CN102173234A - Water-based resin thermal transfer printing ribbon and preparation method thereof - Google Patents
Water-based resin thermal transfer printing ribbon and preparation method thereof Download PDFInfo
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- CN102173234A CN102173234A CN201110060622XA CN201110060622A CN102173234A CN 102173234 A CN102173234 A CN 102173234A CN 201110060622X A CN201110060622X A CN 201110060622XA CN 201110060622 A CN201110060622 A CN 201110060622A CN 102173234 A CN102173234 A CN 102173234A
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Abstract
The invention relates to a water-based resin thermal transfer printing ribbon and a preparation method thereof. The water-base resin thermal transfer printing ribbon comprises a support, one surface of the support is coated with an ink layer, the other surface of the support is coated with a heat-resisting back coating, and the ink layer comprises an adhesive agent, a coloring agent, fillers and accessory ingredients. The water-base resin thermal transfer printing ribbon is characterized in that the adhesive agent comprises an alkali soluble resin and one or more water-based resins or alkali soluble resins, and the solvents of the raw materials in the ink layer comprise water, a small amount of alkali compound solvents and alcohols solvents. The preparation method comprises the steps of: preparing a resin mixed liquid; preparing an ink coating liquid by using the resin mixed liquid; and coating the ink coating liquid after the concentration thereof is adjusted on the support. The water-based resin thermal transfer printing ribbon has the advantages of good image quality, excellent abrasion resistance, resistance to chemicals, such as gasoline, machine oil, and the like, and good medium adaptability. The preparation method of the water-based resin thermal transfer printing ribbon has simple process and is clean and environmental friendly, and the prepared thermal transfer ribbon has superior performance.
Description
Technical field
The present invention relates to a kind of heat transfer colour ribbon, particularly a kind of have chemicals such as excellent in resistance scraping and anti-gasoline, machine oil and the outstanding adaptive water-base resin base of medium heat transfer colour ribbon and preparation method thereof.
Background technology
Heat transfer colour ribbon is that essential consumable material is printed in hot transfer printing, also is the core material of decision thermal transfer imaging quality.The heat transfer colour ribbon of selling on the market can be divided into cerul, wax and mixed with resin base, pure resin-based three major types according to composition now.The cerul colour band contains the cerul raw material of high percentage usually, and is cheap, is mainly used in the printing of low-grade paper substrates.Wax/tree mixed base colour band generally contains the resinous principle raw material of high percentage, scratch resistant property of the figure that prints and anti-chemical corrosivity are also better than the cerul, cost performance is higher relatively, have endurance quality concurrently, most widely used at present, but also there is shortcoming in it aspect hear resistance, wearability, corrosion resistance and the printing definition.The resin-based colour band contains the most a high proportion of resinous principle, and the energy level that printing needs is also than cerul and mixed base height, because most resins is harder than wax, the resin of high-load makes this colour band have fabulous anti-scratch and resistance to chemical corrosion.
Compare with the heat transfer colour ribbon of mixed with resin base with cerul, wax, the main feature of resin-based heat transfer colour ribbon is to print clearly, has remarkable image scratch-resistant, anti-ly smears, high temperature resistant, chemical proofing, can satisfy various severe rugged environment requirements.Mainly be applicable to the PET(polyester), the PVC(polyvinyl chloride), the BOPP(polypropylene), the PE(polyethylene), the PS(polystyrene) etc. the high-grade label of plastic sheeting class base material.
Present most resin-based heat transfer colour ribbon is solvent-borne type, as the patent No. is 200510008696.3, patent name discloses a kind of solvent type resin base heat transfer colour ribbon and preparation method thereof in the Chinese patent of " a kind of heat transfer colour ribbon and preparation method thereof ", adhesive in this thermal transfer-printing ink ribbon ink layer adopts two kinds or above resin, described resin employing " polyethylene; polypropylene ... or SBR styrene butadiene rubbers ", these resins all can only be dissolved in butanone, cyclohexanone, organic solvents such as ethyl acetate, therefore this heat transfer colour ribbon can discharge a large amount of organic solvents in process of production, environment is caused serious pollution, also jeopardize simultaneously producers' physical and mental health, on the other hand with an organic solvent with solvent recovery or burn the also corresponding cost that increases product.Along with the idea of environmental protection is rooted in the hearts of the people day by day, restriction volatile thing discharge capacity (VOC) has become rules in succession in various countries in recent years.From environmental protection, economize on resources, fire service law etc. is to the restriction of dangerous material, improves the viewpoint of working environment to set out, the restricted trend of the use of organic solvent strengthens.
Summary of the invention
Technical problem to be solved by this invention is to overcome deficiency of the prior art and a kind of water-base resin base heat transfer colour ribbon and preparation method thereof is provided, this water-base resin base heat transfer colour ribbon has the excellent images quality, excellent rub resistance and the wet goods of anti-gasoline engine chemicals and outstanding medium adaptability.Preparation method's technology of this water-base resin base heat transfer colour ribbon is simple, clean environment firendly, the carbon ribbon superior performance that obtains.
The technical scheme that the present invention solves the problems of the technologies described above employing is: this water-base resin base heat transfer colour ribbon, comprise support, one side at support scribbles ink lay, another side scribbles heat-resisting back coating, ink lay comprises adhesive, colouring agent, filler and auxiliary agent, it is characterized in that: described adhesive comprises a kind of alkali soluble resins and one or more water-base resin or alkali soluble resins, and the solvent of each raw material is water, a spot of alkali compounds solvent and alcohols solvent in the ink lay.
The parts by weight ratio of each component is in the ink lay of the present invention: 50 ~ 90 parts in adhesive, 10 ~ 30 parts of colouring agents, 1 ~ 10 part of filler, 1 ~ 10 part of auxiliary agent.
Water-base resin of the present invention is that the dispersible PVC of waterborne polyurethane resin, epoxy resin, styrene-propene yogurt liquid, ethene-vinyl acetate emulsion and water miscible polyvinylpyrrolidone, polyethylene alcohol and water sticks with paste resin etc.; Described alkali soluble resins is mylar, acrylic resin, EAA resin, casein, modified rosin resin etc.
Water-base resin of the present invention is preferably waterborne polyurethane resin, epoxy resin, polyvinylpyrrolidone, polyvinyl alcohol and PVC and sticks with paste resin etc., especially is preferably waterborne polyurethane resin, polyvinyl alcohol and PVC and sticks with paste resin.
Alkali soluble resins preferred polyester resin of the present invention, acrylic resin, EAA resin, casein, modified rosin resin etc. especially are preferably mylar, acrylic resin, casein, and more special preferred acid number is 8 ~ 100 mylar.
Alkali soluble resins of the present invention is to heat to dissolve self-emulsifying in the presence of alkali compounds and/or alcohols solvent in water, forms the alkali soluble resins dispersion liquid of homogeneous.Wherein alkali compounds comprises ammoniacal liquor, triethylamine, diethylamine, triethanolamine or diethanol amine, and alcohols solvent is ethanol or isopropyl alcohol.Self-emulsifying is meant that under alkali condition, alkali soluble resins does not need to add emulsifying agent, and part or all of its carboxyl is neutralized and produces hydrophilic ion group, thereby the mylar particulate can not be condensed and stably is dispersed in phenomenon in the water.
Colouring agent of the present invention is a carbon black, and filler is PE micro mist or micronized talc powder, and auxiliary agent is dispersant and defoamer.
The preparation method of water-base resin base heat transfer colour ribbon of the present invention is characterized in that may further comprise the steps:
A, alkali soluble resins is placed in the water that has added alkali compounds and/or alcohols solvent heating and dissolves self-emulsifying, obtain the alkali soluble resins dispersion liquid of homogeneous; Water-base resin is dissolved in obtains aqueous resin solution in the water; Then alkali soluble resins dispersion liquid and aqueous resin solution are mixed, obtain mass percent and be 10% ~ 30% resin mixture liquor;
B, resin mixture liquor, colouring agent, filler, auxiliary agent are mixed, disperse, grind and obtain the ink lay coating fluid;
C, water, alcohol are adjusted the viscosity of ink lay coating fluid, with the intaglio plate coating machine ink lay coating fluid are coated on the support, and the described support back side scribbles heat-resisting backing layer, obtain water-base resin base heat transfer colour ribbon.
It is the high-strength polyester film of 3 ~ 10um that support of the present invention adopts thickness.
The present invention includes support, coat the ink lay on support surface and the heat-resisting backing layer at the support back side, and be coated with the peel ply of one deck content of wax particularly preferably in support surface ink layer down.
Support can be films such as polyester, Merlon, polyimides, polyamide, polystyrene, polysulfones, polypropylene, polyethylene, cellulose acetate, and thickness is 3 ~ 10um, the support of preferred thickness 4 ~ 6um.The selection of support need be considered its comprehensive strength, heat resistance, ink adhesion etc., and being fit to the special preferred thickness of support of the present invention is the polyester film of 4.5um.
Ink lay is made up of adhesive, colouring agent, filler, auxiliary agent.The parts by weight of each component are in the wherein said ink lay: 50 ~ 90 parts in adhesive, 10 ~ 30 parts of colouring agents, 1 ~ 10 part of filler, 1 ~ 10 part of auxiliary agent.
At least contain a kind of alkali soluble resins in the adhesive among the present invention, all the other can adopt one or more water-base resin or alkali soluble resins, being fit to resin of the present invention can be mylar, polyurethane resin, acrylic resin, styrene-propene acid resin, EAA resin, ethylene-vinyl acetate resin, polyvinylpyrrolidone, polyvinyl alcohol, casein, modified rosin resin, PVC paste resin etc., special preferred bases soluble resin, epoxy resin, waterborne polyurethane resin.Wherein the alkali soluble resins preferred acid number is mylar, the acrylic resin of 8 ~ 100mgKOH/g.Acid number is lower than 8mgKOH/g, and then its dissolving self-emulsifying process is difficult, is difficult to obtain the fine water-borne dispersions of homogeneous; Acid number is higher than 100mgKOH/g, and then gained heat transfer image scratch-resistant solvent resistance is inferior.
Colouring agent in the ink lay plays painted effect, and colouring agent of the present invention is to use maximum carbon blacks at heat transfer colour ribbon.Auxiliary agent in the ink lay plays the booster action of regulating ink performance, is fit to auxiliary agent of the present invention and comprises aqueous dispersion, defoamer etc.Filler in the ink lay plays a part to improve some performance of colour band, and being fit to filler of the present invention is micronized talc powder, PE micro mist, PP micro mist etc., plays a part to improve scratch-resistant, reduce cost.
Among the above-mentioned preparation method, solvent for use is water, alcohol or isopropyl alcohol, alkali compounds.Wherein alkali compounds comprises ammoniacal liquor, triethylamine, diethylamine, triethanolamine, diethanol amine etc.In coating process, the viscosity of ink lay coating fluid can be adjusted by water, alcohol.
The present invention compared with prior art has the following advantages: the water-base resin base thermal transfer ribbon that adopts preparation method of the present invention to produce is adapted at film class label surface and prints, and the image of printing and literal have very high resolution ratio; Have high adhesion between trace and the recording medium, rub resistance, damage resistant can not fog because of friction.High temperature resistant, ageing-resistant, anti-solvent, corrosion-resistant simultaneously can be applicable to many occasions that specific (special) requirements arranged and long preservation.
The specific embodiment
Embodiment 1
With acid number is that 70 parts in 20 mylar and ammoniacal liquor, isopropyl alcohol add in the entry according to the ratio of 4:1:1, is heated to 85 ℃, makes percentage by weight and be 15% ~ 30% alkali soluble resins dispersion liquid.Add 5 parts of poly-vinyl alcohol solutions again, obtain percentage by weight and be 10% ~ 30% resin mixture liquor.Add 5 parts of PE micro mists then, 20 parts of carbon blacks carry out dispersion grinding, obtain the ink lay coating fluid.The ink lay coating fluid is passed through the intaglio plate coating machine with 2g/m
2Coating weight coat on the polyester film of 4.5um thickness that the back side scribbles heat-resisting backing layer, obtain thermal transfer ribbon.
Embodiment 2
With acid number is that 23 parts in 75 mylar and acid number are that 20 46 parts in mylar and ammoniacal liquor, ethanol add in the entry according to the ratio of 4:1:1, is heated to 85 ℃, makes percentage by weight and be 15% ~ 30% alkali soluble resins dispersion liquid; Add 6 parts of PVC again and stick with paste resin, obtaining percentage by weight is 10% ~ 30% resin mixture liquor.Add 5 parts of PE micro mists then, 20 parts of carbon blacks carry out dispersion grinding, obtain the ink lay coating fluid.The ink lay coating fluid is passed through the intaglio plate coating machine with 2g/m
2Coating weight coat on the polyester film of 4.5um thickness that the back side scribbles heat-resisting backing layer, obtain thermal transfer ribbon.
Embodiment 3
With acid number is that 60 parts in 65 mylar and ammoniacal liquor, ethanol add in the entry according to the ratio of 4:1:1, is heated to 85 ℃, makes percentage by weight and be 15% ~ 30% alkali soluble resins dispersion liquid; Add 5 parts of waterborne polyurethane resin solution again, obtain percetage by weight and be 10% ~ 30% resin mixture liquor.Add 5 parts of PE micro mists, 5 parts of superfine talcum powders, 20 parts of carbon blacks then and carry out dispersion grinding, obtain the ink lay coating fluid.The ink lay coating fluid is passed through the intaglio plate coating machine with 2g/m
2Coating weight coat on the polyester film of 4.5um thickness that the back side scribbles heat-resisting backing layer, obtain thermal transfer ribbon.
Embodiment 4
With acid number is that 55 parts in 75 mylar and ammoniacal liquor, ethanol add in the entry according to the ratio of 4:1:1, is heated to 85 ℃, makes percentage by weight and be 15% ~ 30% alkali soluble resins dispersion liquid; 20 parts of alkaline soluble acrylic resin and ammoniacal liquor are heated to 85 ℃ according to the ratio of 4:1, obtain percentage by weight and be 15% ~ 35% alkali soluble resins emulsion; Two kinds of resin emulsions are mixed to such an extent that percentage by weight is 10% ~ 30% resin mixture liquor again.Add 5 parts of PE micro mists then, 20 parts of carbon blacks carry out dispersion grinding, obtain the ink lay coating fluid.The ink lay coating fluid is passed through the intaglio plate coating machine with 2g/m
2Coating weight coat on the polyester film of 4.5um thickness that the back side scribbles heat-resisting backing layer, obtain thermal transfer ribbon.
Though the present invention with embodiment openly as above; but it is not in order to limit protection scope of the present invention; any technical staff who is familiar with this technology, change and the retouching done in not breaking away from design of the present invention and scope all should belong to protection scope of the present invention.
Claims (9)
1. water-base resin base heat transfer colour ribbon, comprise support, one side at support scribbles ink lay, another side scribbles heat-resisting back coating, ink lay comprises adhesive, colouring agent, filler and auxiliary agent, it is characterized in that: described adhesive comprises a kind of alkali soluble resins and one or more water-base resin or alkali soluble resins, and the solvent of each raw material is water, alkali compounds solvent and alcohols solvent in the ink lay.
2. water-base resin base heat transfer colour ribbon according to claim 1 is characterized in that: the parts by weight ratio of each component is in the described ink lay: 50 ~ 90 parts in adhesive, 10 ~ 30 parts of colouring agents, 1 ~ 10 part of filler, 1 ~ 10 part of auxiliary agent.
3. water-base resin base heat transfer colour ribbon according to claim 1 is characterized in that: described water-base resin is that the dispersible PVC of waterborne polyurethane resin, epoxy resin, styrene-propene yogurt liquid, ethene-vinyl acetate emulsion, water miscible polyvinylpyrrolidone, water miscible polyvinyl alcohol or water sticks with paste resin; Described alkali soluble resins is mylar, acrylic resin, EAA resin, casein or modified rosin resin.
4. water-base resin base heat transfer colour ribbon according to claim 3, it is characterized in that: described water-base resin is preferably the dispersible PVC of waterborne polyurethane resin, epoxy resin, water miscible polyvinylpyrrolidone, water miscible polyvinyl alcohol or water and sticks with paste resin, especially is preferably the dispersible PVC of waterborne polyurethane resin, water miscible polyvinyl alcohol or water and sticks with paste resin.
5. water-base resin base heat transfer colour ribbon according to claim 3, it is characterized in that: described alkali soluble resins is preferably mylar, acrylic resin, EAA resin, casein or modified rosin resin, especially be preferably mylar, acrylic resin or casein, more special preferred acid number is 8 ~ 100 mylar.
6. according to claim 1,3 or 5 described water-base resin base heat transfer colour ribbons, it is characterized in that: described alkali soluble resins is to heat in water in the presence of alkali compounds and/or alcohols solvent, dissolve self-emulsifying, form the fine alkali soluble resins dispersion liquid of homogeneous, wherein alkali compounds comprises ammoniacal liquor, triethylamine, diethylamine, triethanolamine or diethanol amine, and alcohols solvent is ethanol or isopropyl alcohol.
7. water-base resin base heat transfer colour ribbon according to claim 2 is characterized in that: described colouring agent is a carbon black, and filler is PE micro mist or micronized talc powder, and auxiliary agent is dispersant and defoamer.
8. according to the preparation method of claim 1,2 or 3 described water-base resin base heat transfer colour ribbons, it is characterized in that may further comprise the steps:
A, alkali soluble resins is placed in the water that has added alkali compounds and/or alcohols solvent heating and dissolves self-emulsifying, obtain the fine alkali soluble resins dispersion liquid of homogeneous; Water-base resin is dissolved in obtains aqueous resin solution in the water; Then alkali soluble resins dispersion liquid and aqueous resin solution are mixed, obtain mass percent and be 10% ~ 30% resin mixture liquor;
B, resin mixture liquor, colouring agent, filler, auxiliary agent are mixed, disperse, grind and obtain the ink lay coating fluid;
C, water, alcohol are adjusted the viscosity of ink lay coating fluid, with the intaglio plate coating machine ink lay coating fluid are coated on the support, and the described support back side scribbles heat-resisting backing layer, obtain water-base resin base heat transfer colour ribbon.
9. the preparation method of water-base resin base heat transfer colour ribbon according to claim 8 is characterized in that: it is the high-strength polyester film of 3 ~ 10um that described support adopts thickness.
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