CN102174747B - Environment-friendly textile printing pearlescent adhesive cement and preparation method and application thereof - Google Patents
Environment-friendly textile printing pearlescent adhesive cement and preparation method and application thereof Download PDFInfo
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- 239000004568 cement Substances 0.000 title claims abstract description 74
- 238000007639 printing Methods 0.000 title claims abstract description 65
- 239000004753 textile Substances 0.000 title claims abstract description 39
- 239000000853 adhesive Substances 0.000 title claims abstract description 26
- 230000001070 adhesive effect Effects 0.000 title claims abstract description 26
- 238000002360 preparation method Methods 0.000 title abstract description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims abstract description 23
- 239000000843 powder Substances 0.000 claims abstract description 22
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 22
- 239000002562 thickening agent Substances 0.000 claims abstract description 19
- 239000002245 particle Substances 0.000 claims abstract description 15
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 13
- 239000002270 dispersing agent Substances 0.000 claims abstract description 13
- 230000000844 anti-bacterial effect Effects 0.000 claims abstract description 12
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 12
- UYTPUPDQBNUYGX-UHFFFAOYSA-N guanine Chemical compound O=C1NC(N)=NC2=C1N=CN2 UYTPUPDQBNUYGX-UHFFFAOYSA-N 0.000 claims description 34
- 238000003756 stirring Methods 0.000 claims description 15
- 239000002002 slurry Substances 0.000 claims description 14
- 238000000034 method Methods 0.000 claims description 8
- 239000011248 coating agent Substances 0.000 claims description 6
- 238000000576 coating method Methods 0.000 claims description 6
- 239000010985 leather Substances 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- 238000009736 wetting Methods 0.000 claims description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 2
- 125000000129 anionic group Chemical group 0.000 claims description 2
- 229920000642 polymer Polymers 0.000 claims description 2
- 229920001296 polysiloxane Polymers 0.000 claims description 2
- -1 polysiloxanes Polymers 0.000 claims description 2
- 239000000049 pigment Substances 0.000 abstract description 9
- 238000007650 screen-printing Methods 0.000 abstract description 5
- 230000008901 benefit Effects 0.000 abstract description 4
- 238000002485 combustion reaction Methods 0.000 abstract description 3
- 230000002269 spontaneous effect Effects 0.000 abstract description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 abstract 1
- 230000003647 oxidation Effects 0.000 abstract 1
- 238000007254 oxidation reaction Methods 0.000 abstract 1
- 231100000331 toxic Toxicity 0.000 abstract 1
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- 150000002500 ions Chemical class 0.000 description 10
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- 230000000694 effects Effects 0.000 description 6
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- 230000001360 synchronised effect Effects 0.000 description 6
- 239000002253 acid Substances 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 239000011347 resin Substances 0.000 description 5
- 229920005989 resin Polymers 0.000 description 5
- SJEYSFABYSGQBG-UHFFFAOYSA-M Patent blue Chemical compound [Na+].C1=CC(N(CC)CC)=CC=C1C(C=1C(=CC(=CC=1)S([O-])(=O)=O)S([O-])(=O)=O)=C1C=CC(=[N+](CC)CC)C=C1 SJEYSFABYSGQBG-UHFFFAOYSA-M 0.000 description 4
- 239000000980 acid dye Substances 0.000 description 4
- 239000004567 concrete Substances 0.000 description 4
- 239000000986 disperse dye Substances 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 235000010215 titanium dioxide Nutrition 0.000 description 4
- 238000005406 washing Methods 0.000 description 4
- 239000007767 bonding agent Substances 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- 239000000975 dye Substances 0.000 description 3
- 238000004043 dyeing Methods 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- 239000004922 lacquer Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 2
- 244000144730 Amygdalus persica Species 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 2
- 235000006040 Prunus persica var persica Nutrition 0.000 description 2
- 230000009102 absorption Effects 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
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- 230000000845 anti-microbial effect Effects 0.000 description 2
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- 238000005201 scrubbing Methods 0.000 description 2
- 238000010792 warming Methods 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 230000003026 anti-oxygenic effect Effects 0.000 description 1
- 238000004500 asepsis Methods 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 238000010018 discharge printing Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000004534 enameling Methods 0.000 description 1
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- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
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- 238000012986 modification Methods 0.000 description 1
- 239000008601 oleoresin Substances 0.000 description 1
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- 229920002647 polyamide Polymers 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 238000013112 stability test Methods 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 238000009955 starching Methods 0.000 description 1
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Abstract
The invention discloses an environment-friendly textile printing pearlescent adhesive cement and a preparation method and application thereof. The adhesive cement comprises the following components in percentage by weight: 49 to 39 percent of environment-friendly ultra-soft adhesive, 15 to 25 percent of rutile silvery white pearlescent powder in the particle size range of between 5 and 25 microns, 15 to 25 percent of anatase silvery white pearlescent powder in the particle size range of between 10 and 60 microns, 4 to 6 percent of glycol, 1 to 2 percent of dispersing agent, 1 to 3 percent of leveling agent, 1 to 2 percent of mould-proof antibacterial auxiliary agent, 2 to 4 percent of nano negative ion far-infrared powder and 2 to 4 percent of thickening agent. The adhesive cement cannot block a screen during screen printing, has high weather resistance and has the obvious advantages of environment friendliness, no toxic hazard, high-temperature resistance, acid-base resistance, incapability of spontaneous combustion and combustion supporting, high oxidation resistance, high covering power and the like which are obviously distinguished from those of the common dye and pigment.
Description
Technical field
The invention belongs to the printing technique field, be specifically related to a kind of environment-friendly type textile printing with the pearly-lustre rubber cement.
Background technology
Rubber cement can be divided into common rubber cement and special rubber cement according to purposes.Common rubber cement just is used for the slurry that general stamp uses, and does not require to reach special effect.Itself generally can be divided into interspongioplastic substance, PVA glue, color printing slurry and Lacquer finish slurry.It is but that transparent nothing is appointed covering power that interspongioplastic substance is imprinted on cloth itself; Only be applicable to that light cloth stamp uses; Advantage is because the content of resin own is high, so firmness is better than PVA glue, mixes with PVA glue to use and not only can improve firmness; Can also increase gloss and elasticity, but covering power is poor; And PVA glue itself is the usefulness that can be used in white stamp of white, strong covering power, and the content of itself titanium white powder of PVA glue is high, so firmness is relatively poor; The two combines thus, and promptly 30% left and right sides PVA glue adds interspongioplastic substance about 70% can be used for the dark cloth stamp of enameling be the color printing slurry, can reduce the consumption of mill base with the color printing slurry, can reach good color and luster saturation degree and colored covering power again; Because some rubber cement intrinsic brightness is not very high, can stamp one deck Lacquer finish slurry on its surface, the Lacquer finish slurry mainly is a kind of slurry that improves stamp article surface brightness.
The used rubber cement of existing domestic print works all is that adhesive and rutile-type, anatase thpe white powder and other filler compatibility with common or environment-friendly type forms.The stamp of rubber cement also mostly is confined to the straight seal of rubber cement itself, and uses till today always.Human body is being protected the research on functional and similarly rubber cement is domestic did not also have.
Pearl essence is at coating, plastics, and printing ink, leather, rubber, papermaking is though be widely used in the industries such as cosmetics.But because color production theory, the particle diameter form and pigment, dyestuff and different fully with the particle diameter of the titanium white powder of stuffing as conventional rubber cement of pearl essence, the pure so far environment-friendly type textile printing prepared behind any stuffing and the environment-friendly type adhesive compatibility of not adding with pearl essence is with also not having in the domestic and international stamp industry of pearly-lustre rubber cement.The present invention therefore.
Summary of the invention
The object of the invention is to provide a kind of environment-friendly type textile printing to use the pearly-lustre rubber cement, the pearly-lustre rubber cement that provides a kind of new, compliance with environmental protection requirements, modern printing technology to require stamp to use.
In order to solve these problems of the prior art, technical scheme provided by the invention is:
A kind of environment-friendly type textile printing is used the pearly-lustre rubber cement, it is characterized in that said rubber cement counts with the percentage by weight of its component: the ultra soft adhesive 49-39% of environment-friendly type; Particle size range is at the rutile-type silvery white pearl essence 15-25% of 5-25 μ m; Particle size range is at the anatase titanium dioxide silvery white pearl essence 25-15% of 10-60 μ m; Ethylene glycol 4-6%; Dispersant 1-2%; Levelling agent 1-3%; Antimildew and antibacterial auxiliary agent 1-2%; Nano-negative ion far-infrared powder 2-4%; Thickener 2-4%.The nano-negative ion far-infrared powder is a kind of composite powder material that integrates various ingredients.
Preferably, the ultra soft adhesive of said environment-friendly type is selected unique synthetic denaturing acrylamide lonitrile copolymer for use, the ultra soft printing adhesive of described synthetic denaturing acrylamide lonitrile copolymer, and the market model is T-608.
Preferably, said dispersant is selected the wetting dispersing agent that is used for water-based system for use, is the polymer that anionic species contains hydrophilic radical, and the market model of the wetting dispersing agent of water-based system is WinSperse 4010.
Preferably, said levelling agent is to select polyether-modified polysiloxanes for use, belongs to novel extraordinary organic silicon surfactant, and the market model is a LY-3308 leather coating levelling agent.
Preferably, said thickener is that to select acrylic acid for use be main multiple copolymer, has the thickener of stronger thickening capabilities.The market model of selecting for use is a SH201 environmental protection coating material printing thickening agent.
Preferably, said mite-proofing and antimicrobial auxiliary agent can be that model commonly used is SCJ-998 on the market, is the mite-proofing and antimicrobial finishing agent that is applicable to fabrics such as cotton, fiber crops, silk, hair, polyester-cotton blend, polyamide fibre, sticking fibre.
Preferably, it is I-13 that said nano-negative ion far-infrared powder adopts model, and it contains the anion body, has significantly to be excited to produce the anion effect.
Preferably, to select model for use be the anatase titanium dioxide silvery white pearl essence of TZ1004 to said anatase titanium dioxide silvery white pearl essence; It is the rutile-type silvery white pearl essence of TZ1202 that said rutile-type silvery white pearl essence is selected model for use.
Wherein rutile-type silvery white pearl essence, anatase titanium dioxide silvery white pearl essence are market product commonly used in the prior art; Different according to the particle grain size scope, comprise particle size range 1-15 μ m, 5-25 μ m, 10-40 μ m, 10-60 μ m, 10-70 μ m, 10-100 μ m, 10-125 μ m,＜product of 15 μ m, 20-80 μ m, 20-100 μ m, 30-70 μ m, 40-200 μ m, 50-500 μ m etc.Pearlescent flake pigments varies in size with its particle, in use shows different effects.Generally speaking, particle is big more, and flicker effect is strong more, and to the covering power of background color more a little less than; Otherwise particle is more little, and strong more to the covering power of background color, gloss is soft more.
The present invention also provides a kind of method for preparing the environment-friendly type textile printing with the pearly-lustre rubber cement, it is characterized in that said pearly-lustre rubber cement prepares through following method:
Regulate after the pH value of environment-friendly type adhesive anatase titanium dioxide silvery white pearl essence, the silvery white pearl essence of rutile-type, ethylene glycol, dispersant, levelling agent, antimildew and antibacterial auxiliary agent; The nano-negative ion far-infrared powder is poured in the adhesive of the good pH value of adjusted; Stir 5min with low speed 1400 commentaries on classics/min earlier; Gap 5min, 2850 commentaries on classics/min add thickener while stirring at a high speed again, stop to add thickener when waiting to meet the requirements of denseness; After continuing high speed 2850 commentaries on classics/min stirring 8/min, confirm that slurry outward appearance light exquisiteness is a finished product.
Another purpose of the present invention be to provide a kind of environment-friendly type textile printing with the pearly-lustre rubber cement in the application aspect hand printing or the machine stamp.
Environment-friendly type textile printing with the preparation of rutile-type, anatase titanium dioxide pearl essence use the pearly-lustre rubber cement, and used pearl essence ratio rutile-type, anatase thpe white powder consumption on year-on-year basis will be lacked about 15%, and breathe freely, glossiness is good.As with rutile-type, anatase titanium dioxide pearl essence and ultrafine kaolin compatibility; Not only hiding rare is excellent, suspension is good, dispersiveness is good, anti-strong acid is good; And distinguishing feature is to compare about 15% with the manufacturing cost of the rubber cement of filling class compatibilities such as environment-friendly type adhesive and titanium white powder with existing market, and the environment-friendly type textile printing can be fit to technology all in the present stamp with the pearly-lustre rubber cement.
The present invention uses the environment-friendly type textile printing to comprise hand printing, machine stamp with the technology that the pearly-lustre rubber cement carries out textile printing; Wherein can carry out stamp with the pearly-lustre rubber cement through independent use environment-friendly type textile printing, generally can pass course 1 (hand printing): screen printing-oven dry or air dry-135 ℃ ± 5 ℃ high temperature 4min ± 1mi of warp bake-finished product or route 2 (plain net machine seal): screen printing-elder generation initially dries-135 ℃ again ± 5 ℃ high temperature 4min ± 1mi through 100 ℃ ± 5 ℃ high temperature 5min ± 1mi and bakes-finished product.
Certainly, environment-friendly type textile printing of the present invention is with pearly-lustre rubber cement and the synchronous stamp of coating combination carrying out; Can adopt route 3 (hand printing): screen printing elder generation seal pigment printing paste prints pearly-lustre rubber cement-oven dry at last or air dry-135 ℃ ± 5 ℃ high temperature 4min ± 1mi of warp bake-finished product.Perhaps pass course 4 (plain net machine seal): screen printing seal pigment printing paste is earlier printed pearly-lustre rubber cement-100 ℃ ± 5 ℃ high temperature 5min ± 1mi of warp of elder generation at last and is initially dried-135 ℃ again ± 5 ℃ high temperature 4min ± 1mi and bake-finished product.
In addition, environment-friendly type textile printing of the present invention can make up with pearly-lustre rubber cement and dyestuff and carry out synchronous stamp; Can adopt route 5 (hand printing): pearly-lustre rubber cement-oven dry or air dry-evaporate-wash-bake-finished product are printed in screen printing earlier printing and dyeing material mill base at last.Perhaps pass course 6 (plain net machine seal): pearly-lustre rubber cement-oven dry or air dry-evaporate-wash-bake-finished product are printed in screen printing printing and dyeing material mill base earlier at last.
The environment-friendly type textile printing is uniquely to use simultaneously as the major ingredient stuffing with pearl essence with the pearly-lustre rubber cement; Only utilize the different particle diameter of pearl essence, through after the reasonable proportioning when not increasing equipment, fund input, both improved hiding rare; Reduce pearl essence again on year-on-year basis and increased gas permeability with 15%; Be standard owing to selecting the operability with various printing technologies at the environment-friendly type adhesive more, therefore, environment-friendly type pearly-lustre rubber cement can be sent out with REACTIVE DYES, ACID DYES, DISPERSE DYES and the synchronous stamp of pigment printing paste; The antimildew and antibacterial additive compatibility is in environment-friendly type pearly-lustre rubber cement; Even make stock under room temperature and moistening environment, also can play the effect of the propagation that suppresses bacterium, mould and acarid, more can not go mouldy, fade and produce peculiar smell.Widened the purposes of environment-friendly type pearly-lustre rubber cement thus greatly.Stamp behind nano-negative ion far-infrared powder and the pearly-lustre rubber cement compatibility; For example can make stock: have unique functional health effect on the mouth mask in bedding, clothes, socks cap and the health treatment, waist support, knee-pad, patch, underwear, the shoe-pad etc., can play the not characteristic done of tool such as the general rubber cement that improves microcirculation in human body, warming, catalytic action, deodorizing, absorption ultraviolet ray.In the real comprehensive quality that has promoted the environment-friendly type rubber cement when widening the scope of undertaking the printing of, selected materials is production domesticization fully absolutely, reduces the dependence to external product, has reduced production cost.
With respect to scheme of the prior art, advantage of the present invention is:
1. the present invention has broken through the straight seal that conventional rubber cement can only be confined to rubber cement itself, and environment-friendly type textile printing of the present invention is suitable for machine seal and hand printing fully with the pearly-lustre rubber cement.And can with REACTIVE DYES, ACID DYES, the synchronous stamp of DISPERSE DYES, under the situation that is not increasing any investment gold, greatly enriched the plane presentation technique of various stamps.
2. the present invention has added antimildew and antibacterial auxiliary agent, nano-negative ion far-infrared powder in the environment-friendly type textile printing with the pearly-lustre rubber cement; Even stock is under room temperature and moistening environment; Also can the effect that the propagation that suppresses bacterium, mould and acarid is arranged; When can not going mouldy, fading and producing peculiar smell.Widened the purposes of environment-friendly type pearly-lustre rubber cement thus greatly.The present invention's nano-negative ion far-infrared powder compatibility in rubber cement uses stamp; For example can make stock: have unique functional health effect on the mouth mask in bedding, clothes, socks cap and the health treatment, waist support, knee-pad, patch, underwear, the shoe-pad etc., can play the not characteristic done of tool such as the general rubber cement that improves microcirculation in human body, warming, catalytic action, deodorizing, absorption ultraviolet ray.In the real comprehensive quality that has promoted the environment-friendly type rubber cement when widening the scope of undertaking the printing of.
3, the environment-friendly type textile printing that obtains of the present invention with the pearly-lustre rubber cement from truly having broken through the bottleneck that conventional printing paste with adhesive and coating, pigment class preparation is prone to the plug net when the stamp; No matter it is the cold platen or the extraordinary manual hot platen of machine seal; Environment-friendly type pearly-lustre rubber cement can not filled in net when wire mark, and good weatherability.And have that environment-protecting asepsis is harmful, high temperature resistant, acid and alkali-resistance, can not spontaneous combustion and the obvious remarkable advantage of difference and common dye, pigment such as combustion-supporting, antioxygenic property.And utilizing the pearl essence particle diameter when increasing hiding rare after the collocation rationally, the titanium white powder and the filler of rule rubber cement commonly used on year-on-year basis reduce about 15%.
The specific embodiment
Below in conjunction with specific embodiment such scheme is further specified.Should be understood that these embodiment are used to the present invention is described and are not limited to limit scope of the present invention.The implementation condition that adopts among the embodiment can be done further adjustment according to the condition of concrete producer, and not marked implementation condition is generally the condition in the normal experiment.
Embodiment 1 manual platen pearly-lustre bonding agent printing technology:
The environment-friendly type textile printing that present embodiment adopts is filled a prescription with the pearly-lustre rubber cement:
After the pH value of adjusting environment-friendly type adhesive anatase titanium dioxide silvery white pearl essence, rutile-type silvery white pearl essence, ethylene glycol, dispersant, levelling agent, antimildew and antibacterial auxiliary agent, nano-negative ion far-infrared powder are poured in the adhesive of the good pH value of adjusted; Stir 5min with low speed 1400 commentaries on classics/min earlier; Gap 5min; 2850 commentaries on classics/min add thickener while stirring at a high speed again, stop to add thickener when waiting to meet the requirements of denseness, after continuation high speed 2850 commentaries on classics/min stir 8/min; Confirm that slurry outward appearance light is fine and smooth, promptly make the rubber cement finished product of present embodiment.
With the printed fabric that 14656 plain crepe-back satins are the basis, use the environment-friendly type textile printing of present embodiment to carry out the wire mark stamp with the pearly-lustre rubber cement, bake through high temperature and be molded into finished product.Concrete steps are following: adopt meshcount: 80 orders, and platen temperature: room temperature, platen pastes silk fabric: water-base resin; Stamp mode: straight seal; Stamp chromatography: single chromatography pearly-lustre rubber cement; Scraper specification: resin angle cutter; Wire mark pass: come and go one time; High temperature bakes; 140 ℃ ± 5 ℃; Bake the time: 4min ± 1min, the machine-clot that falls-finished product.
Embodiment 2 manual platen pearly-lustre rubber cements and the synchronous printing technology of ACID DYES
The environment-friendly type textile printing that present embodiment adopts is filled a prescription with the pearly-lustre rubber cement:
After the pH value of adjusting environment-friendly type adhesive anatase titanium dioxide silvery white pearl essence, rutile-type silvery white pearl essence, ethylene glycol, dispersant, levelling agent, antimildew and antibacterial auxiliary agent, nano-negative ion far-infrared powder are poured in the adhesive of the good pH value of adjusted; Stir 5min with low speed 1400 commentaries on classics/min earlier; Gap 5min; 2850 commentaries on classics/min add thickener while stirring at a high speed again, stop to add thickener when waiting to meet the requirements of denseness, after continuation high speed 2850 commentaries on classics/min stir 8/min; Confirm that slurry outward appearance light is fine and smooth, promptly make the rubber cement finished product of present embodiment.
The printed fabric that is the basis with 65111 tall suedes uses the environment-friendly type textile printing of present embodiment to carry out the wire mark stamp with the pearly-lustre rubber cement with acid mill base combination, through high temperature bake-steam-wash-oven dry, bristle, tentering, typing-finished product step obtain final products.Concrete process conditions are following: meshcount: 100 orders; Platen temperature: 40 ℃ ± 5 ℃; Platen pastes silk fabric: starch slurry resin; Printed fabric: 65111 tall suedes; Thickening agent: ACID DYES; Stamp side's examination: discharge printing; Stamp chromatography: five chromatographys; Chromatography program: print acid mill base earlier, print the pearly-lustre rubber cement at last; Scraper specification: resin angle cutter; Wire mark pass: come and go two times; Initial dry: air dry under the room temperature state; Evaporate the time: 15min ± 1min (steam discharge 5min evaporates 9min); Evaporate temperature: 105 ℃ ± 5 ℃; The washing time: 20min ± 5min; Washing temperature: 40 ℃ ± 5 ℃; Baking swishing sound fixed: i.e. oven dry, bristle, tentering, typing are accomplished synchronously; Pulling temperature: 105 ℃ ± 5 ℃; Synchronous rice number: 1min/5m-8m, the machine-clot that falls-finished product.
Embodiment 3 machines seal plain net pearly-lustre rubber cement and DISPERSE DYES print the technology circuit synchronously
The environment-friendly type textile printing that present embodiment adopts is filled a prescription with the pearly-lustre rubber cement:
After the pH value of adjusting environment-friendly type adhesive anatase titanium dioxide silvery white pearl essence, rutile-type silvery white pearl essence, ethylene glycol, dispersant, levelling agent, antimildew and antibacterial auxiliary agent, nano-negative ion far-infrared powder are poured in the adhesive of the good pH value of adjusted; Stir 5min with low speed 1400 commentaries on classics/min earlier; Gap 5min; 2850 commentaries on classics/min add thickener while stirring at a high speed again, stop to add thickener when waiting to meet the requirements of denseness, after continuation high speed 2850 commentaries on classics/min stir 8/min; Confirm that slurry outward appearance light is fine and smooth, promptly make the rubber cement finished product of present embodiment.
Wash the printed fabric that the twill peach face is the basis to refine white brocade, use the environment-friendly type textile printing of present embodiment to carry out the wire mark stamp with the pearly-lustre rubber cement, through high temperature bake-steam-wash-oven dry, bristle, tentering, typing-finished product step obtain final products.Concrete process conditions are following: meshcount: 100 orders; Platen temperature: room temperature; Platen pastes silk fabric: the oleoresin starching; Printed fabric: refine white brocade and wash the twill peach face; Thickening agent: DISPERSE DYES; Stamp side's examination: straight seal; Stamp chromatography: three chromatographys; Chromatography program: print acid mill base earlier, print the pearly-lustre rubber cement at last; Scraper specification: rubber flat blade; Scraper angle: fixing; Scrape pass: one floating one scrapes; Wire mark speed: 1min/5m-8m; Initially bake: 120 ℃ ± 5 ℃; Evaporate the time: 7min ± 1min; Evaporate temperature: 178 ℃ ± 5 ℃; The washing time: 20min ± 5min; Washing temperature: 40 ℃ ± 5 ℃; Drying and shaping: accomplish synchronously; Pulling temperature: 170 ℃ ± 10 ℃, the machine-clot that falls-finished product.
The product quality of embodiment 4 environment-friendly type textile printings after with the pearly-lustre bonding agent printing investigated
The environment-friendly type textile printing that embodiment 1～3 is obtained is with pearly-lustre bonding agent printing product; Detect testing result through national silk and dress-goods quality supervision and test center by national standard " GB/T420-2009 textile color stability test pigment dyeing textile article scrubbing-resistant color fastness ": scrubbing-resistant color fastness is 4 grades (annotating: scrub number of times 100 times).
Above-mentioned instance only is explanation technical conceive of the present invention and characteristics, and its purpose is to let the people who is familiar with this technology can understand content of the present invention and enforcement according to this, can not limit protection scope of the present invention with this.All equivalent transformations that spirit is done according to the present invention or modification all should be encompassed within protection scope of the present invention.
Claims (9)
1. an environment-friendly type textile printing is used the pearly-lustre rubber cement, it is characterized in that said rubber cement counts with the percentage by weight of its component: the ultra soft adhesive 49-39% of environment-friendly type; Particle size range is at the rutile-type silvery white pearl essence 15-25% of 5-25 μ m; Particle size range is at the anatase titanium dioxide silvery white pearl essence 25-15% of 10-60 μ m; Ethylene glycol 4-6%; Dispersant 1-2%; Levelling agent 1-3%; Antimildew and antibacterial auxiliary agent 1-2%; Nano-negative ion far-infrared powder 2-4%; Thickener 2-4%.
2. environment-friendly type textile printing according to claim 1 is used the pearly-lustre rubber cement, it is characterized in that the ultra soft adhesive of said environment-friendly type selects acrylic adhesives T-608 for use.
3. environment-friendly type textile printing according to claim 1 is used the pearly-lustre rubber cement, it is characterized in that said dispersant selects for use anionic species to contain the polymer of hydrophilic radical, and the market model of the wetting dispersing agent of this water-based system is WinSperse 4010.
4. environment-friendly type textile printing according to claim 1 is used the pearly-lustre rubber cement, it is characterized in that said levelling agent selects polyether-modified polysiloxanes leather coating levelling agent for use, and the market model is LY-3308.
5. environment-friendly type textile printing according to claim 1 is used the pearly-lustre rubber cement, it is characterized in that said thickener selects SH201 for use.
6. environment-friendly type textile printing according to claim 1 is used the pearly-lustre rubber cement, it is characterized in that said antimildew and antibacterial auxiliary agent is to select antimildew and antibacterial auxiliary agent SCJ-998 for use.
7. environment-friendly type textile printing according to claim 1 is used the pearly-lustre rubber cement, it is characterized in that it is the anatase titanium dioxide silvery white pearl essence of TZ1004 that said anatase titanium dioxide silvery white pearl essence is selected model for use; It is the rutile-type silvery white pearl essence of TZ1202 that said rutile-type silvery white pearl essence is selected model for use.
8. method for preparing the described environment-friendly type textile printing of claim 1 with the pearly-lustre rubber cement is characterized in that said pearly-lustre rubber cement prepares through following method:
After the pH value of adjusting environment-friendly type adhesive anatase titanium dioxide silvery white pearl essence, rutile-type silvery white pearl essence, ethylene glycol, dispersant, levelling agent, antimildew and antibacterial auxiliary agent, nano-negative ion far-infrared powder are poured in the adhesive of the good pH value of adjusted; Stir 5min with low speed 1400 commentaries on classics/min earlier; Gap 5min; 2850 commentaries on classics/min add thickener while stirring at a high speed again; Stop to add thickener when waiting to meet the requirements of denseness, after continuation high speed 2850 commentaries on classics/min stir 8min, confirm that slurry outward appearance light exquisiteness is a finished product.
The described environment-friendly type textile printing of claim 1 with the pearly-lustre rubber cement in the application aspect hand printing or the machine stamp.
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| CN102677486B (en) * | 2012-03-30 | 2014-01-15 | 四川省纺织科学研究院 | Formaldehyde-free pigment printing covering white slurry, preparation method and application thereof |
| CN103938444B (en) * | 2014-04-22 | 2016-04-27 | 刘曜彰 | The antibacterial glue of a kind of anion |
| CN104120608A (en) * | 2014-07-29 | 2014-10-29 | 湖州诚鑫纺织印染有限公司 | Coatings for rotary screen printing |
| CN104404790A (en) * | 2014-12-15 | 2015-03-11 | 蒋瑾 | Difficult-to-fade dye formula |
| CN104805718A (en) * | 2015-04-30 | 2015-07-29 | 王东 | Microcirculation heating printing process |
| CN104846662B (en) * | 2015-05-21 | 2017-01-11 | 辽宁华福实业股份有限公司 | Multi-set color pearl powder printing technology for printing and dyeing decorative fabrics |
| CN106638043B (en) * | 2016-12-30 | 2019-08-16 | 广州市盛勤实业有限公司 | A kind of reflective slurry of water-based system and its application in sportswear fabric |
| CN107503193B (en) * | 2017-08-21 | 2020-08-07 | 东莞市钟亿阻燃粘胶实业有限公司 | Penetrating agent, glitter paste containing penetrating agent, and preparation method and application of glitter paste |
| CN108532331A (en) * | 2018-05-07 | 2018-09-14 | 刘焕新 | One kind is containing lanthanum weaving pearly-lustre rubber cement and preparation method thereof |
| CN110846907A (en) * | 2019-11-27 | 2020-02-28 | 山东黄河三角洲纺织科技研究院有限公司 | High-brightness and high-fastness silver powder printing paste and printing process |
| CN114703684A (en) * | 2022-04-12 | 2022-07-05 | 绍兴市柯桥区信和数码纺织技术有限公司 | Printing process of ultrathin fabric |
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