CN102485813A - Preparation method of alcohol water-soluble plastic intaglio plate golden oil - Google Patents
Preparation method of alcohol water-soluble plastic intaglio plate golden oil Download PDFInfo
- Publication number
- CN102485813A CN102485813A CN2010105670209A CN201010567020A CN102485813A CN 102485813 A CN102485813 A CN 102485813A CN 2010105670209 A CN2010105670209 A CN 2010105670209A CN 201010567020 A CN201010567020 A CN 201010567020A CN 102485813 A CN102485813 A CN 102485813A
- Authority
- CN
- China
- Prior art keywords
- gold
- water
- intaglio plate
- preparation
- mixed
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention relates to a preparation method of alcohol water-soluble plastic intaglio plate golden oil. The alcohol water-soluble plastic intaglio plate golden oil comprises a polyacrylate resin having a specific structure, ethanol, water and one or more lipid solvents. The polyacrylate resin having a specific structure is prepared from acrylate, vinylacetate and one or more functional monomers, has alcohol water dissolubility, can produce good dispersion effects on gold powder and has good gold powder dispersion stability. The preparation method provided by the invention has the advantages that 1, the polyacrylate resin having a specific structure is utilized as a binder in golden oil preparation so that gold powder dispersion is improved; a gold powder use amount is reduced; and a cost is reduced; 2, gold powder adhesion and printing effects are improved; and 3, because of alcohol water dissolubility of the polyacrylate resin having a specific structure, only ethanol and water are utilized as solvents in gold ink preparation so that other poisonous and harmful solvents and plasticizers are avoided. Therefore, the alcohol water-soluble plastic intaglio plate golden oil obtained by the preparation method has good safety and environmentally friendly characteristics, satisfies modern plastic composite package printing requirements, and has wide application prospects in the fields of plastic intaglio plate composite printing ink.
Description
Technical field
The present invention relates to plastic rotogravure composite ink, particularly plastics intaglio plate composite print gold China ink is with pure water-based gold-mixed oil and preparation method thereof.
Technical background
In recent years,, not only driven the growth at full speed of packaging industry, also promoted the continuous development in plastics base gravure ink technology and market along with the continuous lifting of living standards of the people.The plastics base gravure ink has obtained to use very widely in plastic wrapping at present, and like all types of plastic film substrate packing in industries such as food, medicine, agricultural byproducts, daily necessities, its range of application has almost been included all packaging fields.For adapting to the pursuit of social development to " green and environmental protection "; Plastics base gravure ink enterprise and correlative study mechanism are devoted to the research and development of " environmental protection " printing ink in recent years always; Substitute traditional benzene soluble ink in the hope of dissolving printing ink, thereby alleviate to the pollution of environment with to the threat of HUMAN HEALTH with cleanliness without any pollution or oligosaprobic alcohol-soluble and water-soluble or alcohol.Disclose the pure water-based compound oil ink that is used for intaglio plate like number of patent application CN200610022514.2, number of patent application CN200510044632.9 discloses a kind of environment protection plastic printing ink and preparation method thereof.
Joint efforts through R&D institution and printing, wrapping enterprise; Alcohol-soluble and water-soluble or alcohol dissolve printing ink just with its environmental protection and performance advantage at present; Beginning progressively substitutes traditional benzene soluble ink in the printing of plastics intaglio plate composite packaging, is expected to become the composite printing ink of plastic intaglio printing of one type of main flow.But; Because it is still short that alcohol-soluble and water-soluble or alcohol dissolve the printing ink search time; The supporting defectiveness still of its kind; As lack high-quality alcohol-soluble and water-soluble or pure dissolubility gold and silver, pearl lusting printing ink etc., directly cause present alcohol-soluble and water-soluble or alcohol to dissolve printing ink and in the printing of high-quality metal-like composite packaging, still need use existing traditional benzene dissolubility gold China ink.
When dissolving the supporting use of printing ink with alcohol-soluble and water-soluble or alcohol, also there is tangible printing quality problem in the neither environmental protection of use of benzene dissolubility gold China ink simultaneously.So-called golden China ink is the printing-ink that forms with modulation such as copper bronze and suitable gold-mixed oil and organic solvents.Gold-mixed oil is the key of golden black quality quality, and the filmogen that wherein used resin binder is Jin Mo, the quality and the physicochemical property thereof of final gained gold China ink determine by resin binder.Tradition benzene dissolubility plastics intaglio plate compound golden China ink is to be resin binder with benzene dissolubility Chlorinated Polypropylene III, and the gold-mixed oil modulation of forming with poisonous and harmful benzene kind solvents such as toluene, YLENE forms.When being used with alcohol-soluble and water-soluble or the molten printing ink of alcohol; The residual height of benzene kind solvent not only; Big to environment with human harm; Chlorinated Polypropylene III is big with the type difference that alcohol-soluble and water-soluble or the molten ink resin of alcohol are connected material-polynary ROHM (ester) resin simultaneously, causes printing transfer effect and the obvious variation of cohesive force of Jin Mo, is prone to disadvantages such as golden black pull-up falls, trace is fuzzy.
At present domestic disclosed non-benzene blending oil data relates generally to paper, carton and purposes such as preprints.Wherein number of patent application CN03112266 discloses the modulation of paperboard printing gold China ink with solvent type photogravure, flexographic special gold varnish; Number of patent application CN200610038142.2 discloses the modulation of a kind of yew paper printing gold China ink and has used non-benzene blending oil, number of patent application CN200610048325.2 then to disclose a kind of no benzene carton pre-printing metal varnish.These non-benzene blending oils belong to ester dissolubility gold-mixed oil; Because of its used resin binder is common acrylate resin; So be only soluble in the esters solvents such as ETHYLE ACETATE, propylene glycol methyl ether acetate; And need to add plasticizer components such as octyl phthalate, and traditional relatively benzene dissolubility gold-mixed oil, its feature of environmental protection is had large improvement.
But; Ester dissolubility gold-mixed oil contains plasticizer components to be difficult in the compound golden China ink of plastics intaglio plate it to use; And high boiling solvents such as propylene glycol methyl ether acetate also can make the printing ink organic solvent residual obviously higher; The used normal ester soluble acrylic resin of ester dissolubility gold-mixed oil still has certain difference with the structure that alcohol-soluble and water-soluble or the molten ink resin of alcohol are connected material-polynary ROHM (ester) resin simultaneously, and still there is certain problem in the transfer of bonding and printing ink between the two.For avoiding the weak point of above-mentioned prior art; The present invention provides a kind of plastic rotogravure composite ink with pure water-based gold-mixed oil and preparation method thereof; To pass through the synthetic of the polynary vinyl resin of ad hoc structure, obtain the compound gold China ink of pure water-based plastic intaglio plate and use gold-mixed oil, not only can effectively improve the dispersiveness of bronze; Reduce the bronze consumption, reduce cost; Also can improve sticking power and the cohesive strength of bronze when the supporting printing of pure water color ink simultaneously, improve transitivity and printing effect.Because the alcohol-soluble and water-soluble of ad hoc structure multicomponent methacrylate resin makes it only need use the second alcohol and water to be solvent at allotment Jin Moshi, has avoided the use of other poisonous and harmful solvent and softening agent, has good Safety and Environmental Protection.
Summary of the invention
The object of the present invention is to provide a kind of plastic rotogravure composite ink with pure water-based gold-mixed oil and preparation method thereof; With synthesizing through the polynary vinyl resin of ad hoc structure; Obtain the compound gold China ink of pure water-based plastic intaglio plate and use gold-mixed oil; Not only can effectively improve the dispersiveness of bronze, reduce the bronze consumption, reduce cost; Also can improve sticking power and the cohesive strength of bronze when the supporting printing of pure water color ink simultaneously, improve transitivity and printing effect.Because ad hoc structure multicomponent methacrylate resin is to be polymerized by propenoate, vinyl acetate, function monomer; Has alcohol-soluble and water-soluble; Make it only need use the second alcohol and water to be solvent at allotment Jin Moshi; Avoid the use of other poisonous and harmful solvent and softening agent, had good Safety and Environmental Protection, can be used for the allotment of all kinds of pure water-based plastic intaglio plate composite packaging printing gold China inks.
The objective of the invention is to realize through following technical scheme:
Alcohol water-based plastic intaglio plate gold-mixed oil is made up of ad hoc structure multicomponent methacrylate resin, ethanol, water and esters solvent, and, allotment synthetic through solution radical one-step polymerization method gets.It is with solution radical one-step polymerization method synthetic ad hoc structure multicomponent methacrylate resin that the resin of gold-mixed oil links agent.Each weight proportion of forming is in the gold-mixed oil:
Ad hoc structure multicomponent methacrylate resin 40～60
Ethanol 15～30
Esters solvent 15～30
Water 1.0～15
Polyketone resin 0.5～5.0
Wax powder 0.1～0.3
Dispersion aids 0.05～0.2
Wherein the raw material monomer of the multicomponent methacrylate resin of ad hoc structure composition weight proportion is:
(methyl) acrylic ester monomer 40～60
Vinyl acetate 20～45
Function monomer 15～25
Initiator 0.1～1.5
The preparation of alcohol water-based plastic intaglio plate gold-mixed oil adopts solution radical one-step polymerization method to synthesize, allocate and get, and its polymerization technique is the conventional soln polymerization technique, perhaps selects following technology:
1) earlier with the initiator adding reaction kettle of esters solvent and 50wt%, after stirring, is warming up to 50～85 ℃;
2) treat temperature-stable after, (methyl) propenoate, vinyl acetate, function monomer and remaining 50wt% initiator are mixed, in 3～8 hours, evenly be added dropwise to reaction kettle;
3) dropwise after, keep 50～85 ℃ of temperature, continue to stir 2～5 hours, then cooling;
4) polyketone resin, wax powder and dispersion aids are dissolved in ethanol, mix with water then, form the mixing solutions of ethanol, water;
5) treat the still temperature drop to room temperature, add the above-mentioned ethanol that has mixed, water mixed solution, stir and go out still after accomplishing allotment in 30 minutes.Promptly get pure water-based plastic intaglio plate gold-mixed oil finished product.
Wherein: (methyl) propenoate is methyl acrylate, ethyl propenoate, Bing Xisuandingzhi, the own ester of ethyl propenoate, TEB 3K, Jia Jibingxisuanyizhi, NSC 20956, the own ester of Jia Jibingxisuanyizhi, the mixture of one or more above compositions; Function monomer is Hydroxyethyl acrylate, Propylene glycol monoacrylate, Rocryl 400, Rocryl 410; Maleic anhydride, acrylic amide, USAF RH-1, NMA, methylol methacrylamide, the mixture of one or more above compositions; Initiator is Diisopropyl azodicarboxylate or Lucidol; Esters solvent is vinyl acetic monomer, n-propyl acetate, Iso Butyl Acetate, n-butyl acetate, isobutyl acetate, the mixture of one or more above compositions; The wax powder is polyethylene wax, Microcrystalline Wax, the mixture of above one or both kind of composition; Dispersion aids is Triple Pressed Stearic Acid, sodium stearate, oleic acid, sodium oleate, Sodium Benzoate, sodium laurylsulfonate, the mixture of one or more above compositions.
Biggest advantage of the present invention is to participate in free-radical polymerized through function monomer; Make and have hydroxyl, carboxamido-group, acid anhydrides isopolarity group on the polynary vinyl resin molecular chain of institute's synthetic; Thereby improved the polarity of polynary vinyl resin, made it can be dissolved in the pure water mixed solvent well; Hydroxyl, carboxamido-group, acid anhydrides isopolarity group have good dispersive ability to bronze simultaneously, can effectively improve the dispersiveness of bronze, reduce the bronze consumption, reduce cost; Meanwhile, the polarity that resin obtained can also strengthen transitivity and the cohesive force when gold is black to be printed on plastic basis material.The adjustable height property of polynary in addition vinyl resin structure makes it can obtain enough flexibilities and initial bonding strength through the adjustment of molecular structure, could obtain enough flexibilities and initial bonding strength and need as the normal ester soluble acrylic resin, must not add softening agent.Above advantage makes this alcohol water-based gold-mixed oil have broad application prospects in the plastic rotogravure composite ink field.
The preparation technology of the compound gold China ink of corresponding pure water-based plastic intaglio plate is conventional golden black preparation technology, perhaps selects following preparation technology for use:
1) absolute ethyl alcohol and water are processed mixed solvent in 9.5: 0.5～8: 1 ratio;
2) with mixed solvent bronze is soaked, wherein the weight ratio of bronze and mixed solvent is 1.0: 0.2～2.0; Soak time 5～30 minutes starts low-speed agitator simultaneously and stirs, and soaks swelling fully to guarantee metallic pigment;
3) add the gold-mixed oil of pressing aforementioned prepared, wherein the weight ratio of bronze and gold-mixed oil is 1.0: 0.8～2.0; Start low-speed agitator simultaneously, stirred 5～30 minutes;
4) add mixed solvent, regulate the required viscosity of gained gold black viscosity to plastics intaglio plate composite print, promptly get plastics intaglio plate composite print with the gold China ink.
Wherein bronze is the copper bronze of the medium fineness of 800～1200 orders.
Embodiment:
Embodiment one
The Diisopropyl azodicarboxylate of 0.4g, the vinyl acetic monomer of 50g are added reaction kettle, after stirring, be warming up to 70 ℃; After treating temperature-stable, beginning evenly drips monomer mixture (Bing Xisuandingzhi of 30g, the TEB 3K of 20g, 30g vinyl acetate, the Hydroxyethyl acrylate of 10g, the maleic anhydride of 3g, the USAF RH-1 of 7g, the Diisopropyl azodicarboxylate uniform mixing of 0.4g form); The dropping time is 3 hours, and keeping temperature during the dropping is 70 ℃; After dropwising, keep 70 ℃ of temperature, continue to stir 4 hours, then cooling; The polyketone resin of 2.0g, the polyethylene wax of 0.2g, the StNa of 0.2g are dissolved in the absolute ethyl alcohol of 45g, and the water that adds 5g then mixes, and forms the mixing solutions of ethanol, water; The above-mentioned ethanol that has mixed, water mixed solution are added reaction kettle, stirs to accomplish in 30 minutes and go out still after allocating.Promptly get pure water-based plastic intaglio plate gold-mixed oil finished product.
Embodiment two
The Lucidol of 0.5g, the vinyl acetic monomer of 40g are added reaction kettle, after stirring, be warming up to 75 ℃; After treating temperature-stable, beginning evenly drips monomer mixture (Bing Xisuandingzhi of 30g, the TEB 3K of 10g, 42g vinyl acetate, the Hydroxyethyl acrylate of 12g, the maleic anhydride of 2g, the NMA of 4g, the Lucidol uniform mixing of 0.5g form); The dropping time is 3 hours, and keeping temperature during the dropping is 75 ℃; After dropwising, keep 75 ℃ of temperature, continue to stir 3 hours, then cooling; The polyketone resin of 2.5g, the polyethylene wax of 0.3g, the StNa of 0.1g, the Triple Pressed Stearic Acid of 0.1g are dissolved in the absolute ethyl alcohol of 52g, and the water that adds 8g then mixes, and forms the mixing solutions of ethanol, water; The above-mentioned ethanol that has mixed, water mixed solution are added reaction kettle, stirs to accomplish in 30 minutes and go out still after allocating.Promptly get pure water-based plastic intaglio plate gold-mixed oil finished product.
Embodiment three
The Diisopropyl azodicarboxylate of 0.6g, the vinyl acetic monomer of 30g, the n-propyl acetate of 15g are added reaction kettle, after stirring, be warming up to 75 ℃; After treating temperature-stable, beginning evenly drips monomer mixture (NSC 20956 of 35g, the TEB 3K of 10g, 42g vinyl acetate, the Hydroxyethyl acrylate of 8g, the maleic anhydride of 4g, the acrylic amide of 6g, the Diisopropyl azodicarboxylate uniform mixing of 0.6g form); The dropping time is 4 hours, and keeping temperature during the dropping is 75 ℃; After dropwising, keep 75 ℃ of temperature, continue to stir 3 hours, then cooling; The polyketone resin of 3.0g, the polyethylene wax of 0.3g, the StNa of 0.1g, the sodium oleate of 0.1g are dissolved in the absolute ethyl alcohol of 45g, and the water that adds 10g then mixes, and forms the mixing solutions of ethanol, water; The above-mentioned ethanol that has mixed, water mixed solution are added reaction kettle, stirs to accomplish in 30 minutes and go out still after allocating.Promptly get pure water-based plastic intaglio plate gold-mixed oil finished product.
Embodiment four
Absolute ethyl alcohol and water are processed mixed solvent in 9.5: 0.5 ratio; The fineness that takes by weighing 100g is 1200 order copper bronzes, adds the above-mentioned mixed solvent of 80g, soaks 15 minutes, starts low-speed agitator simultaneously and stirs, and soaks swelling fully to guarantee metallic pigment; Add the pure water-based plastic intaglio plate gold-mixed oil of 100g, start low-speed agitator simultaneously, stirred 20 minutes by aforementioned prepared; Add mixed solvent then, regulate the required viscosity of gained gold black viscosity to plastics intaglio plate composite print, through after the assay was approved, packing promptly gets pure water-based plastic intaglio plate composite print with the gold China ink.
The pure water-based plastic intaglio plate composite print that makes is as shown in the table with the key technical indexes of gold China ink:
| Test item | National standard | Detected value | The result |
| Viscosity (s) (4# cup/25 ℃) | 25～70 | 28～50 | Qualified |
| Just do (mm) (30s/25 ℃) | 25～50 | 28～38 | Qualified |
| Attachment fastness (%) (adhesive tape method) | ≥85 | 90～98 | Qualified |
| Benzene content (ppm) | / | Do not have | Qualified |
Above detected result is according to the QB/T2024-1994 standard testing, and wherein the attachment fastness specimen is full version printing gold China ink.The metal-like contrast visual observation of printing is good.
Claims (2)
1. the preparation method of a kind of pure water-based plastic intaglio plate gold-mixed oil that relates to of this patent is made up of ad hoc structure multicomponent methacrylate resin, ethanol, water and esters solvent, and, allotment synthetic through solution radical one-step polymerization method gets.It is characterized in that with the resin low-melting ink vehicle of solution radical one-step polymerization method synthetic ad hoc structure multicomponent methacrylate resin wherein each weight proportion of forming is as gold-mixed oil:
Ad hoc structure multicomponent methacrylate resin 40～60
Ethanol 15～30
Esters solvent 15～30
Water 1.0～15
Polyketone resin 0.5～5.0
Wax powder 0.1～0.3
Dispersion aids 0.05～0.2
Wherein the raw material monomer of the multicomponent methacrylate resin of ad hoc structure composition weight proportion is:
(methyl) acrylic ester monomer 40～60
Vinyl acetate 20～45
Function monomer 15～25
Initiator 0.1～1.5
The preparation of alcohol water-based plastic intaglio plate gold-mixed oil adopts solution radical one-step polymerization method to synthesize, allocate and get, and its polymerization technique is the conventional soln polymerization technique, perhaps selects following technology:
1) earlier with the initiator adding reaction kettle of esters solvent and 50wt%, after stirring, is warming up to 50～85 ℃;
2) treat temperature-stable after, (methyl) propenoate, vinyl acetate, function monomer and remaining 50wt% initiator are mixed, in 3～8 hours, evenly be added dropwise to reaction kettle;
3) dropwise after, keep 50～85 ℃ of temperature, continue to stir 2～5 hours, then cooling;
4) polyketone resin, wax powder and dispersion aids are dissolved in ethanol, mix with water then, form the mixing solutions of ethanol, water;
5) treat the still temperature drop to room temperature, add the above-mentioned ethanol that has mixed, water mixed solution, stir and go out still after accomplishing allotment in 30 minutes.Promptly get pure water-based plastic intaglio plate gold-mixed oil finished product;
The preparation technology of the compound gold China ink of corresponding pure water-based plastic intaglio plate is conventional golden black preparation technology, perhaps selects following preparation technology for use:
1) absolute ethyl alcohol and water are processed mixed solvent in 9.5: 0.5～8: 1 ratio;
2) with mixed solvent bronze is soaked, wherein the weight ratio of bronze and mixed solvent is 1.0: 0.2～2.0; Soak time 5～30 minutes starts low-speed agitator simultaneously and stirs, and soaks swelling fully to guarantee metallic pigment;
3) add the gold-mixed oil of pressing aforementioned prepared, wherein the weight ratio of bronze and gold-mixed oil is 1.0: 0.8～2.0; Start low-speed agitator simultaneously, stirred 5～30 minutes;
4) add mixed solvent, regulate the required viscosity of gained gold black viscosity to plastics intaglio plate composite print, promptly get plastics intaglio plate composite print with the gold China ink.
2. the preparation method of a kind of pure water-based plastic intaglio plate gold-mixed oil according to claim 1; It is characterized in that: (methyl) propenoate is methyl acrylate, ethyl propenoate, Bing Xisuandingzhi, the own ester of ethyl propenoate, TEB 3K, Jia Jibingxisuanyizhi, NSC 20956, the own ester of Jia Jibingxisuanyizhi, the mixture of one or more above compositions; Function monomer is Hydroxyethyl acrylate, Propylene glycol monoacrylate, Rocryl 400, Rocryl 410; Maleic anhydride, acrylic amide, USAF RH-1, NMA, methylol methacrylamide, the mixture of one or more above compositions; Initiator is Diisopropyl azodicarboxylate or Lucidol; Esters solvent is vinyl acetic monomer, n-propyl acetate, Iso Butyl Acetate, n-butyl acetate, isobutyl acetate, the mixture of one or more above compositions; The wax powder is polyethylene wax, Microcrystalline Wax, the mixture of above one or both kind of composition; Dispersion aids is Triple Pressed Stearic Acid, sodium stearate, oleic acid, sodium oleate, Sodium Benzoate, sodium laurylsulfonate, the mixture of one or more above compositions; Bronze is the copper bronze of the medium fineness of 800～1200 orders.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010105670209A CN102485813A (en) | 2010-12-01 | 2010-12-01 | Preparation method of alcohol water-soluble plastic intaglio plate golden oil |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010105670209A CN102485813A (en) | 2010-12-01 | 2010-12-01 | Preparation method of alcohol water-soluble plastic intaglio plate golden oil |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102485813A true CN102485813A (en) | 2012-06-06 |
Family
ID=46151388
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2010105670209A Pending CN102485813A (en) | 2010-12-01 | 2010-12-01 | Preparation method of alcohol water-soluble plastic intaglio plate golden oil |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102485813A (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103725086A (en) * | 2014-01-15 | 2014-04-16 | 云南侨通包装印刷有限公司 | High-performance water-based golden ink for gravure printing and preparation method thereof |
| WO2014113858A1 (en) * | 2013-01-28 | 2014-07-31 | Mota Ferreira Flavio Roberto | Water-soluble plastic composition and method for producing the same |
| CN105111818A (en) * | 2015-07-21 | 2015-12-02 | 漳州市芳远印务有限公司 | Tangle film with excellent printing adhesion |
| CN105713451A (en) * | 2016-04-18 | 2016-06-29 | 厦门欧化实业有限公司 | Benzene-free environment-friendly high-tolerance gravure ink |
| CN106118234A (en) * | 2016-07-25 | 2016-11-16 | 合众（佛山）化工有限公司 | A kind of environmental protection clean taste type high-performance printing ink resin binder and preparation method thereof |
| CN106280700A (en) * | 2016-08-05 | 2017-01-04 | 云南通印股份有限公司 | Gravure water-based metal ink and production method thereof |
| CN115141547A (en) * | 2022-06-01 | 2022-10-04 | 科顺防水科技股份有限公司 | Non-curing waterproof coating and preparation method thereof |
Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3203917A (en) * | 1960-09-30 | 1965-08-31 | Sumitomo Chemical Co | Pigment resin printing paste comprising a brominated vinyl polymer |
| JPS51125182A (en) * | 1974-10-02 | 1976-11-01 | Showa Highpolymer Co Ltd | Curable resin compositions |
| EP0119330A1 (en) * | 1983-02-22 | 1984-09-26 | METALLURGIE HOBOKEN-OVERPELT Société anonyme dite: | Drop collector for an electrode transportation apparatus |
| CN1281883A (en) * | 2000-06-13 | 2001-01-31 | 湖北省化学研究所 | Multi-component copolymer acrylate adhesive, its preparation method and application for covering aluminium plate with polyimide |
| US20020137850A1 (en) * | 1998-06-17 | 2002-09-26 | Westvaco Corporation, New York, Ny | Hybrid polymers for phase change ink jet inks |
| CN1482185A (en) * | 2003-05-27 | 2004-03-17 | 王尔建 | Solvent type gold-mixed oil for gravure and flexible print |
| CN1944546A (en) * | 2006-09-21 | 2007-04-11 | 山西精华科工贸有限公司 | No-benzene pre-printing metal regulating oil for concave paper box |
| CN1970655A (en) * | 2006-12-15 | 2007-05-30 | 成都市新津托展油墨有限公司 | Alcohol-soluble aqueous composite plastic ink for gravure and making method thereof |
| CN101831049A (en) * | 2010-05-24 | 2010-09-15 | 新东方油墨有限公司 | Modified polyurethane resin and benzene-free and ketone-free composite plastic ink containing same, as well as preparation methods thereof |
-
2010
- 2010-12-01 CN CN2010105670209A patent/CN102485813A/en active Pending
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3203917A (en) * | 1960-09-30 | 1965-08-31 | Sumitomo Chemical Co | Pigment resin printing paste comprising a brominated vinyl polymer |
| JPS51125182A (en) * | 1974-10-02 | 1976-11-01 | Showa Highpolymer Co Ltd | Curable resin compositions |
| EP0119330A1 (en) * | 1983-02-22 | 1984-09-26 | METALLURGIE HOBOKEN-OVERPELT Société anonyme dite: | Drop collector for an electrode transportation apparatus |
| US20020137850A1 (en) * | 1998-06-17 | 2002-09-26 | Westvaco Corporation, New York, Ny | Hybrid polymers for phase change ink jet inks |
| CN1281883A (en) * | 2000-06-13 | 2001-01-31 | 湖北省化学研究所 | Multi-component copolymer acrylate adhesive, its preparation method and application for covering aluminium plate with polyimide |
| CN1482185A (en) * | 2003-05-27 | 2004-03-17 | 王尔建 | Solvent type gold-mixed oil for gravure and flexible print |
| CN1944546A (en) * | 2006-09-21 | 2007-04-11 | 山西精华科工贸有限公司 | No-benzene pre-printing metal regulating oil for concave paper box |
| CN1970655A (en) * | 2006-12-15 | 2007-05-30 | 成都市新津托展油墨有限公司 | Alcohol-soluble aqueous composite plastic ink for gravure and making method thereof |
| CN101831049A (en) * | 2010-05-24 | 2010-09-15 | 新东方油墨有限公司 | Modified polyurethane resin and benzene-free and ketone-free composite plastic ink containing same, as well as preparation methods thereof |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2014113858A1 (en) * | 2013-01-28 | 2014-07-31 | Mota Ferreira Flavio Roberto | Water-soluble plastic composition and method for producing the same |
| CN103725086A (en) * | 2014-01-15 | 2014-04-16 | 云南侨通包装印刷有限公司 | High-performance water-based golden ink for gravure printing and preparation method thereof |
| CN105111818A (en) * | 2015-07-21 | 2015-12-02 | 漳州市芳远印务有限公司 | Tangle film with excellent printing adhesion |
| CN105713451A (en) * | 2016-04-18 | 2016-06-29 | 厦门欧化实业有限公司 | Benzene-free environment-friendly high-tolerance gravure ink |
| CN106118234A (en) * | 2016-07-25 | 2016-11-16 | 合众（佛山）化工有限公司 | A kind of environmental protection clean taste type high-performance printing ink resin binder and preparation method thereof |
| CN106280700A (en) * | 2016-08-05 | 2017-01-04 | 云南通印股份有限公司 | Gravure water-based metal ink and production method thereof |
| CN115141547A (en) * | 2022-06-01 | 2022-10-04 | 科顺防水科技股份有限公司 | Non-curing waterproof coating and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102485813A (en) | Preparation method of alcohol water-soluble plastic intaglio plate golden oil | |
| CN102718916B (en) | Alcohol-water-soluble vinyl versatate modified vinegar C system acrylic resin and preparation method thereof | |
| CN101260259B (en) | Ink resin used for intaglio printing and preparation method thereof | |
| CN102010485B (en) | Preparation method of integrated plastic gravure alcohol-soluble aqueous composite ink resin | |
| CN102533068B (en) | Ultraviolet curing aluminized transferring coating and preparation method and application thereof | |
| JP5149174B2 (en) | Alcohol-soluble resin and preparation method thereof | |
| CN101125977A (en) | Water flexible painting plate ink and preparing method thereof | |
| CN102464918A (en) | High-performance alcohol/water-based printing ink and preparation method thereof | |
| CN102040726A (en) | Preparation method of high-performance printing ink resin | |
| EP3668933B1 (en) | Water-based inks with high renewable content | |
| CN101020797A (en) | Water-base ink for intaglio printing on aluminium foil and its prepn process and application | |
| CN107384011A (en) | A kind of PVC floor film intaglio printing water-based ink and preparation method thereof | |
| CN100473670C (en) | Alcohol water-soluble resin and method for making the same | |
| CN104861778A (en) | Water-based ink for grainy paper printing and preparation method thereof | |
| CN103183831B (en) | Universal binder resin for water-based plastic surface printing ink, preparation method thereof and printing ink using binder resin | |
| CN103613999A (en) | Water-based ink | |
| CN102010631B (en) | Single-fluid general type plastic intaglio alcohol-water soluble composite ink and preparation method thereof | |
| CN106147451A (en) | Fire resistant water-based aluminizing transfer paint compositions and preparation method thereof | |
| CN108102458A (en) | A kind of preparation method of flexographic plate water-based ink | |
| CN102140272A (en) | Ink resin composite used for plastic gravure printing and preparation method thereof | |
| CN111827003A (en) | High-temperature-resistant gloss oil for tipping paper and preparation method thereof | |
| CN102732098A (en) | Ink for low-heavy metal tipping paper, and preparation method thereof | |
| CN107652772A (en) | A kind of aqueous, environmental protective printing-ink and preparation method thereof | |
| CN101921374B (en) | Preparation method of polyacrylate-polyurethane resin binder for single-fluid general plastic gravure alcohol-soluble and water-soluble composite ink | |
| CN101314699B (en) | Water-based adhesion agent and preparation thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20120606 |