CN106243995A - A kind of water paint of oil resistant and preparation method thereof - Google Patents
A kind of water paint of oil resistant and preparation method thereof Download PDFInfo
- Publication number
- CN106243995A CN106243995A CN201610620172.8A CN201610620172A CN106243995A CN 106243995 A CN106243995 A CN 106243995A CN 201610620172 A CN201610620172 A CN 201610620172A CN 106243995 A CN106243995 A CN 106243995A
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- water paint
- oil resistant
- preparation
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses the water paint of a kind of oil resistant, be made up of following raw materials according: organic siliconresin, acrylate and vinyl acetate emulsion, epoxy resin, acrylic resin, n-propyl acetate, ethylene glycol, hexone, synergist, levelling agent, firming agent, ferrophosphorus powder, nano-calcium carbonate, deionized water, rosin resin；Its preparation method comprises the steps: that (1) prepares mixed liquor；(2) supending；(3) solution is prepared；(4) liquid mixing of These steps is uniform, filter to obtain finished product.The present invention, by using combination property preferably high-molecular organic material and carrying out optimum organization, improves the oil resistance of compositions；Preparation method of the present invention is simple, it is achieved that making full use of of resource and the energy, production process is environment friendly and pollution-free, and cost is relatively low, with short production cycle, is suitable to industrialized mass production, possesses preferable economic benefit and social benefit.
Description
Technical field
The invention belongs to coating industry technical field, relate to a kind of water paint, the aqueous particularly relating to a kind of oil resistant is coated with
Material and preparation method thereof.
Background technology
Coating, at the entitled paint of Chinese tradition, refer to coat body surface can form thin film under certain conditions and
Play protection, a class I liquid I of decoration or other specific functions (insulation, antirust, mildew-resistant, heat-resisting etc.) or solid material.Because of early stage
Coating is mostly with vegetable oil as primary raw material, therefore also referred to as paint.Synthetic resin instead of vegetable oil now, therefore is referred to as being coated with
Material.Coating belongs to organic chemical industry's macromolecular material, and the film formed belongs to macromolecular compound type.Current according to the modern times
The classification of chemical products, coating belongs to fine chemical product.Modern coating the most progressively becomes a polyfunctional engineering of class
Material, is an important industry in chemical industry.
At present, the coating industry of China is the most ripe, and market is close to saturated, in addition in the overall situation of green economy globalization
Under, people become more concerned with economy the most flourishing after, environment is by great destruction.Along with new " environmental law " promulgates, country is " green
Environmental protection, beautiful China " etc. environmental protection advocate the most no longer to stay on slogan, but implement to perform, implement to promote energetically green
The development of color science and technology industry.Traditional coating is one of important sources of air major pollutants VOC, by the aqueous of environmental protection
Paint replacement paint is the most imperative.Compare traditional paint, and water paint is the one of environment-friendly type paint, and it saves oil
Coal resources, and free from environmental pollution, it is to guide consumption to realize energy-saving and emission-reduction.2015, China's Coating Market sales volume 15,000,000
About Dun, the industrial paint accounting by 70% converts, and paint consumption then reaches ten million ton, not only wastes 5,000,000 tons of energy, crucial
It is to cause 5,000,000 tons of toxic and harmful discharges to air.Paint consumes the energy and pollutes environment, and it is big row in the common people consume
Its road, runs in the opposite direction with national energy consumption revolution requirement and guide.Along with the enhancing of people's environmental consciousness, water paint will
Being widely used, research and development water paint has the biggest economic benefit and social benefit.Existing water paint can
To apply the application in industries such as pharmacy, food, hospital, weaving, chemical industry, electronics.Water paint from raw material sources to produce and
The Life cycle used, the most beneficially sound development of environment.It is the most in process of production by volatile organic solvent
Substitute, and when using, coating tool can wash by water, and decreases the consumption of cleaning solvent.The production of organic solvent needs to disappear
Consumption fossil feedstock, is a major challenge to resource in the present stage of resource scarcity, and the appearance of water paint solves this and asks
Topic.Meanwhile, the reduction of solvent, greatly reduce the discharge of VOC during producing and using, for improving week
Limit atmospheric environment has made positive contribution.
Country curbs environmental pollution severely, and national environmental consciousness promotes, consuming behavior changes, the sealing wax coating of energy-conserving and environment-protective
Industry is just welcoming unprecedented opportunity to develop, and market presents " blowout formula " Requirement.Efforts To Develop basic research, reduces
The difficulty of construction of water paint, improve serviceability, be water paint expansive approach field, extensive popularization and application when business
Anxious.Meanwhile, strengthen policy guides, promotional technique, transformation concept, the elimination public the prejudice of water paint and misgivings etc.
The attention of related work, also will play the effect of promotion to the application development of water paint.As Green Product, aqueous is coated with
Material necessarily obtains the accreditation of people and is widely used.Before the market demand huge in the face of water paint and ever-increasing application
Scape, strengthens research and development capabilities, and updates and promote the properties of product of water paint, accelerates product quality upgrading, develops in skill
The water paint more showing powerful competitive advantage in art, on cost, in performance has the meaning of reality and wide market
Space.
Summary of the invention
The invention aims to overcome the deficiencies in the prior art, it is provided that the water paint of a kind of oil resistant and
Preparation method, this coating products excellent performance, there are good oil resistance, and energy-conserving and environment-protective, possess preferable economic benefit
And social benefit.
For solve above-mentioned technical problem, the present invention by the following technical solutions:
The water paint of a kind of oil resistant, is prepared by the raw materials in: organic siliconresin 15～35 parts, acrylate and vinyl acetate emulsion
5～20 parts, epoxy resin 5～20 parts, acrylic resin 3～15 parts, n-propyl acetate 3～15 parts, ethylene glycol 0.3～1.5 parts,
Hexone 0.5～2 parts, synergist 0.3～1.5 parts, levelling agent 1～5 parts, firming agent 0.5～2 parts, ferrophosphorus powder 1～
5 parts, nano-calcium carbonate 2～8 parts, deionized water 20～45 parts, rosin resin 3～15 parts；
Its preparation method in turn includes the following steps:
(1) organic siliconresin, acrylate and vinyl acetate emulsion, epoxy resin, acrylic resin, n-propyl acetate and ethylene glycol are put into instead
Answer in container, be slowly heated to 40～50 DEG C, be stirred continuously and be uniformly completely dissolved to material, obtain mixed liquor standby；
(2) ferrophosphorus powder, nano-calcium carbonate, hexone are joined in blender with rosin resin, constantly stir
Mix until mix homogeneously, obtain suspension standby；
(3) synergist, levelling agent, firming agent are dissolved in deionized water and obtain solution；
(4), after the suspension that mixed liquor step (1) prepared and step (2) prepare is mixed and stirred for uniformly, step is added
Suddenly the solution that (3) prepare, continues to stir, and crosses 100～200 mesh sieves, gets product.
Preferably, described synergist is that butyl triphenyl is fluorinated phosphine.
Preferably, described levelling agent is polyester modification siloxanes.
Preferably, described firming agent is isocyanates.
The beneficial effects of the present invention is:
The present invention, by using combination property preferably high-molecular organic material and carrying out optimum organization, improves compositions
Oil resistance, use the coating surface that obtains of the present invention smooth, fine and smooth, smooth, gloss retention is good, hot strength and extension at break
Rate is superior to common coating, can meet coated-body and use requirement for anticorrosion, weather-proof etc.；Preparation method of the present invention is simple, it is achieved
Making full use of of resource and the energy, production process is environment friendly and pollution-free, and cost is relatively low, with short production cycle, be suitable to industrial mass
Produce, possess preferable economic benefit and social benefit.
Detailed description of the invention
Below in conjunction with embodiment, the invention will be further described.
Embodiment 1:
The water paint of a kind of oil resistant, is prepared by the raw materials in: organic siliconresin 15 parts, acrylate and vinyl acetate emulsion 5 parts,
Epoxy resin 5 parts, acrylic resin 3 parts, n-propyl acetate 3 parts, ethylene glycol 0.3 part, hexone 0.5 part, potentiation
Agent 0.3 part, levelling agent 1 part, 0.5 part of firming agent, 1 part of ferrophosphorus powder, nano-calcium carbonate 2 parts, deionized water 20 parts, rosin resin 3
Part；
Its preparation method in turn includes the following steps:
(1) organic siliconresin, acrylate and vinyl acetate emulsion, epoxy resin, acrylic resin, n-propyl acetate and ethylene glycol are put into instead
Answer in container, be slowly heated to 40～50 DEG C, be stirred continuously and be uniformly completely dissolved to material, obtain mixed liquor standby；
(2) ferrophosphorus powder, nano-calcium carbonate, hexone are joined in blender with rosin resin, constantly stir
Mix until mix homogeneously, obtain suspension standby；
(3) synergist, levelling agent, firming agent are dissolved in deionized water and obtain solution；
(4), after the suspension that mixed liquor step (1) prepared and step (2) prepare is mixed and stirred for uniformly, step is added
Suddenly the solution that (3) prepare, continues to stir, and crosses 100 mesh sieves, gets product.
Embodiment 2:
The water paint of a kind of oil resistant, is prepared by the raw materials in: organic siliconresin 35 parts, acrylate and vinyl acetate emulsion 20
Part, epoxy resin 20 parts, acrylic resin 15 parts, n-propyl acetate 15 parts, ethylene glycol 1.5 parts, hexone 2 parts,
Synergist 1.5 parts, levelling agent 5 parts, 2 parts of firming agent, 5 parts of ferrophosphorus powder, nano-calcium carbonate 8 parts, deionized water 45 parts, rosin resin
15 parts；
Its preparation method in turn includes the following steps:
(1) organic siliconresin, acrylate and vinyl acetate emulsion, epoxy resin, acrylic resin, n-propyl acetate and ethylene glycol are put into instead
Answer in container, be slowly heated to 40～50 DEG C, be stirred continuously and be uniformly completely dissolved to material, obtain mixed liquor standby；
(2) ferrophosphorus powder, nano-calcium carbonate, hexone are joined in blender with rosin resin, constantly stir
Mix until mix homogeneously, obtain suspension standby；
(3) synergist, levelling agent, firming agent are dissolved in deionized water and obtain solution；
(4), after the suspension that mixed liquor step (1) prepared and step (2) prepare is mixed and stirred for uniformly, step is added
Suddenly the solution that (3) prepare, continues to stir, and crosses 150 mesh sieves, gets product.
In the above embodiment of the present invention:
Described synergist is that butyl triphenyl is fluorinated phosphine；
Described levelling agent is polyester modification siloxanes；
Described firming agent is isocyanates.
During the present invention implements, by using combination property preferably high-molecular organic material and carrying out optimum organization, improve
The oil resistance of compositions, the coating surface using the present invention to obtain is smooth, fine and smooth, smooth, and gloss retention is good, hot strength and
Elongation at break is superior to common coating, can meet coated-body and use requirement for anticorrosion, weather-proof etc.；Preparation method of the present invention letter
Single, production process is environment friendly and pollution-free, and cost is relatively low, with short production cycle, is suitable to industrialized mass production.
Finally it should be noted that above example only in order to illustrative not limiting technical scheme, although reference
The present invention has been described in detail by above-described embodiment, it will be appreciated by those skilled in the art that and still can carry out the present invention
Amendment or equivalent, any modification or partial replacement without departing from the spirit and scope of the present invention, it all should be contained
In scope of the presently claimed invention.
Claims (4)
1. the water paint of an oil resistant, it is characterised in that be prepared by the raw materials in: organic siliconresin 15～35
Part, acrylate and vinyl acetate emulsion 5～20 parts, epoxy resin 5～20 parts, acrylic resin 3～15 parts, n-propyl acetate 3～15 parts, ethylene glycol
0.3～1.5 part, hexone 0.5～2 parts, synergist 0.3～1.5 parts, levelling agent 1～5 parts, firming agent 0.5～2
Part, ferrophosphorus powder 1～5 parts, nano-calcium carbonate 2～8 parts, deionized water 20～45 parts, rosin resin 3～15 parts；
Its preparation method in turn includes the following steps:
(1) organic siliconresin, acrylate and vinyl acetate emulsion, epoxy resin, acrylic resin, n-propyl acetate and ethylene glycol are put into reaction to hold
In device, it is slowly heated to 40～50 DEG C, is stirred continuously and is uniformly completely dissolved to material, obtain mixed liquor standby；
(2) ferrophosphorus powder, nano-calcium carbonate, hexone are joined in blender with rosin resin, be stirred continuously straight
To mix homogeneously, obtain suspension standby；
(3) synergist, levelling agent, firming agent are dissolved in deionized water and obtain solution；
(4), after the suspension that mixed liquor step (1) prepared and step (2) prepare is mixed and stirred for uniformly, step (3) is added
The solution prepared, continues to stir, and crosses 100～200 mesh sieves, gets product.
The water paint of a kind of oil resistant the most according to claim 1, it is characterised in that described synergist is butyl triphenyl
Fluorination phosphine.
The water paint of a kind of oil resistant the most according to claim 1, it is characterised in that described levelling agent is polyester modification silicon
Oxygen alkane.
The water paint of a kind of oil resistant the most according to claim 1, it is characterised in that described firming agent is isocyanates.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610620172.8A CN106243995A (en) | 2016-08-01 | 2016-08-01 | A kind of water paint of oil resistant and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610620172.8A CN106243995A (en) | 2016-08-01 | 2016-08-01 | A kind of water paint of oil resistant and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106243995A true CN106243995A (en) | 2016-12-21 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610620172.8A Pending CN106243995A (en) | 2016-08-01 | 2016-08-01 | A kind of water paint of oil resistant and preparation method thereof |
Country Status (1)
| Country | Link |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0962502A1 (en) * | 1998-06-02 | 1999-12-08 | Dai Nippon Toryo Co., Ltd. | Process for preparing an aqueous dispersion coating material and process for preparing a powder coating material |
| CN101041760A (en) * | 2007-04-25 | 2007-09-26 | 沈阳市航达科技有限责任公司 | Water-based anticorrosive paint and preparation method thereof |
| CN103709865A (en) * | 2013-12-20 | 2014-04-09 | 柳州译海网络科技有限公司 | Water-based silicon steel sheet paint |
| CN105199570A (en) * | 2015-09-22 | 2015-12-30 | 天长市开林化工有限公司 | Oil-resistant anti-corrosion waterborne paint and preparation method thereof |
-
2016
- 2016-08-01 CN CN201610620172.8A patent/CN106243995A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0962502A1 (en) * | 1998-06-02 | 1999-12-08 | Dai Nippon Toryo Co., Ltd. | Process for preparing an aqueous dispersion coating material and process for preparing a powder coating material |
| CN101041760A (en) * | 2007-04-25 | 2007-09-26 | 沈阳市航达科技有限责任公司 | Water-based anticorrosive paint and preparation method thereof |
| CN103709865A (en) * | 2013-12-20 | 2014-04-09 | 柳州译海网络科技有限公司 | Water-based silicon steel sheet paint |
| CN105199570A (en) * | 2015-09-22 | 2015-12-30 | 天长市开林化工有限公司 | Oil-resistant anti-corrosion waterborne paint and preparation method thereof |
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Application publication date: 20161221 |
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