CN1944546A - No-benzene pre-printing metal regulating oil for concave paper box - Google Patents

No-benzene pre-printing metal regulating oil for concave paper box Download PDF

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Publication number
CN1944546A
CN1944546A CN 200610048325 CN200610048325A CN1944546A CN 1944546 A CN1944546 A CN 1944546A CN 200610048325 CN200610048325 CN 200610048325 CN 200610048325 A CN200610048325 A CN 200610048325A CN 1944546 A CN1944546 A CN 1944546A
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China
Prior art keywords
acetate
resin
printing metal
paper box
printing
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN 200610048325
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Chinese (zh)
Inventor
王尔健
白鹏飞
王重声
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jinghua Science and Industry and Trade Co Ltd Shanxi
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Jinghua Science and Industry and Trade Co Ltd Shanxi
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Jinghua Science and Industry and Trade Co Ltd Shanxi filed Critical Jinghua Science and Industry and Trade Co Ltd Shanxi
Priority to CN 200610048325 priority Critical patent/CN1944546A/en
Publication of CN1944546A publication Critical patent/CN1944546A/en
Pending legal-status Critical Current

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Abstract

The no-benzene pre-printing metal varnish consists of thermoplastic methyl methacylate resin 25-48 wt%, propylene glycol methyl ether acetate 4-12 wt%, dioctyl phthalate 2-6 wt%, and ethyl acetate 34-69 wt%. The no-benzene pre-printing metal varnish has methyl methacylate resin with excellent metallic pigment wetting performance and softening temperature not lower than the corrugated line compounding temperature as the main material and ester with less harm to the environment and human body as the main solvent, so that it has excellent metal adaptability, excellent brightness, environment friendship, capacity of resisting temperature up to 180 deg.c and other advantages.

Description

No-benzene pre-printing metal regulating oil for concave paper box
Technical field
No-benzene pre-printing metal regulating oil for concave paper box of the present invention is specifically related to the intaglio plate carton and preprints, do not have a kind of resistant to elevated temperatures blending oil that aromatic solvent, fluting board Compound Machining are special procured.
Background technology
The method of the colored Corrugated Box of traditional mode of production is directly to utilize the flexo technology to print on the good carton of cross cutting, generally adopts low-grade ink, can't use the gold China ink, can only be applied in some low-grade occasions.
Occur the employing lithographic plate afterwards and preprinted technology production carton, and promptly on monolithic carton facial tissue, adopted the method for offset printing to print earlier, and utilized facing machine that the facial tissue and the corrugation that print is compound then, be die-cut to various box-shapeds again.Because the offset printing low-melting ink vehicle never adopts bronze printing technology to the wetting non-constant of metallic pigment.
It is to adopt large-scale set type gravure printing machine reel to web feed printing that the intaglio plate carton is preprinted technology, and the rolled paper that prints directly is combined into carton board with corrugation as the carton facial tissue on corrugated paper production line, again shape by die-cutting.This kind method has been compared remarkable advantages with preceding two kinds: with consistence height between a collection of and different batches, and production efficiency height, carton intensity height.
Preprint in the technology owing to adopt the gravure mode to make bronze printing that possibility arranged at the intaglio plate carton, embody metalluster and luxurious magnificent speciality, simultaneously on the printing picture, produce sharp contrast, increase fresh colour and obtain sparkling and crystal-clear brilliant effect, particularly spill on the packings such as mark, gift box, bronze printing is achieved.
Summary of the invention
The technical problem to be solved in the present invention provides a kind of no-benzene pre-printing metal regulating oil for concave paper box, having solved the intaglio plate carton preprints technical matters and requires used blending oil to remove to have the metallic pigment wettability, satisfy outside the print request, also satisfy resistant to elevated temperatures requirement in the printing post-treatment.
The technical solution used in the present invention: no-benzene pre-printing metal regulating oil for concave paper box, (mass percent) that it is made by the component of following proportioning:
Thermoplastic methacrylic methyl esters resin 25~48%
Propylene glycol methyl ether acetate 4~12%
Dioctyl phthalate (DOP) 2~6%
Ethyl acetate 34~69%
The substitute of thermoplastic methacrylic methyl esters resin is a thermoplastic acrylic resin, or the ethylene/vinyl acetate copolymer resins, or vinylchlorid/vinyl acetate between to for plastic copolymer resins, or Mierocrystalline cellulose and derivatives resin and maleic anhydride Gum Rosin.
The substitute of ethyl acetate is a n-propyl acetate, or isopropyl acetate and n-butyl acetate.
A kind of manufacture method of no-benzene pre-printing metal regulating oil for concave paper box: thermoplastic methacrylic methyl esters resin, propylene glycol methyl ether acetate, dioctyl phthalate (DOP) and ethyl acetate are pressed above-mentioned mass percent weighing, the substitute of thermoplastic methacrylic methyl esters resin is a thermoplastic acrylic resin, or ethylene/vinyl acetate copolymer resins, or vinylchlorid/vinyl acetate between to for plastic copolymer resins, or Mierocrystalline cellulose and derivatives resin and maleic anhydride Gum Rosin; The substitute of ethyl acetate is a n-propyl acetate, or isopropyl acetate and n-butyl acetate.Pour stirrer into, be stirred to dissolving cmpletely, temperature is no more than 60 ℃ in the entire operation process.
No-benzene pre-printing metal regulating oil for concave paper box of the present invention and traditional intaglio plate carton are preprinted to compare with blending oil has following beneficial effect:
1, metallic pigment wetting good, pollute little: adopt the wetting superior acrylic resin of metallic pigment is made the main body resin, resin softening point is not less than corrugation line combined temp, adopts the solvent based on ester simultaneously, will drop to minimum to environment and personnel's harm.
2, glossiness is good, high temperature resistant: adopt thermoplastic methacrylic methyl esters resin, ester is a primary solvent, has excellent gloss, superior metal suitability, each batch preprinted the pattern color unanimity, has antifalsification, and special the connection expected design, ability is high temperature more than 180 ℃, guarantees the compound and use properties of corrugation.
The effect of invention is illustrated by the contrast experiment, by common intaglio printing is made comparisons with blending oil, no-benzene pre-printing metal regulating oil for concave paper box of the present invention.
Experimental result is as follows:
Figure A20061004832500041
Embodiment
Embodiment 1, and no-benzene pre-printing metal regulating oil for concave paper box is made by the component of following proportioning, and consumption is mass percent:
Thermoplastic methacrylic methyl esters resin 38%
Propylene glycol methyl ether acetate 8%
Dioctyl phthalate (DOP) 2%
Butylacetate 52%
After above-mentioned confected materials mixing, pour heating while stirring on the stirrer into, Heating temperature is 51~57 ℃, to dissolving cmpletely.
Embodiment 2, and no-benzene pre-printing metal regulating oil for concave paper box is made by the component of following proportioning, and consumption is mass percent:
Thermoplastic acrylic resin 28%
Propylene glycol methyl ether acetate 4%
Dioctyl phthalate (DOP) 4%
N-propyl acetate 64%
After above-mentioned confected materials mixing, pour heating while stirring on the stirrer into, Heating temperature is 52~58 ℃, to dissolving cmpletely.
Embodiment 3, and no-benzene pre-printing metal regulating oil for concave paper box is made by the component of following proportioning, and consumption is mass percent:
Ethylene/vinyl acetate copolymer resins 45%
Propylene glycol methyl ether acetate 6%
Dioctyl phthalate (DOP) 8%
Isopropyl acetate 41%
After above-mentioned confected materials mixing, pour heating while stirring on the stirrer into, Heating temperature is 53~59 ℃, to dissolving cmpletely.

Claims (3)

1. no-benzene pre-printing metal regulating oil for concave paper box, it is characterized in that: it is to be made by the component of following proportioning, and consumption is weight percentage:
Thermoplastic methacrylic methyl esters resin 25~48%
Propylene glycol methyl ether acetate 4~12%
Dioctyl phthalate (DOP) 2~6%
Ethyl acetate 34~69%.
2. blending oil as claimed in claim 1, it is characterized in that: the substitute of thermoplastic methacrylic methyl esters resin is a thermoplastic acrylic resin, or ethylene/vinyl acetate copolymer resins, or vinylchlorid/vinyl acetate between to for plastic copolymer resins, or Mierocrystalline cellulose and derivatives resin and maleic anhydride Gum Rosin.
3. blending oil as claimed in claim 1 is characterized in that: the substitute of ethyl acetate is a n-propyl acetate, or isopropyl acetate and n-butyl acetate.
CN 200610048325 2006-09-21 2006-09-21 No-benzene pre-printing metal regulating oil for concave paper box Pending CN1944546A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN 200610048325 CN1944546A (en) 2006-09-21 2006-09-21 No-benzene pre-printing metal regulating oil for concave paper box

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN 200610048325 CN1944546A (en) 2006-09-21 2006-09-21 No-benzene pre-printing metal regulating oil for concave paper box

Publications (1)

Publication Number Publication Date
CN1944546A true CN1944546A (en) 2007-04-11

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN 200610048325 Pending CN1944546A (en) 2006-09-21 2006-09-21 No-benzene pre-printing metal regulating oil for concave paper box

Country Status (1)

Country Link
CN (1) CN1944546A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102485813A (en) * 2010-12-01 2012-06-06 成都市新津托展油墨有限公司 Preparation method of alcohol water-soluble plastic intaglio plate golden oil
CN105111818A (en) * 2015-07-21 2015-12-02 漳州市芳远印务有限公司 Tangle film with excellent printing adhesion
CN113956712A (en) * 2021-12-09 2022-01-21 玉溪接装纸制造有限公司 Golden gravure metal ink for tipping paper and preparation method thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102485813A (en) * 2010-12-01 2012-06-06 成都市新津托展油墨有限公司 Preparation method of alcohol water-soluble plastic intaglio plate golden oil
CN105111818A (en) * 2015-07-21 2015-12-02 漳州市芳远印务有限公司 Tangle film with excellent printing adhesion
CN113956712A (en) * 2021-12-09 2022-01-21 玉溪接装纸制造有限公司 Golden gravure metal ink for tipping paper and preparation method thereof

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