CN106381063B - A kind of heat transfer colour ribbon and preparation method thereof near side (ns) printing - Google Patents
A kind of heat transfer colour ribbon and preparation method thereof near side (ns) printing Download PDFInfo
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- CN106381063B CN106381063B CN201610777158.9A CN201610777158A CN106381063B CN 106381063 B CN106381063 B CN 106381063B CN 201610777158 A CN201610777158 A CN 201610777158A CN 106381063 B CN106381063 B CN 106381063B
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- Prior art keywords
- emulsion
- aqueous
- lotion
- heat transfer
- adhesion layer
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D191/00—Coating compositions based on oils, fats or waxes; Coating compositions based on derivatives thereof
- C09D191/06—Waxes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41J—TYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
- B41J31/00—Ink ribbons; Renovating or testing ink ribbons
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D123/00—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers
- C09D123/02—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
- C09D123/04—Homopolymers or copolymers of ethene
- C09D123/08—Copolymers of ethene
- C09D123/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
- C09D123/0853—Vinylacetate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses a kind of aqueous heat transfer colour ribbons and preparation method thereof near side (ns) printing, which includes releasing layer, adhesion layer and hypothallus；The releasing layer includes waterborne wax emulsion, auxiliary agent and deionized water, and the adhesion layer includes resin aqueous emulsion, waterborne wax emulsion, inorganic pigment, auxiliary agent and deionized water；The all water-based emulsions of lotion used in the releasing layer and adhesion layer, do not add any organic solvent；The viscosity of the releasing layer and adhesion layer lotion is different, and when transfer will not interpenetrate.The heat transfer colour ribbon of the present invention disclosure satisfy that the printing speed of near side (ns) printer, and printing character and image clearly, wear-resisting scratch resistance effect are good.
Description
Technical field
The present invention relates to thermal transfer fields, and in particular to a kind of aqueous heat transfer colour ribbon near side (ns) printing.
Background technology
Thermal transfer printer is divided into flat-crushing type printer and side crush type printer, and opposite flat-crushing type prints, the printing of side pressure type
Speed is fast, saves colour band, and side crush type printer print speed is up to 600mm/s, and flat-crushing type printer speed can only achieve
300mm/s.Since print speed is one times relatively fast, side crush type printer is widely used in the factory of various Large-scale Manufacturings
It uses.
Side crush type printer ink ribbon peace crush type printer ink ribbon is not general, currently used for side crush type printer
The colour band of printing is mostly dicyandiamide solution, and dicyandiamide solution can largely use toluene, dimethylbenzene, butanone, methyl in use
The organic solvents such as isobutyl ketone and ethers, in being coated with drying process, these organic solvents largely volatilize, and not only cause the wave of material
Take, the increase of cost；Meanwhile solvent volatilization is also easy to cause fire in air, causes security risk；A large amount of solvents can be dealt into
In air, Workshop Production bad environments are caused, influence the health of worker；In addition, these organic solvents are diffused into air
It will also result in air pollution.Since solvent type colour band has the shortcomings that numerous, the colour band of water-based system is increasingly by everybody weight
Depending on.
Although the colour band currently used for side crush type printer, which also has, takes water-based system, turn after most of colour band printings
Print is not complete, and trace is unintelligible, and the poor effect under transformation printer printing speed is concluded its reason, essentially consisted in presently used
The single coating that mostly uses greatly of transformation colour band, single coating is difficult that meet print pattern intensity after release temperature is low and printing high
Requirement；Minority uses double-coated colour band, but different without the viscosity of control releasing layer and adhesion layer, due to releasing layer with
The viscosity differences of adhesion layer are too small, and releasing layer and ink layer is caused to mix in thermal histories, and pattern transfer is not complete, print
Mark effect is poor.
Invention content
In order to solve the problems existing in the prior art, the scheme of the invention taken is：A kind of heat near side (ns) printing turns
Red ink paste used for seals band, the heat transfer colour ribbon include releasing layer, adhesion layer and hypothallus；The releasing layer include waterborne wax emulsion, auxiliary agent and
Deionized water, the adhesion layer include resin aqueous emulsion, waterborne wax emulsion, inorganic pigment, auxiliary agent and deionized water；It is described to release
The all water-based emulsions of lotion used in layer and adhesion layer are put, do not add any organic solvent；The releasing layer and adhesion layer
The viscosity of lotion is different, and when transfer will not interpenetrate.
Resin aqueous emulsion of the present invention is selected from aqueous EVA resin lotion, aqueous EEA resin emulsions, aqueous polyurethane
Lotion, water polyacrylic acid lotion, waterborne polyester lotion, aqueous rosin milk, one kind in water-base epoxy alkane lotion or
It is a variety of, preferably aqueous EVA resin lotion, aqueous EEA resin emulsions, water polyacrylic acid lotion, waterborne polyester lotion, water
It is one or more in property rosin milk.
Waterborne wax emulsion of the present invention includes aqueous Brazilian wax emulsion, aqueous candelila wax lotion or brazil wax and small candle
The aqueous compound wax emulsion of vegetable wax, the preferably aqueous complex emulsions of brazil wax and candelila wax, particularly preferably brazil wax and
Candelila wax mass ratio is 7:3 water-borne wax breast complex emulsions.
It is of the present invention release layer component weight proportion be waterborne wax emulsion 10%-20%, auxiliary agent 1%-5%, go from
Sub- water 70%-80%.
The weight proportion of adherency layer component of the present invention is resin aqueous emulsion 10%-20%, waterborne wax emulsion 5%-
10%, inorganic pigment 5%-10%, auxiliary agent 1%-5%, deionized water 50%-70%.
Inorganic pigment of the present invention is carbon black, and auxiliary agent is selected from aqueous silica sol lotion, dispersant, levelling agent, antifoaming agent
In it is one or more.
Hypothallus of the present invention is the polyester film for being coated with heat-resisting coated, and thickness is 3-10 μm, preferred thickness 4-6
μm。
The releasing layer of heat transfer colour ribbon of the present invention is different with the viscosity of adhesion layer, and releasing layer emulsion viscosity is about 100-
1000mPa.s, adhesion layer emulsion viscosity are about 104-105mPa.s。
The present invention also provides a kind of preparation methods of the heat transfer colour ribbon near side (ns) printing, include the following steps：
A, waterborne wax emulsion, auxiliary agent and deionized water are uniformly dispersed, adjust viscosity, releasing layer lotion is made；
B, by releasing layer emulsion coating on hypothallus；
C, resin aqueous emulsion, waterborne wax emulsion, inorganic pigment, auxiliary agent and deionized water are uniformly dispersed, are ground, adjusted
Adhesion layer lotion is made in viscosity；
D, adhesion layer emulsion coating is obtained into heat transfer colour ribbon on the hypothallus for having coated releasing layer.
The polished fineness of adhesion layer lotion of the present invention is less than 5 μm, and temperature is less than 30 DEG C, it is therefore an objective to when making coating
Flour milling more uniformly, it is fine and smooth, pattern is more clear when printing.
Temperature is 70-80 DEG C when heat transfer colour ribbon drying of the present invention, and releasing layer coating weight is 0.8-1.2g/m2,
Adhesion layer coating weight is 1.0-1.5g/m2, total coating weight is 1.5-2.0g/m2。
Compared to the prior art, the present invention has the following advantages：
(1) heat transfer colour ribbon of the invention uses the coating method that releasing layer and adhesion layer are separately coated with, and proposes and release
The viscosity control range of layer and adhesion layer is put, wherein releasing layer emulsion viscosity control range is 100-1000mPa.s, adhesion layer breast
Fluid viscosity control range is 104-105The viscosity of mPa.s, releasing layer and adhesion layer water-based emulsion is different, it is ensured that by when thermal transfer not
It can interpenetrate.
(2) heat transfer colour ribbon of the invention produces the volatilization of organic solvent-free in drying process, production process peace in coating
Atoxic, it is environmentally safe, while adopting water as medium and being greatly reduced production cost.
(3) heat transfer colour ribbon of the invention disclosure satisfy that printing speed of the near side (ns) printer to various art papers and plastics,
Print speed is fast, and the high resolution of pattern and word, trace are clear after printing, at the same adhesion strength of the trace between medium it is strong,
Wear-resisting scratch-resistant effect is good, and ageing-resistant, corrosion resistance and good can preserve for a long time.
Specific implementation mode
The present invention is further described with reference to embodiment, embodiments of the present invention are not limited thereto.With
In lower embodiment, releasing layer emulsion viscosity ranging from 100-1000mPa.s, adhesion layer emulsion viscosity ranging from 104-105MPa.s,
Waterborne wax emulsion is brazil wax in the releasing layer and adhesion layer and candelila wax mass ratio is 7:3 water-borne wax breast Composite Milk
Liquid, dispersant are the Surfynol CT-136 purchased from Shanghai Sang Jing Chemical Co., Ltd.s, and levelling agent and antifoaming agent are purchased from upper
The Dynol 604 of Hai Sang wells Chemical Co., Ltd..Experimental method used in following embodiments is normal unless otherwise specified
The dosage of rule method, the component is in parts by weight.
Embodiment 1
20 parts of waterborne wax emulsion, 1 part of aqueous silica sol lotion, 1 part of dispersant and 78 parts of deionized water are mixed
Stirring, is uniformly dispersed, and releasing layer coating fluid is made；The drying tunnel temperature of gravure coater is set as 80 DEG C, by releasing layer coating fluid
By coating machine with 1g/m2Coating weight to be coated on heat-resisting back coating thickness be to be carried on 4.5 μm of polyester film
The base material of releasing layer.
By 12 parts of aqueous EVA lotions, 2 parts of aqueous EEA lotions, 3 parts of aqueous rosin milk, 5 parts of water-borne wax breast
Liquid, 6 parts of carbon black, 0.7 part of dispersant, 1 part of levelling agent, 0.3 part of antifoaming agent and 70 parts of deionized water are mixed,
It is uniformly dispersed, is ground to 5 μm of fineness or less；The drying tunnel temperature of gravure coater is set as 75 DEG C, releasing layer coating fluid is passed through
Coating machine is with 1g/m2Coating weight be coated on the base material for coating releasing layer, obtain the heat transfer colour ribbon printed near side (ns).
Embodiment 2
20 parts of waterborne wax emulsion, 1 part of aqueous silica sol lotion, 1 part of dispersant and 78 parts of deionized water are mixed
Stirring, is uniformly dispersed, and releasing layer coating fluid is made；The drying tunnel temperature of gravure coater is set as 80 DEG C, by releasing layer coating fluid
By coating machine with 1g/m2Coating weight to be coated on heat-resisting back coating thickness be to be carried on 4.5 μm of polyester film
The base material of releasing layer.
By 10 parts of aqueous EVA lotions, 2 parts of aqueous EEA lotions, 2 parts of waterborne polyester lotion, 2 parts of aqueous poly- ammonia
Ester lotion, 6 parts of waterborne wax emulsion, 6 parts of carbon black, 0.7 part of dispersant, 1 part of levelling agent, 0.3 part of antifoaming agent and 70
The deionized water of part is mixed, and is uniformly dispersed, is ground to 5 μm of fineness or less；The drying tunnel temperature of gravure coater is set as 75
DEG C, by releasing layer coating fluid by coating machine with 1g/m2Coating weight be coated on the base material for coating releasing layer, obtain for close
The heat transfer colour ribbon of side printing.
Embodiment 3
20 parts of waterborne wax emulsion, 1 part of aqueous silica sol lotion, 1 part of dispersant and 78 parts of deionized water are mixed
Stirring, is uniformly dispersed, and releasing layer coating fluid is made；The drying tunnel temperature of gravure coater is set as 80 DEG C, by releasing layer coating fluid
By coating machine with 1g/m2Coating weight to be coated on heat-resisting back coating thickness be to be carried on 4.5 μm of polyester film
The base material of releasing layer.
By 10 parts of aqueous EVA lotions, 2 parts of aqueous EEA lotions, 2 parts of aqueous acrylic emulsion, 2 parts aqueous poly-
Urethane lotion, 6 parts of waterborne wax emulsion, 6 parts of carbon black, 0.7 part of dispersant, 1 part of levelling agent, 0.3 part of antifoaming agent and
70 parts of deionized water is mixed, and is uniformly dispersed, is ground to 5 μm of fineness or less；Set the drying tunnel temperature of gravure coater as
75 DEG C, by releasing layer coating fluid by coating machine with 1g/m2Coating weight be coated on the base material for coating releasing layer, be used for
The heat transfer colour ribbon of near side (ns) printing.
Embodiment 4
20 parts of waterborne wax emulsion, 1 part of aqueous silica sol lotion, 1 part of dispersant and 78 parts of deionized water are mixed
Stirring, is uniformly dispersed, and releasing layer coating fluid is made；The drying tunnel temperature of gravure coater is set as 80 DEG C, by releasing layer coating fluid
By coating machine with 1g/m2Coating weight to be coated on heat-resisting back coating thickness be to be carried on 4.5 μm of polyester film
The base material of releasing layer.
By 10 parts of aqueous EVA lotions, 1 part of aqueous EEA lotions, 1 part of aqueous acrylic emulsion, 2 parts aqueous poly-
Ester lotion, 3 parts of aqueous rosin milk, 5 parts of waterborne wax emulsion, 6 parts of carbon black, 0.7 part of dispersant, 1 part of levelling agent,
0.3 part of antifoaming agent and 70 parts of deionized water are mixed, and are uniformly dispersed, are ground to 5 μm of fineness or less；Set intaglio plate coating
The drying tunnel temperature of machine is 75 DEG C, by releasing layer coating fluid by coating machine with 1g/m2Coating weight be coated on and coat releasing layer
On base material, the heat transfer colour ribbon printed near side (ns) is obtained.
Embodiment 5
Waterborne wax emulsion in releasing layer and adhesion layer is substituted for etc. to the brazil wax of quality, remaining is same as Example 4.
Embodiment 6
Waterborne wax emulsion in releasing layer and adhesion layer is substituted for etc. to the candelila wax of quality, remaining and 4 phase of embodiment
Together.
1 heat transfer colour ribbon printing effect of the present invention of test example is tested
The heat transfer colour ribbon that respectively prepared by Example 1-6, English is printed with thermal transfer printer on 70g art papers
Arial fonts " F " (16 font sizes, 12 font sizes, 10 font sizes) and the Chinese Song typeface " type " (12 font size), the trace of character after observation printing
Clarity, test result are shown in Table 1.
A 70g art papers are covered on the trace of above-mentioned art paper respectively, then put 500g's on art paper
Standard test weight, at the uniform velocity drags copy paper, the number that record trace drags when being wiped paste back and forth on trace, and test result is shown in Table 1.
1 heat transfer colour ribbon of the present invention of table prints trace clarity and erasibility test result
| Test group | Trace clarity | Trace erasibility |
| Embodiment 1 | It is very clear | 71 times |
| Embodiment 2 | It is very clear | 66 times |
| Embodiment 3 | It is very clear | 68 times |
| Embodiment 4 | It is very clear | 78 times |
| Embodiment 5 | It is more visible | 55 times |
| Embodiment 6 | It is more visible | 52 times |
As shown in Table 1, the trace using heat transfer colour ribbon printable character of the present invention is clear, and color and luster is without mutation, sharp outline,
Without apparent stain, trace erasibility is good, and indices meet the standard of heat transfer colour ribbon general specification.
Above example is the description of the invention, but it is not limited to protection scope of the present invention, any to be familiar with being somebody's turn to do
The technical staff of item technology should all belong to the present invention in the change and retouching done without departing from the spirit and scope of the invention
Protection domain.
Claims (8)
1. a kind of heat transfer colour ribbon near side (ns) printing, which includes releasing layer, adhesion layer and hypothallus；It is described
Releasing layer includes waterborne wax emulsion, auxiliary agent and deionized water, and the adhesion layer includes resin aqueous emulsion, waterborne wax emulsion, nothing
Machine pigment, auxiliary agent and deionized water；It is characterized in that：The all aqueous breasts of lotion used in the releasing layer and adhesion layer
Liquid does not add any organic solvent；The viscosity of the releasing layer and adhesion layer lotion is different, and when transfer will not interpenetrate, institute
It is 100-1000mPa.s to state releasing layer emulsion viscosity, and the adhesion layer emulsion viscosity is 104-105mPa.s。
2. heat transfer colour ribbon according to claim 1, which is characterized in that the hypothallus is to be coated with gathering for heat-resisting back coating
Ester film, thickness are 3-10 μm.
3. heat transfer colour ribbon according to claim 1, which is characterized in that the weight proportion of the release layer component is aqueous
Wax emulsion 10%-20%, auxiliary agent 1%-5%, deionized water 70%-80%.
4. heat transfer colour ribbon according to claim 1, which is characterized in that the weight proportion of the adherency layer component is aqueous
Resin emulsion 10%-20%, waterborne wax emulsion 5%-10%, inorganic pigment 5%-10%, auxiliary agent 1%-5%, deionized water 50-
70%.
5. heat transfer colour ribbon according to claim 1, which is characterized in that waterborne wax emulsion in the releasing layer and adhesion layer
Selected from aqueous Brazilian wax emulsion, the aqueous compound wax emulsion of aqueous candelila wax lotion or brazil wax and candelila wax.
6. heat transfer colour ribbon according to claim 1, which is characterized in that auxiliary agent is selected from water in the releasing layer and adhesion layer
It is one or more in property silica gel lotion, dispersant, levelling agent, antifoaming agent.
7. heat transfer colour ribbon according to claim 1, which is characterized in that resin aqueous emulsion is selected from water in the adhesion layer
Property EVA resin lotion, aqueous EEA resin emulsions, aqueous polyurethane emulsion, water polyacrylic acid lotion, waterborne polyester lotion,
It is one or more in aqueous rosin milk, water-base epoxy alkane lotion.
8. a kind of preparation method of any one of claim 1-7 heat transfer colour ribbons, which is characterized in that include the following steps：
A, waterborne wax emulsion, auxiliary agent and deionized water are uniformly dispersed, adjust viscosity, releasing layer lotion is made；
B, by releasing layer emulsion coating on hypothallus；
C, resin aqueous emulsion, waterborne wax emulsion, inorganic pigment, auxiliary agent and deionized water are uniformly dispersed, are ground, adjusted viscous
Degree, is made adhesion layer lotion；
D, adhesion layer emulsion coating is obtained into heat transfer colour ribbon on the hypothallus for having coated releasing layer.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610777158.9A CN106381063B (en) | 2016-08-30 | 2016-08-30 | A kind of heat transfer colour ribbon and preparation method thereof near side (ns) printing |
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| CN201610777158.9A CN106381063B (en) | 2016-08-30 | 2016-08-30 | A kind of heat transfer colour ribbon and preparation method thereof near side (ns) printing |
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| CN106381063B true CN106381063B (en) | 2018-10-30 |
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| CN107603335B (en) * | 2017-10-30 | 2020-11-03 | 李炽仁 | Preparation method of environment-friendly nontoxic water-based pyrograph material |
| CN110370835A (en) * | 2019-01-21 | 2019-10-25 | 湖南鼎一致远科技发展有限公司 | Heat transfer printing carbon tape and preparation method thereof |
| CN110423553B (en) * | 2019-08-30 | 2021-09-14 | 深圳市联星服装辅料有限公司 | Heat transfer printing metal zipper cloth belt coating liquid, heat transfer printing metal zipper and preparation method thereof |
| CN113025233A (en) * | 2021-04-13 | 2021-06-25 | 海南必凯水性新材料有限公司 | Water-based low-temperature heat transfer adhesive and preparation method thereof |
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| CN106381063A (en) | 2017-02-08 |
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