CN111662592A - Antistatic flame-retardant thermal transfer printing ink for carbon ribbon and preparation method thereof - Google Patents
Antistatic flame-retardant thermal transfer printing ink for carbon ribbon and preparation method thereof Download PDFInfo
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- CN111662592A CN111662592A CN202010686418.8A CN202010686418A CN111662592A CN 111662592 A CN111662592 A CN 111662592A CN 202010686418 A CN202010686418 A CN 202010686418A CN 111662592 A CN111662592 A CN 111662592A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
- C09D11/103—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds of aldehydes, e.g. phenol-formaldehyde resins
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
- C09D11/104—Polyesters
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
- C09D11/38—Inkjet printing inks characterised by non-macromolecular additives other than solvents, pigments or dyes
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/52—Electrically conductive inks
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
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- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Thermal Transfer Or Thermal Recording In General (AREA)
Abstract
The invention relates to ink for an antistatic flame-retardant thermal transfer ribbon, which is characterized by comprising the following raw materials in percentage by weight: 10-30% of resin binder, 5-10% of pigment, 0-5% of filler, 0.1-1% of dispersing agent, 1-5% of antistatic agent, 5-10% of flame retardant and 50-70% of solvent. The carbon ribbon is prepared by coating the ink on a substrate, so that the conductive capability and the flame retardant property of the thermal transfer carbon ribbon can be obviously improved, static electricity generated in the practical application process is effectively eliminated, and potential safety hazards are avoided.
Description
Technical Field
The invention belongs to the technical field of ink formulas, and particularly relates to ink for an antistatic flame-retardant thermal transfer ribbon and a preparation method thereof.
Background
In the middle of the twentieth century, with the rapid development of industrial production and the rapid popularization and application of polymer materials, the thermal transfer ribbon rapidly occupies a place in the printing industry due to the wide substrate adaptability, wide application range, clear printing and the like. Thermal transfer ribbons generally use polyethylene terephthalate (PET) as a base film on which ink is applied to meet various application requirements. However, static electricity is easily generated in the conventional processes of rolling, slitting and the like of the carbon tape, and during the application process, the damage of the printing head is easily caused by the static electricity discharge, and even a fire disaster is caused. Safety accidents due to static electricity are common.
In the precision coating industry, due to various serious consequences caused by static electricity, static electricity eliminating devices matched with static brushes, static electricity ropes, static electricity rods and the like are formed for years, but the static electricity eliminating devices can only eliminate the static electricity formed in the winding and unwinding processes in the coating process and cannot eliminate the static electricity generated in the practical application process, so research and development of carbon belts suitable for the practical production requirements are urgently needed.
Disclosure of Invention
The invention aims to overcome the defects of the prior art, and provides the antistatic flame-retardant ink for the thermal transfer ribbon, which is coated on a substrate to prepare the thermal transfer ribbon, so that the conductive capability and the flame retardant property of the thermal transfer ribbon can be obviously improved, static electricity generated in the practical application process is effectively eliminated, and potential safety hazards are avoided.
The invention also provides a preparation method of the ink for the antistatic flame-retardant thermal transfer ribbon, which adopts a one-time coating mode, reduces the production cost and the influence on equipment and environment, and has the advantages of simple method conditions, simple and convenient operation and easy industrial popularization and use.
In order to achieve the purpose, the invention adopts the following technical scheme:
the antistatic flame-retardant thermal transfer printing ink for the carbon ribbon comprises the following raw materials in percentage by weight: 10-30% of resin binder, 5-10% of pigment, 0-5% of filler, 0.1-1% of dispersing agent, 1-5% of antistatic agent, 5-10% of flame retardant and 50-70% of solvent. The ink layer thickness is required to be 1 to 2 μm.
Specifically, the flame retardant is one or a mixture of more than two of polyborosiloxane, benzoxazine and tri (xylene) phosphate (TXP).
Specifically, the resin binder is one or a mixture of more than two of polyester resin, polyacrylic resin, phenolic resin, petroleum resin, terpene resin, rosin resin and polyurethane resin.
Specifically, the pigment is black, purple, blue, red, yellow, green or gray, and the like.
Specifically, the filler is one or a combination of talcum powder, fumed silica and kaolin.
Specifically, the dispersing agent is one or a mixture of more than two of BYK111, BYK-AT204 and BYK-104S.
Further, the solvent is one or a mixture of more than two of toluene, butanone, absolute ethyl alcohol, ethyl acetate and isopropanol.
The invention also provides a preparation method of the ink for the antistatic flame-retardant thermal transfer ribbon, which comprises the following steps:
1) weighing the components in proportion, uniformly mixing the resin binder, the solvent and the flame retardant, heating to 80-100 ℃ to fully dissolve the resin, and cooling to room temperature to obtain a flame-retardant resin solution;
2) adding pigment, filler and dispersant into the flame-retardant resin solution obtained in the step 1), and uniformly grinding to obtain flame-retardant ink;
3) and (3) adding an antistatic agent into the flame-retardant ink obtained in the step 2), and uniformly stirring to obtain the antistatic flame-retardant thermal transfer ribbon ink. The antistatic flame-retardant ink can be coated on a PET substrate to be made into a carbon ribbon for use.
In the method for preparing the antistatic flame-retardant ink, a material melting kettle and a sand mill are required in the ink preparation process, and the material melting time is generally 1-3 h.
Compared with the prior art, the invention has the following beneficial effects:
1) the flame retardant polyborosiloxane, benzoxazine, tri (xylene) phosphate (TXP) and the antistatic agent added in the ink obviously improve the conductive capability and the flame retardant property of the thermal transfer ribbon;
2) the preparation method of the antistatic flame-retardant ink adopts a one-time coating mode, reduces the production cost and the influence on equipment and environment, has simple preparation method conditions, is simple and convenient to operate, and is easy to industrially popularize and use;
3) according to the invention, the flame-retardant material and the resin binder are mutually soluble, and other raw materials are ground and dispersed into a mutually soluble resin system, so that the antistatic and flame-retardant performances of the carbon ribbon are improved, and the scratch resistance and the alcohol resistance after transfer printing are increased. In addition, the prepared ink is uniformly dispersed, and the whole system is uniform and stable.
Detailed Description
The technical solution of the present invention is further described in detail with reference to the following examples, but the scope of the present invention is not limited thereto.
In the following examples, the selected raw material information is as follows:
polyester resin, korean SK group ES420, a proxy of kagao, kaoya chemical technology ltd;
petroleum resin, product TN120 of luteger shanghai trade ltd, germany;
polyacrylic acid resin, Guangzhou City communications commercial and trade Co., Ltd, DSM Dismann NeoCryl B-814;
phenolic resin, tin-free gmyo adhesive materials ltd 2123 phenolic;
terpene resin, tin-free carbene chemical plant BN-5 terpene resin;
dispersant, product of bike chemical china ltd;
antistatic agents, available from JWPS02, from wuxi megaplastizium materials ltd;
talcum powder, YF818, a Jiangsu Yifeng powder raw material Limited company;
the flame retardant selected from polycarboborane methyl siloxane Dexsil300, DCPD type benzoxazine and tri (xylene) phosphate (TXP) are all common commercial products.
Example 1
The antistatic flame-retardant thermal transfer printing ink for the carbon ribbon comprises the following raw materials in parts by weight: 4 parts of polyester resin, 3 parts of petroleum resin, 3 parts of polyacrylic resin, 5 parts of pigment carbon black, 5 parts of filler talcum powder, 5 parts of dispersant BYK 1110.7, 1 part of antistatic agent, 1 part of flame retardant Dexsi 30010, 48.3 parts of butanone and 20 parts of toluene.
The preparation method of the antistatic flame-retardant thermal transfer printing ink for the carbon ribbon specifically comprises the following steps:
1) weighing the components in proportion, adding resin binders (polyester resin, petroleum resin and polyacrylic resin), butanone and toluene as solvents and Dexsi l300 as a flame retardant into a material kettle, uniformly mixing, heating to 80-100 ℃ for full dissolution, and cooling to room temperature to obtain a flame-retardant resin solution;
2) adding pigment carbon black, filler talcum powder and a dispersant BYK111 into the flame-retardant resin solution obtained in the step 1), and uniformly grinding by using a sand mill to obtain flame-retardant ink;
3) and (3) adding an antistatic agent into the flame-retardant ink obtained in the step 2), and uniformly stirring to obtain the antistatic flame-retardant thermal transfer ribbon ink.
Comparative example 1
The ink formulation differs from example 1 in that: no antistatic agent and flame retardant Dexsi l300 were added, the solvent was used to make up to 100%.
Example 2
The antistatic flame-retardant thermal transfer printing ink for the carbon ribbon comprises the following raw materials in parts by weight: 13 parts of polyester resin, 8 parts of petroleum resin, 9 parts of polyacrylic resin, 10 parts of carbon black, 1 part of kaolin, 1 part of dispersant BYK-AT 2040.3 parts, 1 part of antistatic agent, 5 parts of tri (xylene) phosphate (TXP), 32.7 parts of butanone, 17 parts of toluene and 3 parts of absolute ethyl alcohol.
The preparation method of the antistatic flame-retardant thermal transfer ribbon ink is as described in example 1.
Comparative example 2
The ink formulation differs from example 2 in that: the antistatic and flame retardant TXP was not added, the solvent was used to make up to 100%.
Example 3
The antistatic flame-retardant thermal transfer printing ink for the carbon ribbon comprises the following raw materials in parts by weight: 10 parts of polyester resin, 13 parts of petroleum resin, 7 parts of polyacrylic resin, 10 parts of carbon black, 0.5 part of BYK 1110.5 parts of dispersant BYK-104S, 1 part of antistatic agent, 3 parts of DCPD type benzoxazine, 2 parts of tri (xylene) phosphate (TXP), 33 parts of butanone and 20 parts of toluene.
The preparation method of the antistatic flame-retardant thermal transfer ribbon ink is as described in example 1.
Comparative example 3
The ink formulation differs from example 3 in that: without adding antistatic agent, flame retardant TXP and DCPD type benzoxazine, the solvent is used to complement to 100 percent.
Example 4
The antistatic flame-retardant thermal transfer printing ink for the carbon ribbon comprises the following raw materials in parts by weight: 8 parts of polyester resin; 5 parts of phenolic resin, 5 parts of polyacrylic resin, 5 parts of carbon black, 1 part of fumed silica, 5 parts of dispersant BYK-AT 2040.1, 1 part of antistatic agent, 5 parts of DCPD type benzoxazine, 59.9 parts of butanone and 10 parts of toluene.
The preparation method of the antistatic flame-retardant thermal transfer ribbon ink is as described in example 1.
Comparative example 4
The ink formulation differs from example 4 in that: the antistatic agent and DCPD-type benzoxazine were not added, and the solvent was used to make up to 100%.
Example 5
The antistatic flame-retardant thermal transfer printing ink for the carbon ribbon comprises the following raw materials in parts by weight: 11 parts of polyester resin; 5 parts of terpene resin, 3 parts of polyacrylic resin, 10 parts of carbon black, 2041 parts of dispersant BYK-AT, 5 parts of antistatic agent, 3 parts of DCPD type benzoxazine, 3003 parts of Dexsil, 49 parts of butanone and 10 parts of toluene.
The preparation method of the antistatic flame-retardant thermal transfer ribbon ink is as described in example 1.
Comparative example 5
The ink formulation differs from example 5 in that: no antistatic agent, flame retardant DCPD type benzoxazine and Dexsil300 were added, and the solvent was used to make up to 100%.
Performance test
Pretreatment of the PET substrate: and coating a release layer on the front surface of the PET substrate, and coating a back adhesive on the back surface of the PET substrate. The release layer adopts water-based Fischer-Tropsch wax slurry and is coated with 0.8-1 micron; the back coating is coated with 3% silicone modified acrylic resin 0.2-0.5 micron.
The antistatic flame-retardant ink prepared in each embodiment is coated on the surface of a release layer of a treated PET substrate through an anilox roller, and the coating thickness is 2 microns, so that the antistatic flame-retardant PET carbon belt is prepared. The carbon tapes prepared in the embodiments and the comparative examples are installed on a bar code printer, and the printed writing is clear and bright by selecting gears for printing.
The carbon ribbon is subjected to related performance tests such as surface resistance, limited oxygen index, combustion classification, alcohol resistance, wear resistance and the like, and test results are shown in table 1 below, wherein the antistatic performance is judged by the surface resistance, and the surface resistance is tested by a surface impedance tester ACL-800. The limit oxygen index is tested by an AH68019 oxygen index tester, and the combustion classification is tested by a UL-94 vertical combustion tester. The alcohol resistance is tested by an alcohol wear resistance instrument A20-339, and the load is 500 g; the abrasion resistance is tested by a Liquidambar formosana JM-V paint film abrasion tester, and the load is 500 g.
TABLE 1 results of performance testing of carbon tapes prepared by ink coating PET substrates of different examples
As can be seen from table 1: the carbon tape prepared by adding the antistatic agent and the flame retardant in the embodiment of the invention has the surface resistance far smaller than that of the comparative example, has better conductivity, and has the limited oxygen index and the combustion classification far better than those of the comparative example.
To sum up, the following steps are carried out: the carbon belt has good conductivity and flame retardant property, and simultaneously has good alcohol resistance and wear resistance.
Claims (8)
1. The antistatic flame-retardant thermal transfer printing ink for the carbon ribbon is characterized by comprising the following raw materials in percentage by weight: 10-30% of resin binder, 5-10% of pigment, 0-5% of filler, 0.1-1% of dispersing agent, 1-5% of antistatic agent, 5-10% of flame retardant and 50-70% of solvent.
2. The ink for the antistatic flame-retardant thermal transfer ribbon according to claim 1, wherein the flame retardant is one or a mixture of two or more of polyborosiloxane, benzoxazine and trixylenyl phosphate.
3. The ink for antistatic, flame-retardant and thermal transfer ribbon according to claim 1 or 2, wherein the resin binder is one or a mixture of two or more of polyester resin, polyacrylic resin, phenol resin, petroleum resin, terpene resin, rosin resin and polyurethane resin.
4. The ink for antistatic flame-retardant thermal transfer ribbon according to claim 1, wherein the pigment is black, violet, blue, red, yellow, green or gray.
5. The ink for the antistatic flame-retardant thermal transfer ribbon as claimed in claim 1, wherein the filler is one or a combination of talc, fumed silica and kaolin.
6. The ink for antistatic flame-retardant thermal transfer ribbon as claimed in claim 1, wherein the dispersant is one or a mixture of two or more of BYK111, BYK-AT204 and BYK-104S.
7. The ink for the antistatic flame-retardant thermal transfer ribbon according to claim 1, wherein the solvent is one or a mixture of two or more of toluene, methyl ethyl ketone, absolute ethyl alcohol, ethyl acetate and isopropyl alcohol.
8. The method for preparing the antistatic flame-retardant thermal transfer ribbon ink as claimed in any one of claims 1 to 7, characterized by comprising the steps of:
1) weighing the components in proportion, uniformly mixing the resin binder, the solvent and the flame retardant, heating to 80-100 ℃ for full dissolution, and cooling to room temperature to obtain a flame-retardant resin solution;
2) adding pigment, filler and dispersant into the flame-retardant resin solution obtained in the step 1), and uniformly grinding to obtain flame-retardant ink;
3) and (3) adding an antistatic agent into the flame-retardant ink obtained in the step 2), and uniformly stirring to obtain the antistatic flame-retardant thermal transfer ribbon ink.
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| CN202010686418.8A CN111662592B (en) | 2020-07-16 | 2020-07-16 | Antistatic flame-retardant thermal transfer printing ink for carbon ribbon and preparation method thereof |
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| CN202010686418.8A CN111662592B (en) | 2020-07-16 | 2020-07-16 | Antistatic flame-retardant thermal transfer printing ink for carbon ribbon and preparation method thereof |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112430409A (en) * | 2020-11-19 | 2021-03-02 | 东莞市古川胶带有限公司 | Alcohol-friction-resistant black ink, preparation method thereof and label |
| CN112500736A (en) * | 2020-11-27 | 2021-03-16 | 成都普瑞斯特新材料有限公司 | Environment-friendly flame-retardant ink and preparation method thereof |
| CN112898822A (en) * | 2021-01-26 | 2021-06-04 | 杭州天地数码科技股份有限公司 | Ink for thermal transfer ribbon, preparation method of ink, thermal transfer ribbon and thermal transfer printer |
| CN115124883A (en) * | 2022-07-18 | 2022-09-30 | 焦作卓立膜材料股份有限公司 | High-resistance thermal transfer ribbon containing UV material and preparation method thereof |
Citations (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1461704A (en) * | 2002-05-30 | 2003-12-17 | 刘中原 | Thermal transfer printing ribbon, and its prodn, art |
| CN1609149A (en) * | 2003-10-20 | 2005-04-27 | 张迪 | Ink paint |
| CN102189852A (en) * | 2011-04-02 | 2011-09-21 | 泉州市山水电脑耗材有限公司 | Multi-layer thermal transfer ribbon and manufacturing method thereof |
| CN201998578U (en) * | 2011-04-02 | 2011-10-05 | 泉州市山水电脑耗材有限公司 | Multi-layer heat transfer printing carbon ribbon |
| CN102616023A (en) * | 2012-03-28 | 2012-08-01 | 焦作市卓立烫印材料有限公司 | Care label thermal transfer ribbon and preparation method thereof |
| CN102635018A (en) * | 2012-04-25 | 2012-08-15 | 焦作卓林数码材料有限公司 | Ink bearing paper for thermal dye sublimation record and preparation method of ink bearing paper |
| CN104057733A (en) * | 2014-06-28 | 2014-09-24 | 周永生 | Full-resin thermal transfer printing ribbon suitable for various print substrates |
| CN105172409A (en) * | 2015-08-27 | 2015-12-23 | 鹏码实业(上海)有限公司 | Preparation method for compounded thermal transfer ribbon |
| CN107111969A (en) * | 2014-11-11 | 2017-08-29 | 日绊株式会社 | Label machine colour band |
| WO2018038179A1 (en) * | 2016-08-24 | 2018-03-01 | 三菱瓦斯化学株式会社 | Resin composition, prepreg, metal foil-clad laminated board, resin sheet, and printed wiring board |
| CN109177540A (en) * | 2018-10-29 | 2019-01-11 | 河南卓立膜材料股份有限公司 | Transfer printing print ultra-high temperature resistant carbon ribbon and preparation method thereof |
| JP2019104161A (en) * | 2017-12-12 | 2019-06-27 | 株式会社クラレ | Multilayer structure and product including the same |
| CN110183901A (en) * | 2019-04-15 | 2019-08-30 | 苏州市贝特利高分子材料股份有限公司 | 300 DEG C of lasting color inhibition filament carbon ribbon print label ink of PI substrate |
-
2020
- 2020-07-16 CN CN202010686418.8A patent/CN111662592B/en active Active
Patent Citations (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1461704A (en) * | 2002-05-30 | 2003-12-17 | 刘中原 | Thermal transfer printing ribbon, and its prodn, art |
| CN1609149A (en) * | 2003-10-20 | 2005-04-27 | 张迪 | Ink paint |
| CN102189852A (en) * | 2011-04-02 | 2011-09-21 | 泉州市山水电脑耗材有限公司 | Multi-layer thermal transfer ribbon and manufacturing method thereof |
| CN201998578U (en) * | 2011-04-02 | 2011-10-05 | 泉州市山水电脑耗材有限公司 | Multi-layer heat transfer printing carbon ribbon |
| CN102616023A (en) * | 2012-03-28 | 2012-08-01 | 焦作市卓立烫印材料有限公司 | Care label thermal transfer ribbon and preparation method thereof |
| CN102635018A (en) * | 2012-04-25 | 2012-08-15 | 焦作卓林数码材料有限公司 | Ink bearing paper for thermal dye sublimation record and preparation method of ink bearing paper |
| CN104057733A (en) * | 2014-06-28 | 2014-09-24 | 周永生 | Full-resin thermal transfer printing ribbon suitable for various print substrates |
| CN107111969A (en) * | 2014-11-11 | 2017-08-29 | 日绊株式会社 | Label machine colour band |
| CN105172409A (en) * | 2015-08-27 | 2015-12-23 | 鹏码实业(上海)有限公司 | Preparation method for compounded thermal transfer ribbon |
| WO2018038179A1 (en) * | 2016-08-24 | 2018-03-01 | 三菱瓦斯化学株式会社 | Resin composition, prepreg, metal foil-clad laminated board, resin sheet, and printed wiring board |
| JP2019104161A (en) * | 2017-12-12 | 2019-06-27 | 株式会社クラレ | Multilayer structure and product including the same |
| CN109177540A (en) * | 2018-10-29 | 2019-01-11 | 河南卓立膜材料股份有限公司 | Transfer printing print ultra-high temperature resistant carbon ribbon and preparation method thereof |
| CN110183901A (en) * | 2019-04-15 | 2019-08-30 | 苏州市贝特利高分子材料股份有限公司 | 300 DEG C of lasting color inhibition filament carbon ribbon print label ink of PI substrate |
Non-Patent Citations (1)
| Title |
|---|
| 俞春雷等: "硅氯溴三元素协同高效阻燃剂的制备及性能研究", 《塑料科技》 * |
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| CN112430409A (en) * | 2020-11-19 | 2021-03-02 | 东莞市古川胶带有限公司 | Alcohol-friction-resistant black ink, preparation method thereof and label |
| CN112500736A (en) * | 2020-11-27 | 2021-03-16 | 成都普瑞斯特新材料有限公司 | Environment-friendly flame-retardant ink and preparation method thereof |
| CN112898822A (en) * | 2021-01-26 | 2021-06-04 | 杭州天地数码科技股份有限公司 | Ink for thermal transfer ribbon, preparation method of ink, thermal transfer ribbon and thermal transfer printer |
| CN112898822B (en) * | 2021-01-26 | 2022-10-25 | 杭州天地数码科技股份有限公司 | Ink for thermal transfer ribbon, preparation method of ink, thermal transfer ribbon and thermal transfer printer |
| CN115124883A (en) * | 2022-07-18 | 2022-09-30 | 焦作卓立膜材料股份有限公司 | High-resistance thermal transfer ribbon containing UV material and preparation method thereof |
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