CN103342918A - Highlight high hardness acrylic resin water-based ink - Google Patents
Highlight high hardness acrylic resin water-based ink Download PDFInfo
- Publication number
- CN103342918A CN103342918A CN2013102600725A CN201310260072A CN103342918A CN 103342918 A CN103342918 A CN 103342918A CN 2013102600725 A CN2013102600725 A CN 2013102600725A CN 201310260072 A CN201310260072 A CN 201310260072A CN 103342918 A CN103342918 A CN 103342918A
- Authority
- CN
- China
- Prior art keywords
- acrylic resin
- acetone
- ink
- water color
- resin water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention discloses highlight high hardness acrylic resin water-based ink which is prepared from the following raw materials in percentage by weight: 20-40% of acrylic resin, 10-20% of nitrile rubber, 5-10% of a chloroprene rubber adhesive, 5-10% of acetone, 10-15% of methylbenzene, 5-10% of ethylene glycol butyl ether, 1-5% of a titanate coupler, 20-30% of aluminum paste paint, 1-4% of polyethylene wax, 0.5-3% of aluminum stearate and 0.1-5% of a photocuring photoinitiator. The ink disclosed by the invention can be suitable for printing various plastic carriers and has higher adhesive force and a good adhesive effect. The plastic carriers are not treated on the surface, and can be directly printed, so that highlight bright printing effect can be ensured.
Description
Technical field
The invention belongs to ink area, be specifically related to a kind of highlight high-hardness acrylic resin water color ink.
Background technology
Along with improving constantly of people's environmental consciousness, the water-borne acrylic resin of environment-friendly type in the application in many fields such as coating, tamanori, printing ink more and more widely.As critical material one binder of water color ink, the performance of water-borne acrylic resin greatly affects the quality of printing ink.
Printing ink is mainly formed uniform mixture by materials such as pigment, binder, stopping composition and auxiliary material.Ink used for plastic on the market is aimed at certain plastics and the printing ink that disposes, can not be used for the plastic material of various material.The degree of crystallinity height of polyethylene and polypropylene-base material, anti-dissolubility is strong, and surface polarity and surface energy are low, film to be difficult to adhere to, and must carry out surface treatment before the printing and just can reach adhesion effect, and process complexity and effect are unsatisfactory.Simultaneously, the solvent that contains in the printing ink can volatile emission in printing process, polluted air and influence health of operators.Therefore, reduce the usage quantity of organic solvent in printing ink as far as possible also become the problem that printing ink manufacturing enterprise emphasis is considered.
Water color ink is mainly made solvent with water, thereby in printing process, have nonflammable, can not damage the health that the author is pushed in ink manufacturers and printing violently, advantage to atmospheric environment environmental protection such as pollution-free grade and safety: water color ink is as a kind of novel printing printing ink, do not have that in the solvent type ink some is poisonous, objectionable impurities is residual in printed matter, pollute so can not produce package goods; Simultaneously, water color ink has the advantage of easy cleaning at printing press, thereby has improved productivity.Although water color ink has many advantages with respect to conventional solvent type printing ink, because some inherent characteristicses of water cause water color ink to exist rate of drying slow, shortcomings such as stability, glossiness, rheological property and surface adsorption poor performance.
Summary of the invention
The highlight high-hardness acrylic resin water color ink that provides a kind of environmental protection, low production cost and quality to be easy to control is provided at the deficiencies in the prior art.
Above-mentioned purpose of the present invention is achieved by the following scheme:
A kind of highlight high-hardness acrylic resin water color ink, described printing ink is made by the raw material of following mass percent:
Acrylic resin 20 ~ 40%; Paracril 10 ~ 20%; Neoprene latex 5 ~ 10%; Acetone 5 ~ 10%; Toluene 10 ~ 15%; Butyl glycol ether 5 ~ 10%; Titanate coupling agent 1 ~ 5%; Aluminium paste pigment 20 ~ 30%; Polyethylene wax 1 ~ 4%; Aluminum stearate 0.5 ~ 3 %; UV photocuring light trigger 0.1 ~ 5%.
For the sticking power that improves printing ink to be applicable to different plastic materials, above-mentioned printing ink is made by the raw material of following mass percent:
Acrylic resin 30%; Paracril 12%; Neoprene latex 5%; Acetone 8%; Toluene 10%; Butyl glycol ether 8%; Titanate coupling agent 3%; Aluminium paste pigment 20%; Polyethylene wax 2%; Aluminum stearate 1%; UV photocuring light trigger 1%.
Described photocuring light trigger is the ultraviolet light polymerization light trigger, can select 1-hydroxy-cyclohexyl phenyl-acetone for use.Described acrylic resin can be selected the 2-Hydroxylated acrylic resin for use.
Preparation method of the present invention is as follows: the proportioning according to above-mentioned raw materials takes by weighing corresponding raw material, in the batch mixing bottle, add resin and solvent earlier, stir evenly, add pigment then, being stirred well to does not have till the dry pressed powder, then the raw material that stirs is ground by sand mill, reach in the 200m until its particle diameter, obtain water color ink after filtration.
The using method of water color ink of the present invention is as follows: flame or corona treatment are adopted in the plastic component surface; Printing ink of the present invention is coated on the plastic component surface by screen process press; With ink solidification.
In printing ink of the present invention, paracril is the thermoplasticity synthetic rubber, can significantly improve the sticking power after the printing ink film forming, and pigment is played a protective role, and makes it be difficult to come off; Acetone belongs to strong solvent, and solvency power is extremely strong, and evaporation rate is fast; Toluene belongs to medium solvent, and solvency power is moderate, and evaporation rate is moderate; Butyl glycol ether belongs to excellent surfactant, is again the best solvent of printing ink, and evaporation rate is slow; Polyethylene wax belongs to excellent dispersants, improves dispersing of pigments effect and tinting strength, is used for strengthening gloss and the brightness of printing ink; Aluminum stearate belongs to stablizer, anti-settling agent and rumbling compound, can increase the brightness of printing ink.
Water color ink of the present invention can be used for the printing of various plastic material carriers, has higher sticking power, and adhesion effect is good, and hardness is good, does not need during use the plastic material carrier is carried out surface treatment, can directly print, and can guarantee the printing effect of Gao Guang.
Embodiment
Embodiment 1
Sofa printing ink of the present invention is made by the raw material of following mass percent:
2-Hydroxylated acrylic resin 30%; Paracril 12%; Neoprene latex 5%; Acetone 8%; Toluene 10%; Butyl glycol ether 8%; Titanate coupling agent 3%; Aluminium paste pigment 20%; Polyethylene wax 2%; Aluminum stearate 1%; 1-hydroxy-cyclohexyl phenyl-acetone 1%.
Glossiness and viscosity are observed in the above-mentioned high gloss oil China ink placement for preparing after 24 hours, printing ink is printed off the standard reference example edition by screen process press on vinyon packaging tube surface, solidify the sealing preservation then by the ultraviolet lamp box.
With the printing ink following time period of process, print off example edition respectively and observe and contrast again, the result is as follows: the color and luster through 7 days printing ink does not change; Color and luster through 15 days printing ink does not change; Color and luster through 30 days printing ink does not change.
Embodiment 2
Water color ink of the present invention is made by the raw material of following mass percent:
2-Hydroxylated acrylic resin 30%; Paracril 10%; Neoprene latex 5%; Acetone 8%; Toluene 10%; Butyl glycol ether 5%; Titanate coupling agent 3%; Aluminium paste pigment 25%; Polyethylene wax 2%; Aluminum stearate 1%; 1-hydroxy-cyclohexyl phenyl-acetone 1%.
Embodiment 3
Water color ink of the present invention is made by the raw material of following mass percent:
2-Hydroxylated acrylic resin 30%; Paracril 10%; Neoprene latex 10%; Acetone 8%; Toluene 10%; Butyl glycol ether 5%; Titanate coupling agent 2%; Aluminium paste pigment 21%; Polyethylene wax 2%; Aluminum stearate 1%; 1-hydroxy-cyclohexyl phenyl-acetone 1%.
Applicant's statement, the person of ordinary skill in the field is on the basis of above-described embodiment, concrete content point value with above-described embodiment component, combined with the technical scheme of summary of the invention part, thereby the new numerical range that produces, also be one of record scope of the present invention, the application is no longer enumerated these numerical ranges for making specification sheets simple and clear.
Claims (4)
1. highlight high-hardness acrylic resin water color ink is characterized in that described printing ink is made by the raw material of following mass percent:
Acrylic resin 20 ~ 40%; Paracril 10 ~ 20%; Neoprene latex 5 ~ 10%; Acetone 5 ~ 10%; Toluene 10 ~ 15%; Butyl glycol ether 5 ~ 10%; Titanate coupling agent 1 ~ 5%; Aluminium paste pigment 20 ~ 30%; Polyethylene wax 1 ~ 4%; Aluminum stearate 0.5 ~ 3 %; UV photocuring light trigger 0.1 ~ 5%.
2. a kind of highlight high-hardness acrylic resin water color ink according to claim 1 is characterized in that described printing ink is made by the raw material of following mass percent:
Acrylic resin 30%; Paracril 12%; Neoprene latex 5%; Acetone 8%; Toluene 10%; Butyl glycol ether 8%; Titanate coupling agent 3%; Aluminium paste pigment 20%; Polyethylene wax 2%; Aluminum stearate 1%; UV photocuring light trigger 1%.
3. a kind of highlight high-hardness acrylic resin water color ink according to claim 1 and 2 is characterized in that, described UV photocuring light trigger is 1-hydroxy-cyclohexyl phenyl-acetone.
4. a kind of highlight high-hardness acrylic resin water color ink according to claim 1 and 2 is characterized in that described acrylic resin is the 2-Hydroxylated acrylic resin.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2013102600725A CN103342918A (en) | 2013-06-27 | 2013-06-27 | Highlight high hardness acrylic resin water-based ink |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2013102600725A CN103342918A (en) | 2013-06-27 | 2013-06-27 | Highlight high hardness acrylic resin water-based ink |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103342918A true CN103342918A (en) | 2013-10-09 |
Family
ID=49277749
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2013102600725A Pending CN103342918A (en) | 2013-06-27 | 2013-06-27 | Highlight high hardness acrylic resin water-based ink |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103342918A (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103666050A (en) * | 2013-11-25 | 2014-03-26 | 铜陵方正塑业科技有限公司 | Gloss silk-screen UV-cured printing ink and preparation method thereof |
| CN104356743A (en) * | 2014-10-11 | 2015-02-18 | 惠州市立美特环保油墨有限公司 | UV (ultraviolet) curing rubber printing ink, preparation method thereof and printing method |
| CN105176449A (en) * | 2015-07-24 | 2015-12-23 | 中山市伯伦克专用化学产品有限公司 | UV-curing peelable blue glue and preparation method therefor |
| CN105522834A (en) * | 2016-02-04 | 2016-04-27 | 四川汇利实业有限公司 | Printing technology with automatic ink adding function |
| CN105522833A (en) * | 2016-02-04 | 2016-04-27 | 四川汇利实业有限公司 | Printing technology for composite film for packaging medicines |
| CN107474629A (en) * | 2017-09-26 | 2017-12-15 | 中山市富日印刷材料有限公司 | A kind of high ink and preparation method thereof |
| CN109749155A (en) * | 2017-11-02 | 2019-05-14 | 丹阳市贝尔特橡塑制品有限公司 | A kind of high tenacity rubber material |
-
2013
- 2013-06-27 CN CN2013102600725A patent/CN103342918A/en active Pending
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103666050A (en) * | 2013-11-25 | 2014-03-26 | 铜陵方正塑业科技有限公司 | Gloss silk-screen UV-cured printing ink and preparation method thereof |
| CN103666050B (en) * | 2013-11-25 | 2016-03-23 | 铜陵方正塑业科技有限公司 | A kind of gloss silk-screen UV curing inks and preparation method thereof |
| CN104356743A (en) * | 2014-10-11 | 2015-02-18 | 惠州市立美特环保油墨有限公司 | UV (ultraviolet) curing rubber printing ink, preparation method thereof and printing method |
| CN105176449A (en) * | 2015-07-24 | 2015-12-23 | 中山市伯伦克专用化学产品有限公司 | UV-curing peelable blue glue and preparation method therefor |
| CN105522834A (en) * | 2016-02-04 | 2016-04-27 | 四川汇利实业有限公司 | Printing technology with automatic ink adding function |
| CN105522833A (en) * | 2016-02-04 | 2016-04-27 | 四川汇利实业有限公司 | Printing technology for composite film for packaging medicines |
| CN107474629A (en) * | 2017-09-26 | 2017-12-15 | 中山市富日印刷材料有限公司 | A kind of high ink and preparation method thereof |
| CN109749155A (en) * | 2017-11-02 | 2019-05-14 | 丹阳市贝尔特橡塑制品有限公司 | A kind of high tenacity rubber material |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103342918A (en) | Highlight high hardness acrylic resin water-based ink | |
| CN106590158A (en) | Water-based gravure composite ink for plastic film and preparation method thereof | |
| CN103059644B (en) | Water-based painting brush and preparation method of water-based painting brush | |
| CN102408782B (en) | Transfer printing ink for polypropylene plastics, and preparation method and application thereof | |
| CN104087063A (en) | UV (ultraviolet) photo-curable dip-coating and coloring printing ink and preparation method thereof | |
| CN106590162B (en) | Water-based gravure plastic film surface printing ink and preparation method thereof | |
| CN104194482A (en) | Environment-friendly offset ink and preparation method thereof | |
| CN103305077A (en) | Coating with protection and color alteration functions | |
| CN104073040A (en) | UV-cured white curtaining paint and preparation method thereof | |
| CN105315774A (en) | Environment-friendly printing ink | |
| CN106700723A (en) | Gravure environment-friendly water-based gold-sand printing ink as well as preparation method and application of gravure environment-friendly water-based gold-sand printing ink | |
| CN106488960B (en) | Water-based gravure plastic printing table printing/composite ink, binder and preparation method of water-based gravure plastic printing table printing/composite ink and binder | |
| CN101353498B (en) | Printing ink | |
| CN107189551B (en) | Ultraviolet-curing offset-printing fluorescent anti-counterfeiting ink | |
| CN103756485B (en) | Water-based is coated with tin graphed sheet whitewash and preparation method thereof outward | |
| CN104845447A (en) | Environment-friendly water-based metal printing ink and preparation method thereof | |
| CN104893415A (en) | Environment-friendly water-borne glass ink and preparation method thereof | |
| CN103436098B (en) | Ultraviolet-curing offset printing ink and preparation method thereof | |
| CN105315776A (en) | Printing ink | |
| CN104830210A (en) | Water-based dotting paint | |
| CN109082157B (en) | Ultraviolet curing offset printing ink with ice flower effect and preparation method and application thereof | |
| CN103342940A (en) | Low-temperature water-based glass paint and preparation method thereof | |
| CN103540188A (en) | Aqueous long-wave-ultraviolet-drying package printing ink | |
| CN106590174B (en) | Degradable gravure UV anti-counterfeiting ink and application thereof to gold and silver card paper | |
| CN105802448B (en) | A kind of water-based epoxy zinc rich primer of dual cure |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20131009 |