CN103666064B - A kind of ultraviolet light polymerization quick-dry waterproof ink and preparation method thereof - Google Patents
A kind of ultraviolet light polymerization quick-dry waterproof ink and preparation method thereof Download PDFInfo
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- CN103666064B CN103666064B CN201310602008.0A CN201310602008A CN103666064B CN 103666064 B CN103666064 B CN 103666064B CN 201310602008 A CN201310602008 A CN 201310602008A CN 103666064 B CN103666064 B CN 103666064B
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- ink
- ultraviolet light
- light polymerization
- hydroxyl
- phenyl ketone
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- 238000006116 polymerization reaction Methods 0.000 title claims abstract description 13
- 238000002360 preparation method Methods 0.000 title claims description 8
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims abstract description 21
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 21
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 9
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 8
- HVLLSGMXQDNUAL-UHFFFAOYSA-N triphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)OC1=CC=CC=C1 HVLLSGMXQDNUAL-UHFFFAOYSA-N 0.000 claims abstract description 8
- JHPBZFOKBAGZBL-UHFFFAOYSA-N (3-hydroxy-2,2,4-trimethylpentyl) 2-methylprop-2-enoate Chemical compound CC(C)C(O)C(C)(C)COC(=O)C(C)=C JHPBZFOKBAGZBL-UHFFFAOYSA-N 0.000 claims abstract description 7
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims abstract description 7
- 239000004115 Sodium Silicate Substances 0.000 claims abstract description 7
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 claims abstract description 7
- 239000000975 dye Substances 0.000 claims abstract description 7
- 239000000049 pigment Substances 0.000 claims abstract description 7
- 229920000728 polyester Polymers 0.000 claims abstract description 7
- -1 polysiloxane Polymers 0.000 claims abstract description 7
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 7
- 239000002994 raw material Substances 0.000 claims abstract description 7
- 229910052911 sodium silicate Inorganic materials 0.000 claims abstract description 7
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 claims abstract description 4
- DAKWPKUUDNSNPN-UHFFFAOYSA-N Trimethylolpropane triacrylate Chemical compound C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 claims abstract description 4
- 238000003756 stirring Methods 0.000 claims description 15
- 238000006243 chemical reaction Methods 0.000 claims description 10
- 239000012467 final product Substances 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- 239000000843 powder Substances 0.000 claims description 6
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 4
- KDVYCTOWXSLNNI-UHFFFAOYSA-N 4-t-Butylbenzoic acid Chemical compound CC(C)(C)C1=CC=C(C(O)=O)C=C1 KDVYCTOWXSLNNI-UHFFFAOYSA-N 0.000 claims description 3
- 244000077995 Coix lacryma jobi Species 0.000 claims description 3
- 229920002367 Polyisobutene Polymers 0.000 claims description 3
- ZTHYODDOHIVTJV-UHFFFAOYSA-N Propyl gallate Chemical compound CCCOC(=O)C1=CC(O)=C(O)C(O)=C1 ZTHYODDOHIVTJV-UHFFFAOYSA-N 0.000 claims description 3
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 3
- APZPSKFMSWZPKL-UHFFFAOYSA-N [3-hydroxy-2,2-bis(hydroxymethyl)propyl] 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC(CO)(CO)CO APZPSKFMSWZPKL-UHFFFAOYSA-N 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 238000000227 grinding Methods 0.000 claims description 3
- 239000000463 material Substances 0.000 claims description 3
- 239000010445 mica Substances 0.000 claims description 3
- 229910052618 mica group Inorganic materials 0.000 claims description 3
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 claims description 3
- 239000002002 slurry Substances 0.000 claims description 3
- 235000015112 vegetable and seed oil Nutrition 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 2
- KOMNUTZXSVSERR-UHFFFAOYSA-N 1,3,5-tris(prop-2-enyl)-1,3,5-triazinane-2,4,6-trione Chemical compound C=CCN1C(=O)N(CC=C)C(=O)N(CC=C)C1=O KOMNUTZXSVSERR-UHFFFAOYSA-N 0.000 abstract 1
- 239000002904 solvent Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 240000001624 Espostoa lanata Species 0.000 description 2
- 235000009161 Espostoa lanata Nutrition 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000002932 luster Substances 0.000 description 2
- 101000831616 Homo sapiens Protachykinin-1 Proteins 0.000 description 1
- 240000008415 Lactuca sativa Species 0.000 description 1
- 206010034972 Photosensitivity reaction Diseases 0.000 description 1
- 102100024304 Protachykinin-1 Human genes 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000001723 curing Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 238000000016 photochemical curing Methods 0.000 description 1
- 230000036211 photosensitivity Effects 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 235000012045 salad Nutrition 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 238000002211 ultraviolet spectrum Methods 0.000 description 1
Landscapes
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention discloses a kind of ultraviolet light polymerization quick-dry waterproof ink, it is characterized in that, be made up of the raw material of following weight part: pigment dyestuff 1-3, glycerol 5-9, Tai-Ace S 150 3-4, sodium silicate 1-2, methacrylic ester 20-25, ethyl acetate 10-14, sulfydryl polysiloxane 3-4, polyester acrylate 45-50,1-hydroxyl-ring base in the sixth of the twelve Earthly Branches phenyl ketone 5-8, Viscoat 295 10-12,2-Hydroxy ethyl acrylate 6-9, triphenyl phosphite 3-4, linking agent TAIC? 1-2, auxiliary agent 4-5; Auxiliary agent of the present invention improves the toughness of ink, makes distributes ink even, and maintains the stability of ink; Ink of the present invention has good sticking power, not easy to crack, comes off, and water resistance is good, and curing speed is fast, energy-conserving and environment-protective.
Description
Technical field
The present invention relates to a kind of ink and preparation method thereof, particularly a kind of ultraviolet light polymerization quick-dry waterproof ink and preparation method thereof.
Background technology
Ultraviolet light polymerization (UV) ink refers under uviolizing, utilizes the UV-light of different wave length and energy to make ink film forming and dry ink.Utilize different UV spectrum, can different-energy be produced, the monomer polymerization in different ink vehicle is become polymkeric substance, so the look film of UV ink has good machinery and chemical property.The major advantage of UV ink has: (1) is without solvent; (2) rate of drying is fast, and power consumption is few; (3) good luster, bright in luster; (4) water-fast, solvent resistant, wear resisting property is good.In UV ink, light trigger is that one is subject to light activated compound, after absorb light is shone, be excited into free radical, and energy trasfer, to photosensitivity molecule or photocrosslinking agent, makes UV ink that photocuring reaction occur.Current UV ink has become a kind of more ripe ink technology, and its pollutant emission is almost nil.Except not containing solvent, UV ink also just like not easily scumming, the advantages such as site is clear, the bright-coloured light of mass colour, and chemical resistance is excellent, low-consuming.
Summary of the invention
The object of this invention is to provide a kind of ultraviolet light polymerization quick-dry waterproof ink and preparation method thereof.
In order to realize object of the present invention, the present invention is by following scheme implementation:
A kind of ultraviolet light polymerization quick-dry waterproof ink, is made up of the raw material of following weight part: pigment dyestuff 1-3, glycerol 5-9, Tai-Ace S 150 3-4, sodium silicate 1-2, methacrylic ester 20-25, ethyl acetate 10-14, sulfydryl polysiloxane 3-4, polyester acrylate 45-50,1-hydroxyl-ring base in the sixth of the twelve Earthly Branches phenyl ketone 5-8, Viscoat 295 10-12,2-Hydroxy ethyl acrylate 6-9, triphenyl phosphite 3-4, linking agent TAIC1-2, auxiliary agent 4-5;
Described auxiliary agent is prepared from by the raw material of following weight part: nano diatomite powder 0.2-0.3, nano mica powder 0.2-0.3, double pentaerythritol methacrylate 10-12, neopentyl glycol 5-7, p-tert-butyl benzoic acid 1-2, linking agent TAC2-3, polyisobutene 2-3, silane coupling agent KH5601-2, Tenox PG 2-3, coix seed oil 1-2; Its preparation method is by each mixing of materials, is heated to 60-70 DEG C, and stirring reaction 30-40 minute, to obtain final product.
Ultraviolet light polymerization quick-dry waterproof ink of the present invention, be made up of following concrete steps: first add pigment dyestuff, glycerol, Tai-Ace S 150, sodium silicate, methacrylic ester, ethyl acetate, sulfydryl polysiloxane, polyester acrylate stirring and evenly mixing, be heated to 80-90 DEG C, stir 25-35 minute; Then all the other remaining components except 1-hydroxyl-ring base in the sixth of the twelve Earthly Branches phenyl ketone are added, stirring reaction 3-5 hour; Finally be cooled to 60-70 DEG C, add 1-hydroxyl-ring base in the sixth of the twelve Earthly Branches phenyl ketone, stirring reaction 40-50 minute, after cooling, grinding obtains 20-40 μm of slurry, to obtain final product.
The invention has the beneficial effects as follows: auxiliary agent of the present invention improves the toughness of ink, make distributes ink even, and maintain the stability of ink; Ink of the present invention has good sticking power, not easy to crack, comes off, and water resistance is good, and curing speed is fast, energy-conserving and environment-protective.
Specific embodiments
Below by specific examples, the present invention is described in detail.
A kind of ultraviolet light polymerization quick-dry waterproof ink, is made up of the raw material of following weight part (kilogram): pigment dyestuff 1, glycerol 5, Tai-Ace S 150 3, sodium silicate 1, methacrylic ester 20, ethyl acetate 10, sulfydryl polysiloxane 3, polyester acrylate 45,1-hydroxyl-ring base in the sixth of the twelve Earthly Branches phenyl ketone 5, Viscoat 295 10,2-Hydroxy ethyl acrylate 6, triphenyl phosphite 3, linking agent TAIC1, auxiliary agent 4;
Described auxiliary agent is prepared from by the raw material of following weight part (kilogram): nano diatomite powder 0.2, nano mica powder 0.2, double pentaerythritol methacrylate 10, neopentyl glycol 5, p-tert-butyl benzoic acid 1, linking agent TAC2, polyisobutene 2, silane coupling agent KH5601, Tenox PG 2, coix seed oil 1; Its preparation method is by each mixing of materials, is heated to 60-70 DEG C, and stirring reaction 30-40 minute, to obtain final product.
Ultraviolet light polymerization quick-dry waterproof ink of the present invention, be made up of following concrete steps: first add pigment dyestuff, glycerol, Tai-Ace S 150, sodium silicate, methacrylic ester, ethyl acetate, sulfydryl polysiloxane, polyester acrylate stirring and evenly mixing, be heated to 80-90 DEG C, stir 25-35 minute; Then all the other remaining components except 1-hydroxyl-ring base in the sixth of the twelve Earthly Branches phenyl ketone are added, stirring reaction 3-5 hour; Finally be cooled to 60-70 DEG C, add 1-hydroxyl-ring base in the sixth of the twelve Earthly Branches phenyl ketone, stirring reaction 40-50 minute, after cooling, grinding obtains 20-40 μm of slurry, to obtain final product.
The ink of gained, uses cross-hatching ox-hide tape stripping, draws compartment apart from 1mm, 100% attachment; Use the spirituous cotton balls of leaching, 300 grams of pressure wipings 50 times, are as good as shape; To be soaked in salad oil (normal temperature) 8 hours, to be as good as shape; Use and be soaked with the cotton balls of salt solution, 300 grams of pressure wipings 50 times, are as good as shape.
Claims (2)
1. a ultraviolet light polymerization quick-dry waterproof ink, it is characterized in that, be prepared from by the raw material of following weight part: pigment dyestuff 1-3, glycerol 5-9, Tai-Ace S 150 3-4, sodium silicate 1-2, methacrylic ester 20-25, ethyl acetate 10-14, sulfydryl polysiloxane 3-4, polyester acrylate 45-50,1-hydroxyl-ring base in the sixth of the twelve Earthly Branches phenyl ketone 5-8, Viscoat 295 10-12,2-Hydroxy ethyl acrylate 6-9, triphenyl phosphite 3-4, linking agent TAIC1-2, auxiliary agent 4-5;
Described auxiliary agent is prepared from by the raw material of following weight part: nano diatomite powder 0.2-0.3, nano mica powder 0.2-0.3, double pentaerythritol methacrylate 10-12, neopentyl glycol 5-7, p-tert-butyl benzoic acid 1-2, linking agent TAC2-3, polyisobutene 2-3, silane coupling agent KH5601-2, Tenox PG 2-3, coix seed oil 1-2; Its preparation method is by each mixing of materials, is heated to 60-70 DEG C, and stirring reaction 30-40 minute, to obtain final product.
2. ultraviolet light polymerization quick-dry waterproof ink according to claim 1, it is characterized in that, be made up of following concrete steps: first add pigment dyestuff, glycerol, Tai-Ace S 150, sodium silicate, methacrylic ester, ethyl acetate, sulfydryl polysiloxane, polyester acrylate stirring and evenly mixing, be heated to 80-90 DEG C, stir 25-35 minute; Then all the other remaining components except 1-hydroxyl-ring base in the sixth of the twelve Earthly Branches phenyl ketone are added, stirring reaction 3-5 hour; Finally be cooled to 60-70 DEG C, add 1-hydroxyl-ring base in the sixth of the twelve Earthly Branches phenyl ketone, stirring reaction 40-50 minute, after cooling, grinding obtains 20-40 μm of slurry, to obtain final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310602008.0A CN103666064B (en) | 2013-11-25 | 2013-11-25 | A kind of ultraviolet light polymerization quick-dry waterproof ink and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310602008.0A CN103666064B (en) | 2013-11-25 | 2013-11-25 | A kind of ultraviolet light polymerization quick-dry waterproof ink and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103666064A CN103666064A (en) | 2014-03-26 |
| CN103666064B true CN103666064B (en) | 2016-03-23 |
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| CN201310602008.0A Active CN103666064B (en) | 2013-11-25 | 2013-11-25 | A kind of ultraviolet light polymerization quick-dry waterproof ink and preparation method thereof |
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Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106084998A (en) * | 2016-08-10 | 2016-11-09 | 苏州中亚油墨有限公司 | White waterproof ink |
| KR20190043530A (en) * | 2016-08-22 | 2019-04-26 | 가부시키가이샤 오사카소다 | Photocurable resin composition, ink and paint |
| US12071544B2 (en) * | 2019-02-18 | 2024-08-27 | Solventum Intellectual Properties Company | Radiation-curable composition containing mercapto-functional polyorganosiloxanes for additive-manufacturing technology |
| CN111607098B (en) * | 2020-05-22 | 2022-02-22 | 东莞德芳油墨科技有限公司 | Multi-component UV-LED photocuring screen printing ink for glass substrate and preparation method thereof |
| CN119931408A (en) * | 2024-12-17 | 2025-05-06 | 江门市健鼎包装有限公司 | A kind of UV waterproof ink and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1970656A (en) * | 2006-11-23 | 2007-05-30 | 北京印刷学院 | Thermoforming plastic printing ink adopting ultraviolet-infra red drying technology |
| CN103342921A (en) * | 2013-07-29 | 2013-10-09 | 中国科学院化学研究所 | Ink with high hiding rate for ink-jet printing and application thereof to preparation of flexible plate |
-
2013
- 2013-11-25 CN CN201310602008.0A patent/CN103666064B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1970656A (en) * | 2006-11-23 | 2007-05-30 | 北京印刷学院 | Thermoforming plastic printing ink adopting ultraviolet-infra red drying technology |
| CN103342921A (en) * | 2013-07-29 | 2013-10-09 | 中国科学院化学研究所 | Ink with high hiding rate for ink-jet printing and application thereof to preparation of flexible plate |
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| Publication number | Publication date |
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| CN103666064A (en) | 2014-03-26 |
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