CN106046956A - Insulating water-based coating and preparation method for same - Google Patents

Insulating water-based coating and preparation method for same Download PDF

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Publication number
CN106046956A
CN106046956A CN201610621028.6A CN201610621028A CN106046956A CN 106046956 A CN106046956 A CN 106046956A CN 201610621028 A CN201610621028 A CN 201610621028A CN 106046956 A CN106046956 A CN 106046956A
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China
Prior art keywords
parts
insulation
water paint
synergist
preparation
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CN201610621028.6A
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Chinese (zh)
Inventor
张国文
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Anqing Ruitai Chemical Co Ltd
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Anqing Ruitai Chemical Co Ltd
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Priority to CN201610621028.6A priority Critical patent/CN106046956A/en
Publication of CN106046956A publication Critical patent/CN106046956A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D115/00Coating compositions based on rubber derivatives
    • C09D115/02Rubber derivatives containing halogen
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses an insulating water-based coating, which is prepared from the following raw materials: chlorinated rubber resin, pure acrylic emulsion, vinyl resin, hydroxyl-acrylic resin, methyl isobutyl ketone, butanol, glycol ether, a synergist, a leveling agent, a curing agent, glass powder, nanometer magnesium oxide, de-ionized water and pentaerythritol. A preparation method comprises the following steps: (1) preparing a mixed solution; (2) preparing suspension; (3) preparing a solution; (4) uniformly mixing the solutions and the suspension obtained in the steps, and performing filtration to obtain a finished product. According to the insulating water-based coating, organic high polymer materials with higher comprehensive performance are optimally combined, so that the insulation performance of a composition is improved; the preparation method is simple, lower in cost, short in production cycle and suitable for industrial production, and has better economic benefits and social benefits, resources and energy sources are fully utilized, and a production process is environment-friendly and pollution-free.

Description

A kind of water paint of insulation and preparation method thereof
Technical field
The invention belongs to coating industry technical field, relate to a kind of water paint, the aqueous particularly relating to a kind of insulation is coated with Material and preparation method thereof.
Background technology
Coating, at the entitled paint of Chinese tradition, refer to coat body surface can form thin film under certain conditions and Play protection, a class I liquid I of decoration or other specific functions (insulation, antirust, mildew-resistant, heat-resisting etc.) or solid material.Because of early stage Coating is mostly with vegetable oil as primary raw material, therefore also referred to as paint.Synthetic resin instead of vegetable oil now, therefore is referred to as being coated with Material.Coating belongs to organic chemical industry's macromolecular material, and the film formed belongs to macromolecular compound type.Current according to the modern times The classification of chemical products, coating belongs to fine chemical product.Modern coating the most progressively becomes a polyfunctional engineering of class Material, is an important industry in chemical industry.
At present, the coating industry of China is the most ripe, and market is close to saturated, in addition in the overall situation of green economy globalization Under, people become more concerned with economy the most flourishing after, environment is by great destruction.Along with new " environmental law " promulgates, country is " green Environmental protection, beautiful China " etc. environmental protection advocate the most no longer to stay on slogan, but implement to perform, implement to promote energetically green The development of color science and technology industry.Traditional coating is one of important sources of air major pollutants VOC, by the aqueous of environmental protection Paint replacement paint is the most imperative.Compare traditional paint, and water paint is the one of environment-friendly type paint, and it saves oil Coal resources, and free from environmental pollution, it is to guide consumption to realize energy-saving and emission-reduction.2015, China's Coating Market sales volume 15,000,000 About Dun, the industrial paint accounting by 70% converts, and paint consumption then reaches ten million ton, not only wastes 5,000,000 tons of energy, crucial It is to cause 5,000,000 tons of toxic and harmful discharges to air.Paint consumes the energy and pollutes environment, and it is big row in the common people consume Its road, runs in the opposite direction with national energy consumption revolution requirement and guide.Along with the enhancing of people's environmental consciousness, water paint will Being widely used, research and development water paint has the biggest economic benefit and social benefit.Existing water paint can To apply the application in industries such as pharmacy, food, hospital, weaving, chemical industry, electronics.Water paint from raw material sources to produce and The Life cycle used, the most beneficially sound development of environment.It is the most in process of production by volatile organic solvent Substitute, and when using, coating tool can wash by water, and decreases the consumption of cleaning solvent.The production of organic solvent needs to disappear Consumption fossil feedstock, is a major challenge to resource in the present stage of resource scarcity, and the appearance of water paint solves this and asks Topic.Meanwhile, the reduction of solvent, greatly reduce the discharge of VOC during producing and using, for improving week Limit atmospheric environment has made positive contribution.
Country curbs environmental pollution severely, and national environmental consciousness promotes, consuming behavior changes, the sealing wax coating of energy-conserving and environment-protective Industry is just welcoming unprecedented opportunity to develop, and market presents " blowout formula " Requirement.Efforts To Develop basic research, reduces The difficulty of construction of water paint, improve serviceability, be water paint expansive approach field, extensive popularization and application when business Anxious.Meanwhile, strengthen policy guides, promotional technique, transformation concept, the elimination public the prejudice of water paint and misgivings etc. The attention of related work, also will play the effect of promotion to the application development of water paint.As Green Product, aqueous is coated with Material necessarily obtains the accreditation of people and is widely used.Before the market demand huge in the face of water paint and ever-increasing application Scape, strengthens research and development capabilities, and updates and promote the properties of product of water paint, accelerates product quality upgrading, develops in skill The water paint more showing powerful competitive advantage in art, on cost, in performance has the meaning of reality and wide market Space.
Summary of the invention
The invention aims to overcome the deficiencies in the prior art, it is provided that the water paint of a kind of insulation and Preparation method, this coating products excellent performance, there are good insulating properties, and energy-conserving and environment-protective, possess preferable economic benefit And social benefit.
For solve above-mentioned technical problem, the present invention by the following technical solutions:
The water paint of a kind of insulation, is prepared by the raw materials in: chlorinated rubber resin 15~35 parts, pure third breast Liquid 5~20 parts, vinyl 5~20 parts, Hydroxylated acrylic resin 3~15 parts, hexone 3~15 parts, butanol 0.3 ~1.5 parts, ethylene glycol 0.5~2 parts, synergist 0.3~1.5 parts, levelling agent 0.3~1.2 parts, firming agent 0.2~1 part, Glass dust 1~5 parts, nano magnesia 2~8 parts, deionized water 20~45 parts, tetramethylolmethane 3~15 parts;
Its preparation method in turn includes the following steps:
(1) by chlorinated rubber resin, pure-acrylic emulsion, vinyl, Hydroxylated acrylic resin, hexone and fourth Alcohol is put in reaction vessel, is slowly heated to 40~50 DEG C, is stirred continuously and is uniformly completely dissolved to material, obtains mixed liquor standby With;
(2) glass dust, nano magnesia, ethylene glycol are joined in blender with tetramethylolmethane, be stirred continuously straight To mix homogeneously, obtain suspension standby;
(3) synergist, levelling agent, firming agent are dissolved in deionized water and obtain solution;
(4), after the suspension that mixed liquor step (1) prepared and step (2) prepare is mixed and stirred for uniformly, step is added Suddenly the solution that (3) prepare, continues to stir, and crosses 100~200 mesh sieves, gets product.
Preferably, described synergist is that butyl triphenyl is fluorinated phosphine.
Preferably, described levelling agent is polyester modification siloxanes.
Preferably, described firming agent is isocyanates.
The beneficial effects of the present invention is:
The present invention, by using combination property preferably high-molecular organic material and carrying out optimum organization, improves compositions Insulating properties, use the coating surface that obtains of the present invention smooth, fine and smooth, smooth, gloss retention is good, hot strength and extension at break Rate is superior to common coating, can meet coated-body and use requirement for anticorrosion, weather-proof etc.;Preparation method of the present invention is simple, it is achieved Making full use of of resource and the energy, production process is environment friendly and pollution-free, and cost is relatively low, with short production cycle, be suitable to industrial mass Produce, possess preferable economic benefit and social benefit.
Detailed description of the invention
Below in conjunction with embodiment, the invention will be further described.
Embodiment 1:
The water paint of a kind of insulation, is prepared by the raw materials in: chlorinated rubber resin 15 parts, pure-acrylic emulsion 5 Part, vinyl 5 parts, Hydroxylated acrylic resin 3 parts, hexone 3 parts, 0.3 part of butanol, ethylene glycol 0.5 part, Synergist 0.3 part, levelling agent 0.3 part, 0.2 part of firming agent, 1 part of glass dust, nano magnesia 2 parts, deionized water 20 parts, season penta Tetrol 3 parts;
Its preparation method in turn includes the following steps:
(1) by chlorinated rubber resin, pure-acrylic emulsion, vinyl, Hydroxylated acrylic resin, hexone and fourth Alcohol is put in reaction vessel, is slowly heated to 40~50 DEG C, is stirred continuously and is uniformly completely dissolved to material, obtains mixed liquor standby With;
(2) glass dust, nano magnesia, ethylene glycol are joined in blender with tetramethylolmethane, be stirred continuously straight To mix homogeneously, obtain suspension standby;
(3) synergist, levelling agent, firming agent are dissolved in deionized water and obtain solution;
(4), after the suspension that mixed liquor step (1) prepared and step (2) prepare is mixed and stirred for uniformly, step is added Suddenly the solution that (3) prepare, continues to stir, and crosses 100 mesh sieves, gets product.
Embodiment 2:
The water paint of a kind of insulation, is prepared by the raw materials in: chlorinated rubber resin 35 parts, pure-acrylic emulsion 20 Part, vinyl 20 parts, Hydroxylated acrylic resin 15 parts, hexone 15 parts, 1.5 parts of butanol, ethylene glycol 2 Part, synergist 1.5 parts, levelling agent 1.2 parts, 1 part of firming agent, 5 parts of glass dust, nano magnesia 8 parts, deionized water 45 parts, season Penta tetrol 15 parts;
Its preparation method in turn includes the following steps:
(1) by chlorinated rubber resin, pure-acrylic emulsion, vinyl, Hydroxylated acrylic resin, hexone and fourth Alcohol is put in reaction vessel, is slowly heated to 40~50 DEG C, is stirred continuously and is uniformly completely dissolved to material, obtains mixed liquor standby With;
(2) glass dust, nano magnesia, ethylene glycol are joined in blender with tetramethylolmethane, be stirred continuously straight To mix homogeneously, obtain suspension standby;
(3) synergist, levelling agent, firming agent are dissolved in deionized water and obtain solution;
(4), after the suspension that mixed liquor step (1) prepared and step (2) prepare is mixed and stirred for uniformly, step is added Suddenly the solution that (3) prepare, continues to stir, and crosses 150 mesh sieves, gets product.
In the above embodiment of the present invention:
Described synergist is that butyl triphenyl is fluorinated phosphine;
Described levelling agent is polyester modification siloxanes;
Described firming agent is isocyanates.
During the present invention implements, by using combination property preferably high-molecular organic material and carrying out optimum organization, improve The insulating properties of compositions, the coating surface using the present invention to obtain is smooth, fine and smooth, smooth, and gloss retention is good, hot strength and Elongation at break is superior to common coating, can meet coated-body and use requirement for anticorrosion, weather-proof etc.;Preparation method of the present invention letter Single, production process is environment friendly and pollution-free, and cost is relatively low, with short production cycle, is suitable to industrialized mass production.
Finally it should be noted that above example only in order to illustrative not limiting technical scheme, although reference The present invention has been described in detail by above-described embodiment, it will be appreciated by those skilled in the art that and still can carry out the present invention Amendment or equivalent, any modification or partial replacement without departing from the spirit and scope of the present invention, it all should be contained In scope of the presently claimed invention.

Claims (4)

1. the water paint of an insulation, it is characterised in that be prepared by the raw materials in: chlorinated rubber resin 15~35 Part, pure-acrylic emulsion 5~20 parts, vinyl 5~20 parts, Hydroxylated acrylic resin 3~15 parts, hexone 3~15 Part, butanol 0.3~1.5 parts, ethylene glycol 0.5~2 parts, synergist 0.3~1.5 parts, levelling agent 0.3~1.2 parts, firming agent 0.2~1 part, glass dust 1~5 parts, nano magnesia 2~8 parts, deionized water 20~45 parts, tetramethylolmethane 3~15 parts;
Its preparation method in turn includes the following steps:
(1) chlorinated rubber resin, pure-acrylic emulsion, vinyl, Hydroxylated acrylic resin, hexone and butanol are put Enter in reaction vessel, be slowly heated to 40~50 DEG C, be stirred continuously and be uniformly completely dissolved to material, obtain mixed liquor standby;
(2) glass dust, nano magnesia, ethylene glycol being joined in blender with tetramethylolmethane, being stirred continuously until mixing Close uniformly, obtain suspension standby;
(3) synergist, levelling agent, firming agent are dissolved in deionized water and obtain solution;
(4), after the suspension that mixed liquor step (1) prepared and step (2) prepare is mixed and stirred for uniformly, step (3) is added The solution prepared, continues to stir, and crosses 100~200 mesh sieves, gets product.
The water paint of a kind of insulation the most according to claim 1, it is characterised in that described synergist is butyl triphenyl Fluorination phosphine.
The water paint of a kind of insulation the most according to claim 1, it is characterised in that described levelling agent is polyester modification silicon Oxygen alkane.
The water paint of a kind of insulation the most according to claim 1, it is characterised in that described firming agent is isocyanates.
CN201610621028.6A 2016-08-01 2016-08-01 Insulating water-based coating and preparation method for same Pending CN106046956A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106590184A (en) * 2017-01-11 2017-04-26 合肥英索莱特新材料科技有限公司 Aqueous insulating coating
CN106800836A (en) * 2017-01-11 2017-06-06 合肥英索莱特新材料科技有限公司 Flame-retardant aqueous coatings

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1544559A (en) * 2003-11-26 2004-11-10 公安部上海消防研究所 Fireproof coating composition and application thereof
CN103788814A (en) * 2013-10-21 2014-05-14 溧阳市浙大产学研服务中心有限公司 Fireproof coating used for steel structure buildings, preparation method thereof and coating process
CN104293091A (en) * 2014-09-16 2015-01-21 天长市银狐漆业有限公司 Flame-retardant insulating paint capable of increasing hardness of paint film and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1544559A (en) * 2003-11-26 2004-11-10 公安部上海消防研究所 Fireproof coating composition and application thereof
CN103788814A (en) * 2013-10-21 2014-05-14 溧阳市浙大产学研服务中心有限公司 Fireproof coating used for steel structure buildings, preparation method thereof and coating process
CN104293091A (en) * 2014-09-16 2015-01-21 天长市银狐漆业有限公司 Flame-retardant insulating paint capable of increasing hardness of paint film and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106590184A (en) * 2017-01-11 2017-04-26 合肥英索莱特新材料科技有限公司 Aqueous insulating coating
CN106800836A (en) * 2017-01-11 2017-06-06 合肥英索莱特新材料科技有限公司 Flame-retardant aqueous coatings

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