CN102533006A - High-melting-point solid highlighter - Google Patents
High-melting-point solid highlighter Download PDFInfo
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- CN102533006A CN102533006A CN2011104484876A CN201110448487A CN102533006A CN 102533006 A CN102533006 A CN 102533006A CN 2011104484876 A CN2011104484876 A CN 2011104484876A CN 201110448487 A CN201110448487 A CN 201110448487A CN 102533006 A CN102533006 A CN 102533006A
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- compsn
- pointer
- high melting
- present
- melting solid
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Abstract
The invention provides a solid highlighter composition, which comprises the ingredients in parts by weight shown in the specifications. The invention provides a highlighter capable of ensuring the writing performance and simultaneously providing excellent high-temperature-resistant performance, as well as a preparation method and a purpose of the highlighter.
Description
Technical field
The present invention relates to a kind of e-Pointer, relate to a kind of high melting solid e-Pointer particularly.
Background technology
Existing in the market e-Pointer is the fluorescent liquid pen mostly.This type e-Pointer is very popular in children and student, can be used for drawing, makes card by hand, in addition because the bright-colored fluorescence that has, also is applicable to mark that student and clerical workforce are used to take down notes etc. etc.The shortcoming of such e-Pointer is, because the fluorescent liquid pen is an aqueous product, has the phenomenon of spreading and sinking in when painting on some paper with it, causes the figure delineate unintelligible easily, influence drawing quality.Simultaneously, when when on the writing that some water-base inks are write or printed, marking, being partly dissolved writing with it, it is unclear to cause that the handwriting is blurred.In addition, the fluorescent liquid ink be can in pen, careless slightly, easily leakage, adversary and clothing pollute.And existing solid paintbrush mainly comprises wax crayon, artistic oil painting stick, chalk etc.; Wax crayon and artistic oil painting stick mainly are made up of paraffin, oils and pigment, and used starting material are water insoluble, draw mark and are difficult for wiping; And the color and luster of wax crayon is vivid inadequately, can't use as the mark in the notes etc.Chalk is prone to wipe, and shortcoming is to use condition limited, and can produce a large amount of dust.
Chinese patent publication number CN 1634719A discloses " a kind of paintbrush ", and this invention is formulated in proportion by fatty acid soaps, wetting Agent for Printing Inks and pigment.But this paintbrush only adopts a kind of auxiliary agent, and writing quality is relatively poor, and color is not vivid, is not with fluorescence.
Chinese patent publication number CN 101412868 (application number 200810079842.5) discloses " a kind of solid fluorescent paintbrush ", and this invention is formulated in proportion by soda soap, StNa, optical dye, tensio-active agent, connection material, softening agent, sucrose and zero(ppm) water.This paintbrush does not have dust, and environmentally safe is harmless.
Chinese patent publication number CN 201712305U (application number 201020242087.0) discloses utility model " a kind of transparent solid fluorescence pen ".
The solid fluorescence that makes an in the market resistance to elevated temperatures is all bad, summer preserve or the long haul process in, temperature is higher, this paintbrush possibly melt in this process, thereby has influenced use properties even can not use.
In sum, this area lacks the e-Pointer that outstanding resistance to elevated temperatures is provided in the writing quality that guarantees e-Pointer.The e-Pointer of outstanding resistance to elevated temperatures is provided when therefore, this area presses for a kind of warranty write performance of exploitation.
Summary of the invention
First purpose of the present invention provides the e-Pointer compsn of outstanding resistance to elevated temperatures when being to obtain a kind of warranty write performance.
Second purpose of the present invention provides the e-Pointer of outstanding resistance to elevated temperatures when being to obtain a kind of warranty write performance.
The 3rd purpose of the present invention provides the preparation method of the e-Pointer of outstanding resistance to elevated temperatures when being to obtain a kind of warranty write performance.
In first aspect of the present invention, a kind of high melting solid e-Pointer compsn is provided, the component of said compsn is counted by weight and is comprised:
In an embodiment of the present invention, described water soluble resin is selected from one or more in Z 150PH or the Vinylpyrrolidone polymer.
In an embodiment, said water is zero(ppm) water.
In an embodiment of the present invention, described water soluble resin is selected from Z 150PH 1799; Perhaps Vinylpyrrolidone polymer K-90.
In an embodiment of the present invention, described tensio-active agent is selected from any one in X 2073, sodium laurylsulfonate, the sodium lauryl sulphate.
In an embodiment of the present invention, described softening agent is selected from one or more in terepthaloyl moietie, Ucar 35 or the USP Kosher.
In an embodiment of the present invention, said vehicle is selected from StNa.
The high melting solid e-Pointer that second aspect of the present invention provides a kind of described compsn to make.
In an embodiment of the present invention, its heat resistance is not less than between 60 degrees centigrade.
The third aspect of the invention provides a kind of preparation method of e-Pointer, and it comprises the steps:
Compsn of the present invention is provided;
Said compsn is carried out mixing moulding, obtain said high melting solid e-Pointer.
In an embodiment of the present invention, the zero(ppm) water that takes by weighing aequum earlier under agitation adds water soluble resin in reaction kettle; Heating also is stirred to dissolving fully, then StNa is joined retort, continues heated and stirred to fusion; Add tensio-active agent, softening agent, dyestuff etc. afterwards in proportion; Stir, pour mould, moulding, cooling then into, promptly get the high melting solid e-Pointer.
Embodiment
The inventor through improving preparation technology, has obtained a kind of resistant to elevated temperatures e-Pointer of writing quality while that guarantees e-Pointer through extensive and deep research.Accomplished the present invention on this basis.
Technical conceive of the present invention is set forth as follows:
The purpose of this invention is to provide and a kind ofly can be used for painting or high melting solid e-Pointer that mark uses.This excellent core adopts water-based system, uses water soluble resin, is used toughness and hardness that a certain amount of softening agent improves barred body, and adding tensio-active agent, dyestuff, vehicle can make.The raw material that adopts in the prescription makes the barred body that moulding obtains can anti-60 ℃ of high temperature, in use drawing smooth, be prone to colouring, and do not fall bits, no dust, environmentally safe, harmless; When drawing or mark, feel is soft, smooth, bright-colored, band fluorescence.
Among the present invention, term " contains " or the various compositions of " comprising " expression can be applied in mixture of the present invention or the compsn together.
" HMP " of the present invention is meant: fusing point is not less than 60 ℃; And the fusing point of the drawing pen of prior art is generally between 50-55 ℃.
Below detail to various aspects of the present invention:
High melting solid e-Pointer compsn
High melting solid e-Pointer compsn of the present invention, the component of wherein said compsn is counted by weight and is comprised:
The not concrete restriction of the kind of water of the present invention, only otherwise goal of the invention of the present invention is produced restriction to get final product.In an embodiment, said water is zero(ppm) water.
Among the present invention, described water soluble resin is with connecting material.
In an embodiment of the present invention, described water soluble resin is selected from one or more in Z 150PH or the Vinylpyrrolidone polymer.
Preferred, in an embodiment of the present invention, described water soluble resin is selected from Z 150PH 1799; Perhaps Vinylpyrrolidone polymer K-90.
The consumption of said water soluble resin is the 1-15 parts by weight, preferred 2-15 parts by weight.
Among the present invention, described tensio-active agent is used to improve the lubricity that excellent core is write.
In an embodiment of the present invention, described tensio-active agent is selected from any one in X 2073, sodium laurylsulfonate, the sodium lauryl sulphate.
Among the present invention, described softening agent can increase the toughness and the hardness of excellent core, reduces simultaneously to fall the bits problem when writing, and for example can be selected from polyvalent alcohol, polyoxyethylene glycol, terepthaloyl moietie, Ucar 35 or the USP Kosher one or more.
In an embodiment of the present invention, described softening agent is selected from one or more in terepthaloyl moietie, Ucar 35 or the USP Kosher.
In an embodiment of the present invention, said vehicle is selected from StNa.
The high melting solid e-Pointer that the present invention obtains, its heat resistance is not less than between 60 degrees centigrade.Also promptly in the warranty write performance, fusing point is not less than 60 ℃; And the fusing point of the drawing pen of prior art is generally between 50-55 ℃.
The preparation method of e-Pointer of the present invention comprises the steps:
Compsn of the present invention is provided;
Said compsn is carried out mixing moulding, obtain said high melting solid e-Pointer.
In an embodiment of the present invention, the zero(ppm) water that takes by weighing aequum earlier under agitation adds water soluble resin in reaction kettle; Heating also is stirred to dissolving fully, then StNa is joined retort, continues heated and stirred to fusion; Add tensio-active agent, softening agent, dyestuff etc. afterwards in proportion; Stir, pour mould, moulding, cooling then into, promptly get the high melting solid e-Pointer.
Specify like nothing, various raw materials of the present invention all can obtain through commercially available; Or prepare according to the ordinary method of this area.Only if definition or explanation are arranged in addition, the same meaning that all specialties used herein and scientific words and those skilled in the art are familiar with.Any in addition with the institute similar content of putting down in writing or the equalization method and material all can be applicable in the inventive method.
Other aspects of the present invention are because the disclosure of this paper is conspicuous to those skilled in the art.
Below in conjunction with specific embodiment, further set forth the present invention.Should be understood that these embodiment only to be used to the present invention is described and be not used in the restriction scope of the present invention.The experimental technique of unreceipted actual conditions in the following example is measured according to national standard usually.If there is not a corresponding national standards, then carry out according to general international standard, normal condition or according to the condition that manufacturer advises.Unless otherwise indicated, otherwise all umbers are weight part, and all per-cents are weight percentage, and described polymericular weight is a number-average molecular weight.
Only if definition or explanation are arranged in addition, the same meaning that all specialties used herein and scientific words and those skilled in the art are familiar with.Any in addition with the institute similar content of putting down in writing or the equalization method and material all can be applicable in the inventive method.
Embodiment 1
The zero(ppm) water that takes by weighing aequum earlier under agitation adds and gathers ethanol 1799 in reaction kettle, is heated to 90 ℃ and be stirred to dissolving fully; Be cooled to 80 ℃ and StNa joined retort then; Continue heated and stirred to complete fusion, add X 2073, Macrogol 4000, fluorescein etc. afterwards in proportion, stir; Pour mould, moulding, cooling then into, promptly get the high melting solid e-Pointer.
Embodiment 2
The zero(ppm) water that takes by weighing aequum earlier under agitation adds and gathers ethanol 1799 in reaction kettle, is heated to 90 ℃ and be stirred to dissolving fully; Be cooled to 80 ℃ and StNa joined retort then; Continue heated and stirred to complete fusion, add sodium lauryl sulphate, polyvalent alcohol, fluorescent yellow etc. afterwards in proportion, stir; Pour mould, moulding, cooling then into, promptly get the high melting solid e-Pointer.
Embodiment 3
The zero(ppm) water that takes by weighing aequum earlier under agitation adds Vinylpyrrolidone polymer K-90 in reaction kettle, be heated to 80 ℃ and be stirred to fully dissolving; Then StNa is joined retort; Continue heated and stirred to complete fusion, add sodium lauryl sulphate, polyvalent alcohol, fluorescent yellow etc. afterwards in proportion, stir; Pour mould, moulding, cooling then into, promptly get the high melting solid e-Pointer.
The comparative example
The zero(ppm) water that takes by weighing aequum earlier is in reaction kettle; Be heated to 80 ℃, then StNa joined retort, continue heated and stirred to fusion; Add sodium lauryl sulphate, terepthaloyl moietie, fluorescent yellow dye etc. afterwards in proportion; Stir, pour mould, moulding, cooling then into, promptly get the solid fluorescence pen.
Performance embodiment
The solid fluorescence pen of embodiment 1～3 preparation, bright-colored, write lubricated smooth, the not cleer and peaceful phenomenon of spreading and sinking in that can not cause when mark that the handwriting is blurred, excellent core was preserved 4 hours in 60 ℃ of exsiccators, did not have obviously distortion and thawing phenomenon.The excellent core that Comparative Examples makes is preserved in 50 ℃ of exsiccators promptly had ruckbildung in 4 hours.
The above is merely preferred embodiment of the present invention; Be not in order to limit essence technology contents scope of the present invention; Essence technology contents of the present invention is broadly to be defined in the claim scope of application, and if any technological entity or method that other people accomplish are defined identical with the claim scope of application; Also or a kind of change of equivalence, all will be regarded as and be covered by among this claim scope.
All documents in that the present invention mentions are all quoted as a reference in this application, are just quoted such as a reference separately as each piece document.Should be understood that in addition that after having read foregoing of the present invention those skilled in the art can do various changes or modification to the present invention, these equivalent form of values fall within the application's appended claims institute restricted portion equally.
Claims (10)
1. a high melting solid e-Pointer compsn is characterized in that, the component of said compsn is counted by weight and comprised:
2. compsn as claimed in claim 1 is characterized in that described water soluble resin is selected from one or more in Z 150PH or the Vinylpyrrolidone polymer.
3. compsn as claimed in claim 1 is characterized in that described water soluble resin is selected from Z 150PH 1799; Perhaps Vinylpyrrolidone polymer K-90.
4. compsn as claimed in claim 1 is characterized in that described tensio-active agent is selected from any one in X 2073, sodium laurylsulfonate, the sodium lauryl sulphate.
5. compsn as claimed in claim 1 is characterized in that described softening agent is selected from one or more in terepthaloyl moietie, Ucar 35 or the USP Kosher.
6. compsn as claimed in claim 1 is characterized in that said vehicle is selected from StNa.
7. high melting solid e-Pointer that compsn as claimed in claim 1 makes.
8. e-Pointer as claimed in claim 7 is characterized in that its heat resistance is not less than between 60 degrees centigrade.
9. the preparation method of an e-Pointer as claimed in claim 7 is characterized in that, comprises the steps:
Compsn as claimed in claim 1 is provided;
Said compsn is carried out mixing moulding, obtain said high melting solid e-Pointer.
10. method as claimed in claim 9 is characterized in that the zero(ppm) water that takes by weighing aequum earlier is in reaction kettle; Under agitation add water soluble resin, heat and be stirred to fully and dissolve, then StNa is joined retort; Continue heated and stirred to fusion, add tensio-active agent, softening agent, dyestuff etc. afterwards in proportion, stir; Pour mould, moulding, cooling then into, promptly get the high melting solid e-Pointer.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011104484876A CN102533006A (en) | 2011-12-28 | 2011-12-28 | High-melting-point solid highlighter |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011104484876A CN102533006A (en) | 2011-12-28 | 2011-12-28 | High-melting-point solid highlighter |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102533006A true CN102533006A (en) | 2012-07-04 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2011104484876A Pending CN102533006A (en) | 2011-12-28 | 2011-12-28 | High-melting-point solid highlighter |
Country Status (1)
| Country | Link |
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| CN (1) | CN102533006A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103059644A (en) * | 2013-01-09 | 2013-04-24 | 宁波新安涂料有限公司 | Water-based painting brush and preparation method of water-based painting brush |
| WO2014195532A1 (en) * | 2013-06-05 | 2014-12-11 | Grup 8 S.A. | Solid tempera and method for manufacturing same |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1634719A (en) * | 2004-12-17 | 2005-07-06 | 深圳市深蓝德精细化工科技有限公司 | Drawing pen |
| CN101412868A (en) * | 2008-11-14 | 2009-04-22 | 山西大学 | Solid fluorescent paintbrush |
| CN201712305U (en) * | 2010-06-29 | 2011-01-19 | 王建平 | Transparent solid nite writer pen |
| CN102079901A (en) * | 2010-12-08 | 2011-06-01 | 宋仕良 | Method for manufacturing environmental-protection water-based pigment pen |
-
2011
- 2011-12-28 CN CN2011104484876A patent/CN102533006A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1634719A (en) * | 2004-12-17 | 2005-07-06 | 深圳市深蓝德精细化工科技有限公司 | Drawing pen |
| CN101412868A (en) * | 2008-11-14 | 2009-04-22 | 山西大学 | Solid fluorescent paintbrush |
| CN201712305U (en) * | 2010-06-29 | 2011-01-19 | 王建平 | Transparent solid nite writer pen |
| CN102079901A (en) * | 2010-12-08 | 2011-06-01 | 宋仕良 | Method for manufacturing environmental-protection water-based pigment pen |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103059644A (en) * | 2013-01-09 | 2013-04-24 | 宁波新安涂料有限公司 | Water-based painting brush and preparation method of water-based painting brush |
| US9752041B2 (en) | 2013-05-06 | 2017-09-05 | Grup 8, S.A. | Solid tempera and method for manufacturing same |
| WO2014195532A1 (en) * | 2013-06-05 | 2014-12-11 | Grup 8 S.A. | Solid tempera and method for manufacturing same |
| CN105339447A (en) * | 2013-06-05 | 2016-02-17 | 歌鲁普8公司 | Solid tempera and method for manufacturing same |
| EP3006520A4 (en) * | 2013-06-05 | 2017-06-21 | Grup 8 S.A. | Solid tempera and method for manufacturing same |
| CN105339447B (en) * | 2013-06-05 | 2018-02-13 | 歌鲁普8公司 | Solid Dan Peila and its manufacture method |
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| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20120704 |