CN108342126A - A kind of water-based ink and preparation method thereof for paper high speed printing - Google Patents
A kind of water-based ink and preparation method thereof for paper high speed printing Download PDFInfo
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- CN108342126A CN108342126A CN201710058289.6A CN201710058289A CN108342126A CN 108342126 A CN108342126 A CN 108342126A CN 201710058289 A CN201710058289 A CN 201710058289A CN 108342126 A CN108342126 A CN 108342126A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/108—Hydrocarbon resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
- C09D11/033—Printing inks characterised by features other than the chemical nature of the binder characterised by the solvent
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
- C09D11/037—Printing inks characterised by features other than the chemical nature of the binder characterised by the pigment
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The present invention relates to a kind of water-based inks and preparation method thereof for paper high speed printing, and the water-based ink includes the content of following components and parts by weight:20 40 parts of 20 50 parts of aqueous color paste, 30 60 parts of binder and aqueous solvent, wherein the binder is selected from one or both of styrene alpha-methyl styrene acrylic copolymer or styrene acrylic hydroethyl acrylate copolymer;When preparation, aqueous color paste is added in aqueous solvent by weight, is sufficiently stirred, until aqueous color paste is completely dissolved;Under stirring, binder is continuously added, is uniformly mixed.Compared with prior art, for the present invention using water as primary solvent, alcohol content is low, further reduces VOC emission, it ensure that the wholesomeness of printed matter, printing adaptability is good, and rate of drying is fast, can be used for high speed printing, simple production process, production cost is low, can be used for large-scale industrial production.
Description
Technical field
The invention belongs to safety and environmental protection pigment and technical field of dye, are related to a kind of aqueous oil for paper high speed printing
Ink and preparation method thereof.
Background technology
Printing industry is inseparable with people’s lives as traditional chemical industry.Currently, most printeries are all
It is defined as seriously polluted type, the ink mainly used due to it is using noxious materials such as benzene classes as solvent, the VOC of this ink
Discharge capacity is big, and can also remain on printed matter, all there are many detrimental effects to environment and human security.With America and Europe
Raising of the country to environmental requirement, every country have formulated all standard and regulation limitation VOC emission.These regulations force printing
Quotient find new technology, have developed the ink of aqueous based systems.
Water-based ink mainly makees solvent with water, thus has in printing process nonflammable, will not damage ink manufacturers
With the health of press operator, the advantage of pollution-free to atmospheric environment equal environmental protection and safety.Water-based ink is as a kind of novel print
Brush ink without certain poisonous and harmful substances in solvent-based ink, therefore will not generate pollution to package goods.Meanwhile it is aqueous
Ink has the advantages that easy cleaning on the printer, to improve production efficiency.Water-based ink at present lead by most important application
Domain is flexible version printing and intaglio printing, and the product of both mode of printings mainly packs product, such as food packaging, tobacco and wine packet
Dress, toy for children packaging etc..
The binder of water-based ink can be single or compound resin, the tolerance substituted with wide component.It is water-soluble
Resin must have following group-OH ,-COOH ,-NH using the strong water of polarity as solvent in resin structure2,=C-O ,-
SO2H ,-Cl ,-O- etc..These hydrophilic radicals provide the water solubility of resin.But water-soluble better, the water-resistance of ink film is poorer,
So should also have lipophilic group appropriate in resin, such as-(CH2-CH2)n, phenyl, containing appropriate carboxyl etc..
It is presently used for water paint, the film forming matter of ink has aqueous alkide resin, amino resins, phenolic resin, asphalt mixtures modified by epoxy resin
Fat and acrylic resin etc..Water polyacrylic acid class has stability high, and glossiness is good, rheological property and surface adsorption property
Good advantage, therefore be applied in ink, coating with preferable development prospect.
Water-based ink is still having certain defect using upper at present, and since water-based ink is using water as solvent, there are rate of dryings
Slow problem can not adapt to high speed printing, it is necessary to certain alcohol is added, and alcohols material still has centainly operator and environment
Harm.Therefore it is imperative to develop a kind of adaptation high speed printing water-based ink of low alcohol.Styrene-acrylic resins are one
The typical acrylic system copolymer of kind is a kind of common water-based ink binder can increase tree by being modified to it
The drying and forming-film performance of fat, to improve the print speed printing speed of ink.
Invention content
It is an object of the present invention to overcome the above-mentioned drawbacks of the prior art and provide a kind of properties to stablize, color
It is beautiful, safety and environmental protection, the fast water-based ink for paper high speed printing of rate of drying.
Another object of the present invention provides the preparation method of the above-mentioned water-based ink for paper high speed printing in time.
The purpose of the present invention can be achieved through the following technical solutions:
A kind of water-based ink for paper high speed printing includes the content of following components and parts by weight:Aqueous color paste 20-
50 parts, 20-40 parts of 30-60 parts of binder and aqueous solvent, wherein the binder is selected from styrene-Alpha-Methyl benzene second
One or both of alkene-acrylic copolymer or Styrene And Chloroalkyl Acrylates-propenoic acid beta-hydroxy ethyl ester copolymer, described is aqueous
Solvent is 1-4 in mass ratio by 95wt% ethyl alcohol and water:1-2 is mixed.
The aqueous color paste includes the content of following components and parts by weight:50-60 parts of pigment, 4-6 parts of wetting agent, dispersion
9-12 parts of agent, 6-10 parts of antioxidant, 0.3-0.45 parts of preservative, 0.3-0.5 parts of mould inhibitor, 0.5-0.7 parts of aqueous defoamer,
Thicken 6-8 parts of anti-settling agent, 6-10 parts of ultra-violet absorber, 30-60 parts of deionized water.
The pigment be titanium dioxide, iron oxide red, middle Huang, lemon yellow, bright red, permanent bordeaux, carbon black, permanent violet, phthalocyanine blue or
In phthalocyanine green any one or it is two or more with the mixed mixture of arbitrary ratio.
The wetting agent is alkyl polyoxyethylene ether solution.
The dispersant is styrene maleic anhydride copolymer solution.
The antioxidant is aromatic amine, Hinered phenols or phosphite antioxidant.
The preservative be the chloro- 2 methyl -3- isothiazolones of 5-, the mould inhibitor be dehydroactic acid sodium, sodium sorbate,
Any one in sodium benzoate or sodium pentachlorophenol, the aqueous defoamer are organic silicon antifoaming agent.
The described thickening anti-settling agent be in modified alta-mud, aerosil or hydroxyethyl cellulose any one or
The two or more mixtures with any combination.
The ultra-violet absorber is that salicylic acid esters, benzophenone class, hindered amines, triazines or benzotriazole are ultraviolet
Any one in light absorbers.
A kind of preparation method of water-based ink for paper high speed printing, this method specifically include following steps:
(1) it presses following components and parts by weight content is stocked up:
20-40 parts of 20-50 parts of aqueous color paste, 30-60 parts of binder and aqueous solvent;
Wherein, aqueous color paste includes the content of following components and parts by weight:50-60 parts of pigment, 4-6 parts of wetting agent, dispersion
9-12 parts of agent, 6-10 parts of antioxidant, 0.3-0.45 parts of preservative, 0.3-0.5 parts of mould inhibitor, 0.5-0.7 parts of aqueous defoamer,
Thicken 6-8 parts of anti-settling agent, 6-10 parts of ultra-violet absorber, 30-60 parts of deionized water;
(2) aqueous color paste is added in aqueous solvent by weight, is sufficiently stirred, until aqueous color paste is completely dissolved;
(3) under stirring, binder is continuously added, is uniformly mixed.
The present invention is based on styrene acrylic polymers to have bloom, the characteristic of quick-drying, by being added in the course of the polymerization process
α-methylstyrene can increase the hardness after resin film forming, and the hardness of resin is higher, and drying property is better;Simultaneously as
Its homopolymerization is difficult, by the control of polymerization technique, can reduce molecular weight and the average molecular weight distribution of polymer, obtain large arch dam
The resin of low viscosity.Propenoic acid beta-hydroxy ethyl ester is a kind of typical flexible unit, can improve the water resistance of resin.
Compared with prior art, the invention has the characteristics that:
1) printing adaptability is good, and rate of drying is fast, can be used for high speed printing;
2) using water as primary solvent, alcohol content is low, further reduces VOC emission, ensure that the health of printed matter
Safety is suitably applied food packaging printing;
3) performance is stablized, and printing figure message is clear, color is full, strong adhesive force, excellent wear-resisting property, and printing effect is good;
4) simple production process, production cost is low, can be used for large-scale industrial production.
Specific implementation mode
With reference to specific embodiment, the present invention is described in detail.
Embodiment 1:
The present embodiment is used for the water-based ink of paper high speed printing, includes the content of following components and parts by weight:Aqueous color
36 parts of 32 parts of slurry, 40 parts of binder and aqueous solvent, wherein binder is styrene-α-methylstyrene-acrylic acid copolymer
Object, aqueous solvent are 4 in mass ratio by 95wt% ethyl alcohol and water:1 mixes.
Wherein, aqueous color paste includes the content of following components and parts by weight:52 parts of pigment, 5 parts of wetting agent, dispersant 10
Part, 8 parts of antioxidant, 0.4 part of preservative, 0.4 part of mould inhibitor, 0.6 part of aqueous defoamer, 7 parts of anti-settling agent of thickening, ultraviolet light suction
Receive 8 parts of agent, 42 parts of deionized water.
Pigment is titanium dioxide, and wetting agent is alkyl polyoxyethylene ether solution, and dispersant is styrene maleic anhydride copolymer
Solution, antioxidant 2,6- three-level butyl -4- methylphenols, preservative are the chloro- 2 methyl -3- isothiazolones of 5-, and mould inhibitor is
Dehydroactic acid sodium, aqueous defoamer are organic silicon antifoaming agent, and thickening anti-settling agent is hydroxyethyl cellulose, and ultra-violet absorber is
Phenyl salicylate
The preparation method of the present embodiment water-based ink, specifically includes following steps:
(1) it presses following components and parts by weight content is stocked up:
36 parts of 32 parts of aqueous color paste, 40 parts of binder and aqueous solvent;
Wherein, aqueous color paste includes the content of following components and parts by weight:52 parts of pigment, 5 parts of wetting agent, dispersant 10
Part, 8 parts of antioxidant, 0.4 part of preservative, 0.4 part of mould inhibitor, 0.6 part of aqueous defoamer, 7 parts of anti-settling agent of thickening, ultraviolet light suction
Receive 8 parts of agent, 42 parts of deionized water;
(2) aqueous color paste is added in aqueous solvent by weight, is sufficiently stirred, until aqueous color paste is completely dissolved
(3) under stirring, binder is continuously added, is uniformly mixed.
Embodiment 2:
The present embodiment is used for the water-based ink of paper high speed printing, includes the content of following components and parts by weight:Aqueous color
40 parts of 50 parts of slurry, 60 parts of binder and aqueous solvent, wherein binder is styrene-α-methylstyrene-acrylic acid copolymer
Object, aqueous solvent are 2 in mass ratio by 95wt% ethyl alcohol and water:1 mixes.
Wherein, aqueous color paste includes the content of following components and parts by weight:60 parts of pigment, 6 parts of wetting agent, dispersant 12
Part, 10 parts of antioxidant, 0.45 part of preservative, 0.5 part of mould inhibitor, 0.7 part of aqueous defoamer, 8 parts of anti-settling agent of thickening, ultraviolet light
10 parts of absorbent, 60 parts of deionized water.
Pigment is phthalocyanine blue, and wetting agent is alkyl polyoxyethylene ether solution, and dispersant is styrene maleic anhydride copolymer
Solution, antioxidant are three monooctyl esters, and preservative is the chloro- 2 methyl -3- isothiazolones of 5-, and mould inhibitor is sodium sorbate, aqueous defoaming
Agent be organic silicon antifoaming agent, thickening anti-settling agent be aerosil, ultra-violet absorber for 2- (2 ' hydroxyls -3 ', 5 '-two
Tertiary phenyl) -5- chlorination benzotriazole.
The preparation method of the present embodiment water-based ink, specifically includes following steps:
(1) it presses following components and parts by weight content is stocked up:
40 parts of 50 parts of aqueous color paste, 60 parts of binder and aqueous solvent;
Wherein, aqueous color paste includes the content of following components and parts by weight:60 parts of pigment, 6 parts of wetting agent, dispersant 12
Part, 10 parts of antioxidant, 0.45 part of preservative, 0.5 part of mould inhibitor, 0.7 part of aqueous defoamer, 8 parts of anti-settling agent of thickening, ultraviolet light
10 parts of absorbent, 60 parts of deionized water;
(2) aqueous color paste is added in aqueous solvent by weight, is sufficiently stirred, until aqueous color paste is completely dissolved
(3) under stirring, binder is continuously added, is uniformly mixed.
Embodiment 3:
The present embodiment is used for the water-based ink of paper high speed printing, includes the content of following components and parts by weight:Aqueous color
20 parts of 20 parts of slurry, 30 parts of binder and aqueous solvent, wherein binder is styrene-α-methylstyrene-acrylic acid copolymer
Object, aqueous solvent are 3 in mass ratio by 95wt% ethyl alcohol and water:2 mix.
Wherein, aqueous color paste includes the content of following components and parts by weight:50 parts of pigment, 4 parts of wetting agent, 9 parts of dispersant,
6 parts of antioxidant, 0.3 part of preservative, 0.3 part of mould inhibitor, 0.5 part of aqueous defoamer thicken 6 parts of anti-settling agent, ultraviolet radiation absorption
6 parts of agent, 30 parts of deionized water.
Pigment is carbon black, and wetting agent is alkyl polyoxyethylene ether solution, and dispersant is that styrene maleic anhydride copolymer is molten
Liquid, antioxidant are aniline, and preservative is the chloro- 2 methyl -3- isothiazolones of 5-, and mould inhibitor is dehydroactic acid sodium, aqueous defoamer
For organic silicon antifoaming agent, thickening anti-settling agent is modified alta-mud, and ultra-violet absorber is 2- hydroxyl -4- methoxyl group hexichol first
Ketone.
The preparation method of the present embodiment water-based ink, specifically includes following steps:
(1) it presses following components and parts by weight content is stocked up:
20 parts of 20 parts of aqueous color paste, 30 parts of binder and aqueous solvent;
Wherein, aqueous color paste includes the content of following components and parts by weight:50 parts of pigment, 4 parts of wetting agent, 9 parts of dispersant,
6 parts of antioxidant, 0.3 part of preservative, 0.3 part of mould inhibitor, 0.5 part of aqueous defoamer thicken 6 parts of anti-settling agent, ultraviolet radiation absorption
6 parts of agent, 30 parts of deionized water;
(2) aqueous color paste is added in aqueous solvent by weight, is sufficiently stirred, until aqueous color paste is completely dissolved
(3) under stirring, binder is continuously added, is uniformly mixed.
Embodiment 4:
The present embodiment is used for the water-based ink of paper high speed printing, includes the content of following components and parts by weight:Aqueous color
38 parts of 45 parts of slurry, 40 parts of binder and aqueous solvent, wherein binder is that Styrene And Chloroalkyl Acrylates-propenoic acid beta-hydroxy ethyl ester is total
Polymers, aqueous solvent are 1 in mass ratio by 95wt% ethyl alcohol and water:1 mixes.
Wherein, aqueous color paste includes the content of following components and parts by weight:Paint red 254 part, 5 parts of wetting agent, dispersant 11
Part, 9 parts of antioxidant, 0.4 part of preservative, 0.4 part of mould inhibitor, 0.6 part of aqueous defoamer, 7 parts of anti-settling agent of thickening, ultraviolet light suction
Receive 9 parts of agent, 51 parts of deionized water.
Pigment is lemon yellow, and wetting agent is alkyl polyoxyethylene ether solution, and dispersant is styrene maleic anhydride copolymer
Solution, antioxidant are aniline, and preservative is the chloro- 2 methyl -3- isothiazolones of 5-, and mould inhibitor is dehydroactic acid sodium, aqueous defoaming
Agent is organic silicon antifoaming agent, and thickening anti-settling agent is modified alta-mud and hydroxyethyl cellulose is 1 in mass ratio:3 mix,
Ultra-violet absorber is ESCALOL 567.
The preparation method of the present embodiment water-based ink, specifically includes following steps:
(1) it presses following components and parts by weight content is stocked up:
38 parts of 45 parts of aqueous color paste, 40 parts of binder and aqueous solvent;
Wherein, aqueous color paste includes the content of following components and parts by weight:Paint red 254 part, 5 parts of wetting agent, dispersant 11
Part, 9 parts of antioxidant, 0.4 part of preservative, 0.4 part of mould inhibitor, 0.6 part of aqueous defoamer, 7 parts of anti-settling agent of thickening, ultraviolet light suction
Receive 9 parts of agent, 51 parts of deionized water;
(2) aqueous color paste is added in aqueous solvent by weight, is sufficiently stirred, until aqueous color paste is completely dissolved
(3) under stirring, binder is continuously added, is uniformly mixed.
The above description of the embodiments is intended to facilitate ordinary skill in the art to understand and use the invention.
Person skilled in the art obviously easily can make various modifications to these embodiments, and described herein general
Principle is applied in other embodiment without having to go through creative labor.Therefore, the present invention is not limited to the above embodiments, ability
Field technique personnel announcement according to the present invention, improvement and modification made without departing from the scope of the present invention all should be the present invention's
Within protection domain.
Claims (10)
1. a kind of water-based ink for paper high speed printing, which is characterized in that the content including following components and parts by weight:Water
Property 20-50 parts of mill base, 20-40 parts of 30-60 parts of binder and aqueous solvent, wherein the binder is selected from styrene-α-
One or both of methyl styrene-acrylic acid copolymer or Styrene And Chloroalkyl Acrylates-propenoic acid beta-hydroxy ethyl ester copolymer, institute
The aqueous solvent stated is 1-4 in mass ratio by 95wt% ethyl alcohol and water:1-2 is mixed.
2. a kind of water-based ink for paper high speed printing according to claim 1, which is characterized in that described is aqueous
Mill base includes the content of following components and parts by weight:50-60 parts of pigment, 4-6 parts of wetting agent, 9-12 parts of dispersant, antioxidant
6-10 parts, 0.3-0.45 parts of preservative, 0.3-0.5 parts of mould inhibitor, 0.5-0.7 parts of aqueous defoamer, 6-8 parts of anti-settling agent of thickening,
6-10 parts of ultra-violet absorber, 30-60 parts of deionized water.
3. a kind of water-based ink for paper high speed printing according to claim 2, which is characterized in that the pigment
For any one in titanium dioxide, iron oxide red, middle Huang, lemon yellow, bright red, permanent bordeaux, carbon black, permanent violet, phthalocyanine blue or phthalocyanine green
Or it is two or more with the mixed mixture of arbitrary ratio.
4. a kind of water-based ink for paper high speed printing according to claim 2, which is characterized in that the wetting
Agent is alkyl polyoxyethylene ether solution.
5. a kind of water-based ink for paper high speed printing according to claim 2, which is characterized in that the dispersion
Agent is styrene maleic anhydride copolymer solution.
6. a kind of water-based ink for paper high speed printing according to claim 2, which is characterized in that the antioxygen
Agent is aromatic amine, Hinered phenols or phosphite antioxidant.
7. a kind of water-based ink for paper high speed printing according to claim 2, which is characterized in that the anti-corrosion
Agent is the chloro- 2 methyl -3- isothiazolones of 5-, and the mould inhibitor is dehydroactic acid sodium, sodium sorbate, sodium benzoate or pentachlorophenol
Any one in sodium, the aqueous defoamer are organic silicon antifoaming agent.
8. a kind of water-based ink for paper high speed printing according to claim 2, which is characterized in that the thickening
Anti-settling agent be modified alta-mud, aerosil or hydroxyethyl cellulose in any one or it is two or more arbitrarily to compare group
The mixture of conjunction.
9. a kind of water-based ink for paper high speed printing according to claim 2, which is characterized in that described is ultraviolet
Light absorbers are any one in salicylic acid esters, benzophenone class, hindered amines, triazines or Benzotriazole Ultraviolet Stabilizer
Kind.
10. a kind of preparation method of water-based ink for paper high speed printing as described in claim 1, which is characterized in that
This method specifically includes following steps:
(1) it presses following components and parts by weight content is stocked up:
20-40 parts of 20-50 parts of aqueous color paste, 30-60 parts of binder and aqueous solvent;
Wherein, aqueous color paste includes the content of following components and parts by weight:50-60 parts of pigment, 4-6 parts of wetting agent, dispersant 9-
12 parts, 6-10 parts of antioxidant, 0.3-0.45 parts of preservative, 0.3-0.5 parts of mould inhibitor, 0.5-0.7 parts of aqueous defoamer, thickening
6-8 parts of anti-settling agent, 6-10 parts of ultra-violet absorber, 30-60 parts of deionized water;
(2) aqueous color paste is added in aqueous solvent by weight, is sufficiently stirred, until aqueous color paste is completely dissolved;
(3) under stirring, binder is continuously added, is uniformly mixed.
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Cited By (4)
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CN111497491A (en) * | 2020-04-28 | 2020-08-07 | 江苏可一文化产业集团股份有限公司 | Manufacturing method of green protection exercise book |
CN111548673A (en) * | 2020-06-05 | 2020-08-18 | 苏州市博来特油墨有限公司 | Green environment-friendly curing printing ink for high-speed printing |
CN111978783A (en) * | 2020-08-14 | 2020-11-24 | 龙利得智能科技股份有限公司 | Environment-friendly printing ink for carton printing and preparation process thereof |
CN112574617A (en) * | 2020-11-30 | 2021-03-30 | 江苏科技大学 | Quick-drying water-based ink composition and preparation method and application thereof |
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111497491A (en) * | 2020-04-28 | 2020-08-07 | 江苏可一文化产业集团股份有限公司 | Manufacturing method of green protection exercise book |
CN111497491B (en) * | 2020-04-28 | 2020-12-22 | 江苏可一文化产业集团股份有限公司 | Manufacturing method of green protection exercise book |
CN111548673A (en) * | 2020-06-05 | 2020-08-18 | 苏州市博来特油墨有限公司 | Green environment-friendly curing printing ink for high-speed printing |
CN111978783A (en) * | 2020-08-14 | 2020-11-24 | 龙利得智能科技股份有限公司 | Environment-friendly printing ink for carton printing and preparation process thereof |
CN112574617A (en) * | 2020-11-30 | 2021-03-30 | 江苏科技大学 | Quick-drying water-based ink composition and preparation method and application thereof |
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