CN105968948A - Weather-proof glass printing ink and preparation method thereof - Google Patents
Weather-proof glass printing ink and preparation method thereof Download PDFInfo
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- CN105968948A CN105968948A CN201610540979.0A CN201610540979A CN105968948A CN 105968948 A CN105968948 A CN 105968948A CN 201610540979 A CN201610540979 A CN 201610540979A CN 105968948 A CN105968948 A CN 105968948A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
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- Life Sciences & Earth Sciences (AREA)
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- General Chemical & Material Sciences (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention provides weather-proof glass printing ink and a preparation method thereof. The ink comprises the following components: fluorocarbon resin, 1,6-hexanediol diacrylate, terpilenol, calcium gluconate, isophorone diisocyanate, ground pumice, lepidomelane, sulfosuccinate diethyl ester sodium, 7-acrylic acid coumarin ester, (methyl) acryl oyloxyethyl caffeic acid ester, benzophenone, Michlers Ketone, triphenylphosphine, dibutyltin dilaurate, methoxyphenol, diacetone alcohol, polytetrahydrofuran, propylene glycol phenyl ether, methylene dichloride and pigment. The ink provided by the invention is excellent in adhesive force, heat resistance, water resistance, and acid alkali-resistance, and good in stability. Meanwhile, the ink is green and environmental friendly, excellent in weather-proofness, low in energy consumption, and favorable in using effect, and can widely meet the application requirement of printing ink industry.
Description
Technical field
The invention belongs to technical field of ink, be specifically related to a kind of weather-proof glass ink and preparation method thereof.
Background technology
Ink is the important materials for printing, and pattern, word etc. are showed on the substrate by printing, be made up of link stuff, pigment, filler, auxiliary agent and solvent etc. by it.Glass ink is the one in ink, is primarily referred to as carrying out printing the ink of energy firm attachment on glass.Many fields such as glass ink is widely used in electronic product, windshield, household electrical appliance, decorate with realization, cover, reduce UV transparent rate and prevent the effects such as various chemical reactions.
Along with the fast development of science and technology, people are the highest to the requirement of glass ink.Traditional glass ink is usually hot setting ink, power consumption height, not environmentally, and after hot setting processes, has a certain impact the performance of glass；Additionally, water-fast, acidproof, the heat-resisting and weatherability of existing glass ink is the best, the problem such as even come off easy to change can be produced, it is therefore necessary to provide the glass ink that a kind of environmental friendliness, energy consumption are low and weatherability is good.
Summary of the invention
It is an object of the invention to avoid above-mentioned weak point of the prior art to provide a kind of weather-proof glass ink and preparation method thereof.
The purpose of the present invention is achieved through the following technical solutions:
nullA kind of weather-proof glass ink，By weight，Including following component，Fluorocarbon resin 14-22 part、1,6-hexanediyl ester 10-17 part、Terpineol 5-15 part、Calcium gluconate 4-9 part、Isophorone diisocyanate 5-12 part、Pumice 1-6 part、Zinnwaldite 1-5 part、2-Sulfosuccinic acid ethylhexyl sodium 3-6 part、7-acrylic acid coumarin ester 8-17 part、(methyl) acrylyl oxy-ethyl caffeic acid ester 13-21 part、Benzophenone 4-11 part、Michler's keton 5-9 part、Triphenylphosphine 2-8 part、Dibutyl tin laurate 5-9 part、MEHQ 1-6 part、DAA 7-12 part、Polytetrahydrofuran diol 4-8 part、Propylene glycol phenylate 6-10 part、Dichloromethane 8-15 part、Pigment 0.2-4 part.
Further, at least one during described pigment is quinacridone pigment, red, phthalocyanine blue pigment, benzidine yellow, indigo-blue indigo plant, white carbon black, AZOpigments, benzimidazolone pigment.
Further, by weight, including following component, fluorocarbon resin 16-20 part, 1, 6-hexanediyl ester 11-15 part, terpineol 8-13 part, calcium gluconate 5-8 part, isophorone diisocyanate 6-10 part, pumice 2-4 part, zinnwaldite 1-4 part, 2-Sulfosuccinic acid ethylhexyl sodium 4-6 part, 7-acrylic acid coumarin ester 9-14 part, (methyl) acrylyl oxy-ethyl caffeic acid ester 14-18 part, benzophenone 6-10 part, Michler's keton 6-8 part, triphenylphosphine 4-7 part, dibutyl tin laurate 5-7 part, MEHQ 2-5 part, DAA 8-10 part, polytetrahydrofuran diol 6-8 part, propylene glycol phenylate 6-9 part, dichloromethane 9-14 part, pigment 0.5-3 part.
The preparation method of above-mentioned weather-proof glass ink, including following preparation process:
Step 1, by 7-acrylic acid coumarin ester, (methyl) acrylyl oxy-ethyl caffeic acid ester, isophorone diisocyanate and polytetrahydrofuran diol stirring and dissolving, it is passed through nitrogen half an hour, confined reaction 10-24 hour at 60-90 DEG C, after being cooled to room temperature, add 1,6-hexanediyl ester, stir, add triphenylphosphine, dibutyl tin laurate and MEHQ, it is warming up to 80-110 DEG C, reaction 10-24 hour, dries after completion of the reaction, obtains material I in a nitrogen atmosphere；
Step 2, pumice, zinnwaldite are placed in 300-500 DEG C at calcine 30-60 minute, finely ground after cooling；
Step 3, fluorocarbon resin, terpineol, propylene glycol phenylate, dichloromethane are added in agitator tank, stir at 60-80 DEG C, then 30-45 DEG C it is cooled to, add benzophenone, Michler's keton, 2-Sulfosuccinic acid ethylhexyl sodium, calcium gluconate and DAA to stir, add pumice treated in pigment and step 2, zinnwaldite, high speed dispersion 40-100 minute under 1000-1600rpm, send into three-roller and carry out finely ground, filter, be uniformly dispersed.
Further, in step 1, confined reaction 16 hours at 78 DEG C.
Further, in step 1, it is warming up to 95 DEG C, in a nitrogen atmosphere reaction 15 hours.
Further, in step 2, calcining 50 minutes it is placed at 420 DEG C.
Further, in step 3, stir at 68 DEG C, be then cooled to 35 DEG C；In step 3, high speed dispersion 60 minutes under 1200rpm.
Owing to have employed above technical scheme, beneficial effects of the present invention:
The ink using the present invention can be at room temperature or curing at low temperatures, it is not necessary to high temperature, consumes energy low, and can reduce high temperature to ink and the impact of glass baseplate.It addition, the adhesive force of the ink of the present invention, thermostability, resistance to water and acid and alkali resistance excellent performance, good stability.The ink environmental protection of the present invention, weatherability is good, and energy consumption is low, and using effect is good, can extensively meet the application demand of printing-ink industry.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is described in further detail.Following example are used for illustrating the present invention, but are not limited to the scope of the present invention.
Embodiment 1
A kind of weather-proof glass ink, by weight, including following component, fluorocarbon resin 14 parts, 1, 6-hexanediyl ester 10 parts, terpineol 5 parts, calcium gluconate 4 parts, isophorone diisocyanate 5 parts, pumice 1 part, zinnwaldite 1 part, 3 parts of 2-Sulfosuccinic acid ethylhexyl sodium, 7-acrylic acid coumarin ester 8 parts, (methyl) acrylyl oxy-ethyl caffeic acid ester 13 parts, benzophenone 4 parts, Michler's keton 5 parts, triphenylphosphine 2 parts, dibutyl tin laurate 5 parts, MEHQ 1 part, DAA 7 parts, polytetrahydrofuran diol 4 parts, propylene glycol phenylate 6 parts, dichloromethane 8 parts, pigment 0.2 part.
Described pigment is at least one in quinacridone pigment, red, phthalocyanine blue pigment, benzidine yellow, indigo-blue indigo plant, white carbon black, AZOpigments, benzimidazolone pigment.
The preparation method of above-mentioned weather-proof glass ink, including following preparation process:
Step 1, by 7-acrylic acid coumarin ester, (methyl) acrylyl oxy-ethyl caffeic acid ester, isophorone diisocyanate and polytetrahydrofuran diol stirring and dissolving, being passed through nitrogen half an hour, confined reaction 10 hours at 60 DEG C, after being cooled to room temperature, add 1,6-hexanediyl ester, stirs, and adds triphenylphosphine, dibutyl tin laurate and MEHQ, it is warming up to 80 DEG C, reaction 10 hours, dry after completion of the reaction, obtain material I in a nitrogen atmosphere；
Step 2, pumice, zinnwaldite are placed at 300 DEG C calcining 30 minutes, finely ground after cooling；
Step 3, fluorocarbon resin, terpineol, propylene glycol phenylate, dichloromethane are added in agitator tank, stir at 60 DEG C, then 30 DEG C it are cooled to, add benzophenone, Michler's keton, 2-Sulfosuccinic acid ethylhexyl sodium, calcium gluconate and DAA to stir, add pumice treated in pigment and step 2, zinnwaldite, high speed dispersion 40 minutes under 1000rpm, send into three-roller and carry out finely ground, filter, be uniformly dispersed.
Embodiment 2
A kind of weather-proof glass ink, by weight, including following component, fluorocarbon resin 22 parts, 1, 6-hexanediyl ester 17 parts, terpineol 15 parts, calcium gluconate 9 parts, isophorone diisocyanate 12 parts, pumice 6 parts, zinnwaldite 5 parts, 6 parts of 2-Sulfosuccinic acid ethylhexyl sodium, 7-acrylic acid coumarin ester 17 parts, (methyl) acrylyl oxy-ethyl caffeic acid ester 21 parts, benzophenone 11 parts, Michler's keton 9 parts, triphenylphosphine 8 parts, dibutyl tin laurate 9 parts, MEHQ 6 parts, DAA 12 parts, polytetrahydrofuran diol 8 parts, propylene glycol phenylate 10 parts, dichloromethane 15 parts, pigment 4 parts.
Described pigment is at least one in quinacridone pigment, red, phthalocyanine blue pigment, benzidine yellow, indigo-blue indigo plant, white carbon black, AZOpigments, benzimidazolone pigment.
The preparation method of above-mentioned weather-proof glass ink, including following preparation process:
Step 1, by 7-acrylic acid coumarin ester, (methyl) acrylyl oxy-ethyl caffeic acid ester, isophorone diisocyanate and polytetrahydrofuran diol stirring and dissolving, being passed through nitrogen half an hour, confined reaction 24 hours at 90 DEG C, after being cooled to room temperature, add 1,6-hexanediyl ester, stirs, and adds triphenylphosphine, dibutyl tin laurate and MEHQ, it is warming up to 110 DEG C, reaction 24 hours, dry after completion of the reaction, obtain material I in a nitrogen atmosphere；
Step 2, pumice, zinnwaldite are placed at 500 DEG C calcining 60 minutes, finely ground after cooling；
Step 3, fluorocarbon resin, terpineol, propylene glycol phenylate, dichloromethane are added in agitator tank, stir at 80 DEG C, then 45 DEG C it are cooled to, add benzophenone, Michler's keton, 2-Sulfosuccinic acid ethylhexyl sodium, calcium gluconate and DAA to stir, add pumice treated in pigment and step 2, zinnwaldite, at 1600 rpm high speed dispersion 100 minutes, send into three-roller and carry out finely ground, filter, be uniformly dispersed.
Embodiment 3
A kind of weather-proof glass ink, by weight, including following component, fluorocarbon resin 18 parts, 1, 6-hexanediyl ester 13 parts, terpineol 10 parts, calcium gluconate 7 parts, isophorone diisocyanate 8 parts, pumice 3 parts, zinnwaldite 3 parts, 4.5 parts of 2-Sulfosuccinic acid ethylhexyl sodium, 7-acrylic acid coumarin ester 12 parts, (methyl) acrylyl oxy-ethyl caffeic acid ester 17 parts, benzophenone 7 parts, Michler's keton 7 parts, triphenylphosphine 5 parts, dibutyl tin laurate 7 parts, MEHQ 3 parts, DAA 9 parts, polytetrahydrofuran diol 6 parts, propylene glycol phenylate 8 parts, dichloromethane 11 parts, pigment 2.1 parts.
Described pigment is at least one in quinacridone pigment, red, phthalocyanine blue pigment, benzidine yellow, indigo-blue indigo plant, white carbon black, AZOpigments, benzimidazolone pigment.
The preparation method of above-mentioned weather-proof glass ink, including following preparation process:
Step 1, by 7-acrylic acid coumarin ester, (methyl) acrylyl oxy-ethyl caffeic acid ester, isophorone diisocyanate and polytetrahydrofuran diol stirring and dissolving, being passed through nitrogen half an hour, confined reaction 17 hours at 75 DEG C, after being cooled to room temperature, add 1,6-hexanediyl ester, stirs, and adds triphenylphosphine, dibutyl tin laurate and MEHQ, it is warming up to 95 DEG C, reaction 17 hours, dry after completion of the reaction, obtain material I in a nitrogen atmosphere；
Step 2, pumice, zinnwaldite are placed at 400 DEG C calcining 45 minutes, finely ground after cooling；
Step 3, fluorocarbon resin, terpineol, propylene glycol phenylate, dichloromethane are added in agitator tank, stir at 70 DEG C, then 37 DEG C it are cooled to, add benzophenone, Michler's keton, 2-Sulfosuccinic acid ethylhexyl sodium, calcium gluconate and DAA to stir, add pumice treated in pigment and step 2, zinnwaldite, high speed dispersion 70 minutes under 1300rpm, send into three-roller and carry out finely ground, filter, be uniformly dispersed.
Embodiment 4
A kind of weather-proof glass ink, by weight, including following component, fluorocarbon resin 16 parts, 1, 6-hexanediyl ester 11 parts, terpineol 8 parts, calcium gluconate 5 parts, isophorone diisocyanate 6 parts, pumice 2 parts, zinnwaldite 1 part, 4 parts of 2-Sulfosuccinic acid ethylhexyl sodium, 7-acrylic acid coumarin ester 9 parts, (methyl) acrylyl oxy-ethyl caffeic acid ester 14 parts, benzophenone 6 parts, Michler's keton 6 parts, triphenylphosphine 4 parts, dibutyl tin laurate 5 parts, MEHQ 2 parts, DAA 8 parts, polytetrahydrofuran diol 6 parts, propylene glycol phenylate 6 parts, dichloromethane 9 parts, pigment 0.5 part.
Described pigment is at least one in quinacridone pigment, red, phthalocyanine blue pigment, benzidine yellow, indigo-blue indigo plant, white carbon black, AZOpigments, benzimidazolone pigment.
The preparation method of above-mentioned weather-proof glass ink, including following preparation process:
Step 1, by 7-acrylic acid coumarin ester, (methyl) acrylyl oxy-ethyl caffeic acid ester, isophorone diisocyanate and polytetrahydrofuran diol stirring and dissolving, being passed through nitrogen half an hour, confined reaction 16 hours at 78 DEG C, after being cooled to room temperature, add 1,6-hexanediyl ester, stirs, and adds triphenylphosphine, dibutyl tin laurate and MEHQ, it is warming up to 95 DEG C, reaction 15 hours, dry after completion of the reaction, obtain material I in a nitrogen atmosphere；
Step 2, pumice, zinnwaldite are placed at 420 DEG C calcining 50 minutes, finely ground after cooling；
Step 3, fluorocarbon resin, terpineol, propylene glycol phenylate, dichloromethane are added in agitator tank, stir at 68 DEG C, then 35 DEG C it are cooled to, add benzophenone, Michler's keton, 2-Sulfosuccinic acid ethylhexyl sodium, calcium gluconate and DAA to stir, add pumice treated in pigment and step 2, zinnwaldite, high speed dispersion 60 minutes under 1200rpm, send into three-roller and carry out finely ground, filter, be uniformly dispersed.
Embodiment 5
A kind of weather-proof glass ink, by weight, including following component, fluorocarbon resin 20 parts, 1, 6-hexanediyl ester 15 parts, terpineol 13 parts, calcium gluconate 8 parts, isophorone diisocyanate 10 parts, pumice 4 parts, zinnwaldite 4 parts, 6 parts of 2-Sulfosuccinic acid ethylhexyl sodium, 7-acrylic acid coumarin ester 14 parts, (methyl) acrylyl oxy-ethyl caffeic acid ester 18 parts, benzophenone 10 parts, Michler's keton 8 parts, triphenylphosphine 7 parts, dibutyl tin laurate 7 parts, MEHQ 5 parts, DAA 10 parts, polytetrahydrofuran diol 8 parts, propylene glycol phenylate 9 parts, dichloromethane 14 parts, pigment 3 parts.
Described pigment is at least one in quinacridone pigment, red, phthalocyanine blue pigment, benzidine yellow, indigo-blue indigo plant, white carbon black, AZOpigments, benzimidazolone pigment.
The preparation method of above-mentioned weather-proof glass ink, including following preparation process:
Step 1, by 7-acrylic acid coumarin ester, (methyl) acrylyl oxy-ethyl caffeic acid ester, isophorone diisocyanate and polytetrahydrofuran diol stirring and dissolving, being passed through nitrogen half an hour, confined reaction 18 hours at 70 DEG C, after being cooled to room temperature, add 1,6-hexanediyl ester, stirs, and adds triphenylphosphine, dibutyl tin laurate and MEHQ, it is warming up to 90 DEG C, reaction 16 hours, dry after completion of the reaction, obtain material I in a nitrogen atmosphere；
Step 2, pumice, zinnwaldite are placed at 380 DEG C calcining 50 minutes, finely ground after cooling；
Step 3, fluorocarbon resin, terpineol, propylene glycol phenylate, dichloromethane are added in agitator tank, stir at 68 DEG C, then 35 DEG C it are cooled to, add benzophenone, Michler's keton, 2-Sulfosuccinic acid ethylhexyl sodium, calcium gluconate and DAA to stir, add pumice treated in pigment and step 2, zinnwaldite, at 1500 rpm high speed dispersion 60 minutes, send into three-roller and carry out finely ground, filter, be uniformly dispersed.
Comparative example 1
It is in place of this comparative example and the difference of embodiment: without calcium gluconate, zinnwaldite and Michler's keton.
Comparative example 2
It is in place of this comparative example and the difference of embodiment: without 7-acrylic acid coumarin ester, DAA and propylene glycol phenylate.
Performance test
By the ink printing of the various embodiments described above and comparative example on glass, after it is completely dried, carrying out following performance test according to industry standard, its test result is:
The ink using the present invention can be at room temperature or curing at low temperatures, it is not necessary to high temperature, consumes energy low, and can reduce high temperature to ink and the impact of glass baseplate.By above test result it can be seen that the ink environmental protection of the adhesive force of ink of the present invention, thermostability, resistance to water and acid and alkali resistance excellent performance, good stability, and the present invention, using effect is good, can extensively meet the application demand of printing-ink industry.
Claims (8)
- null1. a weather-proof glass ink，It is characterized in that，By weight，Including following component，Fluorocarbon resin 14-22 part、1,6-hexanediyl ester 10-17 part、Terpineol 5-15 part、Calcium gluconate 4-9 part、Isophorone diisocyanate 5-12 part、Pumice 1-6 part、Zinnwaldite 1-5 part、2-Sulfosuccinic acid ethylhexyl sodium 3-6 part、7-acrylic acid coumarin ester 8-17 part、(methyl) acrylyl oxy-ethyl caffeic acid ester 13-21 part、Benzophenone 4-11 part、Michler's keton 5-9 part、Triphenylphosphine 2-8 part、Dibutyl tin laurate 5-9 part、MEHQ 1-6 part、DAA 7-12 part、Polytetrahydrofuran diol 4-8 part、Propylene glycol phenylate 6-10 part、Dichloromethane 8-15 part、Pigment 0.2-4 part.
- Weather-proof glass ink the most according to claim 1, it is characterised in that described pigment is at least one in quinacridone pigment, red, phthalocyanine blue pigment, benzidine yellow, indigo-blue indigo plant, white carbon black, AZOpigments, benzimidazolone pigment.
- nullWeather-proof glass ink the most according to claim 1，It is characterized in that，By weight，Including following component，Fluorocarbon resin 16-20 part、1,6-hexanediyl ester 11-15 part、Terpineol 8-13 part、Calcium gluconate 5-8 part、Isophorone diisocyanate 6-10 part、Pumice 2-4 part、Zinnwaldite 1-4 part、2-Sulfosuccinic acid ethylhexyl sodium 4-6 part、7-acrylic acid coumarin ester 9-14 part、(methyl) acrylyl oxy-ethyl caffeic acid ester 14-18 part、Benzophenone 6-10 part、Michler's keton 6-8 part、Triphenylphosphine 4-7 part、Dibutyl tin laurate 5-7 part、MEHQ 2-5 part、DAA 8-10 part、Polytetrahydrofuran diol 6-8 part、Propylene glycol phenylate 6-9 part、Dichloromethane 9-14 part、Pigment 0.5-3 part.
- 4. the preparation method of the weather-proof glass ink as described in claim 1-3 is arbitrary, it is characterised in that include following preparation process:Step 1, by 7-acrylic acid coumarin ester, (methyl) acrylyl oxy-ethyl caffeic acid ester, isophorone diisocyanate and polytetrahydrofuran diol stirring and dissolving, it is passed through nitrogen half an hour, confined reaction 10-24 hour at 60-90 DEG C, after being cooled to room temperature, add 1,6-hexanediyl ester, stir, add triphenylphosphine, dibutyl tin laurate and MEHQ, it is warming up to 80-110 DEG C, reaction 10-24 hour, dries after completion of the reaction, obtains material I in a nitrogen atmosphere；Step 2, pumice, zinnwaldite are placed in 300-500 DEG C at calcine 30-60 minute, finely ground after cooling；Step 3, fluorocarbon resin, terpineol, propylene glycol phenylate, dichloromethane are added in agitator tank, stir at 60-80 DEG C, then 30-45 DEG C it is cooled to, add benzophenone, Michler's keton, 2-Sulfosuccinic acid ethylhexyl sodium, calcium gluconate and DAA to stir, add pumice treated in pigment and step 2, zinnwaldite, high speed dispersion 40-100 minute under 1000-1600rpm, send into three-roller and carry out finely ground, filter, be uniformly dispersed.
- The preparation method of weather-proof glass ink the most according to claim 4, it is characterised in that in step 1, confined reaction 16 hours at 78 DEG C.
- The preparation method of weather-proof glass ink the most according to claim 4, it is characterised in that in step 1, is warming up to 95 DEG C, in a nitrogen atmosphere reaction 15 hours.
- The preparation method of weather-proof glass ink the most according to claim 4, it is characterised in that in step 2, is placed at 420 DEG C calcining 50 minutes.
- The preparation method of weather-proof glass ink the most according to claim 4, it is characterised in that in step 3, stirs at 68 DEG C, is then cooled to 35 DEG C；In step 3, high speed dispersion 60 minutes under 1200rpm.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610540979.0A CN105968948A (en) | 2016-07-11 | 2016-07-11 | Weather-proof glass printing ink and preparation method thereof |
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| CN201610540979.0A CN105968948A (en) | 2016-07-11 | 2016-07-11 | Weather-proof glass printing ink and preparation method thereof |
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2016
- 2016-07-11 CN CN201610540979.0A patent/CN105968948A/en active Pending
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN1961046A (en) * | 2004-03-30 | 2007-05-09 | 酷瑞特表面控股有限公司 | Coating composition, coated article and a method to manufacture the same |
| CN102786839A (en) * | 2012-07-31 | 2012-11-21 | 佛山市三求电子材料有限公司 | Glass protecting ink and preparation method thereof |
| JP2015086313A (en) * | 2013-10-31 | 2015-05-07 | 旭硝子株式会社 | Recording liquid composition for ink jet printer and method of recording character and image on recording material |
| CN103666093A (en) * | 2013-11-18 | 2014-03-26 | 蚌埠市英路光电有限公司 | Fluorocarbon-resin-base printing ink and preparation method thereof |
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Application publication date: 20160928 |