CN102399472B - Printing ink substituting gold stamping anodized aluminium - Google Patents

Printing ink substituting gold stamping anodized aluminium Download PDF

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Publication number
CN102399472B
CN102399472B CN 201110345418 CN201110345418A CN102399472B CN 102399472 B CN102399472 B CN 102399472B CN 201110345418 CN201110345418 CN 201110345418 CN 201110345418 A CN201110345418 A CN 201110345418A CN 102399472 B CN102399472 B CN 102399472B
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China
Prior art keywords
parts
printing ink
resin
solvent
pigment
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CN 201110345418
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Chinese (zh)
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CN102399472A (en
Inventor
周贤永
朱丽纯
丁立刚
张凤丽
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JIANGSU TIGER INK CO Ltd
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JIANGSU TIGER INK CO Ltd
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Priority to CN 201110345418 priority Critical patent/CN102399472B/en
Publication of CN102399472A publication Critical patent/CN102399472A/en
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Abstract

The invention provides a printing ink to substitute gold stamping anodized aluminium. The printing ink is characterized by comprising the following raw materials, by weight: 10-30 parts of resin, 30-60 parts of colored sheet, 30-50 parts of ester solvent, 10-30 parts of alcohol solvent, 0.5-3 parts of dispersant and 0.5-3 parts of levelling agent; the colored sheet is prepared by the following raw materials, by weight: 20-45 parts of resin, 45-70 parts of pigment, 1-10 parts of ester solvent and 1-10 parts of alcohol solvent. The printing ink substituting gold stamping anodized aluminium of the invention has prominent advantages of high printing ink glossiness, simple operation, substantially saved cost and excellent antifriction performance. The product is mainly applied to printing technology for tipping paper, art paper, paperboard, various composite paper and aluminium foil paper, etc.

Description

A kind of printing ink that replaces hot stamping foil
Technical field
The present invention relates to a kind of printing ink, particularly a kind of printing ink that replaces hot stamping foil.
Background technology
Electrochemical aluminium thermoprinting is one very important post-press finishing technique in packages printing, is mainly that hot stamping pattern, word, lines are to give prominence to title, the trade mark of product.Beautify product, thereby improve the class of wrapped product.Electrochemical aluminium thermoprinting also often is used to the post-press finishing of the products such as hard-cover book cover, greeting card, wall calendar.
The thermoprint process of anodized aluminium is as follows: by printing plate, anodized aluminium is heated, peel ply fusing, then the gluing layer also melts, gluing layer and stock bonding when impression, pigmented layer and dacron chip base pull-up from, aluminium coated and pigmented layer are stayed on stock.
Its boiling hot front printing of product the having relatively high expectations to printing ink that needs electrochemical aluminium thermoprinting, require dark thin seal, use the stronger printing ink of tinting strength, add less release agent as far as possible and remove glutinous agent in printing ink, do not dust as far as possible, the printability of printing-ink, oil polish and electrochemical aluminium thermoprinting is complementary, and should prevent that also the printing ink crystallization is on the impact of thermoprint.Thermoprint material and hot stamping equipment are two factors that affect the most critical of hot stamping effects.Its price of the influence factor of two keys is all very high.
Summary of the invention
Technical problem to be solved by this invention is for the deficiencies in the prior art, and the printing ink that a kind of new ink degree is high, easy to operate, greatly saved the good replacement hot stamping foil of cost, crocking resistance is provided.
Technical problem to be solved by this invention is to realize by following technical scheme.The present invention is a kind of printing ink that replaces hot stamping foil, is characterized in, it is to be made by the raw material of following weight proportion:
Resin 10-30; Color chips 30-60;
Esters solvent 30-50; Alcoholic solvent 10-30;
Dispersion agent 0.5-3; Flow agent 0.5-3;
Described color chips is to be made by the raw material of following weight proportion:
Resin 20-45; Pigment 45-70;
Esters solvent 1-10; Alcoholic solvent 1-10;
Described dispersion agent can be disclosed any anionic, non-ionic type or high-molecular type dispersing agent that can be used for printing ink in prior art;
Described flow agent can be disclosed any the silicone based of printing ink or fluorine carbon flow agent of can be used in prior art;
Described resin is selected from a kind of in nitrocellulose resin, acrylic resin, urethane resin, chlorine vinegar resin or aldehyde ketone resin;
Described pigment is disclosed any transparent pigment that can be used for printing ink in prior art;
Described esters solvent is selected from the mixture of one or both compositions in n-propyl acetate, ethyl acetate, n-butyl acetate, isobutyl acetate; When using mixture, the blending ratio between raw material can adopt arbitrary proportion on demand.
Described alcoholic solvent is selected from the mixture of one or both compositions in ethanol, Virahol, propyl carbinol.When using mixture, the blending ratio between raw material can adopt arbitrary proportion on demand.
In the ink technology scheme of above-described replacement hot stamping foil: how described dispersion agent preferably from carboxylate salt, sulfuric acid, polyethylene glycol type polyvalent alcohol, polyethylenimine derivates, join polyvalent alcohol-many ethyleneimines segmented copolymer in, a kind of in the reactant of many caprolactones and triethylene tetramine.
In the ink technology scheme of above-described replacement hot stamping foil: described flow agent is a kind of in polydimethylsiloxane, PSI, organic radical modified polyorganosiloxane, polyfluoro polyene hydrocarbon or fluorin modified crylic acid preferably.
In the ink technology scheme of above-described replacement hot stamping foil: described pigment optimization is one or more in transparent yellow, transparent red or transparent basket.
In the ink technology scheme of above-described replacement hot stamping foil: the weight proportion of each raw material is preferably:
Resin 20; Color chips 45;
Esters solvent 40; Alcoholic solvent 20;
Dispersion agent 1.8; Flow agent 1.8;
Described color chips is to be made by the raw material of following weight proportion:
Resin 32; Pigment 58;
Esters solvent 5; Alcoholic solvent 5.
Compared with prior art, it is that this ink degree is high, easy to operate that the present invention replaces the outstanding advantages of the printing ink of hot stamping foil, has greatly saved cost, and crocking resistance is good.Product is mainly used in the typographies such as tipping paper, enamelled paper, paperboard, various Composite Paper, aluminium-foil paper.
Embodiment
Below further describe concrete technical scheme of the present invention, so that those skilled in the art understands the present invention further, and do not consist of its Copyright law.
Embodiment 1, a kind of printing ink that replaces hot stamping foil, and it is to be made by the raw material of following weight proportion:
Resin 10; Color chips 30;
Esters solvent 30; Alcoholic solvent 10;
Dispersion agent 0.5; Flow agent 0.5;
Described color chips is to be made by the raw material of following weight proportion:
Resin 20; Pigment 45;
Esters solvent 1; Alcoholic solvent 10;
Described dispersion agent is anionic, non-ionic type or high-molecular type dispersing agent;
Described flow agent is silicone based or the fluorine carbon flow agent;
Described resin is selected from a kind of in nitrocellulose resin, acrylic resin, urethane resin, chlorine vinegar resin or aldehyde ketone resin;
Described pigment is transparent pigment;
Described esters solvent is selected from the mixture of one or both compositions in n-propyl acetate, ethyl acetate, n-butyl acetate, isobutyl acetate;
Described alcoholic solvent is selected from the mixture of one or both compositions in ethanol, Virahol, propyl carbinol.
Embodiment 2, a kind of printing ink that replaces hot stamping foil, and it is to be made by the raw material of following weight proportion:
Resin 30; Color chips 60;
Esters solvent 50; Alcoholic solvent 30;
Dispersion agent 3; Flow agent 3;
Described color chips is to be made by the raw material of following weight proportion:
Resin 45; Pigment 70;
Esters solvent 10; Alcoholic solvent 1;
Material choice is identical with embodiment 1.
Embodiment 3, a kind of printing ink that replaces hot stamping foil, and it is to be made by the raw material of following weight proportion:
Resin 15; Color chips 40;
Esters solvent 35; Alcoholic solvent 25;
Dispersion agent 1.5; Flow agent 2.5;
Described color chips is to be made by the raw material of following weight proportion:
Resin 30; Pigment 50;
Esters solvent 3; Alcoholic solvent 7;
Material choice is identical with embodiment 1.
Embodiment 4, in the printing ink of embodiment 1 or 2 or 3 described replacement hot stamping foils: described dispersion agent is selected from carboxylate salt, sulfuric acid, polyethylene glycol type polyvalent alcohol, polyethylenimine derivates, how joins polyvalent alcohol-many ethyleneimines segmented copolymer in, a kind of in the reactant of many caprolactones and triethylene tetramine.The reactant of many caprolactones and triethylene tetramine refers to the reactant that many caprolactones, triethylene tetramine reaction generate.
Embodiment 5, and in the printing ink of embodiment 1 or 2 or 3 described replacement hot stamping foils: described flow agent is selected from a kind of in polydimethylsiloxane, PSI, organic radical modified polyorganosiloxane, polyfluoro polyene hydrocarbon or fluorin modified crylic acid.
Embodiment 6, and in the printing ink of embodiment 1 or 2 or 3 described replacement hot stamping foils: described pigment is one or more in transparent yellow, transparent red or transparent basket.
Embodiment 7, a kind of printing ink that replaces hot stamping foil, and the weight proportion of each raw material is:
Resin 20; Color chips 45;
Esters solvent 40; Alcoholic solvent 20;
Dispersion agent 1.8; Flow agent 1.8;
Described color chips is to be made by the raw material of following weight proportion:
Resin 32; Pigment 58;
Esters solvent 5; Alcoholic solvent 5.
Described resin is nitrocellulose resin;
Described esters solvent is the mixture that n-propyl acetate and ethyl acetate form;
Described alcoholic solvent is the mixture that ethanol and Virahol form;
Described dispersion agent is carboxylate salt;
Described flow agent is polydimethylsiloxane;
Described pigment is transparent yellow.
When the present embodiment replaces the printing ink of hot stamping foil to prepare, first prepare color chips.The preparation method of color chips mixes several starting material at first in proportion, material is transferred to two roller machine to be rolled, common rolling 3-4 time, temperature is controlled to be no more than 80 ℃ and is advisable, and takes off material, detects and (to get and a certain amount ofly to make printing ink by ink formulations, detect form and aspect, viscosity, fineness, glossiness, solid content) qualified, if the packing warehouse-in defective, continues rolling until qualified.Then prepare printing ink, during preparation, esters solvent, alcoholic solvent, dispersion agent, flow agent are mixed in proportion and are uniformly dispersed, a certain amount of color chips is added, soak, seal 4-6 hour, start to stir, be uniformly dispersed to color chips and dissolve fully, add a certain amount of resin, be uniformly dispersed, grind check, packing warehouse-in 1-2 time.
The performance index of the present embodiment product following (the disclosed detection method commonly used of prior art and instrument are all adopted in the detection of various indexs):
Index Content
Solid content (%) 30-55
Viscosity (s, 25 ℃) 40-50
Fineness (um) ≤10
Glossiness (60 degree) >70
Attachment fastness (%) 100

Claims (1)

1. a printing ink that replaces hot stamping foil, is characterized in that, it is to be made by the raw material of following weight proportion:
Resin 20; Color chips 45;
Esters solvent 40; Alcoholic solvent 20;
Dispersion agent 1.8; Flow agent 1.8;
Described color chips is to be made by the raw material of following weight proportion:
Resin 32; Pigment 58;
Esters solvent 5; Alcoholic solvent 5;
Described resin is nitrocellulose resin;
Described esters solvent is the mixture that n-propyl acetate and ethyl acetate form;
Described alcoholic solvent is the mixture that ethanol and Virahol form;
Described dispersion agent is carboxylate salt;
Described flow agent is polydimethylsiloxane;
Described pigment is transparent yellow.
CN 201110345418 2011-11-04 2011-11-04 Printing ink substituting gold stamping anodized aluminium Active CN102399472B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN 201110345418 CN102399472B (en) 2011-11-04 2011-11-04 Printing ink substituting gold stamping anodized aluminium

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN 201110345418 CN102399472B (en) 2011-11-04 2011-11-04 Printing ink substituting gold stamping anodized aluminium

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CN102399472A CN102399472A (en) 2012-04-04
CN102399472B true CN102399472B (en) 2013-11-06

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Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104194470A (en) * 2014-07-28 2014-12-10 蚌埠德美过滤技术有限公司 Anti-abrasive plant printing ink
CN104530823A (en) * 2015-01-15 2015-04-22 英科·卡乐油墨(苏州)有限公司 Printing ink combination for aluminum-foil paper and printing ink and gloss oil with same
CN110499069A (en) * 2019-08-22 2019-11-26 青岛嘉泽包装有限公司 A kind of ink and preparation method thereof and the application in heatproof transfevent tipping paper
CN114932765B (en) * 2022-07-04 2024-02-06 青岛嘉泽包装有限公司 Preparation method of positioning hot stamping tipping paper

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102140276A (en) * 2011-04-25 2011-08-03 王学珍 High temperature steaming resistant ink for ink jet recording

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C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
PE01 Entry into force of the registration of the contract for pledge of patent right

Denomination of invention: An ink instead of gilding anodized

Effective date of registration: 20221130

Granted publication date: 20131106

Pledgee: Lianyungang Branch of Suzhou Bank Co.,Ltd.

Pledgor: JIANGSU TAIGE INK CO.,LTD.

Registration number: Y2022320010760

PE01 Entry into force of the registration of the contract for pledge of patent right