CN101173145A - Water-based gloss oil substituting UV gloss oil - Google Patents
Water-based gloss oil substituting UV gloss oil Download PDFInfo
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- CN101173145A CN101173145A CNA2007101395910A CN200710139591A CN101173145A CN 101173145 A CN101173145 A CN 101173145A CN A2007101395910 A CNA2007101395910 A CN A2007101395910A CN 200710139591 A CN200710139591 A CN 200710139591A CN 101173145 A CN101173145 A CN 101173145A
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Abstract
The invention discloses water-base gloss oil in place of UV gloss oil, in particular to the water base gloss oil in place of the UV gloss oil in the process of gravure printing, flexography printing and offset printing for the lacquer coating. The invention adopts the technical proposal that: the water-base gloss oil is prepared by the raw materials in weight percentage as follows: water-borne acrylic emulsion 63 to 98.5 percent, wet 0.2 to 2 percent, defoamer 0.1 to 2 percent, slipping agent 0.2 to 10 percent, cross-linking agent 0 to 8 percent, proplylene glycol methyl ether 1 to 2 percent, ethanol 0 to 8 percent, and water 0 to 5 percent. The invention has the advantages of even film forming, excellent desiccation performance, realized glossiness for the UV gloss oil, environment protection, safety, and bright application prospect in the market, and is widely used to replace the UV (ultraviolet curing) gloss oil in the printing industry.
Description
Technical field
The water-based gloss oil of a kind of alternative UV gloss oil of the present invention is specifically related to a kind of water-based gloss oil that can substitute the UV gloss oil required in gravure, flexo, the offset printing coating process.
Background technology
Since the last century the nineties, UV gloss oil (ultraviolet light polymerization) gloss oil is low with its VOC content, advantages such as less to the ambient atmosphere negative impact, curing speed is fast, and film forming gloss is high printing industry particularly the paper printing industry of higher gears form application market rapidly.But in use UV gloss oil pungency is very big, and the Acrylic Acid Monomer that is adopted, the required UV light source of curing have very big harm to human body.
Water-based gloss oil is primary solvent with water, in most cases is resin with the acrylate copolymer, and the advantage of water-based gloss oil maximum is its environmental protection, health, security, and it has no adverse effects to atmosphere to environment, and is harmless.
Traditional water-based gloss oil solid content is generally super only 60%, and curing mode adopts heat drying; The resin film forming properties is poor.Because of wherein evaporation of water latent heat is big, dry slow, the resin film forming properties is poor, when coating printing must adopt the version roller (shallow version) of higher netting twine thoroughly to do, and can print flatly, so adopted shallow version, the transfer coating amount is very little, make that the printed matter that adopts water-based gloss oil is more much lower than the printed matter gloss that adopts the UV gloss oil, on the same substrate, UV gloss oil gloss 80 water-based gloss oil gloss can only reach 50.
The maximum technological difficulties that water-based gloss oil substitutes the UV gloss oil are: want to improve film forming thickness, must adopt dark version, how to make film forming smooth under dark version prerequisite, how finish-drying.
Summary of the invention
Problem to be solved by this invention provides a kind of the solution under dark version printing prerequisite, and film forming is smooth, and drying property is good, has reached the glossiness of UV gloss oil, and Environmental Safety can substitute the water-based gloss oil of UV gloss oil fully.
In order to address the above problem, the scheme that the present invention adopts is: a kind of water-based gloss oil of alternative UV gloss oil, formulated by following raw materials by weight:
Aqueous acrylic emulsion 63～98.5%
Base material wetting agent 0.2～2%
Defoamer 0.1～2%
Slip(ping)agent 0.2～10%
Linking agent 0～8%
Propylene glycol monomethyl ether 1～2%
Ethanol 0～8%
Water 0～5%
The manufacturing process of the water-based gloss oil of above-mentioned a kind of alternative UV gloss oil is: the order successively of pressing aqueous acrylic emulsion, base material wetting agent, defoamer, slip(ping)agent, linking agent, propylene glycol monomethyl ether, second alcohol and water, add while stirring, and stir and get final product;
The substitute of above-mentioned ACRYLIC EMULSION is a water-based styrene/acrylic emulsion, or aqueous polyurethane dispersing liquid, or aqueous polyurethane/acrylic copolymeric resin, or modified acrylic acid emulsion, or water-borne acrylic resin solution, or water-based styrene/acrylic resin solution, or acrylic resin modified solution;
The substitute of above-mentioned propylene glycol monomethyl ether is an ethylene glycol ethyl ether, or diethylene glycol ether, or butyl glycol ether, or the Diethylene Glycol butyl ether;
Above-mentioned alcoholic acid substitute is a Virahol, or n-propyl alcohol.
Effect of the present invention is illustrated by following contrast experiment, and experimental result is as follows:
By contrast, the water-based gloss oil of a kind of alternative UV compares with the UV gloss oil that print speed is suitable, effect is consistent, printed matter gloss, post-treatment performance are suitable, does not produce water smoke, little, the printing noresidue smell of on-the-spot smell; On printing quality, can substitute fully, have simultaneously that smell is little, pungency is little, pollution-free substantially, harmless substantially to human body.
Embodiment
Embodiment 1:
A kind of water-based gloss oil of alternative UV gloss oil is made by the component of following proportioning, by weight percentage:
Aqueous acrylic emulsion (model is NeoCryl A-1092) 85%
Base material wetting agent (model is Wet 500) 0.5%
Defoamer (model is Foamex 1488) 0.2%
Slip(ping)agent (model is Ultralube E668H) 5%
Linking agent 4%
Propylene glycol monomethyl ether 1%
Ethanol 3%
Water 1.3%
The manufacturing process of the water-based gloss oil of above-mentioned a kind of alternative UV gloss oil is: the order successively of pressing aqueous acrylic emulsion, base material wetting agent, defoamer, slip(ping)agent, linking agent, propylene glycol monomethyl ether, second alcohol and water, add while stirring, and stir and get final product.
Embodiment 2:
A kind of water-based gloss oil of alternative UV gloss oil is made by the component of following proportioning, by weight percentage:
Modified acrylic acid emulsion (model is JonCryl 74) 92%
Base material wetting agent (model is Wet 500) 0.5%
Defoamer (model is Foamex 822) 2%
Slip(ping)agent (model is Dowcorning 51) 0.5%
Ethylene glycol ethyl ether 1%
Virahol 3%
Water 1%
The manufacturing process of the water-based gloss oil of above-mentioned a kind of alternative UV gloss oil is: press the order successively of modified acrylic acid emulsion, base material wetting agent, defoamer, slip(ping)agent, ethylene glycol ethyl ether, Virahol and water, add while stirring, and stir and get final product.
Embodiment 3:
A kind of water-based gloss oil of alternative UV gloss oil is made by the component of following proportioning, by weight percentage:
(model is NeoCryl A-1049 74.8% to water-borne acrylic resin solution
Base material wetting agent (model is Wet 505) 0.2%
Defoamer (model is Foamex 1488) 1%
Slip(ping)agent (model is Ultralube E668H) 8%
Linking agent 2%
Butyl glycol ether 1%
N-propyl alcohol 8%
Water 5%
The manufacturing process of the water-based gloss oil of above-mentioned a kind of alternative UV gloss oil is: the order successively of pressing water-borne acrylic resin solution, base material wetting agent, defoamer, slip(ping)agent, linking agent, butyl glycol ether, n-propyl alcohol and water, add while stirring, and stir and get final product.
Embodiment 4:
A kind of water-based gloss oil of alternative UV gloss oil is made by the component of following proportioning, by weight percentage:
Water-based styrene/acrylic resin solution (model is NeoCryl A-1044) 98.5%
Base material wetting agent (model is Wet 505) 0.2%
Defoamer (model is Foamex 1488) 0.1%
Slip(ping)agent (model is Ultralube E668H) 0.2%
Diethylene Glycol butyl ether 1%
The manufacturing process of the water-based gloss oil of above-mentioned a kind of alternative UV gloss oil is: the order successively by water-based styrene/acrylic resin solution, base material wetting agent, defoamer, slip(ping)agent and Diethylene Glycol butyl ether adds while stirring, and stirs and get final product.
Embodiment 5:
A kind of water-based gloss oil of alternative UV gloss oil is made by the component of following proportioning, by weight percentage:
Aqueous polyurethane dispersing liquid (model is NeoRez R-984) 63%
Base material wetting agent (model is Wet 500) 2%
Defoamer (model is Foamex 1488) 2%
Slip(ping)agent (model is Ultralube E668H) 10%
Linking agent 8%
Propylene glycol monomethyl ether 2%
Ethanol 8%
Water 5%
The manufacturing process of the water-based gloss oil of above-mentioned a kind of alternative UV gloss oil is: the order successively of pressing aqueous polyurethane dispersing liquid, base material wetting agent, defoamer, slip(ping)agent, linking agent, propylene glycol monomethyl ether, second alcohol and water, add while stirring, and stir and get final product.
Embodiment 6:
A kind of water-based gloss oil of alternative UV gloss oil is made by the component of following proportioning, by weight percentage:
Aqueous polyurethane/acrylic copolymeric resin (model is NeoRez R-2040) 68%
Base material wetting agent (model is Wet 500) 2%
Defoamer (model is Foamex 1488) 2%
Slip(ping)agent (model is Ultralube E668H) 7%
Linking agent 7%
Ethylene glycol ethyl ether 2%
Ethanol 7%
Water 5%
The manufacturing process of the water-based gloss oil of above-mentioned a kind of alternative UV gloss oil is: the order successively of pressing aqueous polyurethane/acrylic copolymeric resin, base material wetting agent, defoamer, slip(ping)agent, linking agent, ethylene glycol ethyl ether, second alcohol and water, add while stirring, and stir and get final product.
Embodiment 7:
A kind of water-based gloss oil of alternative UV gloss oil is made by the component of following proportioning, by weight percentage:
This ethylene/propylene of water-based acid resin solution (model is NeoCryl 352) 78%
Base material wetting agent (model is Wet 500) 2%
Defoamer (model is Foamex 1488) 2%
Slip(ping)agent (model is Ultralube E668H) 5%
Linking agent 5%
Diethylene glycol ether 2%
Virahol 5%
Water 1%
The manufacturing process of the water-based gloss oil of above-mentioned a kind of alternative UV gloss oil is: by the order successively of this ethylene/propylene of water-based acid resin solution, base material wetting agent, defoamer, slip(ping)agent, linking agent, diethylene glycol ether, Virahol and water, add while stirring, and stir and get final product.
Embodiment 8:
A kind of water-based gloss oil of alternative UV gloss oil is made by the component of following proportioning, by weight percentage:
Acrylic resin modified solution (model is NeoCryl 74) 83%
Base material wetting agent (model is Wet 500) 1%
Defoamer (model is Foamex 1488) 1%
Slip(ping)agent (model is Ultralube E668H) 4%
Linking agent 4%
Butyl glycol ether 2%
N-propyl alcohol 4%
Water 1%
The manufacturing process of the water-based gloss oil of above-mentioned a kind of alternative UV gloss oil is: the order successively of pressing aqueous polyurethane dispersing liquid, base material wetting agent, defoamer, slip(ping)agent, linking agent, butyl glycol ether, n-propyl alcohol and water, add while stirring, and stir and get final product.
" NeoCryl ", " NeoRez " and " JonCryl " are the resin trade(brand)name of Avecia NeoResins among the above embodiment, and " Wet " is Degussa Tego Coating﹠amp; The base material wetting agent trade(brand)name of Ink Additivest, " Foamex " is Degussa Tego Coating﹠amp; The defoamer trade(brand)name of Ink Additivest, " Ultralube " is KEIM-ADDITEC Surface GmbH water-based wax emulsion trade(brand)name, " Dowcorning " is Dow CorningCorporation slip(ping)agent trade(brand)name.
Claims (4)
1. the water-based gloss oil of an alternative UV gloss oil is characterized in that: formulated by following raw materials by weight:
Aqueous acrylic emulsion 63～98.5%
Base material wetting agent 0.2～2%
Defoamer 0.1～2%
Slip(ping)agent 0.2～10%
Linking agent 0-～8%
Propylene glycol monomethyl ether 1～2%
Ethanol 0～8%
Water 0～5%
2. according to the water-based gloss oil of claims 1 described a kind of alternative UV gloss oil, it is characterized in that: the substitute of ACRYLIC EMULSION is a water-based styrene/acrylic emulsion, or aqueous polyurethane dispersing liquid, or aqueous polyurethane/acrylic copolymeric resin, or modified acrylic acid emulsion, or water-borne acrylic resin solution, or water-based styrene/acrylic resin solution, or acrylic resin modified solution.
3. according to the water-based gloss oil of claims 1 described a kind of alternative UV gloss oil, it is characterized in that: the substitute of propylene glycol monomethyl ether is an ethylene glycol ethyl ether, or diethylene glycol ether, or butyl glycol ether, or the Diethylene Glycol butyl ether.
4. according to the water-based gloss oil of claims 1 described a kind of alternative UV gloss oil, it is characterized in that: the alcoholic acid substitute is a Virahol, or n-propyl alcohol.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2007101395910A CN101173145A (en) | 2007-10-15 | 2007-10-15 | Water-based gloss oil substituting UV gloss oil |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2007101395910A CN101173145A (en) | 2007-10-15 | 2007-10-15 | Water-based gloss oil substituting UV gloss oil |
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| Publication Number | Publication Date |
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| CN101173145A true CN101173145A (en) | 2008-05-07 |
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| CNA2007101395910A Pending CN101173145A (en) | 2007-10-15 | 2007-10-15 | Water-based gloss oil substituting UV gloss oil |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101967341A (en) * | 2010-09-29 | 2011-02-09 | 中国科学院长春应用化学研究所 | Waterborne wear-resisting ultraviolet-cured glazing oil and preparation method thereof |
| CN101984004A (en) * | 2010-10-28 | 2011-03-09 | 上海曾云化工科技有限公司 | Environment friendly water soluble varnish for high temperature sintered coating and preparation method thereof |
| CN102464917A (en) * | 2010-11-09 | 2012-05-23 | 天津天女化工集团股份有限公司 | Ultraviolet-cured overprinting varnish and its preparation method |
| CN103694775A (en) * | 2013-11-29 | 2014-04-02 | 湖北广彩印刷股份有限公司 | Method of processing offset-printing water-base gloss oil to strengthen printing adaptability |
| CN114231088A (en) * | 2021-12-27 | 2022-03-25 | 中山市中益油墨涂料有限公司 | Strippable water-based protective gloss oil and preparation method thereof |
| CN114855501A (en) * | 2022-05-09 | 2022-08-05 | 江西优科工业材料有限公司 | Water-based ultraviolet curing coating for printing and glazing paper |
-
2007
- 2007-10-15 CN CNA2007101395910A patent/CN101173145A/en active Pending
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101967341A (en) * | 2010-09-29 | 2011-02-09 | 中国科学院长春应用化学研究所 | Waterborne wear-resisting ultraviolet-cured glazing oil and preparation method thereof |
| CN101967341B (en) * | 2010-09-29 | 2013-02-20 | 中国科学院长春应用化学研究所 | Waterborne wear-resisting ultraviolet-cured glazing oil and preparation method thereof |
| CN101984004A (en) * | 2010-10-28 | 2011-03-09 | 上海曾云化工科技有限公司 | Environment friendly water soluble varnish for high temperature sintered coating and preparation method thereof |
| CN101984004B (en) * | 2010-10-28 | 2013-04-24 | 上海智倍环保科技有限公司 | Environment friendly water soluble varnish for high temperature sintered coating and preparation method thereof |
| CN102464917A (en) * | 2010-11-09 | 2012-05-23 | 天津天女化工集团股份有限公司 | Ultraviolet-cured overprinting varnish and its preparation method |
| CN102464917B (en) * | 2010-11-09 | 2013-07-10 | 天津天女化工集团股份有限公司 | Ultraviolet-cured overprinting varnish and its preparation method |
| CN103694775A (en) * | 2013-11-29 | 2014-04-02 | 湖北广彩印刷股份有限公司 | Method of processing offset-printing water-base gloss oil to strengthen printing adaptability |
| CN114231088A (en) * | 2021-12-27 | 2022-03-25 | 中山市中益油墨涂料有限公司 | Strippable water-based protective gloss oil and preparation method thereof |
| CN114855501A (en) * | 2022-05-09 | 2022-08-05 | 江西优科工业材料有限公司 | Water-based ultraviolet curing coating for printing and glazing paper |
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Open date: 20080507 |