CN104141243B - Stereoscopic printing is starched - Google Patents
Stereoscopic printing is starched Download PDFInfo
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- CN104141243B CN104141243B CN201410360434.2A CN201410360434A CN104141243B CN 104141243 B CN104141243 B CN 104141243B CN 201410360434 A CN201410360434 A CN 201410360434A CN 104141243 B CN104141243 B CN 104141243B
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- parts
- chain extender
- raw materials
- catalyst
- stirring
- Prior art date
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- 238000007639 printing Methods 0.000 title claims abstract description 34
- 239000002002 slurry Substances 0.000 claims abstract description 16
- 239000004970 Chain extender Substances 0.000 claims abstract description 14
- 239000003054 catalyst Substances 0.000 claims abstract description 14
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 claims abstract description 9
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims abstract description 9
- 229920002319 Poly(methyl acrylate) Polymers 0.000 claims abstract description 9
- 239000002202 Polyethylene glycol Substances 0.000 claims abstract description 9
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims abstract description 9
- 229920002472 Starch Polymers 0.000 claims abstract description 9
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 claims abstract description 9
- KCTMTGOHHMRJHZ-UHFFFAOYSA-N n-(2-methylpropoxymethyl)prop-2-enamide Chemical compound CC(C)COCNC(=O)C=C KCTMTGOHHMRJHZ-UHFFFAOYSA-N 0.000 claims abstract description 9
- 229920001223 polyethylene glycol Polymers 0.000 claims abstract description 9
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 9
- 235000010413 sodium alginate Nutrition 0.000 claims abstract description 9
- 229940005550 sodium alginate Drugs 0.000 claims abstract description 9
- 239000000661 sodium alginate Substances 0.000 claims abstract description 9
- 235000019982 sodium hexametaphosphate Nutrition 0.000 claims abstract description 9
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 claims abstract description 9
- 235000019698 starch Nutrition 0.000 claims abstract description 9
- 239000008107 starch Substances 0.000 claims abstract description 9
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 claims abstract description 9
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims abstract description 8
- 125000004386 diacrylate group Chemical group 0.000 claims abstract description 8
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 claims abstract description 4
- LDZDQDDROJXUBO-UHFFFAOYSA-N acetic acid;dibutyltin Chemical compound CC(O)=O.CC(O)=O.CCCC[Sn]CCCC LDZDQDDROJXUBO-UHFFFAOYSA-N 0.000 claims abstract description 4
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 claims abstract 2
- 238000003756 stirring Methods 0.000 claims description 28
- 238000006116 polymerization reaction Methods 0.000 claims description 16
- 239000002994 raw material Substances 0.000 claims description 16
- 230000001804 emulsifying effect Effects 0.000 claims description 12
- 239000000839 emulsion Substances 0.000 claims description 12
- 229920000642 polymer Polymers 0.000 claims description 8
- 239000011347 resin Substances 0.000 claims description 8
- 229920005989 resin Polymers 0.000 claims description 8
- -1 Polysiloxanes Polymers 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- 239000008367 deionised water Substances 0.000 claims description 5
- 229910021641 deionized water Inorganic materials 0.000 claims description 5
- 239000007864 aqueous solution Substances 0.000 claims description 4
- 238000007664 blowing Methods 0.000 claims description 4
- 238000006243 chemical reaction Methods 0.000 claims description 4
- 238000001035 drying Methods 0.000 claims description 4
- 238000002360 preparation method Methods 0.000 claims description 4
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 claims description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims 3
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims 1
- 239000005977 Ethylene Substances 0.000 claims 1
- 239000004744 fabric Substances 0.000 abstract description 5
- 238000000034 method Methods 0.000 abstract description 3
- CDQSJQSWAWPGKG-UHFFFAOYSA-N butane-1,1-diol Chemical compound CCCC(O)O CDQSJQSWAWPGKG-UHFFFAOYSA-N 0.000 abstract 1
- 239000004753 textile Substances 0.000 description 8
- 238000004144 decalcomania Methods 0.000 description 3
- 239000000975 dye Substances 0.000 description 2
- 125000003916 ethylene diamine group Chemical group 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 239000002932 luster Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 238000007650 screen-printing Methods 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 238000007613 slurry method Methods 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
Landscapes
- Printing Methods (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The present invention relates to a kind of stereoscopic printing slurry, according to the mass fraction, composed of the following components: polyethyleneglycol diacrylate 10～40 parts；Polymethyl acrylate 100～500 parts；Trimethylolpropane 10～50 parts；Polysiloxanes 5～30 parts；N isobutoxymethyl acrylamide 15～80 parts；Vinyl acetate 5～50 parts；Sodium hexameta phosphate 4～60 parts；Sodium alginate 150～300 parts；Soda 5～30 parts；Starch 5～10 parts；Chain extender 3～10 parts；Catalyst 0.2～0.6 part.Described chain extender is one or several in ethylenediamine, Isosorbide-5-Nitrae butanediol, ethylene glycol.Described catalyst is the one in dibutyl tin laurate or acetic acid dibutyl tin.Utilizing above-mentioned formula and process to prepare the stereoscopic printing slurry of gained, in PLATE SCREAM PRINTING or ROTARY SCREAM PRINTING, be printed on after being shaped by baking on cloth, the pattern obtained has convex-concave sense, color clear, and contrast is strong.
Description
Technical field
The present invention relates to a kind of stereoscopic printing slurry, belong to textile printing technical field.
Background technology
Textile printing is the process carrying out limitation dyeing on fabric predetermined area, including preparing mill base, manifests and fixation, and adds with thickening agent, within limiting the preset range that mill base is secured in fabric.Printing in textiles is typically based on dyestuff, especially on silk fabric, need to use corresponding dyestuff by different fibre properties.Technical matters and corollary equipment are more complicated, and stamp textile printing pigment is print material, have people referred to as " water color ink ".Because of the needs of practicality, the color and luster of textile screen printing must have certain fastness (not fugitive color), and its color and luster changes greatly simultaneously, so slurry and colorant typically to be sold respectively and to store, is made into printing paste during use on request.Additionally also having numerous special functional textile printing pigments, it is not limited by textile fibers properties, and therefore coating screen printing occupies certain position.
At present, the pattern that most stamp is formed is all that plane pattern is in the majority, and the formation of space pattern, need to use the concentrator of special formulation, and on market, this slurry is actually rare.
Summary of the invention
It is an object of the invention to provide a kind of stereoscopic printing slurry, and preparation method, in order to prepare application stereo printing paste on the textile as required, increase the stereoeffect of printcloth, improve the multiformity of stamp.
To achieve these goals, technical scheme is as follows.
A kind of stereoscopic printing slurry, according to the mass fraction, composed of the following components: polyethyleneglycol diacrylate: 10～40 parts；Polymethyl acrylate: 100～500 parts；Trimethylolpropane: 10～50 parts；Polysiloxanes: 5～30 parts；N-isobutoxymethyl acrylamide: 15～80 parts；Vinyl acetate: 5～50 parts；Sodium hexameta phosphate: 4～60 parts；Sodium alginate: 150～300 parts；Soda: 5～30 parts；Starch: 5～10 parts；Chain extender: 3～10 parts；Catalyst: 0.2～0.6 part.
Further, one or several during described chain extender is ethylenediamine, BDO, ethylene glycol.
Further, the one during described catalyst is dibutyl tin laurate or acetic acid dibutyl tin.
Stereoscopic printing based on above-mentioned formula is starched, and its preparation process is as follows:
(1) polyethyleneglycol diacrylate, polymethyl acrylate, trimethylolpropane, polysiloxanes, chain extender, catalyst being added in reactor by above-mentioned raw materials quality proportioning, stirring heats up, and reacts 6～10 hours at 50～90 DEG C, prepares performed polymer；
(2) above-mentioned performed polymer is put in emulsifying kettle, cools to 20～50 DEG C, add above-mentioned raw materials quality proportioning, after vinyl acetate stirs, quickly stir, add deionized water 500～2000 parts, carry out emulsifying, make emulsion；
(3) while stirring toward N-isobutoxymethyl acrylamide, soda and the starch of addition above-mentioned raw materials quality proportioning in emulsifying kettle, pre-polymerization emulsion is made；
(4) above-mentioned pre-polymerization emulsion being joined in resin polymerization still, and add the sodium hexameta phosphate of above-mentioned raw materials quality proportioning, sodium alginate, stirring and dissolving is uniform, makes aqueous solution；
(5) stirring of resin polymerization still is warmed up to 65～90 DEG C, carries out chemical reaction 4～10 hours；
(6) then cool to 20～40 DEG C, stir 30～60 minutes, then filter blowing, i.e. obtain this product.
The above-mentioned stereoscopic printing slurry prepared, for plain net or ROTARY SCREAM PRINTING, stamp post-baking temperature is 60～80 DEG C, and drying time is 90～120 minutes, and prepared decalcomania has preferable convex-concave sense.
This beneficial effect of the invention is: utilizing above-mentioned formula and process to prepare the stereoscopic printing slurry of gained, in PLATE SCREAM PRINTING or ROTARY SCREAM PRINTING, be printed on after being shaped by baking on cloth, the pattern obtained has convex-concave sense, color clear, and contrast is strong.
Detailed description of the invention
Below in conjunction with embodiment, the detailed description of the invention of the present invention is described, in order to be better understood from the present invention.
Embodiment
1
The present embodiment neutral body printing paste, composed of the following components: polyethyleneglycol diacrylate 10 kilograms, polymethyl acrylate double centner, trimethylolpropane 10 kilograms, polysiloxanes 5 kilograms, N-isobutoxymethyl acrylamide 15 kilograms, vinyl acetate 5 kilograms, sodium hexameta phosphate 4 kilograms, sodium alginate 150 kilograms, soda 5 kilograms, starch 5 kilograms, chain extender 3 kilograms, catalyst 0.2 kilogram, described chain extender is ethylenediamine, and described catalyst is dibutyl tin laurate.
The measured step of preparing of above-mentioned stereoscopic printing slurry is suddenly:
(1) polyethyleneglycol diacrylate, polymethyl acrylate, trimethylolpropane, polysiloxanes, chain extender, catalyst being added in reactor by above-mentioned raw materials quality, stirring heats up, and reacts 10 hours at 50 DEG C, prepares performed polymer；
(2) above-mentioned performed polymer is put in emulsifying kettle, cools to 20 DEG C, add above-mentioned raw materials quality proportioning, after vinyl acetate stirs, quickly stir, add deionized water 500 kilograms, carry out emulsifying, make emulsion；
(3) while stirring toward N-isobutoxymethyl acrylamide, soda and the starch of addition above-mentioned raw materials quality proportioning in emulsifying kettle, pre-polymerization emulsion is made；
(4) above-mentioned pre-polymerization emulsion being joined in resin polymerization still, and add the sodium hexameta phosphate of above-mentioned raw materials quality, sodium alginate, stirring and dissolving is uniform, makes aqueous solution；
(5) stirring of resin polymerization still is warmed up to 65 DEG C, carries out chemical reaction 10 hours；
(6) then cool to 20 DEG C, stir 60 minutes, then filter blowing, i.e. obtain this product.
Stereoscopic printing slurry in the present embodiment, for PLATE SCREAM PRINTING, stamp post-baking temperature is 80 DEG C, and drying time is 90 minutes, and prepared decalcomania has preferable convex-concave sense.
Embodiment
2
In the embodiment of the present invention stereoscopic printing slurry, composed of the following components: polyethyleneglycol diacrylate 40 kilograms, polymethyl acrylate 500 kilograms, trimethylolpropane 50 kilograms, polysiloxanes 30 kilograms, N-isobutoxymethyl acrylamide 80 kilograms, vinyl acetate 50 kilograms, sodium hexameta phosphate 60 kilograms, sodium alginate 300 kilograms, soda: 30 kilograms, starch 10 kilograms, chain extender 10 kilograms, catalyst 0.6 kilogram；Described chain extender is BDO；Described catalyst is acetic acid dibutyl tin.
The measured step of preparing of above-mentioned stereoscopic printing slurry is suddenly: preparation method:
(1) polyethyleneglycol diacrylate, polymethyl acrylate, trimethylolpropane, polysiloxanes, chain extender, catalyst being added in reactor by above-mentioned raw materials quality proportioning, stirring heats up, and reacts 6 hours at 90 DEG C, prepares performed polymer；
(2) above-mentioned performed polymer is put in emulsifying kettle, cools to 50 DEG C, add above-mentioned raw materials quality proportioning, after vinyl acetate stirs, quickly stir, add deionized water 2000 kilograms, carry out emulsifying, make emulsion；
(3) while stirring toward N-isobutoxymethyl acrylamide, soda and the starch of addition above-mentioned raw materials quality proportioning in emulsifying kettle, pre-polymerization emulsion is made；
(4) above-mentioned pre-polymerization emulsion being joined in resin polymerization still, and add the sodium hexameta phosphate of above-mentioned raw materials quality proportioning, sodium alginate, stirring and dissolving is uniform, makes aqueous solution；
(5) stirring of resin polymerization still is warmed up to 90 DEG C, carries out chemical reaction 4 hours；
(6) then cool to 40 DEG C, stir 30 minutes, then filter blowing, i.e. obtain this product.
Stereoscopic printing slurry in the present embodiment, for ROTARY SCREAM PRINTING, stamp post-baking temperature is 60 DEG C, and drying time is 120 minutes, and prepared decalcomania has preferable convex-concave sense.
The above is the preferred embodiment of the present invention; it should be pointed out that, for those skilled in the art, under the premise without departing from the principles of the invention; can also make some improvements and modifications, these improvements and modifications are also considered as protection scope of the present invention.
Claims (1)
1. a stereoscopic printing slurry, it is characterised in that: according to the mass fraction, composed of the following components: Polyethylene Glycol two
Acrylate 10～40 parts；Polymethyl acrylate 100～500 parts；Trimethylolpropane 10～50 parts；Polysiloxanes 5～
30 parts；N-isobutoxymethyl acrylamide 15～80 parts；Vinyl acetate 5～50 parts；Sodium hexameta phosphate 4～60 parts；
Sodium alginate 150～300 parts；Soda 5～30 parts；Starch 5～10 parts；Chain extender 3～10 parts；Catalyst 0.2～
0.6 part；Deionized water 500～2000 parts；Described chain extender is the one in ethylenediamine, BDO, ethylene glycol
Or it is several；Described catalyst is the one in dibutyl tin laurate or acetic acid dibutyl tin；
The preparation process of described stereoscopic printing slurry is as follows:
(1) press above-mentioned raw materials quality proportioning by polyethyleneglycol diacrylate, polymethyl acrylate, trimethylolpropane,
Polysiloxanes, chain extender, catalyst are added in reactor, and stirring heats up, and react 6～10 hours at 50～90 DEG C, system
Obtain performed polymer；
(2) above-mentioned performed polymer is put in emulsifying kettle, cools to 20～50 DEG C, add the acetic acid of above-mentioned raw materials quality proportioning
After ethylene stirs, quickly stir, add deionized water 500～2000 parts, carry out emulsifying, make emulsion；
(3) in emulsifying kettle, the N-isobutoxymethyl acrylamide of above-mentioned raw materials quality proportioning, soda are added while stirring
And starch, make pre-polymerization emulsion；
(4) above-mentioned pre-polymerization emulsion is joined in resin polymerization still, and add above-mentioned raw materials quality proportioning sodium hexameta phosphate,
Sodium alginate, stirring and dissolving is uniform, makes aqueous solution；
(5) stirring of resin polymerization still is warmed up to 65～90 DEG C, carries out chemical reaction 4～10 hours；
(6) then cool to 20～40 DEG C, stir 30～60 minutes, then filter blowing, i.e. obtain this product；
Described stereoscopic printing is starched, and for plain net or ROTARY SCREAM PRINTING, stamp post-baking temperature is 60～80 DEG C, drying time
It it is 90～120 minutes.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410360434.2A CN104141243B (en) | 2014-07-28 | 2014-07-28 | Stereoscopic printing is starched |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410360434.2A CN104141243B (en) | 2014-07-28 | 2014-07-28 | Stereoscopic printing is starched |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104141243A CN104141243A (en) | 2014-11-12 |
| CN104141243B true CN104141243B (en) | 2016-08-24 |
Family
ID=51850566
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410360434.2A Expired - Fee Related CN104141243B (en) | 2014-07-28 | 2014-07-28 | Stereoscopic printing is starched |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104141243B (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR102037558B1 (en) * | 2015-07-20 | 2019-10-28 | 주식회사 엘지화학 | An Ink Composition for 3D Printing Support and the Manufacturing Method using the Same |
| CN109385918B (en) * | 2018-11-12 | 2021-02-12 | 广州市珠之江环保印花材料实业有限公司 | White glue for printing and dyeing and preparation method thereof |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102619102B (en) * | 2012-04-06 | 2013-09-11 | 辽宁恒星精细化工有限公司 | Embossed printing paste for velvet fabric and preparation method thereof |
| CN102619106B (en) * | 2012-04-16 | 2013-06-19 | 辽宁恒星精细化工有限公司 | Real leather suede leather stereoscopic printing paste and preparation method |
| CN102634999A (en) * | 2012-04-17 | 2012-08-15 | 青岛聚大洋海藻工业有限公司 | Sodium alga acid printing paste and preparation process thereof |
| CN103233375B (en) * | 2013-05-04 | 2014-08-13 | 辽宁恒星精细化工有限公司 | Stereo printing paste for suede and preparation method thereof |
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2014
- 2014-07-28 CN CN201410360434.2A patent/CN104141243B/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CN104141243A (en) | 2014-11-12 |
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| C06 | Publication | ||
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| CB02 | Change of applicant information |
Address after: 312000 room 7009, creative building, Keqiao District, Zhejiang, Shaoxing Applicant after: SHAOXING CAISEYUAN TEXTILE TECHNOLOGY Co.,Ltd. Address before: 312000 room 7009, creative building, Keqiao District, Zhejiang, Shaoxing Applicant before: SHAOXING COUNTY CAISEYUAN TEXTILE TECHNOLOGY Co.,Ltd. |
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| TR01 | Transfer of patent right |
Effective date of registration: 20181008 Address after: 312000 Binhai Industrial Zone, Keqiao District, Shaoxing, Zhejiang Patentee after: SHAOXING BAILIHENG PRINTING & DYEING CO.,LTD. Address before: 312000 room 7009, creative building, Keqiao District, Shaoxing, Zhejiang. Patentee before: SHAOXING CAISEYUAN TEXTILE TECHNOLOGY Co.,Ltd. |
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| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20160824 |