CN103666093A - Fluorocarbon-resin-base printing ink and preparation method thereof - Google Patents
Fluorocarbon-resin-base printing ink and preparation method thereof Download PDFInfo
- Publication number
- CN103666093A CN103666093A CN201310574935.6A CN201310574935A CN103666093A CN 103666093 A CN103666093 A CN 103666093A CN 201310574935 A CN201310574935 A CN 201310574935A CN 103666093 A CN103666093 A CN 103666093A
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- CN
- China
- Prior art keywords
- parts
- acrylate
- fluorocarbon resin
- printing ink
- fluorocarbon
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000007639 printing Methods 0.000 title claims abstract description 15
- 238000002360 preparation method Methods 0.000 title claims description 10
- 239000011347 resin Substances 0.000 claims abstract description 19
- 229920005989 resin Polymers 0.000 claims abstract description 19
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 claims abstract description 18
- JKNCOURZONDCGV-UHFFFAOYSA-N 2-(dimethylamino)ethyl 2-methylprop-2-enoate Chemical compound CN(C)CCOC(=O)C(C)=C JKNCOURZONDCGV-UHFFFAOYSA-N 0.000 claims abstract description 10
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims abstract description 9
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims abstract description 9
- 238000006243 chemical reaction Methods 0.000 claims abstract description 8
- KCTAWXVAICEBSD-UHFFFAOYSA-N prop-2-enoyloxy prop-2-eneperoxoate Chemical compound C=CC(=O)OOOC(=O)C=C KCTAWXVAICEBSD-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000002994 raw material Substances 0.000 claims abstract description 7
- 230000003647 oxidation Effects 0.000 claims abstract description 4
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 4
- 238000003756 stirring Methods 0.000 claims description 15
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 12
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 12
- 239000012752 auxiliary agent Substances 0.000 claims description 7
- XDLMVUHYZWKMMD-UHFFFAOYSA-N 3-trimethoxysilylpropyl 2-methylprop-2-enoate Chemical compound CO[Si](OC)(OC)CCCOC(=O)C(C)=C XDLMVUHYZWKMMD-UHFFFAOYSA-N 0.000 claims description 6
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 claims description 6
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 6
- 239000003153 chemical reaction reagent Substances 0.000 claims description 6
- 230000008878 coupling Effects 0.000 claims description 6
- 238000010168 coupling process Methods 0.000 claims description 6
- 238000005859 coupling reaction Methods 0.000 claims description 6
- 235000011187 glycerol Nutrition 0.000 claims description 6
- 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 claims description 6
- -1 hexanediyl ester Chemical class 0.000 claims description 6
- VVWRJUBEIPHGQF-UHFFFAOYSA-N propan-2-yl n-propan-2-yloxycarbonyliminocarbamate Chemical compound CC(C)OC(=O)N=NC(=O)OC(C)C VVWRJUBEIPHGQF-UHFFFAOYSA-N 0.000 claims description 6
- WBHHMMIMDMUBKC-QJWNTBNXSA-N ricinoleic acid Chemical compound CCCCCC[C@@H](O)C\C=C/CCCCCCCC(O)=O WBHHMMIMDMUBKC-QJWNTBNXSA-N 0.000 claims description 6
- 229960003656 ricinoleic acid Drugs 0.000 claims description 6
- FEUQNCSVHBHROZ-UHFFFAOYSA-N ricinoleic acid Natural products CCCCCCC(O[Si](C)(C)C)CC=CCCCCCCCC(=O)OC FEUQNCSVHBHROZ-UHFFFAOYSA-N 0.000 claims description 6
- 229910000077 silane Inorganic materials 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 238000009826 distribution Methods 0.000 claims description 3
- 239000000975 dye Substances 0.000 claims description 3
- 238000000227 grinding Methods 0.000 claims description 3
- 239000003112 inhibitor Substances 0.000 claims description 3
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 claims description 3
- 239000000049 pigment Substances 0.000 claims description 3
- 239000002002 slurry Substances 0.000 claims description 3
- 238000010792 warming Methods 0.000 claims description 3
- 239000000126 substance Substances 0.000 abstract description 3
- 239000000178 monomer Substances 0.000 abstract description 2
- 230000001681 protective effect Effects 0.000 abstract description 2
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 abstract 1
- FIHBHSQYSYVZQE-UHFFFAOYSA-N 6-prop-2-enoyloxyhexyl prop-2-enoate Chemical compound C=CC(=O)OCCCCCCOC(=O)C=C FIHBHSQYSYVZQE-UHFFFAOYSA-N 0.000 abstract 1
- 150000002148 esters Chemical class 0.000 abstract 1
- 230000002349 favourable effect Effects 0.000 abstract 1
- 230000008014 freezing Effects 0.000 abstract 1
- 238000007710 freezing Methods 0.000 abstract 1
- 125000003976 glyceryl group Chemical group [H]C([*])([H])C(O[H])([H])C(O[H])([H])[H] 0.000 abstract 1
- 239000012860 organic pigment Substances 0.000 abstract 1
- 230000002035 prolonged effect Effects 0.000 abstract 1
- 238000001035 drying Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 235000006708 antioxidants Nutrition 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 210000000988 bone and bone Anatomy 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
Landscapes
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention relates to a fluorocarbon-resin-base printing ink which is prepared from the following raw materials in parts by weight: 6-9 parts of diethylene glycol, 12-15 parts of fluorocarbon resin, 4-5 parts of glyceryl polyglycidyl ester, 2.5-4 parts of azodiisobutyronitrile, 12-14 parts of acrylate, 10-12 parts of dimethylaminoethyl methacrylate, 6-8 parts of 1,6-hexanediol diacrylate, 30-34 parts of epoxy acrylate, 3-4 parts of organic pigment and 4-5 parts of assistant. By using the reaction combination of the fluorocarbon resin, acrylate and many other monomers, the obtained ink has the advantages of excellent heat resistance, excellent chemical resistance, excellent freezing resistance, excellent low-temperature flexibility, excellent weather resistance, excellent electric properties, high fastness, high glossiness, bright color and favorable wear resistance, and is widely used for severely corroded kitchen utensils, tank bodies, transfer lines and the likeThe assistant can form a protective film on the ink surface to resist oxidation, so that the color can be bright permanently; and the smoothness and wear resistance are enhanced, and the service time is prolonged.
Description
Technical field
The invention belongs to printing ink paint field, relate in particular to a kind of fluorocarbon resin based printing ink and preparation method thereof.
Background technology
The color of ink (form and aspect), body bone (rheological property such as rare thick, degree of mobilization) and drying property are three most important performances of ink.Their kind is a lot, and physical properties is also different, and what have is very thick, very sticky; And have quite rare.What have makes low-melting ink vehicle with vegetables oil; Somely with resin and solvent or water etc., make low-melting ink vehicle.These are to be all that the type of stock, printing process, printing plate and drying means etc. decide according to the object of printing.
The rate of drying of ink, thixotropy, skeleton property have tremendous influence to production efficiency, quality product, and the composition of ink has impact to human body, how to study as far as possible little to harm, production efficiency is high, environmental friendliness, ink that cost is low have profound significance.
Summary of the invention
The object of the present invention is to provide a kind of fluorocarbon resin based printing ink and preparation method thereof, this ink is cold-resistant, heat-resisting, chemicals-resistant, light.
Technical scheme of the present invention is as follows:
A kind of fluorocarbon resin based printing ink, it is characterized in that being made by the raw material of following weight part: glycol ether 6-9, fluorocarbon resin 12-15, many glycidyl esters of glycerine 4-5, Diisopropyl azodicarboxylate 2.5-4, acrylate 12-14, dimethylaminoethyl methacrylate 10-12,1,6 hexanediyl ester 6-8, epoxy acrylate 30-34, pigment dyestuff 3-4, auxiliary agent 4-5;
Described auxiliary agent is made by the raw material of following weight part: Silane coupling reagent KH-570 2-3, dimethylaminoethyl methacrylate 3-4, morpholine 1-2, neopentyl glycol 3-4, oxidation inhibitor 1035 1-2, ricinolic acid 1-2, linking agent TAC1-2, ethanol 20-24; Preparation method mixes Silane coupling reagent KH-570, ricinolic acid, ethanol, is heated to 60-70 ℃, stirs after 20-30 minute, then adds other remaining component, is warming up to 80-85 ℃, stirs 30-40 minutes, obtains.
The preparation method of described fluorocarbon resin based printing ink, it is characterized in that comprising the following steps: by glycol ether, the many glycidyl esters of glycerine, acrylate, dimethylaminoethyl methacrylate, 1,6 hexanediyl esters mix, under 1100-1400 rev/min of stirring, add Diisopropyl azodicarboxylate, speed with 5-8 ℃/minute is heated to 60-80 ℃, add fluorocarbon resin, epoxy acrylate, continue stirring reaction 20-30 minute, add other remaining components, continue stirring reaction 1.5-2 hour, grinding distribution becomes the slurry of 20-40 μ m, obtains.
Beneficial effect of the present invention
Ink of the present invention is used the various of monomer reaction bonded such as fluorocarbon resin and acrylate, the ink obtaining has excellent thermotolerance, chemical-resistant, winter hardiness, low temperature flexibility, weathering resistance and electrical property, and fastness is good, glossiness is high, bright-colored, wear resistance good, be widely used in kitchen utensils, tank body, line of pipes of seriously corroded etc.Auxiliary agent of the present invention can form protective membrane in ink pellet surface, isolated air, and the surface that prevents water and other molecules corrosion ink and spraying object in atmosphere, anti-oxidant, make color bright-coloured lastingly, and improve slickness, wear resistance, extend working time.
Embodiment
A kind of fluorocarbon resin based printing ink, by following weight part (kilogram) raw material make: glycol ether 7, fluorocarbon resin 14, the many glycidyl esters 4.5 of glycerine, Diisopropyl azodicarboxylate 3, acrylate 13, dimethylaminoethyl methacrylate 11,1,6 hexanediyl ester 7, epoxy acrylate 32, pigment dyestuff 3.5, auxiliary agent 4.5;
Described auxiliary agent by following weight part (kilogram) raw material make: Silane coupling reagent KH-570 2.5, dimethylaminoethyl methacrylate 3.5, morpholine 1.5, neopentyl glycol 3.5, oxidation inhibitor 1,035 1.5, ricinolic acid 1.5, linking agent TAC1.5, ethanol 23; Preparation method mixes Silane coupling reagent KH-570, ricinolic acid, ethanol, is heated to 65 ℃, stirs after 25 minutes, then adds other remaining component, is warming up to 83 ℃, stirs 35 minutes, obtains.
The preparation method of described fluorocarbon resin based printing ink, comprise the following steps: by glycol ether, the many glycidyl esters of glycerine, acrylate, dimethylaminoethyl methacrylate, 1,6 hexanediyl esters mix, under 1300 revs/min of stirrings, add Diisopropyl azodicarboxylate, with the speed of 7 ℃/minute, be heated to 70 ℃, add fluorocarbon resin, epoxy acrylate, continue stirring reaction 25 minutes, add other remaining components, continue stirring reaction 1.7 hours, grinding distribution becomes the slurry of 30 μ m, obtains.
Ink quality homogeneous of the present invention, tinting strength, adhere firmly degree, viscosity, first dryness and other performances have reached the requirement of QB/T2024-94 standard.
Claims (2)
1. a fluorocarbon resin based printing ink, it is characterized in that being made by the raw material of following weight part: glycol ether 6-9, fluorocarbon resin 12-15, many glycidyl esters of glycerine 4-5, Diisopropyl azodicarboxylate 2.5-4, acrylate 12-14, dimethylaminoethyl methacrylate 10-12,1,6 hexanediyl ester 6-8, epoxy acrylate 30-34, pigment dyestuff 3-4, auxiliary agent 4-5;
Described auxiliary agent is made by the raw material of following weight part: Silane coupling reagent KH-570 2-3, dimethylaminoethyl methacrylate 3-4, morpholine 1-2, neopentyl glycol 3-4, oxidation inhibitor 1035 1-2, ricinolic acid 1-2, linking agent TAC1-2, ethanol 20-24; Preparation method mixes Silane coupling reagent KH-570, ricinolic acid, ethanol, is heated to 60-70 ℃, stirs after 20-30 minute, then adds other remaining component, is warming up to 80-85 ℃, stirs 30-40 minutes, obtains.
2. the preparation method of fluorocarbon resin based printing ink according to claim 1, it is characterized in that comprising the following steps: by glycol ether, the many glycidyl esters of glycerine, acrylate, dimethylaminoethyl methacrylate, 1, 6 hexanediyl esters mix, under 1100-1400 rev/min of stirring, add Diisopropyl azodicarboxylate, speed with 5-8 ℃/minute is heated to 60-80 ℃, add fluorocarbon resin, epoxy acrylate, continue stirring reaction 20-30 minute, add other remaining components, continue stirring reaction 1.5-2 hour, grinding distribution becomes the slurry of 20-40 μ m, obtain.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310574935.6A CN103666093A (en) | 2013-11-18 | 2013-11-18 | Fluorocarbon-resin-base printing ink and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310574935.6A CN103666093A (en) | 2013-11-18 | 2013-11-18 | Fluorocarbon-resin-base printing ink and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103666093A true CN103666093A (en) | 2014-03-26 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310574935.6A Pending CN103666093A (en) | 2013-11-18 | 2013-11-18 | Fluorocarbon-resin-base printing ink and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103666093A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104250469A (en) * | 2014-09-03 | 2014-12-31 | 安徽雅美油墨有限公司 | Soft highly-bright antiwear environment-friendly aqueous fluorocarbon resin printing ink |
| CN104312284A (en) * | 2014-11-10 | 2015-01-28 | 合肥宏图彩印有限公司 | Bacteriostatic special heat-resistant ink and preparation method thereof |
| CN105968948A (en) * | 2016-07-11 | 2016-09-28 | 赵艳丽 | Weather-proof glass printing ink and preparation method thereof |
| CN110437676A (en) * | 2019-09-16 | 2019-11-12 | 杭州科望特种油墨有限公司 | A color-changing ink |
| CN110606668A (en) * | 2019-09-16 | 2019-12-24 | 杭州玻美文化艺术有限公司 | A kind of production method of dual-curing type color changing solar glass panel |
-
2013
- 2013-11-18 CN CN201310574935.6A patent/CN103666093A/en active Pending
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104250469A (en) * | 2014-09-03 | 2014-12-31 | 安徽雅美油墨有限公司 | Soft highly-bright antiwear environment-friendly aqueous fluorocarbon resin printing ink |
| CN104312284A (en) * | 2014-11-10 | 2015-01-28 | 合肥宏图彩印有限公司 | Bacteriostatic special heat-resistant ink and preparation method thereof |
| CN105968948A (en) * | 2016-07-11 | 2016-09-28 | 赵艳丽 | Weather-proof glass printing ink and preparation method thereof |
| CN110437676A (en) * | 2019-09-16 | 2019-11-12 | 杭州科望特种油墨有限公司 | A color-changing ink |
| CN110606668A (en) * | 2019-09-16 | 2019-12-24 | 杭州玻美文化艺术有限公司 | A kind of production method of dual-curing type color changing solar glass panel |
| WO2021051824A1 (en) * | 2019-09-16 | 2021-03-25 | 杭州科望特种油墨有限公司 | Ink capable of changing color with environment and solar glass product |
| CN110606668B (en) * | 2019-09-16 | 2022-07-26 | 杭州玻美文化艺术有限公司 | A kind of production method of double-curing type color changing solar glass panel |
| US12404418B2 (en) | 2019-09-16 | 2025-09-02 | Hangzhou Bomei Solar Energy Technology Co., Ltd | Scenario-adaptable color-changing ink and solar glass product |
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| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C12 | Rejection of a patent application after its publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20140326 |