CN104141243A - Three-dimensional printing paste - Google Patents
Three-dimensional printing paste Download PDFInfo
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- CN104141243A CN104141243A CN201410360434.2A CN201410360434A CN104141243A CN 104141243 A CN104141243 A CN 104141243A CN 201410360434 A CN201410360434 A CN 201410360434A CN 104141243 A CN104141243 A CN 104141243A
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Abstract
The invention relates to three-dimensional printing paste. The three-dimensional printing paste is composed of, by mass, 10-40 parts of polyethylene glycol 200 diacrylate, 100-500 parts of polymethyl acrylate, 10-50 parts of trimethylolpropane, 5-30 parts of polysiloxane, 15-80 parts of N-(isobutoxymethyl)acrylamide, 5-50 parts of vinyl acetate, 4-60 parts of sodium hexametaphosphate, 150-300 parts of sodium alginate, 5-30 parts of sodium carbonate, 5-10 parts of starch, 3-10 parts of chain extenders and 0.2-0.6 part of a catalyst. The chain extenders are one or more of ethidene diamine, 1,4-butanediol and ethanediol. The catalyst is dibutyltin dilaurate or dibutyl tin acetate. After the three-dimensional printing paste prepared through the formula and the technical method is printed on cloth through baking setting during flat screen printing or rotary screen printing, obtained patterns have convex-concave feeling, bright colors and a sharp contrast.
Description
Technical field
The present invention relates to a kind of stereoscopic printing slurry, belong to textile printing technical field.
Background technology
Textile printing is the process of limiting to dyeing on fabric predetermined area, comprising preparing mill base, manifests and fixation, and adds with thickener, be secured in the preset range of fabric to limit mill base within.Printing in textiles generally be take dyestuff as main, especially, on silk fabric, need adopt corresponding dyestuff by different fibre properties.Technical matters and corollary equipment more complicated, stamp textile printing pigment is to print material, someone is referred to as " water color ink ".Because of the needs of practicality, the color and luster of textiles screen printing must have certain fastness (not fugitive color), and its color and luster changes greatly simultaneously, so slurry and colorant generally will be sold respectively and store, is made on request printing paste during use.Also have in addition numerous special functional textile printing pigments, it is not often subject to the restriction of textile fibers properties, so coating screen printing occupies certain position.
At present, the pattern that mostly stamp forms is all that plane pattern is in the majority, and the formation of space pattern, need to adopt the concentrator of special formulation, and on market, this slurry is actually rare.
Summary of the invention
The object of the present invention is to provide a kind of stereoscopic printing slurry, and preparation method, to prepare as required the stereoscopic printing slurry being applied on textiles, increase the stereoeffect of printcloth, improve the diversity of stamp.
To achieve these goals, technical scheme of the present invention is as follows.
A kind of stereoscopic printing slurry, according to the mass fraction, composed of the following components: polyethyleneglycol diacrylate: 10～40 parts; PMA: 100～500 parts; Trimethylolpropane: 10～50 parts; Polysiloxanes: 5～30 parts; N-isobutoxy Methacrylamide: 15～80 parts; Vinyl acetate: 5～50 parts; Calgon: 4～60 parts; Sodium alginate: 150～300 parts; Soda ash: 5～30 parts; Starch: 5～10 parts; Chain extender: 3～10 parts; Catalyst: 0.2～0.6 part.
Further, described chain extender is one or several in ethylenediamine, BDO, ethylene glycol.
Further, described catalyst is a kind of in dibutyl tin laurate or acetic acid dibutyl tin.
Stereoscopic printing slurry based on above-mentioned formula, its preparation process is as follows:
(1) by above-mentioned raw materials quality proportioning, polyethyleneglycol diacrylate, PMA, trimethylolpropane, polysiloxanes, chain extender, catalyst are added in reactor, stir and heat up, 50～90 ℃ of reactions 6～10 hours, make performed polymer;
(2) above-mentioned performed polymer is put in emulsifying kettle, cools to 20～50 ℃, add above-mentioned raw materials quality proportioning, after vinyl acetate stirs, rapid stirring, adds 500～2000 parts of deionized waters, carries out emulsification, makes emulsion;
(3) while stirring toward the N-isobutoxy Methacrylamide, soda ash and the starch that add above-mentioned raw materials quality proportioning in emulsifying kettle, make pre-polymerization emulsion;
(4) above-mentioned pre-polymerization emulsion is joined in resin polymerization still, and add calgon, the sodium alginate of above-mentioned raw materials quality proportioning, stirring and dissolving is even, makes the aqueous solution;
(5) resin polymerization still is stirred and is warmed up to 65～90 ℃, carry out chemical reaction 4～10 hours;
(6) then cool to 20～40 ℃, stir 30～60 minutes, then filter blowing, obtain this product.
The above-mentioned stereoscopic printing slurry preparing, for plain net or ROTARY SCREAM PRINTING, stamp post-drying temperature is 60～80 ℃, and drying time is 90～120 minutes, and prepared decalcomania has good convex-concave sense.
This beneficial effect of the invention is: utilize above-mentioned formula and process to prepare the stereoscopic printing slurry of gained, in PLATE SCREAM PRINTING or ROTARY SCREAM PRINTING, after being printed on and shaping by baking on cloth, the pattern obtaining has convex-concave sense, and color clear contrasts strongly.
The specific embodiment
Below in conjunction with embodiment, the specific embodiment of the present invention is described, to better understand the present invention.
embodiment 1
The present embodiment neutral body printing paste, composed of the following components: 10 kilograms of polyethyleneglycol diacrylates, PMA double centner, 10 kilograms of trimethylolpropanes, 5 kilograms of polysiloxanes, 15 kilograms of N-isobutoxy Methacrylamides, 5 kilograms of vinyl acetates, 4 kilograms of calgons, 150 kilograms of sodium alginates, 5 kilograms of soda ash, 5 kilograms of starch, 3 kilograms of chain extenders, 0.2 kilogram of catalyst, described chain extender is ethylenediamine, and described catalyst is dibutyl tin laurate.
The measured step of preparing of above-mentioned stereoscopic printing slurry is suddenly:
(1) by above-mentioned raw materials quality, polyethyleneglycol diacrylate, PMA, trimethylolpropane, polysiloxanes, chain extender, catalyst are added in reactor, stir and heat up, 50 ℃ of reactions 10 hours, make performed polymer;
(2) above-mentioned performed polymer is put in emulsifying kettle, cools to 20 ℃, add above-mentioned raw materials quality proportioning, after vinyl acetate stirs, rapid stirring, adds 500 kilograms of deionized waters, carries out emulsification, makes emulsion;
(3) while stirring toward the N-isobutoxy Methacrylamide, soda ash and the starch that add above-mentioned raw materials quality proportioning in emulsifying kettle, make pre-polymerization emulsion;
(4) above-mentioned pre-polymerization emulsion is joined in resin polymerization still, and add calgon, the sodium alginate of above-mentioned raw materials quality, stirring and dissolving is even, makes the aqueous solution;
(5) resin polymerization still is stirred and is warmed up to 65 ℃, carry out chemical reaction 10 hours;
(6) then cool to 20 ℃, stir 60 minutes, then filter blowing, obtain this product.
Stereoscopic printing slurry in the present embodiment, for PLATE SCREAM PRINTING, stamp post-drying temperature is 80 ℃, and drying time is 90 minutes, and prepared decalcomania has good convex-concave sense.
embodiment 2
Stereoscopic printing in embodiment of the present invention slurry, composed of the following components: 40 kilograms of polyethyleneglycol diacrylates, 500 kilograms of PMAs, 50 kilograms of trimethylolpropanes, 30 kilograms of polysiloxanes, 80 kilograms of N-isobutoxy Methacrylamides, 50 kilograms of vinyl acetates, 60 kilograms of calgons, 300 kilograms of sodium alginates, soda ash: 30 kilograms, 10 kilograms of starch, 10 kilograms of chain extenders, 0.6 kilogram of catalyst; Described chain extender is BDO; Described catalyst is acetic acid dibutyl tin.
The measured step of preparing of above-mentioned stereoscopic printing slurry is suddenly: preparation method:
(1) by above-mentioned raw materials quality proportioning, polyethyleneglycol diacrylate, PMA, trimethylolpropane, polysiloxanes, chain extender, catalyst are added in reactor, stir and heat up, 90 ℃ of reactions 6 hours, make performed polymer;
(2) above-mentioned performed polymer is put in emulsifying kettle, cools to 50 ℃, add above-mentioned raw materials quality proportioning, after vinyl acetate stirs, rapid stirring, adds 2000 kilograms of deionized waters, carries out emulsification, makes emulsion;
(3) while stirring toward the N-isobutoxy Methacrylamide, soda ash and the starch that add above-mentioned raw materials quality proportioning in emulsifying kettle, make pre-polymerization emulsion;
(4) above-mentioned pre-polymerization emulsion is joined in resin polymerization still, and add calgon, the sodium alginate of above-mentioned raw materials quality proportioning, stirring and dissolving is even, makes the aqueous solution;
(5) resin polymerization still is stirred and is warmed up to 90 ℃, carry out chemical reaction 4 hours;
(6) then cool to 40 ℃, stir 30 minutes, then filter blowing, obtain this product.
Stereoscopic printing slurry in the present embodiment, for ROTARY SCREAM PRINTING, stamp post-drying temperature is 60 ℃, and drying time is 120 minutes, and prepared decalcomania has good convex-concave sense.
The above is the preferred embodiment of the present invention; it should be pointed out that for those skilled in the art, under the premise without departing from the principles of the invention; can also make some improvements and modifications, these improvements and modifications are also considered as protection scope of the present invention.
Claims (5)
1. a stereoscopic printing slurry, is characterized in that: according to the mass fraction, composed of the following components: 10～40 parts of polyethyleneglycol diacrylates; 100～500 parts of PMAs; 10～50 parts of trimethylolpropanes; 5～30 parts of polysiloxanes; 15～80 parts of N-isobutoxy Methacrylamides; 5～50 parts of vinyl acetates; 4～60 parts of calgons; 150～300 parts of sodium alginates; 5～30 parts of soda ash; 5～10 parts of starch; 3～10 parts of chain extenders; 0.2～0.6 part of catalyst.
2. stereoscopic printing slurry according to claim 1, is characterized in that: described chain extender is one or several in ethylenediamine, BDO, ethylene glycol.
3. stereoscopic printing according to claim 1 slurry, is characterized in that: described catalyst is a kind of in dibutyl tin laurate or acetic acid dibutyl tin.
4. according to the stereoscopic printing slurry described in claims 1 to 3, it is characterized in that: the preparation process of described stereoscopic printing slurry is as follows:
(1) by above-mentioned raw materials quality proportioning, polyethyleneglycol diacrylate, PMA, trimethylolpropane, polysiloxanes, chain extender, catalyst are added in reactor, stir and heat up, 50～90 ℃ of reactions 6～10 hours, make performed polymer;
(2) above-mentioned performed polymer is put in emulsifying kettle, cools to 20～50 ℃, add above-mentioned raw materials quality proportioning, after vinyl acetate stirs, rapid stirring, adds 500～2000 parts of deionized waters, carries out emulsification, makes emulsion;
(3) while stirring toward the N-isobutoxy Methacrylamide, soda ash and the starch that add above-mentioned raw materials quality proportioning in emulsifying kettle, make pre-polymerization emulsion;
(4) above-mentioned pre-polymerization emulsion is joined in resin polymerization still, and add calgon, the sodium alginate of above-mentioned raw materials quality proportioning, stirring and dissolving is even, makes the aqueous solution;
(5) resin polymerization still is stirred and is warmed up to 65～90 ℃, carry out chemical reaction 4～10 hours;
(6) then cool to 20～40 ℃, stir 30～60 minutes, then filter blowing, obtain this product.
5. according to the stereoscopic printing slurry described in claim 1 to 4, it is characterized in that: described stereoscopic printing slurry, for plain net or ROTARY SCREAM PRINTING, stamp post-drying temperature is 60～80 ℃, drying time is 90～120 minutes.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410360434.2A CN104141243B (en) | 2014-07-28 | 2014-07-28 | Stereoscopic printing is starched |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201410360434.2A CN104141243B (en) | 2014-07-28 | 2014-07-28 | Stereoscopic printing is starched |
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| CN104141243A true CN104141243A (en) | 2014-11-12 |
| CN104141243B CN104141243B (en) | 2016-08-24 |
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| CN201410360434.2A Active CN104141243B (en) | 2014-07-28 | 2014-07-28 | Stereoscopic printing is starched |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107849381A (en) * | 2015-07-20 | 2018-03-27 | 株式会社Lg化学 | For 3D printing supporter ink composition and use its 3D printing manufacture method |
| CN109385918A (en) * | 2018-11-12 | 2019-02-26 | 广州市珠之江环保印花材料实业有限公司 | Printing and dyeing PVA glue and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102619106A (en) * | 2012-04-16 | 2012-08-01 | 辽宁恒星精细化工有限公司 | Real leather suede leather stereoscopic printing paste and preparation method |
| CN102619102A (en) * | 2012-04-06 | 2012-08-01 | 辽宁恒星精细化工有限公司 | Embossed printing paste for velvet fabric and preparation method thereof |
| CN102634999A (en) * | 2012-04-17 | 2012-08-15 | 青岛聚大洋海藻工业有限公司 | Sodium alga acid printing paste and preparation process thereof |
| CN103233375A (en) * | 2013-05-04 | 2013-08-07 | 辽宁恒星精细化工有限公司 | Stereo printing paste for suede and preparation method thereof |
-
2014
- 2014-07-28 CN CN201410360434.2A patent/CN104141243B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102619102A (en) * | 2012-04-06 | 2012-08-01 | 辽宁恒星精细化工有限公司 | Embossed printing paste for velvet fabric and preparation method thereof |
| CN102619106A (en) * | 2012-04-16 | 2012-08-01 | 辽宁恒星精细化工有限公司 | Real leather suede leather stereoscopic printing paste and preparation method |
| CN102634999A (en) * | 2012-04-17 | 2012-08-15 | 青岛聚大洋海藻工业有限公司 | Sodium alga acid printing paste and preparation process thereof |
| CN103233375A (en) * | 2013-05-04 | 2013-08-07 | 辽宁恒星精细化工有限公司 | Stereo printing paste for suede and preparation method thereof |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107849381A (en) * | 2015-07-20 | 2018-03-27 | 株式会社Lg化学 | For 3D printing supporter ink composition and use its 3D printing manufacture method |
| EP3327095A4 (en) * | 2015-07-20 | 2018-08-01 | LG Chem, Ltd. | Ink composition for 3d printing support and 3d printing manufacturing method using same |
| US10954404B2 (en) | 2015-07-20 | 2021-03-23 | Lg Chem, Ltd. | Ink composition for 3D printing support and 3D printing manufacturing method using the same |
| CN109385918A (en) * | 2018-11-12 | 2019-02-26 | 广州市珠之江环保印花材料实业有限公司 | Printing and dyeing PVA glue and preparation method thereof |
| CN109385918B (en) * | 2018-11-12 | 2021-02-12 | 广州市珠之江环保印花材料实业有限公司 | White glue for printing and dyeing and preparation method thereof |
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| Publication number | Publication date |
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| CN104141243B (en) | 2016-08-24 |
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Address after: 312000 room 7009, creative building, Keqiao District, Zhejiang, Shaoxing Applicant after: SHAOXING CAISEYUAN TEXTILE SCIENCE & TECHNOLOGY CO., LTD. Address before: 312000 room 7009, creative building, Keqiao District, Zhejiang, Shaoxing Applicant before: SHAOXING CAISEYUAN TEXTILE SCIENCE & TECHNOLOGY CO., LTD. |
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Effective date of registration: 20181008 Address after: 312000 Binhai Industrial Zone, Keqiao District, Shaoxing, Zhejiang Patentee after: Shaoxing BELLE constant printing and dyeing Co., Ltd. Address before: 312000 room 7009, creative building, Keqiao District, Shaoxing, Zhejiang. Patentee before: SHAOXING CAISEYUAN TEXTILE SCIENCE & TECHNOLOGY CO., LTD. |