester) solvents, 2-5 parts of DPM (Propylene Glycol Monomethyl Ether) solvents, 1-2 parts of 2-methylimidazole, 20-30 parts of urethane acrylate, 10-12 parts of ethyl acrylate, 2-3 parts of dimethyl silicon oil, 4-5 parts of silicon dioxide, 8-10 parts of polyvinyl formal resin, 3-4 parts of dimethyl formamide, 1-2 parts of methyl phenol, 3-6 parts of photoinitiators 184, 3-4 parts of organic pigments and 4-5 parts of auxiliary agents. The durable printing ink disclosed by the invention has excellent durability, achieves the abrasion resistance, the scraping resistance and the ageing resistance by being printed on the surfaces of a household appliance, a touch panel, a home decoration, and the like and ensures that the decoration oil is not desquamated for a long time. The auxiliary agent can form a protective film on the surface of the ink, prevent the water molecule and other molecules which are contained in atmosphere from corroding the surfaces of the ink and a sprayed object by isolating air, keep the color lasting and brilliant by resisting oxidation and prolong the usage time.
Description
Technical field
The invention belongs to printing ink paint field, relate in particular to a kind of weather resistance printing-ink and preparation method thereof.
Background technology
The color of ink (form and aspect), body bone (rheological property such as rare thick, degree of mobilization) and drying property are three most important performances of ink.Their kind is a lot, and physical properties is also different, and what have is very thick, very sticky; And have quite rare.What have makes low-melting ink vehicle with vegetables oil; Somely with resin and solvent or water etc., make low-melting ink vehicle.These are to be all that the type of stock, printing process, printing plate and drying means etc. decide according to the object of printing.
The rate of drying of ink, thixotropy, skeleton property have tremendous influence to production efficiency, quality product, and the composition of ink has impact to human body, how to study as far as possible little to harm, production efficiency is high, environmental friendliness, ink that cost is low have profound significance.
Summary of the invention
The object of the present invention is to provide a kind of weather resistance printing-ink and preparation method thereof, this ink cohesive force is strong, durable, difficult drop-off.
Technical scheme of the present invention is as follows:
A weather resistance printing-ink, is characterized in that being made by the raw material of following weight part: aminoresin 10-12, ethanol 8-10, isophorone 2-5, DBE solvent 2-4, DPM solvent 2-5, glyoxal ethyline 1-2, urethane acrylate 20-30, ethyl propenoate 10-12, dimethyl silicone oil 2-3, silicon-dioxide 4-5, vinyl-formal resin 8-10, dimethyl formamide 3-4, cresols 1-2, light trigger 184 3-6, pigment dyestuff 3-4, auxiliary agent 4-5;
Described auxiliary agent is made by the raw material of following weight part: Silane coupling reagent KH-570 2-3, Viscoat 295 3-4,2-n-octyl-4-isothiazoline-3-ketone 1-2,2-amino-2-methyl-1-propyl alcohol 1-2, polyoxyethylene sorbitan monooleate 2-3, ricinolic acid 1-2, oxidation inhibitor 1035 1-2, linking agent TAC1-2, ethanol 20-24; Preparation method mixes Silane coupling reagent KH-570, ricinolic acid, ethanol, is heated to 60-70 ℃, stirs after 20-30 minute, then adds other remaining component, is warming up to 80-85 ℃, stirs 30-40 minutes, obtains.
The preparation method of described weather resistance printing-ink, it is characterized in that comprising the following steps: by ethanol, isophorone, DBE solvent, DPM solvent, urethane acrylate, ethyl propenoate, dimethyl silicone oil mixes, under 1000-1400 rev/min of stirring, add aminoresin, light trigger 184, speed with 5-8 ℃/minute is heated to 60-90 ℃, add silicon-dioxide, vinyl-formal resin, dimethyl formamide, cresols, continue stirring reaction 10-20 minute, add other remaining components, continue stirring reaction 2-2.5 hour, grinding distribution becomes the slurry of 20-40 μ m, obtain.
Beneficial effect of the present invention
Ink of the present invention has excellent weather resistance, is printed on the surfaces such as household electrical appliances, contact panel, house ornamentation upper, and wear-resisting, scrape resistant, ageing-resistant, has guaranteed that decoration oil does not come off for a long time.Auxiliary agent of the present invention can form protective membrane in ink pellet surface, isolated air, and the surface that prevents water and other molecules corrosion ink and spraying object in atmosphere, anti-oxidant, make color bright-coloured lastingly, and improve slickness, wear resistance, extend working time.
Embodiment
A weather resistance printing-ink, by following weight part (kilogram) raw material make: aminoresin 11, ethanol 9, isophorone 3, DBE solvent 3, DPM solvent 4, glyoxal ethyline 1.5, urethane acrylate 25, ethyl propenoate 11, dimethyl silicone oil 2.5, silicon-dioxide 4.5, vinyl-formal resin 9, dimethyl formamide 3.5, cresols 1.5, light trigger 184 4, pigment dyestuff 3.5, auxiliary agent 4.5;
Described auxiliary agent by following weight part (kilogram) raw material make: Silane coupling reagent KH-570 2.5, Viscoat 295 3.5,2-n-octyl-4-isothiazoline-3-ketone 1.5,2-amino-2-methyl-1-propyl alcohol 1.5, polyoxyethylene sorbitan monooleate 2.5, ricinolic acid 1.5, oxidation inhibitor 1,035 1.5, linking agent TAC1.5, ethanol 22; Preparation method mixes Silane coupling reagent KH-570, ricinolic acid, ethanol, is heated to 65 ℃, stirs after 26 minutes, then adds other remaining component, is warming up to 83 ℃, stirs 34 minutes, obtains.
The preparation method of described weather resistance printing-ink, comprise the following steps: ethanol, isophorone, DBE solvent, DPM solvent, urethane acrylate, ethyl propenoate, dimethyl silicone oil are mixed, under 1200 revs/min of stirrings, add aminoresin, light trigger 184, with the speed of 6 ℃/minute, be heated to 70 ℃, add silicon-dioxide, vinyl-formal resin, dimethyl formamide, cresols, continue stirring reaction 15 minutes, add other remaining components, continue stirring reaction 2.3 hours, grinding distribution becomes the slurry of 30 μ m, obtains.
Ink quality homogeneous of the present invention, tinting strength, adhere firmly degree, viscosity, first dryness and other performances have reached the requirement of QB/T2024-94 standard.
Claims (2)
1. a weather resistance printing-ink, is characterized in that being made by the raw material of following weight part: aminoresin 10-12, ethanol 8-10, isophorone 2-5, DBE solvent 2-4, DPM solvent 2-5, glyoxal ethyline 1-2, urethane acrylate 20-30, ethyl propenoate 10-12, dimethyl silicone oil 2-3, silicon-dioxide 4-5, vinyl-formal resin 8-10, dimethyl formamide 3-4, cresols 1-2, light trigger 184 3-6, pigment dyestuff 3-4, auxiliary agent 4-5;
Described auxiliary agent is made by the raw material of following weight part: Silane coupling reagent KH-570 2-3, Viscoat 295 3-4,2-n-octyl-4-isothiazoline-3-ketone 1-2,2-amino-2-methyl-1-propyl alcohol 1-2, polyoxyethylene sorbitan monooleate 2-3, ricinolic acid 1-2, oxidation inhibitor 1035 1-2, linking agent TAC1-2, ethanol 20-24; Preparation method mixes Silane coupling reagent KH-570, ricinolic acid, ethanol, is heated to 60-70 ℃, stirs after 20-30 minute, then adds other remaining component, is warming up to 80-85 ℃, stirs 30-40 minutes, obtains.
2. the preparation method of weather resistance printing-ink according to claim 1, it is characterized in that comprising the following steps: by ethanol, isophorone, DBE solvent, DPM solvent, urethane acrylate, ethyl propenoate, dimethyl silicone oil mixes, under 1000-1400 rev/min of stirring, add aminoresin, light trigger 184, speed with 5-8 ℃/minute is heated to 60-90 ℃, add silicon-dioxide, vinyl-formal resin, dimethyl formamide, cresols, continue stirring reaction 10-20 minute, add other remaining components, continue stirring reaction 2-2.5 hour, grinding distribution becomes the slurry of 20-40 μ m, obtain.
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CN201310574931.8A CN103666084A (en) | 2013-11-18 | 2013-11-18 | Durable printing ink and preparation method thereof |
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CN201310574931.8A CN103666084A (en) | 2013-11-18 | 2013-11-18 | Durable printing ink and preparation method thereof |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106084987A (en) * | 2016-08-29 | 2016-11-09 | 苏州安洁科技股份有限公司 | A kind of UV ink |
CN106118232A (en) * | 2016-06-30 | 2016-11-16 | 安徽智博新材料科技有限公司 | A kind of medical equipment printing-ink and preparation method thereof |
CN109762399A (en) * | 2018-08-29 | 2019-05-17 | 东莞市浩彩油墨科技有限公司 | A kind of aqueous anti-scratch ink and its production technology for plastic film |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103160170A (en) * | 2011-12-13 | 2013-06-19 | 金甲化工企业(中山)有限公司 | Printing ink |
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2013
- 2013-11-18 CN CN201310574931.8A patent/CN103666084A/en active Pending
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103160170A (en) * | 2011-12-13 | 2013-06-19 | 金甲化工企业(中山)有限公司 | Printing ink |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106118232A (en) * | 2016-06-30 | 2016-11-16 | 安徽智博新材料科技有限公司 | A kind of medical equipment printing-ink and preparation method thereof |
CN106084987A (en) * | 2016-08-29 | 2016-11-09 | 苏州安洁科技股份有限公司 | A kind of UV ink |
CN109762399A (en) * | 2018-08-29 | 2019-05-17 | 东莞市浩彩油墨科技有限公司 | A kind of aqueous anti-scratch ink and its production technology for plastic film |
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Application publication date: 20140326 |
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