CN103666093A - Fluorocarbon-resin-base printing ink and preparation method thereof - Google Patents
Fluorocarbon-resin-base printing ink and preparation method thereof Download PDFInfo
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- CN103666093A CN103666093A CN201310574935.6A CN201310574935A CN103666093A CN 103666093 A CN103666093 A CN 103666093A CN 201310574935 A CN201310574935 A CN 201310574935A CN 103666093 A CN103666093 A CN 103666093A
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Abstract
The invention relates to a fluorocarbon-resin-base printing ink which is prepared from the following raw materials in parts by weight: 6-9 parts of diethylene glycol, 12-15 parts of fluorocarbon resin, 4-5 parts of glyceryl polyglycidyl ester, 2.5-4 parts of azodiisobutyronitrile, 12-14 parts of acrylate, 10-12 parts of dimethylaminoethyl methacrylate, 6-8 parts of 1,6-hexanediol diacrylate, 30-34 parts of epoxy acrylate, 3-4 parts of organic pigment and 4-5 parts of assistant. By using the reaction combination of the fluorocarbon resin, acrylate and many other monomers, the obtained ink has the advantages of excellent heat resistance, excellent chemical resistance, excellent freezing resistance, excellent low-temperature flexibility, excellent weather resistance, excellent electric properties, high fastness, high glossiness, bright color and favorable wear resistance, and is widely used for severely corroded kitchen utensils, tank bodies, transfer lines and the likeThe assistant can form a protective film on the ink surface to resist oxidation, so that the color can be bright permanently; and the smoothness and wear resistance are enhanced, and the service time is prolonged.
Description
Technical field
The invention belongs to printing ink paint field, relate in particular to a kind of fluorocarbon resin based printing ink and preparation method thereof.
Background technology
The color of ink (form and aspect), body bone (rheological property such as rare thick, degree of mobilization) and drying property are three most important performances of ink.Their kind is a lot, and physical properties is also different, and what have is very thick, very sticky; And have quite rare.What have makes low-melting ink vehicle with vegetables oil; Somely with resin and solvent or water etc., make low-melting ink vehicle.These are to be all that the type of stock, printing process, printing plate and drying means etc. decide according to the object of printing.
The rate of drying of ink, thixotropy, skeleton property have tremendous influence to production efficiency, quality product, and the composition of ink has impact to human body, how to study as far as possible little to harm, production efficiency is high, environmental friendliness, ink that cost is low have profound significance.
Summary of the invention
The object of the present invention is to provide a kind of fluorocarbon resin based printing ink and preparation method thereof, this ink is cold-resistant, heat-resisting, chemicals-resistant, light.
Technical scheme of the present invention is as follows:
A kind of fluorocarbon resin based printing ink, it is characterized in that being made by the raw material of following weight part: glycol ether 6-9, fluorocarbon resin 12-15, many glycidyl esters of glycerine 4-5, Diisopropyl azodicarboxylate 2.5-4, acrylate 12-14, dimethylaminoethyl methacrylate 10-12,1,6 hexanediyl ester 6-8, epoxy acrylate 30-34, pigment dyestuff 3-4, auxiliary agent 4-5;
Described auxiliary agent is made by the raw material of following weight part: Silane coupling reagent KH-570 2-3, dimethylaminoethyl methacrylate 3-4, morpholine 1-2, neopentyl glycol 3-4, oxidation inhibitor 1035 1-2, ricinolic acid 1-2, linking agent TAC1-2, ethanol 20-24; Preparation method mixes Silane coupling reagent KH-570, ricinolic acid, ethanol, is heated to 60-70 ℃, stirs after 20-30 minute, then adds other remaining component, is warming up to 80-85 ℃, stirs 30-40 minutes, obtains.
The preparation method of described fluorocarbon resin based printing ink, it is characterized in that comprising the following steps: by glycol ether, the many glycidyl esters of glycerine, acrylate, dimethylaminoethyl methacrylate, 1,6 hexanediyl esters mix, under 1100-1400 rev/min of stirring, add Diisopropyl azodicarboxylate, speed with 5-8 ℃/minute is heated to 60-80 ℃, add fluorocarbon resin, epoxy acrylate, continue stirring reaction 20-30 minute, add other remaining components, continue stirring reaction 1.5-2 hour, grinding distribution becomes the slurry of 20-40 μ m, obtains.
Beneficial effect of the present invention
Ink of the present invention is used the various of monomer reaction bonded such as fluorocarbon resin and acrylate, the ink obtaining has excellent thermotolerance, chemical-resistant, winter hardiness, low temperature flexibility, weathering resistance and electrical property, and fastness is good, glossiness is high, bright-colored, wear resistance good, be widely used in kitchen utensils, tank body, line of pipes of seriously corroded etc.Auxiliary agent of the present invention can form protective membrane in ink pellet surface, isolated air, and the surface that prevents water and other molecules corrosion ink and spraying object in atmosphere, anti-oxidant, make color bright-coloured lastingly, and improve slickness, wear resistance, extend working time.
Embodiment
A kind of fluorocarbon resin based printing ink, by following weight part (kilogram) raw material make: glycol ether 7, fluorocarbon resin 14, the many glycidyl esters 4.5 of glycerine, Diisopropyl azodicarboxylate 3, acrylate 13, dimethylaminoethyl methacrylate 11,1,6 hexanediyl ester 7, epoxy acrylate 32, pigment dyestuff 3.5, auxiliary agent 4.5;
Described auxiliary agent by following weight part (kilogram) raw material make: Silane coupling reagent KH-570 2.5, dimethylaminoethyl methacrylate 3.5, morpholine 1.5, neopentyl glycol 3.5, oxidation inhibitor 1,035 1.5, ricinolic acid 1.5, linking agent TAC1.5, ethanol 23; Preparation method mixes Silane coupling reagent KH-570, ricinolic acid, ethanol, is heated to 65 ℃, stirs after 25 minutes, then adds other remaining component, is warming up to 83 ℃, stirs 35 minutes, obtains.
The preparation method of described fluorocarbon resin based printing ink, comprise the following steps: by glycol ether, the many glycidyl esters of glycerine, acrylate, dimethylaminoethyl methacrylate, 1,6 hexanediyl esters mix, under 1300 revs/min of stirrings, add Diisopropyl azodicarboxylate, with the speed of 7 ℃/minute, be heated to 70 ℃, add fluorocarbon resin, epoxy acrylate, continue stirring reaction 25 minutes, add other remaining components, continue stirring reaction 1.7 hours, grinding distribution becomes the slurry of 30 μ m, obtains.
Ink quality homogeneous of the present invention, tinting strength, adhere firmly degree, viscosity, first dryness and other performances have reached the requirement of QB/T2024-94 standard.
Claims (2)
1. a fluorocarbon resin based printing ink, it is characterized in that being made by the raw material of following weight part: glycol ether 6-9, fluorocarbon resin 12-15, many glycidyl esters of glycerine 4-5, Diisopropyl azodicarboxylate 2.5-4, acrylate 12-14, dimethylaminoethyl methacrylate 10-12,1,6 hexanediyl ester 6-8, epoxy acrylate 30-34, pigment dyestuff 3-4, auxiliary agent 4-5;
Described auxiliary agent is made by the raw material of following weight part: Silane coupling reagent KH-570 2-3, dimethylaminoethyl methacrylate 3-4, morpholine 1-2, neopentyl glycol 3-4, oxidation inhibitor 1035 1-2, ricinolic acid 1-2, linking agent TAC1-2, ethanol 20-24; Preparation method mixes Silane coupling reagent KH-570, ricinolic acid, ethanol, is heated to 60-70 ℃, stirs after 20-30 minute, then adds other remaining component, is warming up to 80-85 ℃, stirs 30-40 minutes, obtains.
2. the preparation method of fluorocarbon resin based printing ink according to claim 1, it is characterized in that comprising the following steps: by glycol ether, the many glycidyl esters of glycerine, acrylate, dimethylaminoethyl methacrylate, 1, 6 hexanediyl esters mix, under 1100-1400 rev/min of stirring, add Diisopropyl azodicarboxylate, speed with 5-8 ℃/minute is heated to 60-80 ℃, add fluorocarbon resin, epoxy acrylate, continue stirring reaction 20-30 minute, add other remaining components, continue stirring reaction 1.5-2 hour, grinding distribution becomes the slurry of 20-40 μ m, obtain.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310574935.6A CN103666093A (en) | 2013-11-18 | 2013-11-18 | Fluorocarbon-resin-base printing ink and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310574935.6A CN103666093A (en) | 2013-11-18 | 2013-11-18 | Fluorocarbon-resin-base printing ink and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
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| CN103666093A true CN103666093A (en) | 2014-03-26 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201310574935.6A Pending CN103666093A (en) | 2013-11-18 | 2013-11-18 | Fluorocarbon-resin-base printing ink and preparation method thereof |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104250469A (en) * | 2014-09-03 | 2014-12-31 | 安徽雅美油墨有限公司 | Soft highly-bright antiwear environment-friendly aqueous fluorocarbon resin printing ink |
| CN104312284A (en) * | 2014-11-10 | 2015-01-28 | 合肥宏图彩印有限公司 | Bacteriostatic special heat-resistant ink and preparation method thereof |
| CN105968948A (en) * | 2016-07-11 | 2016-09-28 | 赵艳丽 | Weather-proof glass printing ink and preparation method thereof |
| CN110437676A (en) * | 2019-09-16 | 2019-11-12 | 杭州科望特种油墨有限公司 | One kind is with scape color shifting ink |
| CN110606668A (en) * | 2019-09-16 | 2019-12-24 | 杭州玻美文化艺术有限公司 | Production method of dual-curing type scene-following color-changing solar glass panel |
-
2013
- 2013-11-18 CN CN201310574935.6A patent/CN103666093A/en active Pending
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104250469A (en) * | 2014-09-03 | 2014-12-31 | 安徽雅美油墨有限公司 | Soft highly-bright antiwear environment-friendly aqueous fluorocarbon resin printing ink |
| CN104312284A (en) * | 2014-11-10 | 2015-01-28 | 合肥宏图彩印有限公司 | Bacteriostatic special heat-resistant ink and preparation method thereof |
| CN105968948A (en) * | 2016-07-11 | 2016-09-28 | 赵艳丽 | Weather-proof glass printing ink and preparation method thereof |
| CN110437676A (en) * | 2019-09-16 | 2019-11-12 | 杭州科望特种油墨有限公司 | One kind is with scape color shifting ink |
| CN110606668A (en) * | 2019-09-16 | 2019-12-24 | 杭州玻美文化艺术有限公司 | Production method of dual-curing type scene-following color-changing solar glass panel |
| WO2021051824A1 (en) * | 2019-09-16 | 2021-03-25 | 杭州科望特种油墨有限公司 | Ink capable of changing color with environment and solar glass product |
| CN110606668B (en) * | 2019-09-16 | 2022-07-26 | 杭州玻美文化艺术有限公司 | Production method of dual-curing scene-following color-changing solar glass panel |
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Application publication date: 20140326 |