CN104449040A - Food packaging printing water-borne ink - Google Patents
Food packaging printing water-borne ink Download PDFInfo
- Publication number
- CN104449040A CN104449040A CN201410829762.2A CN201410829762A CN104449040A CN 104449040 A CN104449040 A CN 104449040A CN 201410829762 A CN201410829762 A CN 201410829762A CN 104449040 A CN104449040 A CN 104449040A
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention relates to food packaging printing water-borne ink. 100 parts by weight of the ink comprises, in proportion, 9-12 parts of water-soluble pure acrylic emulsion, 8-10 parts of water-soluble polyurethane resin, 9-18 parts of pigments, 10-15 parts of PH stabilizers, 5-7 parts of dispersing agents, 3-5 parts of defoaming agents, 2-3 parts of abrasion-resistant agents, 3-5 parts of ethanol and the rest deionized water. Dyes with poor weather resistance of the ink are omitted, combined resin is used, the ink has fine acid and alkali resistance, formula cost is saved, the ink is easily degraded, and environmental pressure is low.
Description
[technical field]
The present invention relates to ink area, particularly one is used for food product pack printing water-based type ink.
[background technology]
Ink is printing common used material, is usually formed by allotments such as pigment, binder, auxiliary agent and solvents, is widely used on the various products such as books and periodicals, packaging, decoration, building decoration.Ink is various in style, has different requirements in all trades and professions, and the ink wherein food product pack used is the most harsh to safety requirements.On the wrapping paper of some candies, owing to containing some soda acid compositions in candy, therefore ink not only itself can not have toxicity, also needs to possess acid-proof alkaline.But traditional food ink formulations is based on nitro-cotton and aldehyde ketone resin, can contain a large amount of halogen and part heavy metal in pigment, weather resistance is poor, undesirable to the tolerance of soda acid especially.Therefore the ink that a kind of nontoxic resistance to acids and bases is provided is needed.
[summary of the invention]
Main purpose of the present invention is to provide a kind of for food product pack printing water-based type ink.
The present invention is achieved through the following technical solutions above-mentioned purpose: a kind of for food product pack printing water-based type ink, the component proportion of every 100 weight part ink is as follows: water-soluble pure-acrylic emulsion resin 9-12 part, water soluble polyurethane resin 8-10 part, pigment 9-18 part, PH stablizer 10-15 part, dispersion agent 5-7 part, defoamer 3-5 part, anti-wear agent 2-3 part, ethanol 3-5 part, clout is deionized water.
Concrete, described water-soluble pure-acrylic emulsion resin is BASF 7602LV type resin.
Concrete, described water soluble polyurethane resin is A101 type resin.
Concrete, described dispersion agent is SP-712 type dispersion agent.
Concrete, described defoamer is AP 1622 type defoamer.
Concrete, described anti-wear agent is PEW-0251 type anti-wear agent.
Concrete, described PH stablizer is the ammoniacal liquor of concentration 28-35%.
Compared with prior art, the present invention is for the beneficial effect of food product pack printing water-based type ink: present invention, avoiding the dyestuff using weathering resistance poor, and employ combination resin, not only there is good resistance to acids and bases, and formulation cost saving, and easily degrade, little to environmental stress.
[embodiment]
Following examples for illustration of the present invention, but are not used for limiting the scope of the invention.
Embodiment 1
First add aqueous ethanolic solution in a reservoir, stirring at normal temperature under the rotating speed of 1000 revs/min of dispersion machines, the ammoniacal liquor adding 10 part 28% slowly, 5 parts of SP-712 type dispersion agents, 3 parts of AP1622 type defoamers and 2 parts of PEW-0251 type anti-wear agents, again slowly add 9 parts of DIC5711 red pigments, then mixed solution is risen heat to 35 DEG C, dispersing speed is to 2000 revs/min simultaneously, stir 40 minutes, then 9 parts of water-soluble pure acrylic latex resins of BASF7602LV type and 8 parts of A101 type water soluble polyurethane resins are added, temperature is kept to be 35 DEG C and to improve mixing speed to 2500 revs/min, reach after 60 seconds/4# examines grace cup until viscosity, get its liquid two roller machines and do color chips, color chips is dissolved in after pulverizing in the solution that 5 parts of ethanol and 49 parts of water makes and obtains ink, then test is smeared.
Embodiment 2
First add aqueous ethanolic solution in a reservoir, stirring at normal temperature under the rotating speed of 1000 revs/min of dispersion machines, the ammoniacal liquor adding 15 part 28% slowly, 7 parts of SP-712 type dispersion agents, 5 parts of AP1622 type defoamers and 3 parts of PEW-0251 type anti-wear agents, again slowly add 18 parts of P-HRE yellow ultramarines, then mixed solution is risen heat to 35 DEG C, dispersing speed is to 2000 revs/min simultaneously, stir 40 minutes, then 12 parts of water-soluble pure acrylic latex resins of BASF7602LV type and 10 parts of A101 type water soluble polyurethane resins are added, temperature is kept to be 35 DEG C and to improve mixing speed to 2500 revs/min, reach after 60 seconds/4# examines grace cup until viscosity, get its liquid two roller machines and do color chips, color chips is dissolved in after pulverizing in the solution that 3 parts of ethanol and 27 parts of water makes and obtains ink, then test is smeared.
Embodiment 3
First add aqueous ethanolic solution in a reservoir, stirring at normal temperature under the rotating speed of 1000 revs/min of dispersion machines, the ammoniacal liquor adding 12 part 35% slowly, 6 parts of SP-712 type dispersion agents, 4 parts of AP1622 type defoamers and 3 parts of PEW-0251 type anti-wear agents, again slowly add 15 parts of FOCUSPB15:4 blue pigmentss, then mixed solution is risen heat to 35 DEG C, dispersing speed is to 2000 revs/min simultaneously, stir 40 minutes, then 10 parts of water-soluble pure acrylic latex resins of BASF7602LV type and 10 parts of A101 type water soluble polyurethane resins are added, temperature is kept to be 35 DEG C and to improve mixing speed to 2500 revs/min, reach after 60 seconds/4# examines grace cup until viscosity, get its liquid two roller machines and do color chips, color chips is dissolved in after pulverizing in the solution that 5 parts of ethanol and 35 parts of water makes and obtains ink, then test is smeared.
Embodiment 4
First add aqueous ethanolic solution in a reservoir, stirring at normal temperature under the rotating speed of 1000 revs/min of dispersion machines, the ammoniacal liquor adding 13 part 28% slowly, 6 parts of SP-712 type dispersion agents, 3 parts of AP1622 type defoamers and 2 parts of PEW-0251 type anti-wear agents, again slowly add 17 parts of CABOT250 black pigments, then mixed solution is risen heat to 35 DEG C, dispersing speed is to 2000 revs/min simultaneously, stir 40 minutes, then 11 parts of water-soluble pure acrylic latex resins of BASF7602LV type and 9 parts of A101 type water soluble polyurethane resins are added, temperature is kept to be 35 DEG C and to improve mixing speed to 2500 revs/min, reach after 60 seconds/4# examines grace cup until viscosity, get its liquid two roller machines and do color chips, color chips is dissolved in after pulverizing in the solution that 4 parts of ethanol and 35 parts of water makes and obtains ink, then test is smeared.
Embodiment 5
First add aqueous ethanolic solution in a reservoir, stirring at normal temperature under the rotating speed of 1000 revs/min of dispersion machines, the ammoniacal liquor adding 14 part 35% slowly, 5 parts of SP-712 type dispersion agents, 4 parts of AP1622 type defoamers and 3 parts of PEW-0251 type anti-wear agents, again slowly add 10 parts of RDIS white pigments, then mixed solution is risen heat to 35 DEG C, dispersing speed is to 2000 revs/min simultaneously, stir 40 minutes, then 11 parts of water-soluble pure acrylic latex resins of BASF7602LV type and 9 parts of A101 type water soluble polyurethane resins are added, temperature is kept to be 35 DEG C and to improve mixing speed to 2500 revs/min, reach after 60 seconds/4# examines grace cup until viscosity, get its liquid two roller machines and do color chips, color chips is dissolved in after pulverizing in the solution that 4 parts of ethanol and 40 parts of water makes and obtains ink, then test is smeared.
Ink performance is tested:
Embodiment 1-5 ink is carried out correlated performance test, and routine in contrast with ink described in CN102382510A, and concrete outcome is in table 1.
Table 1 ink performance is tested:
As shown in Table 1, the ink of embodiment 1-5 is compared with reference examples ink, and sun-proof, acid and alkali-resistance, resistance to essence, crocking resistance are all better than prior art, have a distinct increment to printing performance, and resin accounting in filmogen is comparatively large, and easily degrades.As can be seen here, the ink performance of the present invention's protection is given prominence to, and avoids and uses weathering resistance poor and the dyestuff that cost is higher, formulation cost saving, little to environmental stress.
Above-described is only some embodiments of the present invention.For the person of ordinary skill of the art, without departing from the concept of the premise of the invention, can also make some distortion and improvement, these all belong to protection scope of the present invention.
Claims (7)
1. one kind is printed water-based type ink for food product pack, it is characterized in that the component proportion of every 100 weight part ink is as follows: water-soluble pure-acrylic emulsion resin 9-12 part, water soluble polyurethane resin 8-10 part, pigment 9-18 part, PH stablizer 10-15 part, dispersion agent 5-7 part, defoamer 3-5 part, anti-wear agent 2-3 part, ethanol 3-5 part, clout is deionized water.
2. according to claim 1 for food product pack printing water-based type ink, it is characterized in that: described water-soluble pure-acrylic emulsion resin is BASF 7602LV type resin.
3. according to claim 1 for food product pack printing water-based type ink, it is characterized in that: described water soluble polyurethane resin is A101 type resin.
4. according to claim 1 for food product pack printing water-based type ink, it is characterized in that: described dispersion agent is SP-712 type dispersion agent.
5. according to claim 1 for food product pack printing water-based type ink, it is characterized in that: described defoamer is AP 1622 type defoamer.
6. according to claim 1 for food product pack printing water-based type ink, it is characterized in that: described anti-wear agent is PEW-0251 type anti-wear agent.
7. according to claim 1 for food product pack printing water-based type ink, it is characterized in that: described PH stablizer is the ammoniacal liquor of concentration 28-35%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410829762.2A CN104449040A (en) | 2014-12-26 | 2014-12-26 | Food packaging printing water-borne ink |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410829762.2A CN104449040A (en) | 2014-12-26 | 2014-12-26 | Food packaging printing water-borne ink |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104449040A true CN104449040A (en) | 2015-03-25 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410829762.2A Pending CN104449040A (en) | 2014-12-26 | 2014-12-26 | Food packaging printing water-borne ink |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107177235A (en) * | 2017-06-30 | 2017-09-19 | 太仓市鑫鹤印刷包装有限公司 | A kind of food packaging environmental printing ink and preparation method thereof |
| CN107502039A (en) * | 2017-10-12 | 2017-12-22 | 安徽同利塑胶彩印有限公司 | One kind is used for packaging for foodstuff and prints water-based type ink |
| CN107573757A (en) * | 2017-09-30 | 2018-01-12 | 安徽嘉美包装有限公司 | One kind is used for packaging for foodstuff and prints water-based type ink |
| CN107603333A (en) * | 2017-11-08 | 2018-01-19 | 安徽顺彤包装材料有限公司 | A kind of plastics package printing ink |
| CN108129908A (en) * | 2017-12-22 | 2018-06-08 | 澧县津溥包装制品有限责任公司 | A kind of food packaging timber-used ink and its preparation method and application |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH04328176A (en) * | 1991-04-26 | 1992-11-17 | Toyo Ink Mfg Co Ltd | Aqueous printing ink having boil adaptability |
| CN101429359A (en) * | 2008-12-08 | 2009-05-13 | 山西鹰鲲科技有限公司 | Water-based plastic composite inner-printing ink |
| CN103408994A (en) * | 2013-08-26 | 2013-11-27 | 深圳扬丰印刷有限公司 | Water-based gloss oil and preparation method thereof |
| CN104031470A (en) * | 2014-06-05 | 2014-09-10 | 哈尔滨绿科科技有限公司 | Water-based laser anti-counterfeit printing ink |
-
2014
- 2014-12-26 CN CN201410829762.2A patent/CN104449040A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH04328176A (en) * | 1991-04-26 | 1992-11-17 | Toyo Ink Mfg Co Ltd | Aqueous printing ink having boil adaptability |
| CN101429359A (en) * | 2008-12-08 | 2009-05-13 | 山西鹰鲲科技有限公司 | Water-based plastic composite inner-printing ink |
| CN103408994A (en) * | 2013-08-26 | 2013-11-27 | 深圳扬丰印刷有限公司 | Water-based gloss oil and preparation method thereof |
| CN104031470A (en) * | 2014-06-05 | 2014-09-10 | 哈尔滨绿科科技有限公司 | Water-based laser anti-counterfeit printing ink |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107177235A (en) * | 2017-06-30 | 2017-09-19 | 太仓市鑫鹤印刷包装有限公司 | A kind of food packaging environmental printing ink and preparation method thereof |
| CN107573757A (en) * | 2017-09-30 | 2018-01-12 | 安徽嘉美包装有限公司 | One kind is used for packaging for foodstuff and prints water-based type ink |
| CN107502039A (en) * | 2017-10-12 | 2017-12-22 | 安徽同利塑胶彩印有限公司 | One kind is used for packaging for foodstuff and prints water-based type ink |
| CN107603333A (en) * | 2017-11-08 | 2018-01-19 | 安徽顺彤包装材料有限公司 | A kind of plastics package printing ink |
| CN108129908A (en) * | 2017-12-22 | 2018-06-08 | 澧县津溥包装制品有限责任公司 | A kind of food packaging timber-used ink and its preparation method and application |
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| C06 | Publication | ||
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| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20150325 |