CN102189852A - Multi-layer thermal transfer ribbon and manufacturing method thereof - Google Patents
Multi-layer thermal transfer ribbon and manufacturing method thereof Download PDFInfo
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- CN102189852A CN102189852A CN2011100829143A CN201110082914A CN102189852A CN 102189852 A CN102189852 A CN 102189852A CN 2011100829143 A CN2011100829143 A CN 2011100829143A CN 201110082914 A CN201110082914 A CN 201110082914A CN 102189852 A CN102189852 A CN 102189852A
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Abstract
The invention relates to a multi-layer thermal transfer ribbon and a manufacturing method thereof, and the multi-layer thermal transfer ribbon comprises a membranous base band, a heat-resistant printing ink layer and a heat transfer printing ink layer, wherein the heat-resistant printing ink layer is coated on one side of the base band, the heat transfer printing ink layer is coated on the other side of the base band, the heat transfer printing ink layer comprises a stripping printing ink layer and an adhesive printing ink layer, the stripping printing ink layer is directly coated on the surface of the base band, the adhesive printing ink layer is coated on the stripping printing ink layer, printing ink in the striping printing ink layer is hot-melting type printing ink, and the printing ink in the adhesive printing ink layer is the hot-melting type printing ink or solvent type printing ink. The heat transfer printing ink layer of the multi-layer mixed-based ribbon can be easily completely stripped off the base band, and the great adhesive ability is realized on a smooth medium; in addition, the multi-layer thermal transfer ribbon further has the advantages of high resolution, clear printing, anti-friction property, moisture resistance, chemical corrosion resistance, environment friendliness and the like.
Description
Technical field
The present invention relates to a kind of heat transfer printing carbon tape, particularly a kind of multilayer heat transfer printing carbon tape and preparation method thereof.
Background technology
In the information society arrival of economic globalization, information networking, life internationalization, cultural territoryization, originate from the forties, studied, popularize bar code and barcode technology, resemble a rule economic information tie all over the world producer, exporter, whole seller, retailer and client are organically linked together the eighties the sixties, the seventies of being applied to.Along with the development of computer technology and thermal transfer printer, the application of barcode ribbon has also obtained development rapidly, and progressively is penetrated in many technical fields.
It is that Mille invented in nineteen fifty-three that heat shifts formation method, as a kind of computer peripheral equipment output equipment of contactless printing, has become the very high class special printer of occupation rate of market.Its image-forming principle is that the computer output signal drives the electrothermal semiconductor head, the thermal transfer-printing ink ribbon ink fusion is transferred to is subjected to the picture medium, forms the process of writings and image.
The heat transfer colour ribbon product that can simply be divided three classes:
The cerul colour band: contain the cerul raw material (ratio of wax is greater than 65%) of high percentage usually, because the fusing point of wax is generally far below resin, and most wax is softer than resin, and the durability of cerul colour band printing curve is not as mixed base and resin-based.The cerul colour band has the characteristics of high density, high sensitivity usually, is applied to paper labels, and printing effect is good, cost economy, and most cerul colour band has only one deck coating.
Wax/mixed with resin primary colours band: the resinous principle raw material (ratio of resin is between 30%-50%) that generally contains high percentage, the fusing point of such colour band is higher, hardness is bigger, the scratch resistant property and the anti-chemical corrosivity of the figure of printing are also good than cerul colour band, the mixed base colour band has letter quality printing effect and endurance quality concurrently, be widely used, valency is imitated all good.
Resin-based colour band: contain a high proportion of resinous principle, it prints required energy level than the former two's height, its hardness is also quite maximum, tool durability, rub resistance, performance such as heat-resisting, corrosion-resistant, some prescription energy vapor-proof pressure, some then can be through washing or dry-cleaning, compares the highlyest with the first two class but print cost, and medium adaptability is the poorest.
The mixed base bar code carbon ribbon of world's main flow all adopts the solvent-borne type coating method, its solvent that adopts is generally organic solvents such as gasoline, toluene, dimethylbenzene, ethyl acetate, butyl acetate, butanone and cyclohexanone, health to the producer causes very big threat, also environment is caused certain pollution.
At present, its coating of most product on the market has only the hot transfer ink layer of one deck, the such problem of normal appearance in print procedure, be that printing ink on the carbon ribbon can not break away from base band well and be attached to print media, and the cohesive of printing ink and print media is also bad, the figure of being printed is easily destroyed because of external force, this is because ink lay both need possess the superperformance of peeling off from base band, need possess superperformance again with the print media bonding, this the two very difficult realization in one, its production technology is also more complicated.In addition, the not scratch resistance of ink lay that existing product exists and also comprise with the generation reason of the problem of smooth media attachment power difference: the content of resin is low excessively in its component, and the too high levels of wax, and the straight-chain hydrocarbons content of employed wax is lower, its hardness is less, ink lay integral hardness and viscosity do not reach instructions for use, cause not scratch resistance of trace, resistance to acids and bases poor.
For this reason, we provide a kind of ink lay easily to peel off in base band and with the multilayer heat transfer printing carbon tape of the strong scratch resistance of smooth media attachment power to be very important to address the above problem.
Summary of the invention
The objective of the invention is to overcome the deficiencies in the prior art, a kind of multilayer heat transfer printing carbon tape and preparation method thereof is provided, to strengthen that the carbon belt printing ink layer is peeled off baseband capability, anti-scratch ability and the adhesive force of smooth medium.
The present invention adopts following technical scheme:
A kind of multilayer heat transfer printing carbon tape, it comprises base band, heat-resistant inks layer and the hot transfer ink layer that is membranaceous, the heat-resistant inks layer is coated on the one side of base band, hot transfer ink layer is coated on the another side of base band, it is characterized in that: described hot transfer ink layer is formed with the bonding ink lay by peeling off ink lay, it is peeled off ink lay and directly is coated on described base band surface, the bonding ink lay is coated on to be peeled off on the ink lay, and peeling off ink lay printing ink is heat molten type printing ink, and bonding ink lay printing ink is heat molten type printing ink or solvent type ink.
Further, above-mentioned heat-resistant inks layer printing ink comprises the main material and an amount of xylene solvent of 107 silica gel 85-95%, containing hydrogen silicone oil 3-4.5%, curing agent 1.5-3%, promoter 0.5-1.5% composition by weight percentage, and the solid content of this main material is 1-5%.
The above-mentioned ink lay printing ink of peeling off is made of following component by weight percentage: Wax 30-70%, resin 20-40%, auxiliary agent 0.5-5%, colouring agent 10-30%.
Further, the above-mentioned ink lay printing ink of peeling off can be made of following component by weight percentage: brazil wax 40%, synthetic wax 20%, polyamide 15%, Petropols 10%, dispersant 2%, carbon black 13%.
The above-mentioned ink lay printing ink of peeling off also can be made of following component by weight percentage: brazil wax 30%, synthetic wax 30%, EVA resin 15%, Petropols 10%, carbon black 13%, dispersant 2%.
Above-mentioned bonding ink lay printing ink is heat molten type printing ink, and it is made of following component by weight percentage: wax class 20-40%, resin 45-65%, colouring agent 5-15%, auxiliary agent 0.5-5%; Described resin is thermoplastics type's solid resin, its fusing point is 60-130 ℃, and described resin is one or more in polyethylene, polyvinyl chloride, polyvinyl acetate, polypropylene, ethylene-vinyl acetate copolymer, epoxy resin, polyamide, polyketone resin, polystyrene, SBS, SIS, chlorination EVA, terpene resin, Petropols, PVA, mylar or the vinyl chloride-vinyl acetate resin.
Above-mentioned bonding ink lay printing ink is made of following component by weight percentage: brazil wax 25%, synthetic wax 15%, polyamide 30%, terpene resin 20%, carbon black 9%, dispersant 1%.
Above-mentioned bonding ink lay printing ink is solvent type ink, and it is made of resin, solvent, auxiliary agent and colouring agent; Described resin is thermoplastics type's solid resin, its fusing point is 60-130 ℃, and described resin is one or more in polyethylene, polyvinyl chloride, polyvinyl acetate, polypropylene, ethylene-vinyl acetate copolymer, epoxy resin, polyamide, polyketone resin, polystyrene, SBS, SIS, chlorination EVA, terpene resin, Petropols, PVA, mylar or the vinyl chloride-vinyl acetate resin.
Above-mentioned bonding ink lay printing ink is made of following component by weight percentage: EVA resin 5%, terpene resin 15%, dimethylbenzene 40%, butanone 25%, carbon black 13%, dispersant 2%.
A kind of multilayer heat transfer printing carbon tape preparation method may further comprise the steps:
A. prepare base band: choose thickness and be the 4.5-5.0 micron without the sided corona treatment biaxially oriented polyester film as base band;
B. prepare heat-resistant inks layer printing ink: 107 silica gel, containing hydrogen silicone oil, curing agent and the promoter that take by weighing weight portion according to said ratio; 107 silica gel are dissolved fully in dimethylbenzene, add containing hydrogen silicone oil, curing agent, promoter more successively, stir, wherein, the solid content of main materials such as 107 silica gel, containing hydrogen silicone oil, curing agent and promoter is 1-5%; Pass through the drying tunnel baking and curing again, make heat-resistant inks layer printing ink;
C. ink lay printing ink is peeled off in preparation: the Wax, resin, auxiliary agent, the colouring agent that take by weighing weight portion according to said ratio; Wax and resin are fully mixed under the situation of heat fused, re-use the basket grinding machine and itself and colouring agent, auxiliary agent are fully mixed to make peel off ink lay printing ink;
D. prepare bonding ink lay printing ink: the wax class, resin, colouring agent, the auxiliary agent that take by weighing weight portion according to said ratio; Wax and resin are fully mixed under the situation of heat fused, re-use the basket grinding machine with itself and colouring agent, auxiliary agent fully mixes makes bonding ink lay printing ink;
E. last, adopt intaglio printing with the one side of above-mentioned heat-resistant inks layer ink coats in base band, its coating weight is every square metre of 0.1-1 gram, forms the heat-resistant inks layer; Adopt intaglio printing with the above-mentioned another side of peeling off the ink lay ink coats in base band again, its coating weight is every square metre of 0.5-2.2 gram, forms and peels off ink lay; At last, on the surface of peeling off ink lay, every square metre of 0.5-2.0 gram of its coating weight forms the bonding ink lay with above-mentioned bonding ink lay ink coats in the employing intaglio printing.
By above-mentioned description to structure of the present invention as can be known, compare with prior art, the present invention has following advantage: the hot transfer ink layer of the multilayer mixed base carbon ribbon that the present invention obtains is by peeling off ink lay and the bonding ink lay is formed; Directly being coated in base band, lip-deep to peel off ink lay hardness big, and hot transfer ink layer stripping performance is good during printing, guarantees that hot transfer ink layer can increase substantially trace scratch resistance, acid and alkali-resistance anticorrosive property simultaneously from complete peeling off on the base band; Bonding ink lay caking property is good, makes to have enough cohesives between trace and the print media, makes hot transfer ink layer possess adhesive ability well on smooth medium.Comprehensively above-mentioned, the invention provides multilayer mixed base carbon ribbon and possess the resolution ratio height, print advantages such as clear, friction resistant, moisture resistance are wet, resist chemical, environmental protection.
Description of drawings
Fig. 1 is the structural representation of multilayer heat transfer printing carbon tape provided by the invention.
The specific embodiment
The specific embodiment of the present invention is described with reference to the accompanying drawings.
With reference to Fig. 1, a kind of multilayer heat transfer printing carbon tape, this multilayer heat transfer printing carbon tape comprises that by thickness be the base band 1 that the biaxially oriented polyester film without sided corona treatment of 4.5-5.0 micron is made, and heat-resistant inks layer 2 is coated on the one side of base band 1, and hot transfer ink layer 3 is coated on the another side of base band 1.In order to make the image that prints on the medium keep permanent definition, just necessarily require ink lay both to peel off again from base band 1 easily and sufficiently high adhesion strength is arranged with print media, for this reason, this hot transfer ink layer 3 is formed with bonding ink lay 32 by peeling off ink lay 31, peeling off ink lay 31 directly is coated on the surface of base band 1, bonding ink lay 32 is coated on to be peeled off on the ink lay 31, and peeling off ink lay 31 printing ink is heat molten type printing ink, and bonding ink lay 32 is heat molten type printing ink or solvent type ink.
Above-mentioned heat-resistant inks layer 2 comprises main material and an amount of xylene solvents such as 107 silica gel 85-95%, containing hydrogen silicone oil 3-4.5%, curing agent 1.5-3%, promoter 0.5-1.5% by weight percentage, and the solid content of this main material is 1-5%.This heat-resistant inks layer 2 mainly plays antistatic, soaking and reduces friction, and can protect printhead, prolongs the service life of printhead.
The above-mentioned ink lay 31 of peeling off is made of following component by weight percentage: Wax 30-70%, resin 20-40%, auxiliary agent 0.5-5%, colouring agent 10-30%.
The bonding ink lay 32 of above-mentioned heat molten type is made of following component by weight percentage: wax class 20-40%, resin 45-65%, colouring agent 5-15%, auxiliary agent 0.5-5%.Above-mentioned solvent type bonding ink lay 32 is made of resin, solvent, auxiliary agent and colouring agent.Resin in heat molten type or solvent type bonding ink lay 32 printing ink is thermoplastics type's solid resin, its fusing point is 60-130 ℃, and this resin can be chosen any one kind of them from polyethylene, polyvinyl chloride, polyvinyl acetate, polypropylene, ethylene-vinyl acetate copolymer, epoxy resin, polyamide, polyketone resin and polystyrene, SBS, SIS, chlorination EVA, terpene resin, Petropols, PVA, mylar or vinyl chloride-vinyl acetate resin or be multiple.
More specifically, above-mentioned preparation of peeling off ink lay 31 can be adopted one of following four schemes, and whole recipe ingredient quality is 100 parts in the scheme, and scheme is as follows:
Scheme 1:, add 13 parts of carbon blacks and 2 parts dispersant use basket grinding machine grinding and the back that is uniformly dispersed again and use earlier with 40 parts brazil wax, 20 parts synthetic wax, polyamide and 10 parts of Petropols heat fused of 15 parts.
Scheme 2:, add 13 parts of carbon blacks and 2 parts dispersant use basket grinding machine grinding and the back that is uniformly dispersed again and use earlier with 40 parts brazil wax, 20 parts synthetic wax, polyamide and 10 parts of terpene resin heat fused of 15 parts.
Scheme: 3:, add 13 parts of carbon blacks and 2 parts dispersant use basket grinding machine grinding and the back that is uniformly dispersed again and use earlier with 30 parts brazil wax, 30 parts synthetic wax, EVA resin and 10 parts of Petropols heat fused of 15 parts.
Scheme 4:, add 13 parts of carbon blacks and 2 parts dispersant use basket grinding machine grinding and the back that is uniformly dispersed again and use earlier with 30 parts brazil wax, 30 parts synthetic wax, EVA resin and 10 parts of terpene resin heat fused of 15 parts.
In addition, the preparation of above-mentioned bonding ink lay 32 can be adopted one of following six schemes particularly, and whole recipe ingredient quality is 100 parts in the scheme, and scheme is as follows:
Scheme 1:, add 9 parts of carbon blacks and 1 part dispersant use basket grinding machine grinding and the back that is uniformly dispersed again and use earlier with 25 parts brazil wax, 15 parts synthetic wax, polyamide and 20 parts of terpene resin heat fused of 30 parts.
Scheme 2:, add 9 parts of carbon blacks and 1 part dispersant use basket grinding machine grinding and the back that is uniformly dispersed again and use earlier with 25 parts brazil wax, 15 parts synthetic wax, polyamide and 20 parts of Petropols heat fused of 30 parts.
Scheme 3: earlier with 10 parts of polyamides, 10 parts Petropols, 40 parts of dimethylbenzene, 25 parts of isopropyl alcohols, 13 parts of carbon blacks, 2 parts of dispersants are made printing ink and are used after three-roller grinds.
Scheme 4: earlier with 10 parts of polyamides, 10 parts terpene resin, 40 parts of dimethylbenzene, 25 parts of isopropyl alcohols, 13 parts of carbon blacks, 2 parts of dispersants are made printing ink and are used after three-roller grinds.
Scheme 5: earlier with 5 parts of EVA resins, 15 parts terpene resin, 40 parts of dimethylbenzene, 25 parts of butanone, 13 parts of carbon blacks, 2 parts of dispersants are made printing ink and are used after three-roller grinds.
Scheme 6: earlier with 5 parts of SBS resins, 15 parts terpene resin, 25 parts of dimethylbenzene, 40 parts of butanone, 13 parts of carbon blacks, 2 parts of dispersants are made printing ink and are used after three-roller grinds.
The preparation method of above-mentioned multilayer heat transfer printing carbon tape may further comprise the steps:
A. prepare base band: choose thickness and be the 4.5-5.0 micron without the sided corona treatment biaxially oriented polyester film as base band 1;
B. prepare heat-resistant inks layer 2 printing ink: 107 silica gel, containing hydrogen silicone oil, curing agent and the promoter that take by weighing weight portion according to said ratio; 107 silica gel are dissolved fully in dimethylbenzene, add containing hydrogen silicone oil, curing agent, promoter more successively, stir, wherein, the solid content of main materials such as 107 silica gel, containing hydrogen silicone oil, curing agent and promoter is 1-5%; Pass through the drying tunnel baking and curing again, make heat-resistant inks layer 2 printing ink;
C. ink lay 31 printing ink are peeled off in preparation: the Wax, resin, auxiliary agent, the colouring agent that take by weighing weight portion according to said ratio; Wax and resin are fully mixed under the situation of heat fused, re-use the basket grinding machine and itself and colouring agent, auxiliary agent are fully mixed to make peel off ink lay 31 printing ink;
D. prepare bonding ink lay 32 printing ink: the wax class, resin, colouring agent, the auxiliary agent that take by weighing weight portion according to said ratio; Wax and resin are fully mixed under the situation of heat fused, re-use the basket grinding machine with itself and colouring agent, auxiliary agent fully mixes makes bonding ink lay 32 printing ink;
E. last, adopt intaglio printing with the one side of above-mentioned heat-resistant inks layer 2 ink coats in base band 1, its coating weight is every square metre of 0.1-1 gram, forms heat-resistant inks layer 2; Adopt intaglio printing with the above-mentioned another side of peeling off ink lay 31 ink coats in base band 1 again, its coating weight is every square metre of 0.5-2.2 gram, forms and peels off ink lay 31; At last, on the surface of peeling off ink lay 31, every square metre of 0.5-2.0 gram of its coating weight forms bonding ink lay 32 with above-mentioned bonding ink lay 32 ink coats in the employing intaglio printing.
Above-mentioned only is the specific embodiment of the present invention, but design concept of the present invention is not limited thereto, and allly utilizes this design that the present invention is carried out the change of unsubstantiality, all should belong to the behavior of invading protection domain of the present invention.
Claims (10)
1. multilayer heat transfer printing carbon tape, it comprises base band, heat-resistant inks layer and the hot transfer ink layer that is membranaceous, the heat-resistant inks layer is coated on the one side of base band, hot transfer ink layer is coated on the another side of base band, it is characterized in that: described hot transfer ink layer is formed with the bonding ink lay by peeling off ink lay, it is peeled off ink lay and directly is coated on described base band surface, the bonding ink lay is coated on to be peeled off on the ink lay, and peeling off ink lay printing ink is heat molten type printing ink, and bonding ink lay printing ink is heat molten type printing ink or solvent type ink.
2. a kind of multilayer heat transfer printing carbon tape as claimed in claim 1, it is characterized in that: described heat-resistant inks layer printing ink comprises the main material and an amount of xylene solvent of 107 silica gel 85-95%, containing hydrogen silicone oil 3-4.5%, curing agent 1.5-3%, promoter 0.5-1.5% composition by weight percentage, and the solid content of this main material is 1-5%.
3. a kind of multilayer heat transfer printing carbon tape as claimed in claim 1 is characterized in that: the described ink lay printing ink of peeling off is made of following component by weight percentage: Wax 30-70%, resin 20-40%, auxiliary agent 0.5-5%, colouring agent 10-30%.
4. a kind of multilayer heat transfer printing carbon tape as claimed in claim 3 is characterized in that: the described ink lay printing ink of peeling off is made of following component by weight percentage: brazil wax 40%, synthetic wax 20%, polyamide 15%, Petropols 10%, dispersant 2%, carbon black 13%.
5. a kind of multilayer heat transfer printing carbon tape as claimed in claim 3 is characterized in that: the described ink lay printing ink of peeling off is made of following component by weight percentage: brazil wax 30%, synthetic wax 30%, EVA resin 15%, Petropols 10%, carbon black 13%, dispersant 2%.
6. a kind of multilayer heat transfer printing carbon tape as claimed in claim 1, it is characterized in that: described bonding ink lay printing ink is heat molten type printing ink, and it is made of following component by weight percentage: wax class 20-40%, resin 45-65%, colouring agent 5-15%, auxiliary agent 0.5-5%; Described resin is thermoplastics type's solid resin, its fusing point is 60-130 ℃, and described resin is one or more in polyethylene, polyvinyl chloride, polyvinyl acetate, polypropylene, ethylene-vinyl acetate copolymer, epoxy resin, polyamide, polyketone resin, polystyrene, SBS, SIS, chlorination EVA, terpene resin, Petropols, PVA, mylar or the vinyl chloride-vinyl acetate resin.
7. a kind of multilayer heat transfer printing carbon tape as claimed in claim 6 is characterized in that: described bonding ink lay printing ink is made of following component by weight percentage: brazil wax 25%, synthetic wax 15%, polyamide 30%, terpene resin 20%, carbon black 9%, dispersant 1%.
8. a kind of multilayer heat transfer printing carbon tape as claimed in claim 1 is characterized in that: the solvent type ink of described bonding ink lay printing ink for being made by resin, solvent, auxiliary agent and colouring agent; Described resin is thermoplastics type's solid resin, its fusing point is 60-130 ℃, and described resin is one or more in polyethylene, polyvinyl chloride, polyvinyl acetate, polypropylene, ethylene-vinyl acetate copolymer, epoxy resin, polyamide, polyketone resin, polystyrene, SBS, SIS, chlorination EVA, terpene resin, Petropols, PVA, mylar or the vinyl chloride-vinyl acetate resin.
9. a kind of multilayer heat transfer printing carbon tape as claimed in claim 8 is characterized in that: described bonding ink lay printing ink is made of following component by weight percentage: EVA resin 5%, terpene resin 15%, dimethylbenzene 40%, butanone 25%, carbon black 13%, dispersant 2%.
10. multilayer heat transfer printing carbon tape preparation method may further comprise the steps:
A. prepare base band: choose thickness and be the 4.5-5.0 micron without the sided corona treatment biaxially oriented polyester film as base band;
B. prepare heat-resistant inks layer printing ink: 107 silica gel, containing hydrogen silicone oil, curing agent and the promoter that take by weighing weight portion according to said ratio; 107 silica gel are dissolved fully in dimethylbenzene, add containing hydrogen silicone oil, curing agent, promoter more successively, stir, wherein, the solid content of main materials such as 107 silica gel, containing hydrogen silicone oil, curing agent and promoter is 1-5%; Pass through the drying tunnel baking and curing again, make heat-resistant inks layer printing ink;
C. ink lay printing ink is peeled off in preparation: the Wax, resin, auxiliary agent, the colouring agent that take by weighing weight portion according to said ratio; Wax and resin are fully mixed under the situation of heat fused, re-use the basket grinding machine and itself and colouring agent, auxiliary agent are fully mixed to make peel off ink lay printing ink;
D. prepare bonding ink lay printing ink: the wax class, resin, colouring agent, the auxiliary agent that take by weighing weight portion according to said ratio; Wax and resin are fully mixed under the situation of heat fused, re-use the basket grinding machine with itself and colouring agent, auxiliary agent fully mixes makes bonding ink lay printing ink;
E. last, adopt intaglio printing with the one side of above-mentioned heat-resistant inks layer ink coats in base band, its coating weight is every square metre of 0.1-1 gram, forms the heat-resistant inks layer; Adopt intaglio printing with the above-mentioned another side of peeling off the ink lay ink coats in base band again, its coating weight is every square metre of 0.5-2.2 gram, forms and peels off ink lay; At last, on the surface of peeling off ink lay, every square metre of 0.5-2.0 gram of its coating weight forms the bonding ink lay with above-mentioned bonding ink lay ink coats in the employing intaglio printing.
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Application publication date: 20110921 |