CN103666085A - High-fastness fast-curing printing ink and preparation method thereof - Google Patents
High-fastness fast-curing printing ink and preparation method thereof Download PDFInfo
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- CN103666085A CN103666085A CN201310574942.6A CN201310574942A CN103666085A CN 103666085 A CN103666085 A CN 103666085A CN 201310574942 A CN201310574942 A CN 201310574942A CN 103666085 A CN103666085 A CN 103666085A
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- 238000007639 printing Methods 0.000 title claims abstract description 17
- 238000002360 preparation method Methods 0.000 title claims abstract description 12
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 26
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000003822 epoxy resin Substances 0.000 claims abstract description 7
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 7
- KCTAWXVAICEBSD-UHFFFAOYSA-N prop-2-enoyloxy prop-2-eneperoxoate Chemical compound C=CC(=O)OOOC(=O)C=C KCTAWXVAICEBSD-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000002994 raw material Substances 0.000 claims abstract description 7
- 239000000779 smoke Substances 0.000 claims abstract description 7
- 229920006337 unsaturated polyester resin Polymers 0.000 claims abstract description 7
- 239000003610 charcoal Substances 0.000 claims abstract description 6
- 239000000843 powder Substances 0.000 claims abstract description 6
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims abstract description 4
- 239000000347 magnesium hydroxide Substances 0.000 claims abstract description 4
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims abstract description 4
- 230000003647 oxidation Effects 0.000 claims abstract description 4
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 4
- 238000003756 stirring Methods 0.000 claims description 15
- 239000012752 auxiliary agent Substances 0.000 claims description 7
- XDLMVUHYZWKMMD-UHFFFAOYSA-N 3-trimethoxysilylpropyl 2-methylprop-2-enoate Chemical compound CO[Si](OC)(OC)CCCOC(=O)C(C)=C XDLMVUHYZWKMMD-UHFFFAOYSA-N 0.000 claims description 6
- XZMCDFZZKTWFGF-UHFFFAOYSA-N Cyanamide Chemical compound NC#N XZMCDFZZKTWFGF-UHFFFAOYSA-N 0.000 claims description 6
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 6
- 238000006243 chemical reaction Methods 0.000 claims description 6
- 239000003153 chemical reaction reagent Substances 0.000 claims description 6
- 230000008878 coupling Effects 0.000 claims description 6
- 238000010168 coupling process Methods 0.000 claims description 6
- 238000005859 coupling reaction Methods 0.000 claims description 6
- 238000005502 peroxidation Methods 0.000 claims description 6
- WBHHMMIMDMUBKC-QJWNTBNXSA-N ricinoleic acid Chemical compound CCCCCC[C@@H](O)C\C=C/CCCCCCCC(O)=O WBHHMMIMDMUBKC-QJWNTBNXSA-N 0.000 claims description 6
- 229960003656 ricinoleic acid Drugs 0.000 claims description 6
- FEUQNCSVHBHROZ-UHFFFAOYSA-N ricinoleic acid Natural products CCCCCCC(O[Si](C)(C)C)CC=CCCCCCCCC(=O)OC FEUQNCSVHBHROZ-UHFFFAOYSA-N 0.000 claims description 6
- 229910000077 silane Inorganic materials 0.000 claims description 6
- VXHFNALHLRWIIU-UHFFFAOYSA-N tert-butyl 2,2-dimethylpropanoate Chemical compound CC(C)(C)OC(=O)C(C)(C)C VXHFNALHLRWIIU-UHFFFAOYSA-N 0.000 claims description 6
- 239000000975 dye Substances 0.000 claims description 4
- DAKWPKUUDNSNPN-UHFFFAOYSA-N Trimethylolpropane triacrylate Chemical compound C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 238000009826 distribution Methods 0.000 claims description 3
- 238000000227 grinding Methods 0.000 claims description 3
- 239000003112 inhibitor Substances 0.000 claims description 3
- 239000000049 pigment Substances 0.000 claims description 3
- 239000000244 polyoxyethylene sorbitan monooleate Substances 0.000 claims description 3
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 claims description 3
- 229920000053 polysorbate 80 Polymers 0.000 claims description 3
- 239000002002 slurry Substances 0.000 claims description 3
- 238000010792 warming Methods 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 3
- 235000013305 food Nutrition 0.000 abstract description 2
- 230000001681 protective effect Effects 0.000 abstract description 2
- 230000002349 favourable effect Effects 0.000 abstract 2
- 239000002023 wood Substances 0.000 abstract 2
- HGXJDMCMYLEZMJ-UHFFFAOYSA-N (2-methylpropan-2-yl)oxy 2,2-dimethylpropaneperoxoate Chemical compound CC(C)(C)OOOC(=O)C(C)(C)C HGXJDMCMYLEZMJ-UHFFFAOYSA-N 0.000 abstract 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 abstract 1
- 229940095095 2-hydroxyethyl acrylate Drugs 0.000 abstract 1
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 abstract 1
- 229920000877 Melamine resin Polymers 0.000 abstract 1
- 239000004115 Sodium Silicate Substances 0.000 abstract 1
- 239000003814 drug Substances 0.000 abstract 1
- 229940079593 drug Drugs 0.000 abstract 1
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 abstract 1
- 239000012860 organic pigment Substances 0.000 abstract 1
- 235000019795 sodium metasilicate Nutrition 0.000 abstract 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 abstract 1
- 229910052911 sodium silicate Inorganic materials 0.000 abstract 1
- 238000001035 drying Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 206010059866 Drug resistance Diseases 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 235000006708 antioxidants Nutrition 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 210000000988 bone and bone Anatomy 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
Landscapes
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention relates to high-fastness fast-curing printing ink which is prepared from the following raw materials in parts by weight: 3-4 parts of wood charcoal powder, 5-8 parts of ethanol, 2-4 parts of magnesium hydroxide, 1-2 parts of sodium metasilicate, 4-5 parts of melamine, 4-6 parts of acrylic acid, 24-28 parts of E-12 epoxy resin, 10-12 parts of 196 unsaturated polyester resin, 20-23 parts of epoxy acrylate, 2-3 parts of smoke sheet rubber, 10-12 parts of 2-hydroxy-ethyl acrylate, 1-2 parts of tert-butyl peroxypivalate, 3-4 parts of organic pigment and 4-5 parts of assistant. According to the invention, the ink has favorable visibility; for dark foods, the used transparent dye has no reduction in visibility, is water-resistant, drug-resistant, favorable in toughness and high in fastness, and seems clear and bright; and the preparation method is simple, and the disperse wood charcoal powder can be obtained, thus ensuring the stability of the ink and continuous typing of a printer. The assistant provided by the invention can form a protective film on the surface of the ink, is resistant to oxidation, keeps a brilliant color permanently and prolongs the usage time.
Description
Technical field
The invention belongs to printing ink paint field, relate in particular to fast cured printing ink of a kind of high fastness and preparation method thereof.
Background technology
The color of ink (form and aspect), body bone (rheological property such as rare thick, degree of mobilization) and drying property are three most important performances of ink.Their kind is a lot, and physical properties is also different, and what have is very thick, very sticky; And have quite rare.What have makes low-melting ink vehicle with vegetables oil; Somely with resin and solvent or water etc., make low-melting ink vehicle.These are to be all that the type of stock, printing process, printing plate and drying means etc. decide according to the object of printing.
The rate of drying of ink, thixotropy, skeleton property have tremendous influence to production efficiency, quality product, and the composition of ink has impact to human body, how to study as far as possible little to harm, production efficiency is high, environmental friendliness, ink that cost is low have profound significance.
Summary of the invention
The object of the present invention is to provide fast cured printing ink of a kind of high fastness and preparation method thereof, this ink printing speed is fast, and fastness is good.
Technical scheme of the present invention is as follows:
The fast cured printing ink of high fastness, is characterized in that being made by the raw material of following weight part: charcoal powder 3-4, ethanol 5-8, magnesium hydroxide 2-4, Starso 1-2, trimeric cyanamide 4-5, vinylformic acid 4-6, E-12 epoxy resin 24-28,196 unsaturated polyester resin 10-12, epoxy acrylate 20-23, smoke sheet rubber 2-3, vinylformic acid-2-hydroxy methacrylate 10-12, peroxidation trimethylacetic acid tert-butyl ester 1-2, pigment dyestuff 3-4, auxiliary agent 4-5;
Described auxiliary agent is made by the raw material of following weight part: Silane coupling reagent KH-570 2-3, Viscoat 295 3-4,2-n-octyl-4-isothiazoline-3-ketone 1-2,2-amino-2-methyl-1-propyl alcohol 1-2, polyoxyethylene sorbitan monooleate 2-3, ricinolic acid 1-2, oxidation inhibitor 1035 1-2, linking agent TAC1-2, ethanol 20-24; Preparation method mixes Silane coupling reagent KH-570, ricinolic acid, ethanol, is heated to 60-70 ℃, stirs after 20-30 minute, then adds other remaining component, is warming up to 80-85 ℃, stirs 30-40 minutes, obtains.
The preparation method of the fast cured printing ink of described high fastness, it is characterized in that comprising the following steps: by ethanol, Starso, E-12 epoxy resin, epoxy acrylate, vinylformic acid-2-hydroxy methacrylate mixes, under 1000-1400 rev/min of stirring, add the peroxidation trimethylacetic acid tert-butyl ester, speed with 5-8 ℃/minute is heated to 60-80 ℃, add vinylformic acid, 196 unsaturated polyester resins, smoke sheet rubber, trimeric cyanamide, continue stirring reaction 15-20 minute, add other remaining components, continue stirring reaction 2-2.5 hour, grinding distribution becomes the slurry of 20-30 μ m, obtain.
Beneficial effect of the present invention
Ink visibility of the present invention is good, and for saturate food, the transparency dye visibility meter of use is without decline, and water-fast, drug resistance, good toughness, fastness be high, look clear bright; Its preparation method is simple, can obtain the charcoal powder of dispersion, has guaranteed the stability of ink and the continuous lettering of printer, is applicable to the needs that large-scale industrial is produced, and is applicable to the printing on multiple product surface.Auxiliary agent of the present invention can form protective membrane in ink pellet surface, isolated air, and the surface that prevents water and other molecules corrosion ink and spraying object in atmosphere, anti-oxidant, make color bright-coloured lastingly, and improve slickness, wear resistance, extend working time.
Embodiment
The fast cured printing ink of high fastness, by following weight part (kilogram) raw material make: charcoal powder 3.5, ethanol 7, magnesium hydroxide 3, Starso 1.5, trimeric cyanamide 4.5, vinylformic acid 5, E-12 epoxy resin 26,196 unsaturated polyester resins 11, epoxy acrylate 22, smoke sheet rubber 2.5, vinylformic acid-2-hydroxy methacrylate 11, the peroxidation trimethylacetic acid tert-butyl ester 1.5, pigment dyestuff 3.5, auxiliary agent 4.5;
Described auxiliary agent by following weight part (kilogram) raw material make: Silane coupling reagent KH-570 2.5, Viscoat 295 3.5,2-n-octyl-4-isothiazoline-3-ketone 1.5,2-amino-2-methyl-1-propyl alcohol 1.5, polyoxyethylene sorbitan monooleate 2.5, ricinolic acid 1.5, oxidation inhibitor 1,035 1.5, linking agent TAC1.5, ethanol 22; Preparation method mixes Silane coupling reagent KH-570, ricinolic acid, ethanol, is heated to 65 ℃, stirs after 26 minutes, then adds other remaining component, is warming up to 83 ℃, stirs 34 minutes, obtains.
The preparation method of the fast cured printing ink of described high fastness, comprise the following steps: ethanol, Starso, E-12 epoxy resin, epoxy acrylate, vinylformic acid-2-hydroxy methacrylate are mixed, under 1200 revs/min of stirrings, add the peroxidation trimethylacetic acid tert-butyl ester, with the speed of 6 ℃/minute, be heated to 70 ℃, add vinylformic acid, 196 unsaturated polyester resins, smoke sheet rubber, trimeric cyanamide, continue stirring reaction 17 minutes, add other remaining components, continue stirring reaction 2.4 hours, grinding distribution becomes the slurry of 25 μ m, obtains.
Ink quality homogeneous of the present invention, tinting strength, adhere firmly degree, viscosity, first dryness and other performances have reached the requirement of QB/T2024-94 standard.
Claims (2)
1. the fast cured printing ink of high fastness, is characterized in that being made by the raw material of following weight part: charcoal powder 3-4, ethanol 5-8, magnesium hydroxide 2-4, Starso 1-2, trimeric cyanamide 4-5, vinylformic acid 4-6, E-12 epoxy resin 24-28,196 unsaturated polyester resin 10-12, epoxy acrylate 20-23, smoke sheet rubber 2-3, vinylformic acid-2-hydroxy methacrylate 10-12, peroxidation trimethylacetic acid tert-butyl ester 1-2, pigment dyestuff 3-4, auxiliary agent 4-5;
Described auxiliary agent is made by the raw material of following weight part: Silane coupling reagent KH-570 2-3, Viscoat 295 3-4,2-n-octyl-4-isothiazoline-3-ketone 1-2,2-amino-2-methyl-1-propyl alcohol 1-2, polyoxyethylene sorbitan monooleate 2-3, ricinolic acid 1-2, oxidation inhibitor 1035 1-2, linking agent TAC1-2, ethanol 20-24; Preparation method mixes Silane coupling reagent KH-570, ricinolic acid, ethanol, is heated to 60-70 ℃, stirs after 20-30 minute, then adds other remaining component, is warming up to 80-85 ℃, stirs 30-40 minutes, obtains.
2. the preparation method of the fast cured printing ink of high fastness according to claim 1, it is characterized in that comprising the following steps: by ethanol, Starso, E-12 epoxy resin, epoxy acrylate, vinylformic acid-2-hydroxy methacrylate mixes, under 1000-1400 rev/min of stirring, add the peroxidation trimethylacetic acid tert-butyl ester, speed with 5-8 ℃/minute is heated to 60-80 ℃, add vinylformic acid, 196 unsaturated polyester resins, smoke sheet rubber, trimeric cyanamide, continue stirring reaction 15-20 minute, add other remaining components, continue stirring reaction 2-2.5 hour, grinding distribution becomes the slurry of 20-30 μ m, obtain.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310574942.6A CN103666085A (en) | 2013-11-18 | 2013-11-18 | High-fastness fast-curing printing ink and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310574942.6A CN103666085A (en) | 2013-11-18 | 2013-11-18 | High-fastness fast-curing printing ink and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103666085A true CN103666085A (en) | 2014-03-26 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310574942.6A Pending CN103666085A (en) | 2013-11-18 | 2013-11-18 | High-fastness fast-curing printing ink and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103666085A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104231869A (en) * | 2014-09-16 | 2014-12-24 | 安徽明都电气有限公司 | Natural corrosion-resistant oxidization-resistant epoxy insulating paint and preparation method thereof |
| CN105346266A (en) * | 2015-12-15 | 2016-02-24 | 苏州明锦机械设备有限公司 | Edible printing ink and food printer |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1970656A (en) * | 2006-11-23 | 2007-05-30 | 北京印刷学院 | Thermoforming plastic printing ink adopting ultraviolet-infra red drying technology |
-
2013
- 2013-11-18 CN CN201310574942.6A patent/CN103666085A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1970656A (en) * | 2006-11-23 | 2007-05-30 | 北京印刷学院 | Thermoforming plastic printing ink adopting ultraviolet-infra red drying technology |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104231869A (en) * | 2014-09-16 | 2014-12-24 | 安徽明都电气有限公司 | Natural corrosion-resistant oxidization-resistant epoxy insulating paint and preparation method thereof |
| CN105346266A (en) * | 2015-12-15 | 2016-02-24 | 苏州明锦机械设备有限公司 | Edible printing ink and food printer |
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Application publication date: 20140326 |