CN112500736A - Environment-friendly flame-retardant ink and preparation method thereof - Google Patents
Environment-friendly flame-retardant ink and preparation method thereof Download PDFInfo
- Publication number
- CN112500736A CN112500736A CN202011364413.XA CN202011364413A CN112500736A CN 112500736 A CN112500736 A CN 112500736A CN 202011364413 A CN202011364413 A CN 202011364413A CN 112500736 A CN112500736 A CN 112500736A
- Authority
- CN
- China
- Prior art keywords
- environment
- ink
- retardant
- flame
- friendly flame
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
- C09D11/033—Printing inks characterised by features other than the chemical nature of the binder characterised by the solvent
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/14—Printing inks based on carbohydrates
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention discloses an environment-friendly flame-retardant ink and a preparation method thereof, wherein the environment-friendly flame-retardant ink comprises the following components in percentage by mass: 35-40% of combined resin, 30-40% of combined solvent, 15-25% of pigment and 3-5% of auxiliary agent. The combined solvent is safe and nontoxic, does not contain benzene and ketone solvents, and is safe and environment-friendly; high temperature resistance, and no decolorization and no migration when 4kg is heat-sealed at 180 ℃/0.5 second; the adhesive force reaches more than 99 percent after boiling with boiling water at the temperature of more than 95 ℃; the surface of the printed product is smooth, and the friction coefficient is small (0.18-0.30); the ink has good plasticity, and the printed matter is not curled; the printing ink has excellent printability, the speed of a printing machine can reach more than 200 m/min, and a printed product is not anti-sticky and does not migrate; satisfactory results are also obtained at lower viscosity printing.
Description
Technical Field
The invention relates to the technical field of printing ink, in particular to environment-friendly flame-retardant printing ink and a preparation method thereof.
Background
With the continuous development of economic construction in China and the improvement of the living standard of people, people use food safety and flame retardant materials as novel environment-friendly protective materials, and the flame retardant materials are widely applied to various fields. Along with the establishment and implementation of relevant laws and standards of the flame retardant materials by relevant national departments, the application of the flame retardant materials will be gradually developed.
Since the oxygen index of polyurethane is only 14% -16% of flammable materials. When the polyurethane is heated by combustion, the depolymerization and the cracking can generate a plurality of complex low molecular substances, gaseous toxic substances (HCN, CO) and the like, the substances can be continuously combusted, and a large amount of heat is released to accelerate the cracking of the polyurethane to form a positive feedback cycle. There is therefore a need for an ink having flame retardant properties.
Disclosure of Invention
The invention aims to solve the problems and provides environment-friendly flame-retardant ink and a preparation method thereof.
In order to achieve the purpose, the invention adopts the following technical scheme:
the environment-friendly flame-retardant ink comprises the following components in percentage by mass: 35-40% of combined resin, 30-40% of combined solvent, 15-25% of pigment and 2-5% of auxiliary agent, wherein the combined resin is prepared from polyurethane resin, epoxy resin, cellulose nitrate and EVA resin according to the mass ratio of (10-15): (8-12): (6-10): (4-6), wherein the combined solvent is prepared from ethanol, isopropanol, ethyl acetate and n-butyl acetate according to the mass ratio of (12-18): (5-7): (3-6): (10-15), wherein the auxiliary agent comprises an anti-settling agent, a wear-resisting agent, a plasticizer and a flame retardant according to the mass ratio of (0.8-1.2): (0.8-1.2): (0.8-1.2): (0.8-1.2).
The combined resin has good compatibility with resin and good solvent release, and the problem of solvent residue is greatly solved. In addition, the invention adopts good flame-retardant materials, and can greatly improve the flame-retardant property of the printing ink
As a further description of the above technical solution:
the pigment is titanium dioxide.
As a further description of the above technical solution:
the anti-settling agent is fumed silica.
As a further description of the above technical solution:
the wear-resisting agent is polyethylene wax, and the polyethylene wax is also used as a slipping agent.
As a further description of the above technical solution:
the plasticizer is aliphatic dibasic acid ester, so that the ink layer has better flexibility.
As a further description of the above technical solution:
the flame retardant is antimony trioxide, so that the printing ink has good flame retardant property.
As a further description of the above technical solution:
the preparation method of the environment-friendly flame-retardant ink comprises the steps of weighing the raw materials according to the proportion range, uniformly mixing the raw materials except the anti-settling agent and the flame retardant, grinding, stopping grinding when the fineness reaches below 15 mu m, adjusting the ink, adding the anti-settling agent and the flame retardant, adjusting the viscosity to 35-40S in a No. 4 cup, and filtering to obtain the environment-friendly flame-retardant ink.
In summary, due to the adoption of the technical scheme, the invention has the beneficial effects that:
in the invention, the resin and the resin have good compatibility and good solvent release, so that the problem of solvent residue is greatly solved, the invention adopts non-benzene raw materials, thereby completely eliminating the benzene residue, and in addition, the solvent adopted by the invention is a combined solvent with quicker volatility, so that the solvent residue can be further reduced, and the printing ink is green and environment-friendly; in addition, the invention adopts good flame-retardant materials, and can greatly improve the flame-retardant property of the ink. Meanwhile, the preparation method is simple and easy to implement, low in preparation cost and easy to popularize and use.
Detailed Description
The technical solutions in the embodiments of the present invention are clearly and completely described below, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
The first embodiment is as follows:
the environment-friendly white ink comprises the following components in percentage by mass:
polyurethane resin: 11.2%, epoxy resin: 12%, cellulose nitrate: 9% and EVA resin: 4% and rutile titanium dioxide R-577: 20%, fumed silica: 1.2%, polyethylene wax: 1.2% and antimony trioxide: 1.2%, aliphatic dibasic acid ester: 1.2%, ethanol: 12.2%, isopropyl alcohol: 7%, ethyl acetate: 6%, n-butyl acetate: 15 percent;
and (2) uniformly stirring and mixing the raw materials in the proportion except the fumed silica in a mixing and stirring cylinder, then putting the mixture into a sand mill for grinding until the fineness reaches below 15 mu m, stopping grinding, adjusting the ink, adding the fumed silica, adjusting the viscosity to 35-40S in a coating 4# cup, filtering and packaging to obtain the ink A.
Example two:
the environment-friendly white ink comprises the following components in percentage by mass:
polyurethane resin: 15%, epoxy resin: 8%, cellulose nitrate: 6% and EVA resin: 6 percent, rutile titanium dioxide R-577: 22%, fumed silica: 1.5%, polyethylene wax: 1.5%, antimony trioxide: 1.5%, aliphatic dibasic acid ester: 2% and ethanol: 18%, isopropyl alcohol: 5%, ethyl acetate: 3%, n-butyl acetate: 12 percent;
and (2) uniformly stirring and mixing the raw materials in proportion except the fumed silica in a mixing and stirring cylinder, then putting the raw materials into a sand mill for grinding until the fineness reaches below 15 mu m, stopping grinding, adjusting the ink, adding the fumed silica and the antimony trioxide, adjusting the viscosity to 35-40S in a No. 4 cup, filtering and packaging to obtain the ink B.
Example three:
the environment-friendly white ink comprises the following components in percentage by mass:
polyurethane resin: 13% of epoxy resin: 10%, cellulose nitrate: 8% and EVA resin: 5% and rutile titanium dioxide R-577: 23%, fumed silica: 1% and polyethylene wax: 1%, antimony trioxide: 1% of aliphatic dibasic acid ester: 1% and ethanol: 15%, isopropyl alcohol: 6%, ethyl acetate: 5%, n-butyl acetate: 12 percent;
and (2) uniformly stirring and mixing the raw materials in proportion except the fumed silica in a mixing and stirring cylinder, then putting the raw materials into a sand mill for grinding until the fineness reaches below 15 mu m, stopping grinding, adjusting the ink, adding the fumed silica and the antimony trioxide, adjusting the viscosity to 35-40S in a No. 4 cup, filtering and packaging to obtain the ink C.
Test example:
the test of flame retardant property of the product, which was carried out by using "ink a", "ink B" and "ink C" obtained in examples 1 to 3, and gravure aluminum foil type inks (control a) and "control B) purchased from the market, at a test site outside (simulated outdoor firing environment), and burning the aluminum foil attached to each test ink with the outer flame of a lighter, the test results are shown in table 1 below:
TABLE 1
As can be seen from the table above, the ink prepared by adopting the combined formula obtained by the method is free from fire and spontaneous combustion, has low solvent residue and contains no benzene, so that the ink has the characteristics of environmental protection and flame retardance.
The combined resin has good compatibility with resin and good solvent release, and the problem of solvent residue is greatly solved; meanwhile, the printing ink adopts a special flame retardant, has a good flame retardant effect, greatly improves the fire safety of printed products, and is easy to popularize and use.
The above description is only for the preferred embodiment of the present invention, but the scope of the present invention is not limited thereto, and any person skilled in the art should be considered to be within the technical scope of the present invention, and the technical solutions and the inventive concepts thereof according to the present invention should be equivalent or changed within the scope of the present invention.
Claims (7)
1. The environment-friendly flame-retardant ink is characterized by comprising the following components in percentage by mass: 35-40% of combined resin, 30-40% of combined solvent, 15-25% of pigment and 2-5% of auxiliary agent, wherein the combined resin is prepared from polyurethane resin, epoxy resin, cellulose nitrate and EVA resin according to the mass ratio of (10-15): (8-12): (6-10): (4-6), wherein the combined solvent is prepared from ethanol, isopropanol, ethyl acetate and n-butyl acetate according to the mass ratio of (12-18): (5-7): (3-6): (10-15), wherein the auxiliary agent comprises an anti-settling agent, a wear-resisting agent, a plasticizer and a flame retardant according to the mass ratio of (0.8-1.2): (0.8-1.2): (0.8-1.2): (0.8-1.2).
2. The environment-friendly flame-retardant ink as claimed in claim 1, wherein the pigment is titanium dioxide.
3. The environment-friendly flame-retardant ink as claimed in claim 1, wherein the anti-settling agent is fumed silica.
4. The environment-friendly flame-retardant ink according to claim 1, wherein the anti-wear agent is polyethylene wax.
5. The environment-friendly flame-retardant ink as claimed in claim 1, wherein the plasticizer is an aliphatic dibasic acid ester.
6. The environment-friendly flame-retardant ink as claimed in claim 1, wherein the flame retardant is antimony trioxide.
7. The preparation method of the environment-friendly flame-retardant ink according to claim 1, wherein the environment-friendly flame-retardant ink is prepared by weighing the raw materials according to the proportion range, uniformly mixing the raw materials except the anti-settling agent and the flame retardant, grinding, stopping grinding when the fineness reaches below 15um, adjusting the viscosity to 35-40S in a 4# cup, and filtering.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202011364413.XA CN112500736A (en) | 2020-11-27 | 2020-11-27 | Environment-friendly flame-retardant ink and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202011364413.XA CN112500736A (en) | 2020-11-27 | 2020-11-27 | Environment-friendly flame-retardant ink and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN112500736A true CN112500736A (en) | 2021-03-16 |
Family
ID=74967307
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202011364413.XA Pending CN112500736A (en) | 2020-11-27 | 2020-11-27 | Environment-friendly flame-retardant ink and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN112500736A (en) |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102732096A (en) * | 2012-07-10 | 2012-10-17 | 依利安达电子（昆山）有限公司 | Halogen-free flame-retardant solvent-free double-curing ink composition and preparation method thereof |
| CN105348910A (en) * | 2015-11-12 | 2016-02-24 | 成都普瑞斯特新材料有限公司 | High-temperature aluminum foil environment-friendly black ink and preparation method thereof |
| CN108084777A (en) * | 2017-12-18 | 2018-05-29 | 成都海瑞斯特新材料有限公司 | Environmentally friendly chalk of articles for babies table print and preparation method thereof |
| WO2019182554A1 (en) * | 2018-03-19 | 2019-09-26 | Hewlett-Packard Development Company, L.P. | Fabric printable medium |
| CN111662592A (en) * | 2020-07-16 | 2020-09-15 | 焦作卓立膜材料有限责任公司 | Antistatic flame-retardant thermal transfer printing ink for carbon ribbon and preparation method thereof |
| US20200332140A1 (en) * | 2017-12-18 | 2020-10-22 | Agfa-Gevaert Nv | Solder mask inkjet inks for manufacturing printed circuit boards |
| CN111876014A (en) * | 2020-07-31 | 2020-11-03 | 深圳石墨烯创新中心有限公司 | Water-based flame-retardant graphene printing ink and preparation method thereof |
| CN211892336U (en) * | 2020-01-18 | 2020-11-10 | 惠州市摩码鼎力科技有限公司 | Flame-retardant wear-resistant decorative film for automobile |
-
2020
- 2020-11-27 CN CN202011364413.XA patent/CN112500736A/en active Pending
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102732096A (en) * | 2012-07-10 | 2012-10-17 | 依利安达电子（昆山）有限公司 | Halogen-free flame-retardant solvent-free double-curing ink composition and preparation method thereof |
| CN105348910A (en) * | 2015-11-12 | 2016-02-24 | 成都普瑞斯特新材料有限公司 | High-temperature aluminum foil environment-friendly black ink and preparation method thereof |
| CN108084777A (en) * | 2017-12-18 | 2018-05-29 | 成都海瑞斯特新材料有限公司 | Environmentally friendly chalk of articles for babies table print and preparation method thereof |
| US20200332140A1 (en) * | 2017-12-18 | 2020-10-22 | Agfa-Gevaert Nv | Solder mask inkjet inks for manufacturing printed circuit boards |
| WO2019182554A1 (en) * | 2018-03-19 | 2019-09-26 | Hewlett-Packard Development Company, L.P. | Fabric printable medium |
| CN211892336U (en) * | 2020-01-18 | 2020-11-10 | 惠州市摩码鼎力科技有限公司 | Flame-retardant wear-resistant decorative film for automobile |
| CN111662592A (en) * | 2020-07-16 | 2020-09-15 | 焦作卓立膜材料有限责任公司 | Antistatic flame-retardant thermal transfer printing ink for carbon ribbon and preparation method thereof |
| CN111876014A (en) * | 2020-07-31 | 2020-11-03 | 深圳石墨烯创新中心有限公司 | Water-based flame-retardant graphene printing ink and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 凌云星: "《实用油墨技术指南》", 30 November 2007, 印刷工业出版社 * |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102220066B (en) | Wood-plastic composite inflaming-retarding coating containing inorganic fire retardant | |
| CN105802477B (en) | A kind of environment-friendly water-based paint and preparation method thereof | |
| CN107082876B (en) | A kind of flame retardant type polyester resin, preparation method and the powdery paints comprising it | |
| CN102718916A (en) | Alcohol-water-soluble vinyl versatate modified vinegar C system acrylic resin and preparation method thereof | |
| CN112876888A (en) | Inorganic liquid coating and preparation method thereof | |
| CN108264797A (en) | It is a kind of for gravure pearly-lustre varnish of tipping paper and preparation method thereof | |
| CN103254869A (en) | Benzene-free high-speed alumite stamping gum | |
| CN110885630A (en) | Organic silicon water-based high-temperature-resistant special coating and preparation method thereof | |
| CN102993443A (en) | Acrylic resin modified epoxy resin used as adhesion promoter | |
| CN105153847A (en) | Water-based glass high-temperature baking varnish and preparation method thereof | |
| CN101899237A (en) | Latex-type waterborne pigment oil ink for inkjet printing of non-absorbed substrate as well as preparation method and applications thereof | |
| CN110607093B (en) | Solvent-free glass screen printing ink and preparation method thereof | |
| CN103031773A (en) | Environment-friendly high-gloss water-based back coating and preparation method thereof | |
| CN103012662A (en) | Emulsion used for high temperature-resistant aluminized transfer glue, and preparation method thereof | |
| CN102485813A (en) | Preparation method of alcohol water-soluble plastic intaglio plate golden oil | |
| CN110591488A (en) | Antistatic composition for alumite coloring layer and preparation method thereof | |
| US3318714A (en) | Pigment dispersions | |
| CN103709823A (en) | Silk-screen UV glaze printing ink and preparation method thereof | |
| CN112500736A (en) | Environment-friendly flame-retardant ink and preparation method thereof | |
| CN110903714A (en) | High-temperature-resistant water-based fluorocarbon amino baking paint and preparation method thereof | |
| KR100932722B1 (en) | Composition for paint markerpen and method of preparing the same | |
| CN103409063B (en) | Environment-friendly room temperature curing organic silicon high-temperature resistant coating and preparation method thereof | |
| CN113122094A (en) | Temperature-sensitive color-changing artistic coating and preparation method thereof | |
| CN102585594A (en) | Environment-friendly viscosity reducer | |
| CN104263076A (en) | Environment-friendly coca-red double-PE ink and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20210316 |
|
| RJ01 | Rejection of invention patent application after publication |