CN105968963A - Rapid dry type water-based paint and preparation method thereof - Google Patents

Rapid dry type water-based paint and preparation method thereof Download PDF

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Publication number
CN105968963A
CN105968963A CN201610619849.6A CN201610619849A CN105968963A CN 105968963 A CN105968963 A CN 105968963A CN 201610619849 A CN201610619849 A CN 201610619849A CN 105968963 A CN105968963 A CN 105968963A
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parts
dry type
type water
prepared
resin
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CN201610619849.6A
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Chinese (zh)
Inventor
张国文
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Anqing Ruitai Chemical Co Ltd
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Anqing Ruitai Chemical Co Ltd
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Priority to CN201610619849.6A priority Critical patent/CN105968963A/en
Publication of CN105968963A publication Critical patent/CN105968963A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D101/00Coating compositions based on cellulose, modified cellulose, or cellulose derivatives
    • C09D101/02Cellulose; Modified cellulose
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses rapid dry type water-based paint. The rapid dry type water-based paint is prepared from celluosic resin, silicone acrylic emulsion, fluorocarbon resin, organic silicone modified polyester resin, silicon ash powder, ethanol, butanone, a synergistic agent, a defoaming agent, dispersant, mica powder, ultra-fine calcium carbonate, deionized water and epoxy adhesive. A preparation method comprises the following steps that firstly, mixed liquor is prepared; secondly, suspension liquid is prepared; thirdly, a solution is prepared; fourthly, the liquid of the above steps is mixed to be uniform, the mixture is filtered, and the finished product is obtained. The organic polymer materials with good comprehensive performance are adopted and combined in an optimized mode, and the rapid dry performance of the composition is improved. The preparation method is simple, resources and energy sources are fully utilized, the production process is environmentally friendly, no pollution is caused, the cost is low, the production cycle is short, and the rapid dry type water-based paint is suitable for industrial volume production and has good economic benefits and social benefits.

Description

A kind of quick-dry type water paint and preparation method thereof
Technical field
The invention belongs to coating industry technical field, relate to a kind of water paint, particularly relate to a kind of quick-dry type water paint and Preparation method.
Background technology
Coating, at the entitled paint of Chinese tradition, refer to coat body surface can form thin film under certain conditions and rise protection, One class I liquid I of decoration or other specific functions (insulation, antirust, mildew-resistant, heat-resisting etc.) or solid material.Because of coating in early days Mostly with vegetable oil as primary raw material, therefore also referred to as paint.Now synthetic resin instead of vegetable oil, therefore referred to as coating.It is coated with Material belongs to organic chemical industry's macromolecular material, and the film formed belongs to macromolecular compound type.The chemical industry current according to the modern times produces The classification of product, coating belongs to fine chemical product.Modern coating the most progressively becomes a polyfunctional engineering material of class, is An important industry in chemical industry.
At present, the coating industry of China is the most ripe, and market is close to saturated, in addition under the overall situation of green economy globalization, People become more concerned with economy the most flourishing after, environment is by great destruction.Along with new " environmental law " promulgates, country is " green Environmental protection, beautiful China " etc. environmental protection advocate the most no longer to stay on slogan, but implement to perform, implement to promote energetically green The development of color science and technology industry.Traditional coating is one of important sources of air major pollutants VOC, by the aqueous of environmental protection Paint replacement paint is the most imperative.Compare traditional paint, and water paint is the one of environment-friendly type paint, and it saves oil Coal resources, and free from environmental pollution, it is to guide consumption to realize energy-saving and emission-reduction.2015, China's Coating Market sales volume 1500 About ten thousand tons, the industrial paint accounting by 70% converts, and paint consumption then reaches ten million ton, not only wastes 5,000,000 tons of energy, It is crucial that cause 5,000,000 tons of toxic and harmful discharges to air.Paint consumes the energy and pollutes environment, and it is in the common people consume Propagate its belief on a large scale, run in the opposite direction with national energy consumption revolution requirement and guide.Along with the enhancing of people's environmental consciousness, water paint Will be widely used, research and development water paint has the biggest economic benefit and social benefit.Existing water paint The application in industries such as pharmacy, food, hospital, weaving, chemical industry, electronics can be applied.Water paint is from raw material sources to life The Life cycle produced and use, the most beneficially sound development of environment.It is the most in process of production by volatile organic molten Agent substitutes, and when using, coating tool can wash by water, and decreases the consumption of cleaning solvent.The production of organic solvent needs Consume fossil feedstock, be a major challenge to resource in the present stage of resource scarcity, the appearance of water paint, solve this and ask Topic.Meanwhile, the reduction of solvent, greatly reduce the discharge of VOC during producing and using, for improving week Limit atmospheric environment has made positive contribution.
Country curbs environmental pollution severely, and national environmental consciousness promotes, consuming behavior changes, the sealing wax coating industry of energy-conserving and environment-protective Just welcoming unprecedented opportunity to develop, market presents " blowout formula " Requirement.Efforts To Develop basic research, reduces water The difficulty of construction of property coating, improve serviceability, be water paint expansive approach field, the task of top priority of extensive popularization and application. Meanwhile, strengthen policy guides, promotional technique, transformation concept, the elimination public phases such as the prejudice of water paint and misgivings Close the attention of work, also the application development of water paint will be played the effect of promotion.As Green Product, water paint Necessarily obtain the accreditation of people and be widely used.The market demand huge in the face of water paint and ever-increasing application prospect, add Big R&D intensity, updates and promotes the properties of product of water paint, accelerates product quality upgrading, develop technically, The water paint more showing powerful competitive advantage on cost, in performance has the meaning of reality and the wide market space.
Summary of the invention
The invention aims to overcome the deficiencies in the prior art, it is provided that a kind of quick-dry type water paint and preparation side thereof Method, this coating products excellent performance, there are good quick-drying performance, and energy-conserving and environment-protective, possess preferable economic benefit and society Benefit.
For solve above-mentioned technical problem, the present invention by the following technical solutions:
A kind of quick-dry type water paint, is prepared by the raw materials in: celluosic resin 15~35 parts, silicone acrylic emulsion 5~ 20 parts, fluorocarbon resin 5~20 parts, silicone modified polyester resin 3~15 parts, wollastonite powder 3~15 parts, ethanol 0.3~1.5 Part, butanone 0.5~2 parts, synergist 0.3~1.5 parts, defoamer 0.3~1.2 parts, dispersant 0.2~1 part, mica powder 1~ 5 parts, calcium carbonate superfine powder 2~8 parts, deionized water 20~45 parts, epoxy glue 3~15 parts;
Its preparation method in turn includes the following steps:
(1) celluosic resin, silicone acrylic emulsion, fluorocarbon resin, silicone modified polyester resin, wollastonite powder and ethanol are put into instead Answer in container, be slowly heated to 40~50 DEG C, be stirred continuously and be uniformly completely dissolved to material, obtain mixed liquor standby;
(2) mica powder, calcium carbonate superfine powder, butanone and epoxy glue are joined in blender, are stirred continuously until mix homogeneously, Obtain suspension standby;
(3) synergist, defoamer, dispersant are dissolved in deionized water and obtain solution;
(4), after the suspension that mixed liquor step (1) prepared and step (2) prepare is mixed and stirred for uniformly, step is added (3) solution prepared, continues to stir, and crosses 100~200 mesh sieves, gets product.
Preferably, described synergist is that butyl triphenyl is fluorinated phosphine.
Preferably, described defoamer is polyester modification siloxanes.
Preferably, described dispersant is sodium tetrapolyphosphate.
The beneficial effects of the present invention is:
The present invention, by using combination property preferably high-molecular organic material and carrying out optimum organization, improves the quick-drying of compositions Performance, the coating surface using the present invention to obtain is smooth, fine and smooth, smooth, and gloss retention is good, and hot strength and elongation at break are equal It is better than common coating, coated-body can be met requirement is used for anticorrosion, weather-proof etc.;Preparation method of the present invention is simple, it is achieved that money Making full use of of source and the energy, production process is environment friendly and pollution-free, and cost is relatively low, with short production cycle, is suitable to industrialized mass production, Possess preferable economic benefit and social benefit.
Detailed description of the invention
Below in conjunction with embodiment, the invention will be further described.
Embodiment 1:
A kind of quick-dry type water paint, is prepared by the raw materials in: celluosic resin 15 parts, silicone acrylic emulsion 5 parts, fluorine Carbon resin 5 parts, silicone modified polyester resin 3 parts, wollastonite powder 3 parts, ethanol 0.3 part, butanone 0.5 part, synergist 0.3 Part, defoamer 0.3 part, dispersant 0.2 part, mica powder 1 part, calcium carbonate superfine powder 2 parts, deionized water 20 parts, epoxy glue 3 parts;
Its preparation method in turn includes the following steps:
(1) celluosic resin, silicone acrylic emulsion, fluorocarbon resin, silicone modified polyester resin, wollastonite powder and ethanol are put into instead Answer in container, be slowly heated to 40~50 DEG C, be stirred continuously and be uniformly completely dissolved to material, obtain mixed liquor standby;
(2) mica powder, calcium carbonate superfine powder, butanone and epoxy glue are joined in blender, are stirred continuously until mix homogeneously, Obtain suspension standby;
(3) synergist, defoamer, dispersant are dissolved in deionized water and obtain solution;
(4), after the suspension that mixed liquor step (1) prepared and step (2) prepare is mixed and stirred for uniformly, step is added (3) solution prepared, continues to stir, and crosses 100 mesh sieves, gets product.
Embodiment 2:
A kind of quick-dry type water paint, is prepared by the raw materials in: celluosic resin 35 parts, silicone acrylic emulsion 20 parts, Fluorocarbon resin 20 parts, silicone modified polyester resin 15 parts, wollastonite powder 15 parts, ethanol 1.5 parts, butanone 2 parts, synergist 1.5 parts, defoamer 1.2 parts, dispersant 1 part, mica powder 5 parts, calcium carbonate superfine powder 8 parts, deionized water 45 parts, epoxy 15 parts of glue;
Its preparation method in turn includes the following steps:
(1) celluosic resin, silicone acrylic emulsion, fluorocarbon resin, silicone modified polyester resin, wollastonite powder and ethanol are put into instead Answer in container, be slowly heated to 40~50 DEG C, be stirred continuously and be uniformly completely dissolved to material, obtain mixed liquor standby;
(2) mica powder, calcium carbonate superfine powder, butanone and epoxy glue are joined in blender, are stirred continuously until mix homogeneously, Obtain suspension standby;
(3) synergist, defoamer, dispersant are dissolved in deionized water and obtain solution;
(4), after the suspension that mixed liquor step (1) prepared and step (2) prepare is mixed and stirred for uniformly, step is added (3) solution prepared, continues to stir, and crosses 150 mesh sieves, gets product.
In the above embodiment of the present invention:
Described synergist is that butyl triphenyl is fluorinated phosphine;
Described defoamer is polyester modification siloxanes;
Described dispersant is sodium tetrapolyphosphate.
During the present invention implements, by using combination property preferably high-molecular organic material and carrying out optimum organization, improve combination The quick-drying performance of thing, the coating surface using the present invention to obtain is smooth, fine and smooth, smooth, and gloss retention is good, hot strength and fracture Percentage elongation is superior to common coating, can meet coated-body and use requirement for anticorrosion, weather-proof etc.;Preparation method of the present invention is simple, Production process is environment friendly and pollution-free, and cost is relatively low, with short production cycle, is suitable to industrialized mass production.
Finally it should be noted that above example only in order to illustrative not limiting technical scheme, although with reference to above-mentioned reality Execute example the present invention has been described in detail, it will be appreciated by those skilled in the art that still the present invention can be modified or Equivalent, any modification or partial replacement without departing from the spirit and scope of the present invention, it all should contain the power in the present invention In profit claimed range.

Claims (4)

1. a quick-dry type water paint, it is characterised in that be prepared by the raw materials in: celluosic resin 15~35 Part, silicone acrylic emulsion 5~20 parts, fluorocarbon resin 5~20 parts, silicone modified polyester resin 3~15 parts, wollastonite powder 3~15 Part, ethanol 0.3~1.5 parts, butanone 0.5~2 parts, synergist 0.3~1.5 parts, defoamer 0.3~1.2 parts, dispersant 0.2~ 1 part, mica powder 1~5 parts, calcium carbonate superfine powder 2~8 parts, deionized water 20~45 parts, epoxy glue 3~15 parts;
Its preparation method in turn includes the following steps:
(1) celluosic resin, silicone acrylic emulsion, fluorocarbon resin, silicone modified polyester resin, wollastonite powder and ethanol are put into instead Answer in container, be slowly heated to 40~50 DEG C, be stirred continuously and be uniformly completely dissolved to material, obtain mixed liquor standby;
(2) mica powder, calcium carbonate superfine powder, butanone and epoxy glue are joined in blender, are stirred continuously until mix homogeneously, Obtain suspension standby;
(3) synergist, defoamer, dispersant are dissolved in deionized water and obtain solution;
(4), after the suspension that mixed liquor step (1) prepared and step (2) prepare is mixed and stirred for uniformly, step is added (3) solution prepared, continues to stir, and crosses 100~200 mesh sieves, gets product.
A kind of quick-dry type water paint the most according to claim 1, it is characterised in that described synergist is butyl triphenyl Fluorination phosphine.
A kind of quick-dry type water paint the most according to claim 1, it is characterised in that described defoamer is polyester modification silicon Oxygen alkane.
A kind of quick-dry type water paint the most according to claim 1, it is characterised in that described dispersant is sodium tetrapolyphosphate.
CN201610619849.6A 2016-08-01 2016-08-01 Rapid dry type water-based paint and preparation method thereof Pending CN105968963A (en)

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101125997A (en) * 2007-09-14 2008-02-20 姜鲁锡 Low-temperature quick-drying water road sign coating and preparation method thereof
CN102643586A (en) * 2012-05-08 2012-08-22 合众(佛山)化工有限公司 High-solid-content quick-drying water-based white primer and preparation method thereof
CN102993810A (en) * 2012-11-28 2013-03-27 天长市开林化工有限公司 General water-based quick-drying anti-rust paint and preparation method thereof
CN103525281A (en) * 2013-09-13 2014-01-22 任振州 Waterborne ultrafast-drying and high-adhesion protective coating
CN103965716A (en) * 2014-02-28 2014-08-06 北京东方雨虹防水技术股份有限公司 Water-based quick-drying acrylic acid protective coating and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101125997A (en) * 2007-09-14 2008-02-20 姜鲁锡 Low-temperature quick-drying water road sign coating and preparation method thereof
CN102643586A (en) * 2012-05-08 2012-08-22 合众(佛山)化工有限公司 High-solid-content quick-drying water-based white primer and preparation method thereof
CN102993810A (en) * 2012-11-28 2013-03-27 天长市开林化工有限公司 General water-based quick-drying anti-rust paint and preparation method thereof
CN103525281A (en) * 2013-09-13 2014-01-22 任振州 Waterborne ultrafast-drying and high-adhesion protective coating
CN103965716A (en) * 2014-02-28 2014-08-06 北京东方雨虹防水技术股份有限公司 Water-based quick-drying acrylic acid protective coating and preparation method thereof

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