CN106381063A - Thermal transfer ribbon used for proximal margin printing and production method thereof - Google Patents
Thermal transfer ribbon used for proximal margin printing and production method thereof Download PDFInfo
- Publication number
- CN106381063A CN106381063A CN201610777158.9A CN201610777158A CN106381063A CN 106381063 A CN106381063 A CN 106381063A CN 201610777158 A CN201610777158 A CN 201610777158A CN 106381063 A CN106381063 A CN 106381063A
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- CN
- China
- Prior art keywords
- emulsion
- aqueous
- heat transfer
- releasing layer
- adhesion layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D191/00—Coating compositions based on oils, fats or waxes; Coating compositions based on derivatives thereof
- C09D191/06—Waxes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41J—TYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
- B41J31/00—Ink ribbons; Renovating or testing ink ribbons
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D123/00—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers
- C09D123/02—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
- C09D123/04—Homopolymers or copolymers of ethene
- C09D123/08—Copolymers of ethene
- C09D123/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
- C09D123/0853—Vinylacetate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses a thermal transfer ribbon used for proximal margin printing and a production method thereof. The thermal transfer ribbon comprises a releasing layer, an adhesive coating and a matrix layer; the releasing layer comprises an aqueous wax emulsion, an auxiliary agent and deionized water, the adhesive coating comprises an aqueous resin emulsion, the aqueous wax emulsion, inorganic pigment, an auxiliary agent and deionized water; the emulsions used in the releasing layer and the adhesive coating are aqueous emulsions, an organic solvent is not added; viscosity of the releasing layer and the adhesive coating are different, and cannot be mutually penetrated while transfer printing. The thermal transfer ribbon can realize rapid printing for a proximal margin printer, the printed characters and images are clear, and the wear resistant and scratch resistant effects are good.
Description
Technical field
The present invention relates to thermal transfer field is and in particular to a kind of aqueous heat transfer colour ribbon near side (ns) printing.
Background technology
Thermal transfer printer is divided into flat-crushing type printer and side crush type printer, and flat-crushing type prints relatively, and side pressure type prints
Speed is fast, save colour band, and side crush type printer print speed is up to 600mm/s, and flat-crushing type printer speed can only achieve
300mm/s.Because print speed is relatively fast one times, side crush type printer is widely used in the factory of various Large-scale Manufacturings
Use.
Side crush type printer ink ribbon peace crush type printer ink ribbon is not general, currently used for side crush type printer
The colour band printing is mostly dicyandiamide solution, and dicyandiamide solution can use toluene, dimethylbenzene, butanone, methyl in use in a large number
The organic solvent such as isobutyl ketone and ethers, in coating dry run, these organic solvents volatilize in a large number, not only cause the wave of material
Take, the increase of cost;Meanwhile, solvent volatilization is also easy to initiation fire in atmosphere, causes potential safety hazard;A large amount of solvents can be dealt into
In the air, causes Workshop Production bad environments, and impact workman's is healthy;Additionally, these organic solvents are diffused in the air
Will also result in air pollution.Because solvent-borne type colour band has numerous shortcomings, the colour band of water-based system is increasingly subject to everybody weight
Depending on.
Although the colour band currently used for side crush type printer also has and takes water-based system, most of colour bands turn after printing
Print is not complete, and trace is unintelligible, poor effect under transformation printer printing speed, concludes its reason, essentially consists in presently used
The single coating that mostly adopts of transformation colour band, single coating be difficult to meet release temperature low and after printing print pattern intensity high
Requirement;Minority adopts double-coated colour band, but does not have control release layer different with the viscosity of adhesion layer, due to releasing layer with
The viscosity differences of adhesion layer are too little, lead to releasing layer and ink layer to mix in thermal histories, and pattern transfer is not complete, print
Mark effect is poor.
Content of the invention
For solving the problems, such as prior art, the scheme that the present invention is taken is:A kind of heat near side (ns) printing turns
Red ink paste used for seals band, this heat transfer colour ribbon includes releasing layer, adhesion layer and hypothallus;Described releasing layer include aqueous wax emulsion, auxiliary agent and
Deionized water, described adhesion layer includes resin aqueous emulsion, aqueous wax emulsion, inorganic pigment, auxiliary agent and deionized water;Described release
Put all water-based emulsions of emulsion used in layer and adhesion layer, without any organic solvent;Described releasing layer and adhesion layer
The viscosity of emulsion is different, will not interpenetrate during transfer.
Resin aqueous emulsion of the present invention is selected from aqueous EVA resin emulsion, aqueous EEA resin emulsion, aqueous polyurethane
One of emulsion, water polyacrylic acid emulsion, waterborne polyester emulsion, aqueous rosin milk, water-base epoxy alkane emulsion or
Multiple, preferably aqueous EVA resin emulsion, aqueous EEA resin emulsion, water polyacrylic acid emulsion, waterborne polyester emulsion, water
One or more of property rosin milk.
Aqueous wax emulsion of the present invention includes aqueous Brazil wax emulsion, aqueous candelila wax emulsion or brazil wax and little candle
The aqueous complex emulsions of the aqueous compound wax emulsion of vegetable wax, preferably brazil wax and candelila wax, particularly preferably brazil wax and
Candelila wax mass ratio is 7:3 water-borne wax breast complex emulsions.
Of the present invention release layer component weight proportion be aqueous wax emulsion 10%-20%, auxiliary agent 1%-5%, go from
Sub- water 70%-80%.
The weight proportion of adhesion layer component of the present invention is resin aqueous emulsion 10%-20%, aqueous wax emulsion 5%-
10%, inorganic pigment 5%-10%, auxiliary agent 1%-5%, deionized water 50%-70%.
Inorganic pigment of the present invention is carbon black, and auxiliary agent is selected from aqueous silica sol emulsion, dispersant, levelling agent, defoamer
One or more of.
Hypothallus of the present invention is to scribble heat-resisting coated polyester film, and thickness is 3-10 μm, and preferred thickness is 4-6
μm.
The releasing layer of heat transfer colour ribbon of the present invention is different with the viscosity of adhesion layer, and releasing layer emulsion viscosity is about 100-
1000mPa.s, adhesion layer emulsion viscosity is about 104-105mPa.s.
Present invention also offers a kind of preparation method of the heat transfer colour ribbon near side (ns) printing, comprise the following steps:
A, aqueous wax emulsion, auxiliary agent and deionized water are uniformly dispersed, adjust viscosity, make releasing layer emulsion;
B, by releasing layer emulsion coating on hypothallus;
C, resin aqueous emulsion, aqueous wax emulsion, inorganic pigment, auxiliary agent and deionized water are uniformly dispersed, grind, adjust
Viscosity, makes adhesion layer emulsion;
D, by adhesion layer emulsion coating on the hypothallus coating releasing layer, obtain heat transfer colour ribbon.
The polished fineness of adhesion layer emulsion of the present invention is less than 5 μm, and temperature is less than 30 DEG C it is therefore an objective to when making coating
Flour milling is more uniform, fine and smooth, and during printing, pattern becomes apparent from.
When heat transfer colour ribbon of the present invention is dried, temperature is 70-80 DEG C, and releasing layer coating weight is 0.8-1.2g/m2,
Adhesion layer coating weight is 1.0-1.5g/m2, total coating weight is 1.5-2.0g/m2.
Compared to the prior art, the present invention has the following advantages:
(1) coating process that the heat transfer colour ribbon of the present invention is separately coated with using releasing layer and adhesion layer, and propose and release
Put the viscosity control range of layer and adhesion layer, wherein releasing layer emulsion viscosity control range is 100-1000mPa.s, adhesion layer breast
Fluid viscosity control range is 104-105MPa.s, releasing layer different with the viscosity of adhesion layer water-based emulsion it is ensured that by thermal transfer when not
Can interpenetrate.
(2) heat transfer colour ribbon of the present invention produces the volatilization of organic solvent-free in dry run in coating, and production process is pacified
Atoxic, environmentally safe, adopt water as medium simultaneously and be greatly reduced production cost.
(3) heat transfer colour ribbon of the present invention disclosure satisfy that the printing speed to various art papers and plastics for the near side (ns) printer,
Print speed is fast, and after printing, the high resolution of pattern and word, trace are clear, simultaneously adhesion between medium for the trace strong,
Wear-resisting scratch-resistant effect is good, and ageing-resistant, corrosion resistance and good can preserve for a long time.
Specific embodiment
With reference to embodiment, the present invention is further described, but embodiments of the present invention not limited to this.With
In lower embodiment, releasing layer emulsion viscosity scope is 100-1000mPa.s, and adhesion layer emulsion viscosity scope is 104-105MPa.s,
In described releasing layer and adhesion layer, aqueous wax emulsion is brazil wax and candelila wax mass ratio is 7:3 water-borne wax breast Composite Milk
Liquid, dispersant is the Surfynol CT-136 purchased from Shanghai Sang Jing Chemical Co., Ltd., and levelling agent and defoamer are purchased from upper
The Dynol 604 of Hai Sang well Chemical Co., Ltd..Experimental technique used in following embodiments if no special instructions, is often
Rule method, the consumption of described component is in parts by weight.
Embodiment 1
Deionized water mixing by 20 parts of aqueous wax emulsion, 1 part of aqueous silica sol emulsion, 1 part of dispersant and 78 parts
Stirring, is uniformly dispersed, prepared releasing layer coating fluid;The drying tunnel temperature setting gravure coater as 80 DEG C, by releasing layer coating fluid
By coating machine with 1g/m2Coating weight to coat with heat-resisting back coating thickness be on 4.5 μm of polyester film, carried
The base material of releasing layer.
By 12 parts of aqueous EVA emulsion, 2 parts of aqueous EEA emulsion, 3 parts of aqueous rosin milk, 5 parts water-borne wax breast
The deionized water mix and blend of liquid, 6 parts of carbon black, 0.7 part of dispersant, 1 part of levelling agent, 0.3 part of defoamer and 70 parts,
It is uniformly dispersed, be ground to below 5 μm of fineness;The drying tunnel temperature setting gravure coater, as 75 DEG C, releasing layer coating fluid is passed through
Coating machine is with 1g/m2Coating weight coat on the base material coating releasing layer, obtain near side (ns) print heat transfer colour ribbon.
Embodiment 2
Deionized water mixing by 20 parts of aqueous wax emulsion, 1 part of aqueous silica sol emulsion, 1 part of dispersant and 78 parts
Stirring, is uniformly dispersed, prepared releasing layer coating fluid;The drying tunnel temperature setting gravure coater as 80 DEG C, by releasing layer coating fluid
By coating machine with 1g/m2Coating weight to coat with heat-resisting back coating thickness be on 4.5 μm of polyester film, carried
The base material of releasing layer.
By 10 parts of aqueous EVA emulsion, 2 parts of aqueous EEA emulsion, 2 parts of waterborne polyester emulsion, 2 parts of aqueous poly- ammonia
Ester emulsion, 6 parts of aqueous wax emulsion, 6 parts of carbon black, 0.7 part of dispersant, 1 part of levelling agent, 0.3 part of defoamer and 70
The deionized water mix and blend of part, is uniformly dispersed, is ground to below 5 μm of fineness;Set the drying tunnel temperature of gravure coater as 75
DEG C, releasing layer coating fluid is passed through coating machine with 1g/m2Coating weight coat on the base material coating releasing layer, obtain near
The heat transfer colour ribbon that side prints.
Embodiment 3
Deionized water mixing by 20 parts of aqueous wax emulsion, 1 part of aqueous silica sol emulsion, 1 part of dispersant and 78 parts
Stirring, is uniformly dispersed, prepared releasing layer coating fluid;The drying tunnel temperature setting gravure coater as 80 DEG C, by releasing layer coating fluid
By coating machine with 1g/m2Coating weight to coat with heat-resisting back coating thickness be on 4.5 μm of polyester film, carried
The base material of releasing layer.
By 10 parts of aqueous EVA emulsion, 2 parts of aqueous EEA emulsion, 2 parts of aqueous acrylic emulsion, 2 parts aqueous poly-
Urethane emulsion, 6 parts of aqueous wax emulsion, 6 parts of carbon black, 0.7 part of dispersant, 1 part of levelling agent, 0.3 part of defoamer and
70 parts of deionized water mix and blend, is uniformly dispersed, and is ground to below 5 μm of fineness;Set the drying tunnel temperature of gravure coater as
75 DEG C, releasing layer coating fluid is passed through coating machine with 1g/m2Coating weight coat on the base material coating releasing layer, obtain for
The heat transfer colour ribbon that near side (ns) prints.
Embodiment 4
Deionized water mixing by 20 parts of aqueous wax emulsion, 1 part of aqueous silica sol emulsion, 1 part of dispersant and 78 parts
Stirring, is uniformly dispersed, prepared releasing layer coating fluid;The drying tunnel temperature setting gravure coater as 80 DEG C, by releasing layer coating fluid
By coating machine with 1g/m2Coating weight to coat with heat-resisting back coating thickness be on 4.5 μm of polyester film, carried
The base material of releasing layer.
By 10 parts of aqueous EVA emulsion, 1 part of aqueous EEA emulsion, 1 part of aqueous acrylic emulsion, 2 parts aqueous poly-
Ester emulsion, 3 parts of aqueous rosin milk, 5 parts of aqueous wax emulsion, 6 parts of carbon black, 0.7 part of dispersant, 1 part of levelling agent,
The deionized water mix and blend of 0.3 part of defoamer and 70 parts, is uniformly dispersed, is ground to below 5 μm of fineness;Set intaglio plate coating
The drying tunnel temperature of machine is 75 DEG C, and releasing layer coating fluid is passed through coating machine with 1g/m2Coating weight coat and coat releasing layer
On base material, obtain the heat transfer colour ribbon printing near side (ns).
Embodiment 5
Aqueous wax emulsion in releasing layer and adhesion layer is substituted for etc. the brazil wax of quality, remaining is same as Example 4.
Embodiment 6
Aqueous wax emulsion in releasing layer and adhesion layer is substituted for etc. the candelila wax of quality, remaining and embodiment 4 phase
With.
Test example 1 heat transfer colour ribbon printing effect of the present invention is tested
The heat transfer colour ribbon of Example 1-6 preparation, prints English with thermal transfer printer on 70g art paper respectively
Arial font " F " (16 font sizes, 12 font sizes, 10 font sizes) and the Chinese Song typeface " type " (12 font size), observe the trace of character after printing
Definition, result of the test is shown in Table 1.
Cover a 70g art paper on the trace of above-mentioned art paper respectively, on art paper, then put a 500g's
Standard test weight, at the uniform velocity drags copy paper on trace back and forth, and record trace is shown in Table 1 by wiping the number of times dragging during paste, result of the test.
Table 1 heat transfer colour ribbon of the present invention prints trace definition and erasibility test result
Test group | Trace definition | Trace erasibility |
Embodiment 1 | Very clear | 71 times |
Embodiment 2 | Very clear | 66 times |
Embodiment 3 | Very clear | 68 times |
Embodiment 4 | Very clear | 78 times |
Embodiment 5 | More visible | 55 times |
Embodiment 6 | More visible | 52 times |
As shown in Table 1, the trace using heat transfer colour ribbon printable character of the present invention is clear, and color and luster is no mutated, sharp outline,
No obvious stain, trace erasibility is good, and indices all meet the standard of heat transfer colour ribbon general specification.
Above example is the description of the invention, but it is not limited to protection scope of the present invention, any be familiar with should
The technical staff of item technology, in the change done without departing from the spirit and scope of the invention and retouching, all should belong to the present invention
Protection domain.
Claims (9)
1. a kind of heat transfer colour ribbon near side (ns) printing, this heat transfer colour ribbon includes releasing layer, adhesion layer and hypothallus;Described
Releasing layer includes aqueous wax emulsion, auxiliary agent and deionized water, and described adhesion layer includes resin aqueous emulsion, aqueous wax emulsion, no
Machine pigment, auxiliary agent and deionized water;It is characterized in that:The all aqueous breasts of emulsion used in described releasing layer and adhesion layer
Liquid, without any organic solvent;Described releasing layer is different with the viscosity of adhesion layer emulsion, will not interpenetrate during transfer.
2. heat transfer colour ribbon according to claim 1 is it is characterised in that described hypothallus is to scribble gathering of heat-resisting back coating
Ester film, thickness is 3-10 μm.
3. heat transfer colour ribbon according to claim 1 is it is characterised in that the weight proportion of described release layer component is aqueous
Wax emulsion 10%-20%, auxiliary agent 1%-5%, deionized water 70%-80%.
4. heat transfer colour ribbon according to claim 1 is it is characterised in that the weight proportion of described adhesion layer component is aqueous
Resin emulsion 10%-20%, aqueous wax emulsion 5%-10%, inorganic pigment 5%-10%, auxiliary agent 1%-5%, deionized water
50%-70%.
5. heat transfer colour ribbon according to claim 1 is it is characterised in that described releasing layer emulsion viscosity is about 100-
1000mPa.s, described adhesion layer emulsion viscosity is about 104-105mPa.s.
6. heat transfer colour ribbon according to claim 1 is it is characterised in that aqueous wax emulsion in described releasing layer and adhesion layer
Aqueous compound wax emulsion selected from aqueous Brazil wax emulsion, aqueous candelila wax emulsion or brazil wax and candelila wax.
7. heat transfer colour ribbon according to claim 1 is it is characterised in that auxiliary agent is selected from water in described releasing layer and adhesion layer
One or more of property silica gel emulsion, dispersant, levelling agent, defoamer.
8. heat transfer colour ribbon according to claim 1 is it is characterised in that resin aqueous emulsion is selected from water in described adhesion layer
Property EVA resin emulsion, aqueous EEA resin emulsion, aqueous polyurethane emulsion, water polyacrylic acid emulsion, waterborne polyester emulsion,
One or more of aqueous rosin milk, water-base epoxy alkane emulsion.
9. the preparation method of heat transfer colour ribbon described in a kind of any one of claim 1-8 is it is characterised in that comprise the following steps:
A, aqueous wax emulsion, auxiliary agent and deionized water are uniformly dispersed, adjust viscosity, make releasing layer emulsion;
B, by releasing layer emulsion coating on hypothallus;
C, resin aqueous emulsion, aqueous wax emulsion, inorganic pigment, auxiliary agent and deionized water are uniformly dispersed, grind, adjust viscous
Degree, makes adhesion layer emulsion;
D, by adhesion layer emulsion coating on the hypothallus coating releasing layer, obtain heat transfer colour ribbon.
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CN201610777158.9A CN106381063B (en) | 2016-08-30 | 2016-08-30 | A kind of heat transfer colour ribbon and preparation method thereof near side (ns) printing |
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CN201610777158.9A CN106381063B (en) | 2016-08-30 | 2016-08-30 | A kind of heat transfer colour ribbon and preparation method thereof near side (ns) printing |
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Cited By (4)
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CN107603335A (en) * | 2017-10-30 | 2018-01-19 | 李炽仁 | A kind of environment-protecting and non-poisonous water-based xylopyrography material and preparation method thereof |
CN110370835A (en) * | 2019-01-21 | 2019-10-25 | 湖南鼎一致远科技发展有限公司 | Heat transfer printing carbon tape and preparation method thereof |
CN110423553A (en) * | 2019-08-30 | 2019-11-08 | 深圳市联星服装辅料有限公司 | A kind of thermal transfer metal zip fastener strap coating solution, thermal transfer metal zip fastener and preparation method thereof |
WO2022217672A1 (en) * | 2021-04-13 | 2022-10-20 | 海南必凯水性新材料有限公司 | Water-based low-temperature heat transfer printing adhesive and preparation method therefor |
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CN110423553A (en) * | 2019-08-30 | 2019-11-08 | 深圳市联星服装辅料有限公司 | A kind of thermal transfer metal zip fastener strap coating solution, thermal transfer metal zip fastener and preparation method thereof |
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