CN103059644B - Water-based painting brush and preparation method of water-based painting brush - Google Patents
Water-based painting brush and preparation method of water-based painting brush Download PDFInfo
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- CN103059644B CN103059644B CN201310007107.4A CN201310007107A CN103059644B CN 103059644 B CN103059644 B CN 103059644B CN 201310007107 A CN201310007107 A CN 201310007107A CN 103059644 B CN103059644 B CN 103059644B
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Abstract
The invention provides a water-based painting brush. The water-based painting brush comprises the following raw materials in percentage by weight: 10-50% of a polymer film forming substance, 5-60% of filler, 3-20% of excipient, 0.5-10% of film forming additive, 0.01-3% of pigment, 1-15% of moisturizer and 10-50% of water. The painting brush provided by the invention has the characteristics that a wetting agent, a dispersant and an anti-settling agent are not necessary to be added; the water-based painting brush is odorless, environment-friendly and low in cost; and besides, the color retention, the waterproof property and the ultraviolet resistance of painted articles are good, the painted articles stuck on the skin are easy to be cleaned, while the painted articles coated on the wall are unlikely to be washed by the rain after a film is formed.
Description
Technical field
The present invention relates to a kind of draw tool, specifically a kind of water-based drawing pen and preparation method thereof.
Background technology
Current indoor and family's Freehandhand-drawing wall pigment are based on acrylic paints, metope Freehandhand-drawing is useful wall paint also, these pigment mostly are liquid, although can requirement of generally painting be met, but to adhere to because product is raw materials used on skin not easy cleaning and also smell heavier, and making processes needs to add a series of auxiliary agent such as wetting agent, dispersion agent, anti-settling agent, production cost is high and have pollution to environment.
Summary of the invention
The technical problem to be solved in the present invention is to overcome the deficiencies in the prior art, there is provided a kind of without the need to adding wetting agent, dispersion agent, anti-settling agent, odorlessness and environmental protection, the with low cost water-based drawing pen being applicable to body of wall, paper, the works tint retention drawn, water-repellancy and UV resistant performance are good, adhere to easy cleaning on skin and to be applied on wall after film forming not easily by rain-out.The solid coating that the present invention also can be made into large gauge as required substitutes emulsion paint, and its quick construction is convenient, and can not make dirty workmen, environment-protecting asepsis, and film is moist, and rate of drying is fast, and glossiness abrasion resistance is good.
A technical solution of the present invention is:
A kind of water-based drawing pen, it is made up of the raw material of following weight percent: macromolecule filming thing 10-50%, filler 5-60%, excipient 3-20%, film coalescence aid 0.5-10%, pigment 0.01-3%, wetting Agent for Printing Inks 1-15% and water 10-50%.
Described macromolecule filming thing is one or more the mixture in ACRYLIC EMULSION, organosilicon crylic acid latex, fluorine carbon emulsion, benzene emulsion, acrylate and vinyl acetate emulsion.
Described filler is one or more mixtures in titanium dioxide, talcum powder, zinc sulfide white, pure aluminium silicate, Calucium Silicate powder, zinc oxide.
Described excipient is one or more mixtures in sodium stearate, calcium stearate, potassium stearate, agar, lauric acid, palmitinic acid.
Described wetting Agent for Printing Inks is one or more mixtures in glycerine, ethylene glycol, propylene glycol, sorbyl alcohol.
Described film coalescence aid is alcohol ester 12, Tri(propylene glycol)butyl ether,mixture of isomers, tert.-butyl acetate one or more mixtures wherein.
Described water-based drawing pen, preferred materials in percentage by mass consists of: macromolecule filming thing 20-40%, filler 20-40%, excipient 10-15%, film coalescence aid 3-7%, pigment 1-2%, wetting Agent for Printing Inks 5-10% and water 20-40%.
The preparation method of described water-based paintbrush, is made up of following steps:
(1) macromolecule filming thing, film coalescence aid and water are joined in reactor, stir 10-30 minute;
(2) in step (1) described reactor, add filler and pigment, be warming up to 65-90 DEG C and insulation stirring 10-30 minute simultaneously;
(3) in step (2) described reactor, add wetting Agent for Printing Inks and excipient keep 65-90 DEG C and stir obtaining mixture in 10-30 minute;
(4) mixture that step (3) obtains is injected at 65-90 DEG C of temperature mould and be cooled to 0-45 DEG C of shaping formation water-based drawing pen.
Water-based drawing pen of the present invention compared with prior art has following advantage:
1, water-based drawing pen making processes is without the need to adding wetting agent, dispersion agent, anti-settling agent, odorlessness and environmental protection.
2, water-based drawing pen works tint retention, water-repellancy and the UV resistant performance of drawing is good, adheres to easy cleaning on skin and to be applied on wall after film forming not easily by rain-out, being applicable to the drawing on body of wall, paper.
3, the solid coating that water-based drawing pen also can be made into large gauge as required substitutes emulsion paint, and its quick construction is convenient, and can not make dirty workmen, environment-protecting asepsis, and film is moist, and rate of drying is fast, and glossiness abrasion resistance is good.
Another technical solution of the present invention is to provide a kind of preparation method of water-based drawing pen, by following preparation process:
(1) macromolecule filming thing, film coalescence aid and water are joined in reactor, stir 10-30 minute;
(2) in step (1) described reactor, add filler and pigment, be warming up to 65-90 DEG C and insulation stirring 10-30 minute simultaneously;
(3) in step (2) described reactor, add wetting Agent for Printing Inks and excipient keep 65-90 DEG C and stir obtaining mixture in 10-30 minute;
(4) mixture that step (3) obtains is injected at 65-90 DEG C of temperature mould and be cooled to 0-45 DEG C of shaping formation water-based drawing pen.
Water-based drawing pen making processes of the present invention is without the need to adding wetting agent, dispersion agent, anti-settling agent, and making method is simple, is suitable for promoting the use of.
Embodiment
Below by embodiment, the invention will be further described, but the present invention is not limited only to these examples.
The water-based drawing pen that the present invention makes, raw material used is conventional raw material, can buy in chemical products shop and obtain, pigment can be carbon black, acetylene black, iron oxide yellow, zinc yellow, cadmium yellow, Tartrazol yellow, molybdate orange, red iron oxide, manganese violet, Prussian blue, chrome green, zinc white etc., be convention pigment, all can buy in pigment shop and obtain.
Embodiment 1
Make 10000 water-based drawing pens, often prop up 10g, raw material total mass is 100kg.
Take following quality feeds: ACRYLIC EMULSION 15kg, alcohol ester 12 5kg, glycerine 12kg, sodium stearate 8kg, titanium dioxide 10kg, talcum powder 5kg, carbon black 0.1kg, water 44.9kg.
ACRYLIC EMULSION, alcohol ester 12 and water are joined in reactor, stirs 30 minutes, then add titanium dioxide, talcum powder and carbon black in a kettle., be warming up to 85 DEG C and be incubated and stir 25 minutes simultaneously; Then add glycerine in a kettle., sodium stearate keeps 80 DEG C and stir obtaining mixture in 20 minutes; Finally the mixture obtained is injected at 75 DEG C of temperature mould and be cooled to 20 DEG C, obtained shaping water-based drawing pen.
Embodiment 2:
Make 10000 water-based drawing pens, often prop up 10g, raw material total mass is 100kg.
Take following quality feeds: organosilicon crylic acid latex 30kg, tert.-butyl acetate 5kg, ethylene glycol 7kg, sodium stearate 5kg, calcium stearate 7kg, titanium dioxide 25kg, iron oxide yellow 1.5kg, water 19.5kg.
Organosilicon crylic acid latex, tert.-butyl acetate and water are joined in reactor, stirs 30 minutes, then add titanium dioxide and iron oxide yellow in a kettle., be warming up to 85 DEG C and be incubated and stir 25 minutes simultaneously; Then add ethylene glycol in a kettle., sodium stearate, calcium stearate keep 80 DEG C and stir obtaining mixture in 20 minutes; Finally the mixture obtained is injected at 80 DEG C of temperature mould and be cooled to 25 DEG C, obtained shaping water-based drawing pen.
Embodiment 3:
Make 10000 water-based drawing pens, often prop up 10g, raw material total mass is 100kg.
Take following quality feeds: ACRYLIC EMULSION 25kg, fluorine carbon emulsion 15kg, alcohol ester 12 5kg, glycerine 3kg, sorbyl alcohol 1kg, sodium stearate 8kg, lauric acid 3kg, talcum powder 20kg, zinc sulfide white 5kg, zinc yellow 0.3kg, water 14.7kg.
ACRYLIC EMULSION, fluorine carbon emulsion, alcohol ester 12 and water are joined in reactor, stirs 30 minutes, then add talcum powder, zinc sulfide white and zinc yellow in a kettle., be warming up to 85 DEG C and be incubated and stir 25 minutes simultaneously; Then add glycerine in a kettle., sorbyl alcohol, sodium stearate, lauric acid keep 80 DEG C and stir obtaining mixture in 20 minutes; Finally the mixture obtained is injected at 70 DEG C of temperature mould and be cooled to 10 DEG C, obtained shaping water-based drawing pen.
Embodiment 4:
Make 10000 water-based drawing pens, often prop up 10g, raw material total mass is 100kg.
Take following quality feeds: organosilicon crylic acid latex 20kg, ACRYLIC EMULSION 10kg, alcohol ester 12 5kg, tert.-butyl acetate 2kg, ethylene glycol 5kg, sodium stearate 5kg, titanium dioxide 30kg, chrome green 0.2kg, water 22.8kg.
Organosilicon crylic acid latex, ACRYLIC EMULSION, alcohol ester 12, tert.-butyl acetate and water are joined in reactor, stirs 30 minutes, then add titanium dioxide and chrome green in a kettle., be warming up to 85 DEG C and be incubated and stir 25 minutes simultaneously; Then ethylene glycol is added in a kettle. and sodium stearate keeps 80 DEG C and stir obtaining mixture in 20 minutes; Finally the mixture obtained is injected at 85 DEG C of temperature mould and be cooled to 35 DEG C, obtained shaping water-based drawing pen.
Claims (1)
1. a preparation method for water-based paintbrush, is characterized in that: take following quality feeds: ACRYLIC EMULSION 25kg, fluorine carbon emulsion 15kg, alcohol ester 12 5kg, glycerine 3kg, sorbyl alcohol 1kg, sodium stearate 8kg, lauric acid 3kg, talcum powder 20kg, zinc sulfide white 5kg, zinc yellow 0.3kg, water 14.7kg; ACRYLIC EMULSION, fluorine carbon emulsion, alcohol ester 12 and water are joined in reactor, stirs 30 minutes, then add talcum powder, zinc sulfide white and zinc yellow in a kettle., be warming up to 85 DEG C and be incubated and stir 25 minutes simultaneously; Then add glycerine in a kettle., sorbyl alcohol, sodium stearate, lauric acid keep 80 DEG C and stir obtaining mixture in 20 minutes; Finally the mixture obtained is injected at 70 DEG C of temperature mould and be cooled to 10 DEG C, obtained shaping water-based drawing pen.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310007107.4A CN103059644B (en) | 2013-01-09 | 2013-01-09 | Water-based painting brush and preparation method of water-based painting brush |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201310007107.4A CN103059644B (en) | 2013-01-09 | 2013-01-09 | Water-based painting brush and preparation method of water-based painting brush |
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| Publication Number | Publication Date |
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| CN103059644A CN103059644A (en) | 2013-04-24 |
| CN103059644B true CN103059644B (en) | 2015-05-20 |
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| CN201310007107.4A Expired - Fee Related CN103059644B (en) | 2013-01-09 | 2013-01-09 | Water-based painting brush and preparation method of water-based painting brush |
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Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ES2526270B1 (en) * | 2013-06-05 | 2015-12-11 | Grup 8 S.A. | SOLID TEMPERA AND ITS MANUFACTURING PROCEDURE |
| CN103540178B (en) * | 2013-10-22 | 2016-08-17 | 李俊强 | solid construction paint and preparation method thereof |
| CN104354491B (en) * | 2014-09-30 | 2016-08-24 | 浙江理工大学 | Child's paintbrush |
| TW201710412A (en) * | 2015-09-07 | 2017-03-16 | 吳文州 | A waterproof paint formula and a pen device for using the same |
| CN109385147B (en) * | 2018-11-07 | 2021-09-03 | 哈尔滨隆之道科技有限公司 | Matte pencil lead and preparation method thereof |
| CN110437677A (en) * | 2019-08-13 | 2019-11-12 | 周宇阳 | A kind of preparation method of the color stick of aqueous lubricating type drawing |
| CN111253804B (en) * | 2020-04-08 | 2022-10-21 | 齐齐哈尔大学 | Solid painting brush for art design and preparation method thereof |
| CN114316678A (en) * | 2022-02-24 | 2022-04-12 | 盐城工业职业技术学院 | Cloth painting water color pen coating ink and preparation method thereof |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
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| JP4393055B2 (en) * | 2002-11-26 | 2010-01-06 | 株式会社パイロットコーポレーション | Solid drawing material |
| CN1301303C (en) * | 2004-09-22 | 2007-02-21 | 上海乐美文具有限公司 | Drawing colour rod and its making method |
| CN101033354B (en) * | 2007-04-10 | 2010-09-15 | 上海乐美文具有限公司 | Water-based multipurpose painting pen |
| KR100991362B1 (en) * | 2008-09-19 | 2010-11-02 | 이길원 | Composition of hydrophilic chalk and manufacturing method thereof |
| KR20100022946A (en) * | 2009-09-24 | 2010-03-03 | 주식회사 유니바이오 | The composition and method to manufacture pastel crayon for diy(do it yourself) |
| JP5602527B2 (en) * | 2010-07-26 | 2014-10-08 | 株式会社パイロットコーポレーション | Solid drawing material |
| CN102533006A (en) * | 2011-12-28 | 2012-07-04 | 上海乐美文具有限公司 | High-melting-point solid highlighter |
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