CN101429359A - Water-based plastic composite inner-printing ink - Google Patents
Water-based plastic composite inner-printing ink Download PDFInfo
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- CN101429359A CN101429359A CN 200810080075 CN200810080075A CN101429359A CN 101429359 A CN101429359 A CN 101429359A CN 200810080075 CN200810080075 CN 200810080075 CN 200810080075 A CN200810080075 A CN 200810080075A CN 101429359 A CN101429359 A CN 101429359A
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Abstract
The invention discloses a water-based plastic composite printing ink, in particular to a water-based ink needed in the plastic film intaglio printing composite process. To solve problems, the invention provides the water-based ink which remarkably improves composite strength, sealing strength and printing mass relative to the prior solvent ink on the premise of not reconstructing the prior printing equipment or adjusting the printing process; the water-based ink adopts the following technical proposal: the water-based plastic composite printing ink is prepared from the following raw materials in weight portion: 10 to 35 portions of aqueous polyurethane emulsion, 0 to 8 portions of aqueous acrylic resin, 0 to 7 portions of aqueous wetting dispersant, 0.2 to 2 portions of aqueous dampness levelling agent, 0.1 to 2 portions of aqueous defoaming agent, 0.1 to 5 portions of PH regulator, 6 to 30 portions of pigment, 0 to 5 portions of ethanol and 6 to 73.6 portions of water. The water-based ink can be widely applied in the field of ink manufacturing.
Description
Technical field
The present invention relates to print in a kind of plastics film intaglio plate required water-based inks in the recombination process.
Background technology
The most employing of domestic food soft packaging at present plastic wrapping, wherein exhausted again big the employing in the intaglio plate printed recombining process, and employed printing ink all is the solvent type ink that contains organic volatiles such as toluene, methylethylketone, ethyl acetate, glycol ether, these objectionable impuritiess account for the 60%-80% of total quantity of ink or higher, and in printing process, also to add more this type of objectionable impurities, final these objectionable impuritiess all are disposed in the air, cause the severe contamination to environment; Simultaneously above-mentioned objectionable impurities causes in various degree murder by poisoning to user's health in the operating environment, and the static that the equipment base material produces in running up very easily gathers, and has very large potential safety hazard.
The main body solvent of water-based plastic composite inner-printing ink is a water, water volatilization back cleanliness without any pollution, and user's safety and Health toxicological harmless in use, and also glassware for drinking water electroconductibility can not gather static, and the production scene is as safe as a house.Water-based inks has incomparable advantage with respect to solvent type ink on environmental protection, health, safety, be green product worthy of the name.
The surface tension of water reaches 72 dynes per centimeter, the press plate top layer is a chromium, and printing uses film surface tension force in the 38-48 dynes per centimeter, so the wetting the biggest problem that becomes on water-based plastic composite inner-printing ink mimeograph surface and the printing film, that wetting difference must shift is poor, levelling is poor, and printing effect is poor; The volatilization latent heat of water is much bigger for organic solvent, and the drying of water-based plastic composite inner-printing ink becomes problem on printing press like this; And stripping strength is the index of plastic wrapping most critical forever.
Therefore the difficult point of water-based plastic composite inner-printing ink is its printing quality, drying property and stripping strength etc.
Summary of the invention
The invention provides a kind of the need, the water-based inks that the existing relatively solvent ink of combined strength bination, sealing-strength, printing quality all is significantly increased under the existing prerequisite that printing equipment is transformed, typography is adjusted.
In order to address the above problem, the technical solution used in the present invention is: a kind of water-based plastic composite inner-printing ink, formulated by following raw materials in parts by weight:
Aqueous polyurethane emulsion 10-35 part
Water-borne acrylic resin 0-8 part
Water-based wetting dispersing agent 0-7 part
Water-based moistening flatting agent 0.2-2 part
Water-based defoamer 0.1-2 part
PH conditioning agent 0.1-5 part
Pigment 6-30 part
Ethanol 0-5 part
Water 6-73.6 part.
The quid pro quo of aqueous polyurethane emulsion can be aqueous polyurethane colloidal solution or aqueous polyurethane dispersion or watersoluble polyurethane acrylic acid copolymer emulsion.
The quid pro quo of PH conditioning agent can be trolamine or Monoethanolamine MEA BASF or triethylamine.
Pigment can be pigment dyestuff, mineral dye or pigment precast body.
Effect of the present invention is illustrated by following contrast experiment, and experimental result is as follows:
By above-mentioned contrast, a kind of water-based plastic composite inner-printing ink is compared with solvent ink, and drying quite, print speed is suitable, printing effect is better, attachment fastness is suitable, anti-boiling is suitable, recombining process is constant; In stripping strength height, sealing-strength height, the printing ink in the low order of magnitude of VOC content, the printed matter VOC content low two orders of magnitude, safe; Basically poison minimum to human body to environmental hazard.Therefore a kind of water-based plastic composite inner-printing ink printing quality of the present invention is better, drying effect good, stripping strength is higher, safe, to human body poison little, environmental pollution is little, has extremely remarkable advantages.
Embodiment
Embodiment 1
Aqueous polyurethane emulsion 30.0kg
Water-borne acrylic resin 8.0kg
Water-based wetting dispersing agent 5.0kg
Water-based moistening flatting agent 0.5kg
Water-based defoamer 0.4kg
PH conditioning agent 3.0kg
Pigment dyestuff 15.0kg
Ethanol 4.0kg
Water 34.1kg
The manufacturing process of water-based plastic composite inner-printing ink: elder generation is with water-borne acrylic resin, the PH conditioning agent of said ratio, stir in water-based defoamer and the suitable quantity of water adding reactor, be incubated after being warming up to 60 ℃,, make resin liquid up to being dissolved into clear liquid fully; The back that again pigment dyestuff, water-based wetting dispersing agent, water-based defoamer and the remainder water of said ratio stirred is distributed on ball mill≤fineness of 10 μ m, makes mill base; At last remaining ingredient is joined in resin liquid and the mill base by proportioning, stir.
Embodiment 2
Aqueous polyurethane/acrylate copolymer emulsion 25.0kg
Water-borne acrylic resin 7.0kg
Water-based moistening flatting agent 1.2kg
Water-based defoamer 0.2kg
PH conditioning agent 1.8kg
Pigment precast body 20.0kg
Ethanol 4.0kg
Water 40.8kg
Manufacture craft is identical with embodiment 1.
Embodiment 3
Aqueous polyurethane dispersion 20.0kg
Water-borne acrylic resin 5.0kg
Water-based wetting dispersing agent 6.0kg
Water-based moistening flatting agent 0.7kg
Water-based defoamer 0.8kg
Monoethanolamine MEA BASF 0.5kg
Mineral dye 30.0kg
Ethanol 2.0kg
Water 35.0kg
Manufacture craft is identical with embodiment 1.
Embodiment 4
Aqueous polyurethane dispersion 35.0kg
Water-based wetting dispersing agent 0.6kg
Water-based moistening flatting agent 2.0kg
Water-based defoamer 2.0kg
Trolamine 5.0kg
Pigment precast body 6.0kg
Water 50.9kg
Manufacture craft elder generation: stir in aqueous polyurethane dispersion, water-based wetting dispersing agent, water-based moistening flatting agent, water-based defoamer, trolamine, pigment precast body and the suitable quantity of water adding reactor with said ratio, be incubated after being warming up to 50 ℃, be distributed on ball mill up to dissolving back fully≤fineness of 10 μ m, make mill base; Remaining ingredient is joined in the mill base by proportioning, stir.
Embodiment 5
Aqueous polyurethane dispersion 10.0kg
Water-borne acrylic resin 8.0kg
Water-based wetting dispersing agent 7.0kg
Water-based moistening flatting agent 0.2kg
Water-based defoamer 0.1kg
Triethylamine 0.5kg
Pigment dyestuff 13.0kg
Ethanol 5.0kg
Water 56.2kg
Manufacture craft is identical with embodiment 1.
Claims (4)
1. water-based plastic composite inner-printing ink is characterized in that: formulated by following raw materials in parts by weight:
Aqueous polyurethane emulsion 10-35 part
Water-borne acrylic resin 0-8 part
Water-based wetting dispersing agent 0-7 part
Water-based moistening flatting agent 0.2-2 part
Water-based defoamer 0.1-2 part
PH conditioning agent 0.1-5 part
Pigment 6-30 part
Ethanol 0-5 part
Water 6-73.6 part.
2. according to claims 1 described a kind of water-based plastic composite inner-printing ink, it is characterized in that: the quid pro quo of aqueous polyurethane emulsion can be aqueous polyurethane colloidal solution or aqueous polyurethane dispersion or watersoluble polyurethane acrylic acid copolymer emulsion.
3. according to claims 1 described a kind of water-based plastic composite inner-printing ink, it is characterized in that: the quid pro quo of PH conditioning agent can be trolamine or Monoethanolamine MEA BASF or triethylamine.
4. according to the described a kind of water-based plastic composite inner-printing ink of claim 1, it is characterized in that: pigment can be pigment dyestuff, mineral dye or pigment precast body.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200810080075 CN101429359A (en) | 2008-12-08 | 2008-12-08 | Water-based plastic composite inner-printing ink |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200810080075 CN101429359A (en) | 2008-12-08 | 2008-12-08 | Water-based plastic composite inner-printing ink |
Publications (1)
| Publication Number | Publication Date |
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| CN101429359A true CN101429359A (en) | 2009-05-13 |
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| CN 200810080075 Pending CN101429359A (en) | 2008-12-08 | 2008-12-08 | Water-based plastic composite inner-printing ink |
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Cited By (31)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102040884A (en) * | 2009-10-24 | 2011-05-04 | 湖南荷舜油墨科技有限公司 | Alcohol aqueous composite ink formula |
| CN102153910A (en) * | 2011-01-19 | 2011-08-17 | 厦门格林春天环保科技材料有限公司 | Composite special water-based ink for plastic inner printing |
| CN101665639B (en) * | 2009-09-28 | 2012-02-01 | 英科·卡乐油墨(苏州)有限公司 | Aqueous ink |
| CN102352151A (en) * | 2011-08-24 | 2012-02-15 | 哈尔滨大东方卷烟材料科技开发有限责任公司 | Water-based ink for plastic printing and preparation method thereof |
| CN102382515A (en) * | 2011-11-08 | 2012-03-21 | 北京印刷学院 | Environment-friendly, strong acid-resistant, strong base-resistant and steaming-resistant ink and preparation method |
| CN102021837B (en) * | 2009-09-11 | 2012-10-10 | 上海华峰超纤材料股份有限公司 | Superfine fiber synthetic leather, preparation method thereof and printing material composition |
| CN102040883B (en) * | 2009-10-24 | 2013-05-22 | 湖南荷舜油墨科技有限公司 | Steam resisting alcohol soluble inner print composite ink formula |
| CN104031470A (en) * | 2014-06-05 | 2014-09-10 | 哈尔滨绿科科技有限公司 | Water-based laser anti-counterfeit printing ink |
| CN104059429A (en) * | 2014-06-03 | 2014-09-24 | 苏州中亚油墨有限公司 | Water-soluble inner-printing composite plastic ink |
| CN104073058A (en) * | 2014-07-15 | 2014-10-01 | 揭东县富德印刷材料有限公司 | Method for plastic soft package water-based intaglio printing ink |
| CN104212231A (en) * | 2014-08-12 | 2014-12-17 | 安徽猛牛彩印包装有限公司 | Aqueous polyurethane printing ink containing modified grey tile powder |
| CN104212225A (en) * | 2014-08-12 | 2014-12-17 | 安徽猛牛彩印包装有限公司 | Antibacterial durable aqueous polyurethane printing ink |
| CN104449040A (en) * | 2014-12-26 | 2015-03-25 | 英科·卡乐油墨(苏州)有限公司 | Food packaging printing water-borne ink |
| CN104774502A (en) * | 2015-04-29 | 2015-07-15 | 王金海 | Plastic printing ink with acid-base resistance property and preparation method thereof |
| CN104789034A (en) * | 2015-04-29 | 2015-07-22 | 王金海 | UV-aging-resistant plastic ink and preparation method thereof |
| CN106833116A (en) * | 2017-03-06 | 2017-06-13 | 宁波瑞联特油墨有限公司 | A kind of aqueous polyurethane printing-ink and its preparation technology |
| CN106867307A (en) * | 2017-03-23 | 2017-06-20 | 厦门欧化实业有限公司 | A kind of aqueous composite ink and preparation method thereof |
| CN107955477A (en) * | 2017-11-22 | 2018-04-24 | 华南理工大学 | Erythrocyte shape colloidal particle and spherical colloid particles assembly and preparation method and application |
| CN108059877A (en) * | 2018-02-02 | 2018-05-22 | 东周化学工业（昆山）有限公司 | A kind of new flexographic printing water-based ink |
| CN108690398A (en) * | 2018-08-03 | 2018-10-23 | 张家港市五湖新材料技术开发有限公司 | A kind of aqueous composite ink and preparation method thereof |
| CN108753036A (en) * | 2018-06-14 | 2018-11-06 | 黄山新力油墨科技有限公司 | A kind of water-based plastic printing compound oil ink and preparation method thereof |
| CN108864804A (en) * | 2018-05-31 | 2018-11-23 | 开平市源彩化工有限公司 | A kind of aqueous, environmental protective ink |
| CN108976903A (en) * | 2018-07-09 | 2018-12-11 | 昆山昌易德油墨有限公司 | High-performance environment-friendly water-based ink and preparation method thereof |
| CN109111789A (en) * | 2018-09-03 | 2019-01-01 | 厦门欧化实业有限公司 | A kind of no benzene exempts to handle dumb light base gravure ink and preparation method thereof |
| CN109321030A (en) * | 2018-11-07 | 2019-02-12 | 顾洪杰 | Water-based plastic inner printing ink and water-based plastic table printing ink |
| CN110760221A (en) * | 2019-12-12 | 2020-02-07 | 惠州德斯坤化工有限公司 | Water-based plastic gravure ink and preparation method thereof |
| CN112480737A (en) * | 2020-12-29 | 2021-03-12 | 厦门德瑞雅喷码科技有限公司 | Water-based ink composition resistant to boiling |
| CN112759978A (en) * | 2021-01-19 | 2021-05-07 | 广东英科集团股份有限公司 | Water-based gravure ink for BOPP film inner printing and preparation method thereof |
| CN114230839A (en) * | 2022-01-28 | 2022-03-25 | 孙琇芳 | Rapidly degradable polyvinyl alcohol packaging film |
| CN114790348A (en) * | 2021-09-30 | 2022-07-26 | 毛正卫 | Water-based ink for printing on biodegradable film |
| CN115093751A (en) * | 2022-07-01 | 2022-09-23 | 康美包（苏州）有限公司 | Water-based ink composition, preparation method and application thereof, plastic material and package |
-
2008
- 2008-12-08 CN CN 200810080075 patent/CN101429359A/en active Pending
Cited By (39)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102021837B (en) * | 2009-09-11 | 2012-10-10 | 上海华峰超纤材料股份有限公司 | Superfine fiber synthetic leather, preparation method thereof and printing material composition |
| CN101665639B (en) * | 2009-09-28 | 2012-02-01 | 英科·卡乐油墨(苏州)有限公司 | Aqueous ink |
| CN102040884B (en) * | 2009-10-24 | 2013-03-20 | 湖南荷舜油墨科技有限公司 | Alcohol aqueous composite ink formula |
| CN102040883B (en) * | 2009-10-24 | 2013-05-22 | 湖南荷舜油墨科技有限公司 | Steam resisting alcohol soluble inner print composite ink formula |
| CN102040884A (en) * | 2009-10-24 | 2011-05-04 | 湖南荷舜油墨科技有限公司 | Alcohol aqueous composite ink formula |
| CN102153910A (en) * | 2011-01-19 | 2011-08-17 | 厦门格林春天环保科技材料有限公司 | Composite special water-based ink for plastic inner printing |
| CN102153910B (en) * | 2011-01-19 | 2013-08-07 | 厦门格林春天环保科技材料有限公司 | Composite special water-based ink for plastic inner printing |
| CN102352151A (en) * | 2011-08-24 | 2012-02-15 | 哈尔滨大东方卷烟材料科技开发有限责任公司 | Water-based ink for plastic printing and preparation method thereof |
| CN102352151B (en) * | 2011-08-24 | 2013-11-20 | 哈尔滨绿科科技有限公司 | Water-based ink for plastic printing and preparation method thereof |
| CN102382515A (en) * | 2011-11-08 | 2012-03-21 | 北京印刷学院 | Environment-friendly, strong acid-resistant, strong base-resistant and steaming-resistant ink and preparation method |
| CN104059429A (en) * | 2014-06-03 | 2014-09-24 | 苏州中亚油墨有限公司 | Water-soluble inner-printing composite plastic ink |
| CN104031470B (en) * | 2014-06-05 | 2016-08-17 | 哈尔滨绿科科技有限公司 | A kind of aqueous laser anti-forgery ink |
| CN104031470A (en) * | 2014-06-05 | 2014-09-10 | 哈尔滨绿科科技有限公司 | Water-based laser anti-counterfeit printing ink |
| CN104073058A (en) * | 2014-07-15 | 2014-10-01 | 揭东县富德印刷材料有限公司 | Method for plastic soft package water-based intaglio printing ink |
| CN104212231A (en) * | 2014-08-12 | 2014-12-17 | 安徽猛牛彩印包装有限公司 | Aqueous polyurethane printing ink containing modified grey tile powder |
| CN104212225A (en) * | 2014-08-12 | 2014-12-17 | 安徽猛牛彩印包装有限公司 | Antibacterial durable aqueous polyurethane printing ink |
| CN104449040A (en) * | 2014-12-26 | 2015-03-25 | 英科·卡乐油墨(苏州)有限公司 | Food packaging printing water-borne ink |
| CN104789034A (en) * | 2015-04-29 | 2015-07-22 | 王金海 | UV-aging-resistant plastic ink and preparation method thereof |
| CN104774502A (en) * | 2015-04-29 | 2015-07-15 | 王金海 | Plastic printing ink with acid-base resistance property and preparation method thereof |
| CN106833116A (en) * | 2017-03-06 | 2017-06-13 | 宁波瑞联特油墨有限公司 | A kind of aqueous polyurethane printing-ink and its preparation technology |
| CN106867307A (en) * | 2017-03-23 | 2017-06-20 | 厦门欧化实业有限公司 | A kind of aqueous composite ink and preparation method thereof |
| CN107955477A (en) * | 2017-11-22 | 2018-04-24 | 华南理工大学 | Erythrocyte shape colloidal particle and spherical colloid particles assembly and preparation method and application |
| CN107955477B (en) * | 2017-11-22 | 2019-10-18 | 华南理工大学 | Erythrocyte shape colloidal particle and spherical colloid particles assembly and the preparation method and application thereof |
| CN108059877A (en) * | 2018-02-02 | 2018-05-22 | 东周化学工业（昆山）有限公司 | A kind of new flexographic printing water-based ink |
| CN108864804A (en) * | 2018-05-31 | 2018-11-23 | 开平市源彩化工有限公司 | A kind of aqueous, environmental protective ink |
| CN108753036A (en) * | 2018-06-14 | 2018-11-06 | 黄山新力油墨科技有限公司 | A kind of water-based plastic printing compound oil ink and preparation method thereof |
| CN108976903A (en) * | 2018-07-09 | 2018-12-11 | 昆山昌易德油墨有限公司 | High-performance environment-friendly water-based ink and preparation method thereof |
| CN108690398A (en) * | 2018-08-03 | 2018-10-23 | 张家港市五湖新材料技术开发有限公司 | A kind of aqueous composite ink and preparation method thereof |
| CN109111789A (en) * | 2018-09-03 | 2019-01-01 | 厦门欧化实业有限公司 | A kind of no benzene exempts to handle dumb light base gravure ink and preparation method thereof |
| CN109111789B (en) * | 2018-09-03 | 2021-08-17 | 厦门欧化实业有限公司 | Benzene-free treatment-free matte gravure ink and preparation method thereof |
| CN109321030A (en) * | 2018-11-07 | 2019-02-12 | 顾洪杰 | Water-based plastic inner printing ink and water-based plastic table printing ink |
| CN109321030B (en) * | 2018-11-07 | 2021-12-07 | 顾洪杰 | Water-based plastic inner printing ink and water-based plastic surface printing ink |
| CN110760221A (en) * | 2019-12-12 | 2020-02-07 | 惠州德斯坤化工有限公司 | Water-based plastic gravure ink and preparation method thereof |
| CN112480737B (en) * | 2020-12-29 | 2022-06-28 | 厦门德瑞雅喷码科技有限公司 | Water-based ink composition resistant to boiling |
| CN112480737A (en) * | 2020-12-29 | 2021-03-12 | 厦门德瑞雅喷码科技有限公司 | Water-based ink composition resistant to boiling |
| CN112759978A (en) * | 2021-01-19 | 2021-05-07 | 广东英科集团股份有限公司 | Water-based gravure ink for BOPP film inner printing and preparation method thereof |
| CN114790348A (en) * | 2021-09-30 | 2022-07-26 | 毛正卫 | Water-based ink for printing on biodegradable film |
| CN114230839A (en) * | 2022-01-28 | 2022-03-25 | 孙琇芳 | Rapidly degradable polyvinyl alcohol packaging film |
| CN115093751A (en) * | 2022-07-01 | 2022-09-23 | 康美包（苏州）有限公司 | Water-based ink composition, preparation method and application thereof, plastic material and package |
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Open date: 20090513 |