CN103555059A - Gravure printing ink for plastic thin film and preparation method for gravure printing ink - Google Patents
Gravure printing ink for plastic thin film and preparation method for gravure printing ink Download PDFInfo
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- CN103555059A CN103555059A CN201310523519.3A CN201310523519A CN103555059A CN 103555059 A CN103555059 A CN 103555059A CN 201310523519 A CN201310523519 A CN 201310523519A CN 103555059 A CN103555059 A CN 103555059A
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Abstract
The invention discloses gravure printing ink for a plastic thin film. The gravure printing ink is prepared from the following raw materials in parts by weight: 12 to 15 parts of polyethylene glycol monooleate, 2 to 4 parts of phthalocyanine blue, 5 to 9 parts of isopropyl alcohol, 5 to 9 parts of butyl acetate, 1 to 2 parts of 2,6,4-tri-tert-butylphenol, 1 to 2 parts of barium stearate, 4 to 5 parts of white oil, 3 to 5 parts of isocyanate, 2 to 6 parts of hexabromocyclododecane, 3 to 4 parts of diethylene glycol butyl ether, 4 to 5 parts of eimethoxy-2-phenylacetophenone, 8 to 10 parts of sodium hexametaphosphate, 3 to 4 parts of butyl methacrylate, 14 to 16 parts of 1,6-hexanediol diacrylate, 3 to 4 parts of organic pigment and 4 to 5 parts of auxiliaries. The printing ink has high adhesion force on the plastic thin film, has the characteristics of oil resistance, water resistance, softness, no stickiness and high fastness, has a good flame-retardant effect, and is high in safety coefficient; plastic thin films can be prevented from being adhered to each other; a preparation method is simple and easy to control.
Description
Technical field
The invention belongs to printing ink paint field, relate in particular to a kind of plastics film base gravure ink and preparation method thereof.
Background technology
The color of ink (form and aspect), body bone (rheological property such as rare thick, degree of mobilization) and drying property are three most important performances of ink.Their kind is a lot, and physical properties is also different, and what have is very thick, very sticky; And have quite rare.What have makes low-melting ink vehicle with vegetables oil; Somely with resin and solvent or water etc., make low-melting ink vehicle.These are to be all that the type of stock, printing process, printing plate and drying means etc. decide according to the object of printing.
The rate of drying of ink, thixotropy, skeleton property have tremendous influence to production efficiency, quality product, and the composition of ink is influential to human body, how to study as far as possible little to harm, production efficiency is high, environmental friendliness, ink that cost is low have profound significance.
Summary of the invention
The object of the present invention is to provide a kind of plastics film base gravure ink and preparation method thereof, this ink is to plastics film strong adhesion, fire-retardant.
Technical scheme of the present invention is as follows:
A kind of plastics film base gravure ink, it is characterized in that being made by the raw material of following weight part: polyethylene glycol monooleate 12-15, phthalocyanine blue 2-4, Virahol 5-9, N-BUTYL ACETATE 5-9,2,6,4-tri-butyl-phenol 1-2, barium stearate 1-2, white oil 4-5, isocyanic ester 3-5, hexabromocyclododecane 2-6, Diethylene Glycol butyl ether 3-4, benzoin dimethylether 4-5, Sodium hexametaphosphate 99 8-10, butyl methacrylate 3-4,1,6 hexanediyl ester 14-16, pigment dyestuff 3-4, auxiliary agent 4-5;
Described auxiliary agent is made by the raw material of following weight part: Silane coupling reagent KH-570 2-3, tri (propylene glycol) diacrylate 2-3, methacrylic acid-2-hydroxy methacrylate 2-3, tea-polyphenol 2-3, glyceryl monostearate 4-5, p-tert-butyl benzoic acid 1-2, oxidation inhibitor 1035 1-2, ricinolic acid 1-2, linking agent TAC1-2, ethanol 20-24; Preparation method mixes Silane coupling reagent KH-570, ricinolic acid, ethanol, is heated to 60-70 ℃, stirs after 20-30 minute, then adds other remaining component, is warming up to 80-85 ℃, stirs 30-40 minutes, obtains.
The preparation method of described plastics film base gravure ink, it is characterized in that comprising the following steps: by polyethylene glycol monooleate, Virahol, N-BUTYL ACETATE, 2, 6, 4-tri-butyl-phenol, barium stearate, isocyanic ester, Diethylene Glycol butyl ether, Sodium hexametaphosphate 99 mixes, under 1000-1400 rev/min of stirring, speed with 5-8 ℃/minute is heated to 60-80 ℃, add benzoin dimethylether, , stirring reaction 10-20 minute, add white oil, butyl methacrylate, 1, 6 hexanediyl esters, continue stirring reaction 20-30 minute, add other remaining components, continue stirring reaction 1.5-2 hour, grinding distribution becomes the slurry of 20-40 μ m, obtain.
Beneficial effect of the present invention
Ink of the present invention has very high sticking power on plastics film, has oil resistant, the feature that water-fast, softness is not clamminess, fastness is good, can also prevent from adhering to each other between plastics film, and good flame retardation effect, safety coefficient is high; Its preparation method is simple, easily controls.Auxiliary agent of the present invention can form protective membrane in ink pellet surface, isolated air, and the surface that prevents water and other molecules corrosion ink and spraying object in atmosphere, anti-oxidant, make color bright-coloured lastingly, and improve slickness, wear resistance, extend working time.
Embodiment
A kind of plastics film base gravure ink, by following weight part (kilogram) raw material make: polyethylene glycol monooleate 13, phthalocyanine blue 3, Virahol 7, N-BUTYL ACETATE 7,2,6,4-tri-butyl-phenol 1.6, barium stearate 1.5, white oil 4.5, isocyanic ester 4, hexabromocyclododecane 4, Diethylene Glycol butyl ether 3.4, benzoin dimethylether 4.5, Sodium hexametaphosphate 99 9, butyl methacrylate 3.5,1,6 hexanediyl ester 15, pigment dyestuff 3.5, auxiliary agent 4.5;
Described auxiliary agent by following weight part (kilogram) raw material make: Silane coupling reagent KH-570 2.5, tri (propylene glycol) diacrylate 2.5, methacrylic acid-2-hydroxy methacrylate 2.5, tea-polyphenol 2.5, glyceryl monostearate 4.6, p-tert-butyl benzoic acid 1.4, oxidation inhibitor 1,035 1.5, ricinolic acid 1.5, linking agent TAC1.4, ethanol 23; Preparation method mixes Silane coupling reagent KH-570, ricinolic acid, ethanol, is heated to 65 ℃, stirs after 26 minutes, then adds other remaining component, is warming up to 84 ℃, stirs 38 minutes, obtains.
The preparation method of described plastics film base gravure ink, comprise the following steps: by polyethylene glycol monooleate, Virahol, N-BUTYL ACETATE, 2, 6, 4-tri-butyl-phenol, barium stearate, isocyanic ester, Diethylene Glycol butyl ether, Sodium hexametaphosphate 99 mixes, under 1300 revs/min of stirrings, with the speed of 6 ℃/minute, be heated to 70 ℃, add benzoin dimethylether, , stirring reaction 15 minutes, add white oil, butyl methacrylate, 1, 6 hexanediyl esters, continue stirring reaction 25 minutes, add other remaining components, continue stirring reaction 1.8 hours, grinding distribution becomes the slurry of 30 μ m, obtain.
Ink quality homogeneous of the present invention, tinting strength, adhere firmly degree, viscosity, first dryness and other performances have reached the requirement of QB/T2024-94 standard.
Claims (2)
1. a plastics film base gravure ink, it is characterized in that being made by the raw material of following weight part: polyethylene glycol monooleate 12-15, phthalocyanine blue 2-4, Virahol 5-9, N-BUTYL ACETATE 5-9,2,6,4-tri-butyl-phenol 1-2, barium stearate 1-2, white oil 4-5, isocyanic ester 3-5, hexabromocyclododecane 2-6, Diethylene Glycol butyl ether 3-4, benzoin dimethylether 4-5, Sodium hexametaphosphate 99 8-10, butyl methacrylate 3-4,1,6 hexanediyl ester 14-16, pigment dyestuff 3-4, auxiliary agent 4-5;
Described auxiliary agent is made by the raw material of following weight part: Silane coupling reagent KH-570 2-3, tri (propylene glycol) diacrylate 2-3, methacrylic acid-2-hydroxy methacrylate 2-3, tea-polyphenol 2-3, glyceryl monostearate 4-5, p-tert-butyl benzoic acid 1-2, oxidation inhibitor 1035 1-2, ricinolic acid 1-2, linking agent TAC1-2, ethanol 20-24; Preparation method mixes Silane coupling reagent KH-570, ricinolic acid, ethanol, is heated to 60-70 ℃, stirs after 20-30 minute, then adds other remaining component, is warming up to 80-85 ℃, stirs 30-40 minutes, obtains.
2. the preparation method of plastics film base gravure ink according to claim 1, it is characterized in that comprising the following steps: by polyethylene glycol monooleate, Virahol, N-BUTYL ACETATE, 2, 6, 4-tri-butyl-phenol, barium stearate, isocyanic ester, Diethylene Glycol butyl ether, Sodium hexametaphosphate 99 mixes, under 1000-1400 rev/min of stirring, speed with 5-8 ℃/minute is heated to 60-80 ℃, add benzoin dimethylether, , stirring reaction 10-20 minute, add white oil, butyl methacrylate, 1, 6 hexanediyl esters, continue stirring reaction 20-30 minute, add other remaining components, continue stirring reaction 1.5-2 hour, grinding distribution becomes the slurry of 20-40 μ m, obtain.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310523519.3A CN103555059A (en) | 2013-10-30 | 2013-10-30 | Gravure printing ink for plastic thin film and preparation method for gravure printing ink |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310523519.3A CN103555059A (en) | 2013-10-30 | 2013-10-30 | Gravure printing ink for plastic thin film and preparation method for gravure printing ink |
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| CN103555059A true CN103555059A (en) | 2014-02-05 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201310523519.3A Pending CN103555059A (en) | 2013-10-30 | 2013-10-30 | Gravure printing ink for plastic thin film and preparation method for gravure printing ink |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103865330A (en) * | 2014-02-27 | 2014-06-18 | 安徽颍美彩印包装有限公司 | Rosin gravure printing ink for glass paper and preparation method thereof |
| CN103865321A (en) * | 2014-02-27 | 2014-06-18 | 安徽颍美彩印包装有限公司 | Water-based flexographic printing ink and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101921374A (en) * | 2009-06-12 | 2010-12-22 | 成都市新津托展油墨有限公司 | Preparation method of polyacrylate-polyurethane resin binder for single-fluid general plastic gravure alcohol-soluble and water-soluble composite ink |
| CN103319943A (en) * | 2013-06-05 | 2013-09-25 | 苏州凹凸彩印厂 | Plastic film intaglio ink and preparation method thereof |
-
2013
- 2013-10-30 CN CN201310523519.3A patent/CN103555059A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101921374A (en) * | 2009-06-12 | 2010-12-22 | 成都市新津托展油墨有限公司 | Preparation method of polyacrylate-polyurethane resin binder for single-fluid general plastic gravure alcohol-soluble and water-soluble composite ink |
| CN103319943A (en) * | 2013-06-05 | 2013-09-25 | 苏州凹凸彩印厂 | Plastic film intaglio ink and preparation method thereof |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103865330A (en) * | 2014-02-27 | 2014-06-18 | 安徽颍美彩印包装有限公司 | Rosin gravure printing ink for glass paper and preparation method thereof |
| CN103865321A (en) * | 2014-02-27 | 2014-06-18 | 安徽颍美彩印包装有限公司 | Water-based flexographic printing ink and preparation method thereof |
| CN103865330B (en) * | 2014-02-27 | 2016-04-13 | 安徽颍美彩印包装有限公司 | A kind of glassine paper rosin base gravure ink and preparation method thereof |
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Application publication date: 20140205 |