CN103101342A - Thermal transfer printing product printed by offset printing equipment - Google Patents

Thermal transfer printing product printed by offset printing equipment Download PDF

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Publication number
CN103101342A
CN103101342A CN 201110350923 CN201110350923A CN103101342A CN 103101342 A CN103101342 A CN 103101342A CN 201110350923 CN201110350923 CN 201110350923 CN 201110350923 A CN201110350923 A CN 201110350923A CN 103101342 A CN103101342 A CN 103101342A
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China
Prior art keywords
printing
thermal transfer
product
offset printing
offset
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CN 201110350923
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Chinese (zh)
Inventor
仇俊聪
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TIANJIN JIZHOU PRINTING CO Ltd
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TIANJIN JIZHOU PRINTING CO Ltd
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Application filed by TIANJIN JIZHOU PRINTING CO Ltd filed Critical TIANJIN JIZHOU PRINTING CO Ltd
Priority to CN 201110350923 priority Critical patent/CN103101342A/en
Publication of CN103101342A publication Critical patent/CN103101342A/en
Pending legal-status Critical Current

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Abstract

The invention relates to a thermal transfer printing product printed by offset printing equipment. The thermal transfer printing product includes a thermal transfer film and patterns and characters printed on the film, and is characterized in that: the ink applied in the patterns and characters contains the following components by weight: 38% of rosin modified octylphenol phenolic resin, 14% of isophthalic acid alkyd resin, 32% of soybean oil, 10% of tung oil, 5% of a high boiling point petroleum solvent and 1% of an organic aluminum gel. By adding the ink involved in the invention into ordinary ink, the purpose of printing thermal transfer films by an ordinary offset printing machine can be realized, and the highest printing speed can reach 10000 films per hour. The printing process ends automatically, the work efficiency is greatly improved, and the labor intensity is reduced.

Description

A kind of thermal transfer printing product of offset printing equipment printing
Technical field
The invention belongs to printing technology, especially a kind of thermal transfer printing product of offset printing equipment printing.
Background technology
The thermal transfer printing technology is an emerging typography, by importing the domestic only time in 10 coming year abroad into, this technique has been widely used in the industries such as plastic cement, cosmetics, toy, electrical equipment, building materials, gift, packaging for foodstuff, stationery, take heat transfer film as base material, use special printing ink to print on it in thermal transfer printing process.
Last century the nineties, has the heat transfer film of pattern, word etc. from importing China abroad into, because of the particularity of its printing process, this printed matter dependence on import causes its price very expensive, to initial stage 21st century, the domestic mode of production that begins to follow serigraphy is produced heat transfer film voluntarily, although make some progress, exists production process various, the shortcomings such as production efficiency is low, labour intensity is large, and turn the quality of printed film far away less than external heat.
Summary of the invention
The object of the invention is to overcome the deficiencies in the prior art part, provide that its curing ink adhesive force is good, the thermal transfer printing product of a kind of offset printing equipment printing of quick-drying, high-luster.
A kind of thermal transfer printing product of offset printing equipment printing comprise heat transfer film and upper pattern and the word of printing thereof, and it is characterized in that: the printing ink that described pattern and word use comprises the following component that mixes by weight ratio:
Figure BDA0000106733410000011
And the acid number of described Abietyl modified octyl phenol phenolic resins is 16~24mgKOH/g, and viscosity is 2200~2800mPas/35 ℃.
And the acid number of described isophthalic alkyd resin is less than 18mgKOH/g, and viscosity is 4000~6000mPas/35 ℃.
And the iodine number of described soybean oil is 120~140gl2/100g.
And described high point petroleum solvent is 270~310 ℃ of boiling ranges, the cut of aromatic hydrocarbons≤1%.
And in described organo-aluminium gel, aluminium content is 5.0~5.5%.
And described printing ink is four color inks, and in every kind of monochrome ink, the content of binder is as follows:
Figure BDA0000106733410000021
Another object of the present invention provides a kind of preparation method of thermal transfer printing product of offset printing equipment printing, and the method comprises the following steps:
(1) 28% soybean oil, 10% tung oil and 38% Abietyl modified octyl phenol phenolic resins are added reactor, heat up, liquid level leads to CO 2Or N 2Stirring is started in protection during to 180 ℃;
When (2) continuing to be warming up to 250 ℃, insulated and stirred is 1 hour in the interval of 250~255 ℃;
(3) add 14% isophthalic alkyd resin in reactor, be cooled to 220~225 ℃, stirred 30 minutes, stop logical CO 2Or N 2Protection stops insulation, adds the high point petroleum solvent, stirs 20~30 minutes;
When (4) material is cooled to 160 ℃, add the soybean oil with 4% to dilute in advance uniform 1% organo-aluminium gel, be warming up to 180 ℃, keep 175~180 ℃, stirred 30~40 minutes;
(5) sampling viscosimetric, qualified rear filtration makes finished product.
Advantage of the present invention and good effect are:
in the present invention, Abietyl modified octyl phenol phenolic resins makes printing ink have quick-drying, the advantage of high glaze and high tack, isophthalic alkyd resin makes printing ink have quick-drying, high glaze and the advantage that pigment wetting is disperseed, soybean oil and tung oil copolymerization generate the drying property of approximate drying oil linseed oil, organo-aluminium gel KETALIN-4F can make link stuff viscosity improve 1~1.5 times, and viscosity increases hardly, can shorten the ink setting set time, improve glossiness, water-resistance and dot reproduction, after above each component prepares finished product, add in common ink, can realize the purpose of common offset machine printing heat transfer film, the highest seal scooter to 10000/hour, printing process is completed automatically, greatly improved operating efficiency, reduced labour intensity.
The specific embodiment
Below in conjunction with embodiment, the present invention is further described, and following embodiment is illustrative, is not determinate, can not limit protection scope of the present invention with following embodiment.
A kind of thermal transfer printing product of offset printing equipment printing, comprise heat transfer film and upper pattern and the word of printing thereof, this pattern and word are printed on heat transfer film by four colour offset press, and four color inks that use are respectively magenta, middle Huang, sky blue and black, and the formula of every kind of monochrome ink is as follows:
Figure BDA0000106733410000031
Above-mentioned binder comprises the following component that mixes by weight ratio:
Figure BDA0000106733410000032
The acid number of Abietyl modified octyl phenol phenolic resins is 16~24mgKOH/g, and viscosity is 2200~2800mPas/35 ℃.The acid number of isophthalic alkyd resin is less than 18mgKOH/g, and viscosity is 4000~6000mPas/35 ℃.The iodine number of soybean oil is 120~140gl2/100g.The high point petroleum solvent is 270~310 ℃ of boiling ranges, aromatic hydrocarbons≤1%.In the organo-aluminium gel, aluminium content is 5.0~5.5%.
The preparation method of above-mentioned binder comprises the following steps:
(1) 28% soybean oil, 10% tung oil and 38% Abietyl modified octyl phenol phenolic resins are added reactor, heat up, liquid level leads to CO 2Or N 2Stirring is started in protection during to 180 ℃;
When (2) continuing to be warming up to 250 ℃, insulated and stirred is 1 hour in the interval of 250~255 ℃;
(3) add 14% isophthalic alkyd resin in reactor, be cooled to 220~225 ℃, stirred 30 minutes, stop logical CO 2Or N 2Protection stops insulation, adds the high point petroleum solvent, stirs 20~30 minutes;
When (4) material is cooled to 160 ℃, add the soybean oil with 4% to dilute in advance uniform 1% organo-aluminium gel, be warming up to 180 ℃, keep 175~180 ℃, stirred 30~40 minutes;
(5) sampling viscosimetric, qualified rear filtration makes finished product.
The preparation method of above-mentioned printing ink is: at first binder, pigment, diluent, antiwear additive are mixed, stir, grinding distribution on three-roller or ball mill, after reaching requirement to fineness, add solvent adjustment viscosity and China ink, add again drier, drier activator and anti skinning agent to mix in machine, make after filtering the printing ink finished product.
The printing ink finished product that makes injects four colour offset press, places heat transfer film, prints, and the printed matter tack of printing is good, and gloss is high, and water-resistance is high, and print speed printing speed is fast.Logical common serigraphy relatively, the heat transfer film of 10,000 eight looks of serigraphy needs five people print 10 days, and when adopting offset press automatically to print, only need time half a day, and whole cost only needs 20% of serigraphy, greatly improved operating efficiency, reduced labour intensity.

Claims (8)

1. the thermal transfer printing product of an offset printing equipment printing, comprise heat transfer film and upper pattern and the word of printing thereof, and it is characterized in that: the printing ink that described pattern and word use contains binder, and this binder comprises the following component that mixes by weight ratio:
Figure FDA0000106733400000011
2. the thermal transfer printing product of a kind of offset printing equipment printing according to claim 1, it is characterized in that: the acid number of described Abietyl modified octyl phenol phenolic resins is 16~24mgKOH/g, viscosity is 2200~2800mPas/35 ℃.
3. the thermal transfer printing product of a kind of offset printing equipment printing according to claim 1, it is characterized in that: the acid number of described isophthalic alkyd resin is less than 18mgKOH/g, and viscosity is 4000~6000mPas/35 ℃.
4. the thermal transfer printing product of a kind of offset printing equipment printing according to claim 1, it is characterized in that: the iodine number of described refined soybean oil is 120~140gl2/100g.
5. the thermal transfer printing product of a kind of offset printing equipment printing according to claim 1, it is characterized in that: described high point petroleum solvent is 270~310 ℃ of boiling ranges, the cut of aromatic hydrocarbons≤1%.
6. the thermal transfer printing product of a kind of offset printing equipment printing according to claim 1, it is characterized in that: in described organo-aluminium gel, aluminium content is 5.0~5.5%.
7. the thermal transfer printing product of the described a kind of offset printing equipment printing of according to claim 1~6 any one, it is characterized in that: described printing ink is four color inks, in every kind of monochrome ink, the content of binder is as follows:
Figure FDA0000106733400000012
8. the thermal transfer printing product of the described a kind of offset printing equipment printing of according to claim 1~6 any one, it is characterized in that: the preparation method of described binder is: comprise the following steps:
(1) 28% soybean oil, 10% tung oil and 38% Abietyl modified octyl phenol phenolic resins are added reactor, heat up, liquid level leads to CO 2Or N 2Stirring is started in protection during to 180 ℃;
When (2) continuing to be warming up to 250 ℃, insulated and stirred is 1 hour in the interval of 250~255 ℃;
(3) add 14% isophthalic alkyd resin in reactor, be cooled to 220~225 ℃, stirred 30 minutes, stop logical CO 2Or N 2Protection stops insulation, adds the high point petroleum solvent, stirs 20~30 minutes;
When (4) material is cooled to 160 ℃, add the soybean oil with 4% to dilute in advance uniform 1% organo-aluminium gel, be warming up to 180 ℃, keep 175~180 ℃, stirred 30~40 minutes;
(5) sampling viscosimetric, qualified rear filtration makes finished product.
CN 201110350923 2011-11-09 2011-11-09 Thermal transfer printing product printed by offset printing equipment Pending CN103101342A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
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Application Number Priority Date Filing Date Title
CN 201110350923 CN103101342A (en) 2011-11-09 2011-11-09 Thermal transfer printing product printed by offset printing equipment

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105802332A (en) * 2014-12-30 2016-07-27 天津天女化工集团股份有限公司 High-speed offset printing phenolic resin printing ink and preparation method thereof
CN106564316A (en) * 2015-10-13 2017-04-19 东莞市鼎盛塑胶膜有限公司 High-brightness granular resin transfer film preparation method
CN108485371A (en) * 2018-04-17 2018-09-04 广州市恒远彩印有限公司 The paper wrapper printing faces UV oil and preparation method thereof
CN108587306A (en) * 2018-04-17 2018-09-28 广州市恒远彩印有限公司 Blue ultraviolet cured offset printing ink and preparation method thereof
CN111556887A (en) * 2017-12-18 2020-08-18 阪田油墨株式会社 Ink composition for plasma-curable offset printing, method for producing printed matter using same, and printing method

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105802332A (en) * 2014-12-30 2016-07-27 天津天女化工集团股份有限公司 High-speed offset printing phenolic resin printing ink and preparation method thereof
CN106564316A (en) * 2015-10-13 2017-04-19 东莞市鼎盛塑胶膜有限公司 High-brightness granular resin transfer film preparation method
CN106564316B (en) * 2015-10-13 2019-11-12 东莞市鼎盛塑胶膜有限公司 A kind of preparation method of highlighted particulate resin transfer membrane
CN111556887A (en) * 2017-12-18 2020-08-18 阪田油墨株式会社 Ink composition for plasma-curable offset printing, method for producing printed matter using same, and printing method
CN111556887B (en) * 2017-12-18 2022-12-02 阪田油墨株式会社 Ink composition for plasma-curable offset printing, method for producing printed matter using same, and printing method
US11597847B2 (en) 2017-12-18 2023-03-07 Sakata Inx Corporation Plasma-curable offset printing ink composition, method for producing printed matter using same, and printing method
CN108485371A (en) * 2018-04-17 2018-09-04 广州市恒远彩印有限公司 The paper wrapper printing faces UV oil and preparation method thereof
CN108587306A (en) * 2018-04-17 2018-09-28 广州市恒远彩印有限公司 Blue ultraviolet cured offset printing ink and preparation method thereof

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Application publication date: 20130515