CN105400292A - Active dye ink - Google Patents

Active dye ink Download PDF

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Publication number
CN105400292A
CN105400292A CN201610006537.8A CN201610006537A CN105400292A CN 105400292 A CN105400292 A CN 105400292A CN 201610006537 A CN201610006537 A CN 201610006537A CN 105400292 A CN105400292 A CN 105400292A
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CN
China
Prior art keywords
reactive
dye ink
reactive dye
ink
mass percent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610006537.8A
Other languages
Chinese (zh)
Inventor
葛惠德
王雪亮
王吉祥
李朝阳
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shanghai Anoky Digital Technology Co Ltd
Shanghai Anoky Group Co Ltd
Original Assignee
Shanghai Anoky Digital Technology Co Ltd
Shanghai Anoky Group Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shanghai Anoky Digital Technology Co Ltd, Shanghai Anoky Group Co Ltd filed Critical Shanghai Anoky Digital Technology Co Ltd
Priority to CN201610006537.8A priority Critical patent/CN105400292A/en
Publication of CN105400292A publication Critical patent/CN105400292A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/30Inkjet printing inks
    • C09D11/32Inkjet printing inks characterised by colouring agents
    • C09D11/328Inkjet printing inks characterised by colouring agents characterised by dyes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/30Inkjet printing inks
    • C09D11/38Inkjet printing inks characterised by non-macromolecular additives other than solvents, pigments or dyes
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/38General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using reactive dyes
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/445Use of auxiliary substances before, during or after dyeing or printing
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/64General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
    • D06P1/642Compounds containing nitrogen
    • D06P1/649Compounds containing carbonamide, thiocarbonamide or guanyl groups
    • D06P1/6495Compounds containing carbonamide -RCON= (R=H or hydrocarbons)
    • D06P1/6497Amides of di- or polyamines; Acylated polyamines
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/64General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
    • D06P1/651Compounds without nitrogen
    • D06P1/65106Oxygen-containing compounds
    • D06P1/65118Compounds containing hydroxyl groups
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/653Nitrogen-free carboxylic acids or their salts
    • D06P1/6533Aliphatic, araliphatic or cycloaliphatic
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/008Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated using reactive dyes
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/30Ink jet printing

Abstract

The invention discloses active dye ink, which is prepared from an active dye, an auxiliary and deionized water, wherein the auxiliary is prepared from dihydric alcohol, urea and a surfactant; the mass percent of the dihydric alcohol is 10.0 percent to 35.0 percent, the mass percent of the urea is 8.0 percent to 12.0 percent; the active dye ink does not contain a humectant, a quick drying agent and a buffer agent. According to the active dye ink disclosed by the invention, the humectant, the quick drying agent and the buffer agent in the existing formula are omitted, and the printing fluency and the printing permeability are also improved while the active dye ink has the current active dye ink performance, the higher fixation rate requirement on textile print can be met, the damage on a nozzle of a digital printing machine is lesser, and then the service life of the nozzle is prolonged, the cost of digital inkjet printing is lowered, and the popularization of the digital inkjet printing in China is quickened.

Description

Reactive dye ink
Technical field
The invention belongs to digital ink-jet printed field, be specifically related to a kind of reactive dye ink.
Background technology
Digital ink-jet printed technology is the product of modern science and technology application that formed gradually along with the development of computer technology a kind of integrates computer digital animation, precision optical machinery, optoelectronic information technology.Digital ink-jet printed technology for textiles starts from 20 century 70s, completes the transformation from technology model to production application the nineties.Help one of industry of development as state key, the digital ink-jet printed technology of textiles relies on its obvious green printing technique and unique stamp mode, progressively substitutes traditional printing in textiles technology in the whole world.
After 2000, the digital ink-jet printed technology of textiles is rapidly developed, centre experienced by from be mainly used in textile printing and dyeing early stage draw a design small serial production again to the transition process of large-scale production.Subsequently, textiles digital ink-jet printedly progressively penetrate into clothes, multiple field such as family is spun, automobile decoration, design, advertisement, personalized customization, on-line shop.Nearly ten years, the digital ink-jet printed amount of global textiles was almost every two years doubled, and presents the situation of accelerated development.At present, the digital ink-jet printed ratio in China's textile printing industry is up to about l0%.
Ink is as the digital ink-jet printed basic consumptive material of textiles, and its quality determines digital ink-jet printed quality of textile products.At present, also there is a big difference compared with same kind of products at abroad for the digital ink-jet printed ink overall quality of China's textiles, domestic at present have corresponding product, but owing to being subject to the impact of the correlated condition such as starting material, technology, differing a lot of qualitatively with same kind of products at abroad, cannot substituting import one product, raw-material supply is also restricted, price also cannot reduce, and printing and dyeing mill's cost also cannot decline.Domestic like product price is compared with import ink, does not have too large competitive edge.Wherein, (American-European, Japan and Korea S) monopolization is almost abroad for high-end ink technologies such as high-speed digital are ink-jet printed.Above-mentioned, become the major obstacle affecting China's digit printing industry and popularize and develop.
Reactive dye ink is the one in the digital ink-jet printed ink of textiles, has ink flow good, saturation ratio advantages of higher, is subject to the extensive concern of researchist.In current technology, the formula of common reactive dye ink is as shown in table 1, and percentage ratio is mass percent.
The existing reactive dye ink formula of table 1
Components Name or type External product consumption % Home products consumption %
Monohydroxy-alcohol 1~2 2~5
Dibasic alcohol 5~10 3~5
Trivalent alcohol 2~8 5~10
Binary or ternary alcohol ether 2~3 3~5
Sanitas 0.2~0.5 0.2~0.5
Buffer reagent 2~5 2~5
Tensio-active agent 0.2~0.4 0.2~0.4
Urea 2~5 2~3
Dyestuff 8~15 8~15
Add deionized water extremely 100 100
But existing reactive dye ink in textiles digit printing, mostly there is ink printthrough more shallow, printed fabric is bright-coloured not, and degree of fixation is low, and prints the defects such as smooth not because blocking shower nozzle.
Summary of the invention
The defects such as existing reactive dye ink printthrough in textiles digit printing is poor, fabric stamp is not bright-coloured in order to overcome in the present invention, and degree of fixation is low and block shower nozzle and cause printing not smooth, and provide a kind of reactive dye ink.Reactive dye ink provided by the invention decreases wetting Agent for Printing Inks, quick dry agent and buffer reagent in existing formula, while possessing existing reactive dye ink performance, also improve and print fluency and printthrough, meet the degree of fixation demand that printing in textiles is higher, the damage of the shower nozzle of logarithmic code printing machine is less, and then the shower nozzle life-span can be extended, and reduce digital ink-jet printed cost, digital ink-jet printed at home universal can be accelerated.
The present inventor finds under study for action, in the prior art formula shown in table 1, as the trivalent alcohol of wetting Agent for Printing Inks, mainly prevents digital decorating machine shower nozzle dry; As the monohydroxy-alcohol of quick dry agent, binary or ternary alcohol ether, in order to improve the rate of drying after ink printed, but wetting Agent for Printing Inks and quick dry agent deposit, make the serious contravention of formula own.May be come because the reactive dye ink on market mainly extends from marking ink, and marking ink consumption is little, the existence of this contradiction affect printing effect, and therefore, such contradiction is ignored by those skilled in the art always.Meanwhile, the buffer reagent in above-mentioned formula is generally salts substances, can corrode to a certain extent or blocking digital decorating machine shower nozzle, reduce the shower nozzle life-span, the fluency that impact prints.
The present invention solves above-mentioned technical problem by the following technical solutions.
The invention provides a kind of reactive dye ink, comprise reactive dyestuffs, auxiliary agent and deionized water, described auxiliary agent comprises dibasic alcohol, urea and nonionogenic tenside; The mass percent of described dibasic alcohol is 10.0% ~ 35.0%, and the mass percent of described urea is 8.0% ~ 12.0%; Wherein, described reactive dye ink is not containing wetting Agent for Printing Inks, quick dry agent and buffer reagent.
Wherein, in existing reactive dye ink, described wetting Agent for Printing Inks generally refers to trivalent alcohol, and its effect is generally and prevents digital decorating machine shower nozzle dry; Described quick dry agent generally refers to monohydroxy-alcohol, glycol ether or ternary alcohol ether, and its effect is generally the rate of drying after improving ink printed; Described buffer reagent generally refers to pH buffer reagent, and its effect is generally and hinders reactive dye ink pH change.
Wherein, described reactive dyestuffs can be the reactive dyestuffs that this area routine uses, preferably for having the reactive dyestuffs of a chloro-s-triazine or a fluorine pyridine active group, be more preferably one or more in C.I. reactive yellow 95, C.I. Reactive Red 24, C.I. Reactive Red 2 18, C.I. reactive blue 49, C.I. Reactive blue 72, C.I. reactive black 8, C.I. reactive black 39, C.I. reactive black 5, the active palm fibre 12 of C.I. and C.I. REACTIVE ORANGE 13; The consumption that the mass percent of described reactive dyestuffs in described reactive dye ink can refer to reactive dyestuffs in the regular activated dye ink in this area is selected, and is preferably 8.0% ~ 15.0%.
Wherein, described dibasic alcohol can be the dibasic alcohol that this area routine uses, and preferably for carbonatoms is the dibasic alcohol of 2 ~ 5, being more preferably one or more in ethylene glycol, propylene glycol, butyleneglycol and pentanediol, is ethylene glycol best; The mass percent of described dibasic alcohol in described reactive dye ink is preferably 20% ~ 30%.
Wherein, the mass percent of described urea in described reactive dye ink is preferably 9% ~ 11%.
Wherein, described nonionogenic tenside is the nonionic surface active agent that this area routine uses, be preferably oxyethyl group acetylenic diols tensio-active agent, the article number more preferably produced for gas chemical company of the U.S. is one or more in Surfynol420, Surfynol440, Surfynol465 and Surfynol485 tensio-active agent; The consumption that the mass percent of described nonionogenic tenside in described reactive dye ink can refer to tensio-active agent in the regular activated dye ink in this area is selected, and is preferably 0.2% ~ 0.4%.
In reactive dye ink of the present invention, also sanitas can be comprised; Described sanitas can be the sanitas that this area routine uses, it is preferably the food preservatives kind allowing in " foodstuff additive use standard " (GB2760-2011) to use, such as phenylformic acid, Sodium Benzoate, 4-phenylphenol, 2-phenylphenol sodium, Sorbic Acid and potassium sorbate etc., be more preferably Sorbic Acid; The consumption that the mass percent of described sanitas in described reactive dye ink can refer to sanitas in the regular activated dye ink in this area is selected, and is preferably 0.2% ~ 0.4%.
A kind of screening formulation of reactive dye ink provided by the invention is as shown in table 2:
Table 2
Reactive dye ink of the present invention can adopt this area ordinary method Homogeneous phase mixing to form.
Without prejudice to the field on the basis of common sense, above-mentioned each optimum condition, can arbitrary combination, obtains the preferred embodiments of the invention.
Agents useful for same of the present invention and raw material are all commercially.
Positive progressive effect of the present invention is:
1) reactive dye ink provided by the invention decreases wetting Agent for Printing Inks (trivalent alcohol), quick dry agent (monohydroxy-alcohol, binary or ternary alcohol ether) and the buffer reagent in existing formula, make formula more reasonable, while possessing existing reactive dye ink performance, also improve and print fluency and printthrough, and the damage of the shower nozzle of logarithmic code printing machine is less, and then the shower nozzle life-span can be extended;
2) reactive dye ink provided by the invention in use, can ensure the fluency when continuous seepage, ensures to produce to carry out smoothly, meets 1pass and print;
3) in reactive dye ink provided by the invention, color and luster is rich and gaudy, and printing and dyeing quality better, meets the degree of fixation demand that printing in textiles is higher;
4) invent the reactive dye ink that provides at aspect of performance, meet or exceed the kind of imported product; Product of the present invention completely can import substitutes, can reduce digital ink-jet printed cost, accelerate digital ink-jet printed at home universal.
Embodiment
Mode below by embodiment further illustrates the present invention, but does not therefore limit the present invention among described scope of embodiments.The experimental technique of unreceipted actual conditions in the following example, conventionally and condition, or selects according to catalogue.
The formula of the reactive dye ink of embodiment 1 ~ 9 is as shown in table 3, and in table 3, percentage ratio is mass percent.
Wherein, embodiment 1 reactive dyestuffs used are C.I. Reactive Red 2 18, and dibasic alcohol is ethylene glycol, and tensio-active agent is the Surfynol465 of gas chemical company of the U.S., and sanitas is Sorbic Acid;
Embodiment 2 reactive dyestuffs used are C.I. Reactive blue 72, and dibasic alcohol is ethylene glycol, and tensio-active agent is the Surfynol465 of gas chemical company of the U.S., and sanitas is Sorbic Acid;
Embodiment 3 reactive dyestuffs used are the active palm fibre 12 of C.I. reactive black 39 and C.I., and dibasic alcohol is ethylene glycol, and tensio-active agent is the Surfynol465 of gas chemical company of the U.S., and sanitas is Sorbic Acid;
Embodiment 4 reactive dyestuffs used are C.I. REACTIVE ORANGE 13, and dibasic alcohol is ethylene glycol, and tensio-active agent is the Surfynol465 of gas chemical company of the U.S., and sanitas is Sorbic Acid.
Embodiment 5 reactive dyestuffs used are C.I. reactive yellow 95, and dibasic alcohol is propylene glycol, and tensio-active agent is the Surfynol420 of gas chemical company of the U.S., and sanitas is potassium sorbate.
Embodiment 6 reactive dyestuffs used are C.I. Reactive Red 24, and dibasic alcohol is butyleneglycol, and tensio-active agent is the Surfynol440 of gas chemical company of the U.S., and sanitas is 4-phenylphenol.
Embodiment 7 reactive dyestuffs used are C.I. reactive blue 49, and dibasic alcohol is pentanediol, and tensio-active agent is the Surfynol485 of gas chemical company of the U.S., and sanitas is phenylformic acid.
Embodiment 8 reactive dyestuffs used are C.I. reactive black 8, and dibasic alcohol is ethylene glycol, and tensio-active agent is the Surfynol465 of gas chemical company of the U.S., and sanitas is 2-phenylphenol sodium.
Embodiment 9 reactive dyestuffs used are C.I. reactive black 5, and dibasic alcohol is ethylene glycol, and tensio-active agent is the Surfynol465 of gas chemical company of the U.S., and sanitas is Sodium Benzoate.
Table 3
Effect example
Test the environmental protection of imported product, other products domestic and the embodiment of the present invention 1 ~ 4 product, dress ornament performance, color and luster, 1pass production continuously, ink storage time limit and printing textile colour fastness index respectively.Wherein, the colour fastness to washing in printing textile colour fastness index measures by the method specified in ISO105-C03-1989; Colour fastness to light measures by the method specified in AATCC16-2004, and testing standard is 20h; Colour fastness to rubbing measures by the method specified in GB/T3920-2008.Measurement result is as shown in table 4.
Table 4
Above data presentation, product of the present invention completely can import substitutes, and some aspect is better than imported product.After this product appears on the market, can greatly reduce digital ink-jet printed cost, accelerate digital ink-jet printed at home universal.

Claims (10)

1. a reactive dye ink, it comprises reactive dyestuffs, auxiliary agent and deionized water, and described auxiliary agent comprises dibasic alcohol, urea and tensio-active agent; The mass percent of described dibasic alcohol is 10.0% ~ 35.0%, and the mass percent of described urea is 8.0% ~ 12.0%; Wherein, described reactive dye ink is not containing wetting Agent for Printing Inks, quick dry agent and buffer reagent.
2. reactive dye ink as claimed in claim 1, it is characterized in that, described reactive dyestuffs are the reactive dyestuffs with a chloro-s-triazine or a fluorine pyridine active group, are preferably one or more in C.I. reactive yellow 95, C.I. Reactive Red 24, C.I. Reactive Red 2 18, C.I. reactive blue 49, C.I. Reactive blue 72, C.I. reactive black 8, C.I. reactive black 39, C.I. reactive black 5, the active palm fibre 12 of C.I. and C.I. REACTIVE ORANGE 13.
3. reactive dye ink as claimed in claim 1 or 2, it is characterized in that, the mass percent of described reactive dyestuffs in described reactive dye ink is 8.0% ~ 15.0%.
4. reactive dye ink as claimed in claim 1, is characterized in that, described dibasic alcohol to be carbonatoms be 2 ~ 5 dibasic alcohol, be preferably one or more in ethylene glycol, propylene glycol, butyleneglycol and pentanediol.
5. the reactive dye ink as described in claim 1 or 4, is characterized in that, the consumption of described dibasic alcohol is 20% ~ 30%.
6. reactive dye ink as claimed in claim 1, it is characterized in that, the consumption of described urea is 9% ~ 11%.
7. reactive dye ink as claimed in claim 1, it is characterized in that, described tensio-active agent is oxyethyl group acetylenic diols tensio-active agent, and the article number preferably produced for gas chemical company of the U.S. is one or more in Surfynol420, Surfynol440, Surfynol465 and Surfynol485 tensio-active agent; The mass percent of described tensio-active agent in described reactive dye ink is preferably 0.2% ~ 0.4%.
8. reactive dye ink as claimed in claim 1, is characterized in that, in described reactive dye ink, also comprise sanitas.
9. reactive dye ink as claimed in claim 8, is characterized in that, described sanitas is one or more in phenylformic acid, Sodium Benzoate, 4-phenylphenol, 2-phenylphenol sodium, Sorbic Acid and potassium sorbate.
10. reactive dye ink as claimed in claim 8 or 9, it is characterized in that, the mass percent of described sanitas in described reactive dye ink is preferably 0.2% ~ 0.4%.
CN201610006537.8A 2016-01-06 2016-01-06 Active dye ink Pending CN105400292A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2019513883A (en) * 2016-03-16 2019-05-30 富士フイルム株式会社 ink
WO2022004585A1 (en) * 2020-06-29 2022-01-06 ブラザー工業株式会社 Water-based ink for inkjet recording and ink cartridge

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TW589352B (en) * 2002-03-15 2004-06-01 Everlight Chem Ind Corp Ink compositions for ink-jet textile printing
CN102443314A (en) * 2011-10-26 2012-05-09 日冠(福建)针纺织机械有限公司 Cold dyeing digital direct injection printing ink and its application technology
CN103224729A (en) * 2013-05-02 2013-07-31 浙江亿得化工有限公司 Active dye gravure printing ink and preparation method thereof, and method for applying active dye gravure printing ink for printing

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TW589352B (en) * 2002-03-15 2004-06-01 Everlight Chem Ind Corp Ink compositions for ink-jet textile printing
CN102443314A (en) * 2011-10-26 2012-05-09 日冠(福建)针纺织机械有限公司 Cold dyeing digital direct injection printing ink and its application technology
CN103224729A (en) * 2013-05-02 2013-07-31 浙江亿得化工有限公司 Active dye gravure printing ink and preparation method thereof, and method for applying active dye gravure printing ink for printing

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2019513883A (en) * 2016-03-16 2019-05-30 富士フイルム株式会社 ink
US10544318B2 (en) 2016-03-16 2020-01-28 Fujifilm Corporation Inks
WO2022004585A1 (en) * 2020-06-29 2022-01-06 ブラザー工業株式会社 Water-based ink for inkjet recording and ink cartridge

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Application publication date: 20160316